Code A Question Paper PDF
Code A Question Paper PDF
distan.e
(2) (2)
time
position }rrt.t
(3) (3)
time
velocity {"1
(4) (4)
time
1 T
r T
m13 mrg
,
k k
(l) 0) L
4a2 4a2
k k
(2\ ,7 (2)
(2)
Ir !{ (r)
(2)
I
Jz u.
&rM X
i,o oo
(3) (3)
2 2
.i, t,o
(.1)
J2
(1)
a
tt Seven identical circular planar disks, each 6 r{qla{i €r[.r{ rtut?, *j M 6rrr qrrcrdl r,ti
of mass M and radius R are welded n Qoar{l uc au< <{ot:R ttrr<tdlq (Gr ll
symmetrically as shown- The moment of iil\[i,,{i {(-(,r (q]ztcr) ri(.r t}. +t',[Link] ciq
inertia of the arrangemenl ahout the aris u:i Ag R rriril uur rrdl.,rs[.,rlqqi[i 6/sc{-{l
normal to the plane and passing through r{B1tat
the point P is :
19 l9 2
(r) N{R2 (1) NlR
2 2
(2)
55
MR2 (2) ::l\lR"
2 2
181
(4) 1!lrrrn, (4) MR2
2 2
t
2!
t
2R
l
40
::
9
l\4R' t,\ 19
9
vn'
(3) 10 MR, (3) 10 MR2
It A particle is moving with a urdform speed 8 o)s rgrurt< ur{ n Aoi{u <{ruLr roi
"ls.{
in a circular orbit of radius R in a central G.{r r€,rq.[ qq ] i R il ns tur-u "ln r
force inversely proportional to the nth xqreHiqa B, -{1.{ur trq,G:l t}. ol rcr-il
power of R. lf the period of rotation of the qtrrLR- .tsrdlq T d-i{ a __ .
particle is T, then :
F^?n
9 A sotid sphere of radius r made oi a soft q K iz{r q..3 1iis,&ii [Link] .,r.t . la'..[Link] ,,6
materialof bull modulus K is surrounLled .iiqr O.,t-i [Link] r-L-l )irJi,r. .r,4t5rilq ,{r11{i 4:
by a liquid in a .ylindrical container. A j..{tdi (tir tr?t,1c ir. ., iro-Su e,rii[t.r
".r"et
massless piston of area a fk)ats on the [iv-t [Link]{t-it n rLl[ [Link] ni J. &+z:-t-j ei,it,-r
surface of the liquid, covering entirc cross -rcrELit{ \r1-li}j$.i r,1.:r}e qiL"ti 8. oaii m
section of cylindrical container. \ rhen a ,izr1 eui 6tz+it+ttz1G\a utx{dti Eqlqai.
mass m is placed on the surface of the )r'iqrr{'l Ao,{rr{[ ard r{iGt3 qz rs]
piston to compress the liquid, the fractional
I _ld.l !{i
decrement in the radius of the sphere,
.f )
/drl
t'l
(r) Ilmg (t)
Ka
mg
Ka Ka
(2) (2)
3^g 3-g
mg _r"c
(3) (3)
iKa 3IG
Irrg mg
(1) (4)
K.r Ka
10. Two moles of an ideal monoatomic gas ro. Q {e .,L ,{r{tG"tJ qr[e[ qr).t 2zC qri V
occupies a volume V at 27'C. The gas ,iz( * i& r). 11 ta1".il Q+.nsL .,t1or{ 6
expands adiabatically to a volume 2 V. .ri i1 re z v uBr 6. ai (a) iuti ,iR1 ${r-r
Calculate (a) the final temperature of the q.i (b) d.r1 .riclir Gt.,rai uni ii3i
gas and (b) change in its intemal energt.
(1) (a) r8e K (b) 2.7 kJ (1) (a) 18e K (b) 2.7 kI
(3) (a) 18e K (b) -2.7 kl (3) (") l8e K (b) -2.7 kI
wall is nearly :
(1) 2.35 x 103 N/m2 (1) 2.35 x 103 N/m2
(2) 4.70x103 N/m2 (2) 4.70 x 103 N/m2
(3) 2.3s x 102 N/m2 (3) 2.35 x 102 N/m2
(4) 4.70 x 102 N/m2 (4t 4.70x 102 N/m2
12 A silver atom in a solid oscillates in simple 12. qi61 q-rqi qitl{i \rqrqj i,rts [ltrrql
harmonic motion in some direction with a to12lsec. .{l e,tt"1(i {
nrq .{ted rrQ (Elq.t)
frequency of 1012/sec. What is the force d t). {: .tugi u{lnt .tatq1 tu{ oisru ,,iq
constant of the bonds connecting one atom ("t1-s) aD<r rur uarol+i \e{ }z{ crl ? (qifl
with the other ? (Mole wt of silver = 16 and qrZ-r.i qgarn = 108 u.i [Link] "tr
Avagadro number = 6.02 x 10ts gm mole - l) = 6.02 x 108 gm mole - r)
(1) 6.a N/m (1) 6.4 N/m
(2) 7.1 N/m (2) 7.1 N/m
(3) 2.2 N/m (3) 2.2 N/m
(4) s.s N/m (a) s.s N/m
13. A granite rod of 60 cm length is ctamped l3 6o cm eiqd ltna {3 ,hdz. +{O{ A{i
at its middle point and is set into qr{lqq r{irrsrql nyRrr tr1 <[i i"rn
Iongitudinal vibrations. The density of (longitudinal) e'[Link] }+qrNo srqrqi r{A 8.
granite is 2.7x 103 kg/m3 and its Young s ,)tdz-il q-rtL 2.7\103 [Link] )i{.i,r
modulus is 9.27 xT)to Pa. Wlat will be iislcra 9.27xt0r0 pa r). r,u [Link] rti,[Link]
the fundamental frequencv of the 1,tE t .,tt1R )zc{l tt1 ?
longitudinal vibrations ?
(1) 5 kHz (1) 5 kHz
(2\ 2.5 kHz (2) 2.s kHz
(3) 10 kHz (3) 10 krL
(4) 7.5 kHz (4) 7.5 kHz
A/Page 7 SPACE FOR ROUGH WORK / ?i Ed{ iru,r
14. Three concentric metal shells A, B and C 1,1 :{qt rBc;tir [Link] 5''r?ii A, ts 1,1-i C il 4$i
oI respective ratlii a, b and c {a < b < c) Eo/u,'t't a, b 4'1 c (a < t
1u QqrrorLr < c; il
have surface charge densitjes + o, -tr and 1-l.1t1-{t'.l-it{ - o. - L, -"n I'd tJ. B-!'.lrr I
+ o respectivelv. The potential of shell B [+tr{iqL.r ,
is:
o a2 -b2 +c a_- h_
(1) (l)
a
i
o a b2
(2) +c (2) I
^2 +c
t b l t b
-
d I
,-2 -2 I I b2-c2
(3) +a (3)
t b l t b
-+a
lt2-.2 *" l
I. b2 l
c2
(4) (4) +a
i
L l
-
15. A parallel plate capacitor of capacitance 15. 90 pF .)e1j iiuu: q?r.{(1r qs urri(r laz
90 pF is connected to a battery of emf iqnti zo v ernf qtrqdl 4arl u{ qlsqrqi
5
20 V. If a dielecnic material oI dielectric qra D. }. l
;. A urjdafizr utqftl q qlr
constant K: I is inserted between the sddcltlt urai.i [Link] di vla'Hll qzii srrt<.t
3
plates, the magnitude of the induced jrqrr{i :i{A r}. il&rr r<
"11*otn1
charge will be r qh.
zJ q, .rl >
,Y
16 In an a.c. circuit, thc instantaneous e.m.f 16 + a.c. ,{l\qqi. (.H[Qlr e.m.f. ,.r-r [Link] il{
and current are given bl' 1olq .{r.i[ e6t{ 8.
e=100sin30t e:100 si 30 t
I30t i=20sinl30r nl
i=20sin , I
4) i)
In one cycle of a.c., the average Power a.c. -u qs {td;e ( r{rqd{) 1A .1(?\P{ (Rr
consumed by the circuit and the wattless €.rq1rrqi .jlQe ,{rqr (rrrir,QL) at wattless
curent are, resPechvelv : X'1t{, r,t1ri rriL.
50 50
(3) t; ,0 (3)
7' 0
17. Two batteries with e.m.f. 12 V and 13 V 't7 12 V r,ri 13 V emf qitqal ,;i aizr'l.,rii 10 O
are connected in parallel across a load oui .{qilq u{ +r{d?lli d. "i:i fur1., <r
"itlcr
resistor of 10 O. The intemal resislances of r{i,:t{13 }rci'rq r,qit 1 o o,ti 2 o r}. our
the two batteries ale 1() and 2 O 4.R'rq:t {qi(i q'lao/ -il qu,il
resgectively. The voltage across the load (at.
lies between :
18. An electron, a proton and an alpha I l.i .is diivJ-t, Jtr xlA< ,,ti {r qqt rvdl
"tR
particle having the same kinetic energy are 6tqi tt u-r 6. ital tt rL-t i"uh lia a li,ug{
moving in circular orbits of radii r", rn, r.. r. r, ui ro R"*u trrttdl t{urr:e ttttai ,G
respectively in a udform magnetic field B. sr r). .. .,ti.
- t-e,-p --_o qc{- riuiq
The relation between re tp, t0 is :
(1) r">ro = t" (1) r"
(2) r" < r, = r,, (2) r"
(3) re<rp<rq (3) ."
(4) re<ro <rp (4) r"
A/Page 9 sPAcE FoR RoucH woRK / ri rr,{1i rau
L*- 7{p.
,L
-2,l-
'e'<- rl
J
t".v \ "fo
{oo Xu O,
7K
I
u* r \c
19. Thr dipolc mrrmcnt of i .[Link] loop l9 i xaLc arL"r.[rl
"ir
.[Link]? ]uqr-r:l ktciL qt:rtat
carrying a curont I, is m arrJ thc magnetic md ,q-i ,Lrqr-t i-d .,rprul
i"rih ii1 Br 6)29
field at the centre of tho lo()p is Bi- l4'hen rj. oar, [Link] .[Link] ttr,i|.1 [rti il qE]uar q\git
the dipole moment is doubk d by keeping 5iqr{i .,1..i D, dtri rrrul-1 i< .,rptur
iqJ'l{
the curent constant, thc mnFlotic field at
ql1 82 qr{ u
u, -
i.'1eLi'rl
thc centre ol the loof is 8,. fhc rdtio -31
is.
0) 2 (1) 2
(2\ .6 (2) 15
20. For an RLC circuit driven with voltage of 20. i\ Aku {<2v a", ul {11{i ."=
#
amplifude r,- and freq.,er,.y ,.,= I qrtq Gqrrr{e.{l qr<rol (uiilel) RLC \tl\qi
JLC
the curent exibits rcsonance- The quality ){qr{ r,r1iL€ e ttiq ti. ,lgrqnL i* e
factor, Q is given b\' : ql r,t\tr'I.
o.,L
(1) (r)
It R
(2)
ouR
(2)
o,, R
t.
q u
L
R li
(j) (,.c) (3)
(r.c) >&
d"7
/J
CR CIt
(4) (r)
where the wave number k and 6. oai .ti.r ri,..u t .,rlt uL1[i , d erLi
frequencv l refer to their values in air. The .,r6+fli r) {t.1r1 r{.jq{q 6. .,r .,ri ..,,
'i
medium is non-magnetic. If €r1 and €r2 r,t1sd {"tt ,,,ri ,.lr€trr-il rrtn ,ri:il/[Link].,tl
refer to relative permittivities of air and o'i,{ A -0{ qrq<r qr1 s,rl fuc,{ [Link] 6 ?
t.1 1 t.l 1
(3)
trz 4 (3)
t.l 1 t'r 1
(4) ,r2 2 (4)
22. Unpolarized light of intensity I passes 22. I [Link] qerqa r,[Link] *rst tu lutal tardrr
through an ideal poladzer A. Another A .{i{l \ur qL,r 8. u{lo} r:1< ,lardri s d
identical polarizer B is placed behind A. A -0 \ttrq .ltqt{ {q
8. s -il .{prq/.{t 1
The intensity of liglt beyond B is found to
t.^ at<3 .r1 0. t.), 4l"i
]trnt fl .{[Link]
; "}a<{l
I
be, Now another identical polarizer C rirr-r \'i&Ldr? c I A .,tl B il "r"il $q{
(i.e. distance between dre cenhes of each ("12d] si: Ru-tL ]<er1 i l r"{-j "i.u)
slit.)
(1) 25 pm 0) 25 pm
(2) 50 pm (2) 50 pm
(3) 75 pm (3) 75 pm
24. An electron from various excited states of 24. dd{'i./-r \elttq!-0 Edl-Ed[ 6is.t ssu.,t]t,{iq1
hydrogen atom emit radiation to come to dArql-t ttrRrR { ./ A&tqr €.ttej( ,l t .
the Sround state. Let tr., )., be the trn) ) r. .,ti r, { tJ -4]<-il .a1rl .dl ui
de Broglie wavelength of the elechon in ql[&[a{i s'l-q],dl 4i"rciqtd o. nr1 R iritil
the nth state and the ground state qrLl&r[aqi qdl risili sr',.1r-r qn]t [Link]
respectively. Let ,^n be the wavelength of tlzl<il ni"rciqrd ,r. 0. r,1e {ar n aD 1e, a
the emitted photon in the hansition from qqqli 6)
the n& state to the ground state. For large
n, (A, B are constants)
B
(r) Ai=A + B, (l) ,,\n=A+ --t
xA
\r' vre:
25. If the limit frequency of the Lyman
series 2s. ii Aeiiil {sfl-{[Link] {r1ft (series
({t.t,r-r
seiies is vL, then the series limit frequency limit frequency) ni ,I- tir, ,ii is (Ptun.l)
of the Pfund series is : A,:[ qL Aqil-Rdil "u{i 41r
27. The reading of the ammeter for a silicon 27. mq(1 \[t\or.{i l{ i{gl< sr{s .tD aldlz?1
diode in the given circuit is : a{q(t5.t
200 0 200 (l
3V 3V
(1) 0 0) 0
i
(2) 15 mA .E) 15 mA
(3) 11.5 mA (3) 11.5 mA
(4) 13.5 mA (4) 13.5 mA
..5
t'--b
-t
.{r 5 -\oo
I
Y 15
(
)
2IJ .4, tclephonic communication service is 2ri n: 2..{tl-fl: (p iaLr) {lru"[Link] trGlu
\.rorking at carrier frequency of 10 GHz. 10 GHz -it ii1,ri r{r1fr u sr,i si r}. A{il
OrJ)' l0'-{ of it is utilized for transmission- :,fi 10it 6/ ){ii?q( {iZ .{\?rq r}. tl "it eis
LIow many telephonic channels can be [Link] s tH, -il .i-s-dlq or:r'l elr rt't,li:ur{
transmitted sinultaneously if each channel .,u"ii ]znl2ri&'r<t iH<rt nu&n til lr:rq ?
30. On interchanging the resistances, the 30. qler &6y1i r,t"rilql-0 r{€[Link](fr 5?dr, nlt(lad
balance point of a meter bridge shifts to Ag st"il 'tLg 10 cm o)a( .,r{ t). i'r.r it\tlt
the left by 10 cm. The resistaace of their o-tqr-lq 1 kO r). dl sru{l"ug.{l
"istr"r-rll "ur'l
series combination is 1 kO. How much was (slot) 1ti xr.t1t Lt\q[[ ".t'{a }zcr] orqr'itl Cr'i ?
the resistance on the left slot before the
interchange ?
(1) eeo o 0) 990 o
(2) sos o (2) 505 fl
(3) sso o (3) 550 0
(4) e10 o (1) 910 ()
31. fhe rati,r Lrf mass percent of C and H of an 31. j* [Link]: ii iwr (cxH\oz) r{i-r c .n r I I
organic compound (CxHyOz) is 6 : 1 If -u €or zjr.{u'l-ii rJgt{i 6 : 1 r}. oi i ri'/-t
one nolecule of the aborc comPound (CxHyOz) .t! .lt ,',tr,1ai rtcu .,iGtt.r-tit
(CxHyOz) contains half as much oxygen .iral {,riora gnu" { + orR!.i irur"[Link]
as required to burn onc molecule of rilui i1i co, .,ri Hro ai iuin&rr :irL tD-it
compound CxHy completel)' to CO2 and c/ie'[ qr{ qil r,tstil o . {.Io/+ L\H\O/ i
HrO. The empirical formula oI compound Hngr}l\qJilir lil.!rl.
C1H,O, is :
(1) C3H5O3 (1) c3H6o3 )'x-
(2) C2H4O (2) c2H4o
(3) C1H4O2 (3) c3H4o2
(4) C2H{Or (4) c2H4o3
-
32. Which type of'defec( has the presence of 32. ri{t r3t?-il ttRlti (ut{hi) r{ld (h te&}ri
cations in the intefftitial sites ? q-tB{4 (tzR-t) -ll at6rr'l cl,{ 6 ?
33 According to molecular orbital theory, 33. r4rec{l{ 5qu Ru{i(-u qrqt}. -fl{.{Acrr{eit
which of the following will not be a viable strli 1,tq rt91 Gr-rir n{l ?
molecute ?
1nK In K
IJ I 1
B
(), T(K) (lr T(K)
C C
l) D
35. The combustion of benzene (l) gives CO2(g) 3s. q-rjl-r:i €€.1 5rntco2(8) r{:t H2o0) r,tr{
O
and HrO(l). Given that heat of combustion r]. ZS. C.{r, ,i,r..{ur 3} q-$[Link] 6d-r-6"r{r
(R:8.314 JK I mol I)
(1) (1) i)
(2)
41s2.6
452.46 (2)
.r1s2.6
- 4s2.46
'P t
(3) 3260 (3) 3260
e
trft
For 1 molal aqueous solution of the 36 -ih .-u!<rr riq'i.r-t-'tat t :rlcr(r
arrih ar.r,t.{i,-i[
following compounds, which one will ,,i d5 H1!{t qqii 6ri[qt x€[iin 5i r]i, I
show the highest freezing point ?
HrS is 1.0x10-7 and that of 52 ftom q{qH1 iiqa.i itnqis 1.2 x 10- r3 {\ (l 6/d1,1
HS- ions is 1.2x10 13 then the irqqrqi s2- r4R-rl-{l ifadr ritq:I
concentration of 52 ions in aqueous
solution is :
ltt
.Er
38. An aqueous solution contains an unknown 38. i,lJ
"/(iU iRgrr{i Ba2+ nii(r
-ll o,rqildl -t!il.
concentration of Ba2+. When 50 mL of a .,,{rl t {i 50 mL 1 M NarsOn ,j cnsr 6drd,
1 M solution of NaaSO, is added, BaSO, Basoa -u .{qA\ {q.{t'j rq qr{ d. }iR1t sE
iust begins to precipitate. The final volume 500 mL t). BaSO4 A ircrfir 1gu5ti t x 10 r0
is 500 mL. The solubility product of BaSO4 r]. ar Ba2+ -{l ri0e {ifl
}zdt E ?
is 1x10-lo. What is the original
concenkation of Ba2+ ?
!l
A/PaBe 77 SPACE FOR ROUCH WORK / rl !r.I.i $ltr
K-- ti-
r$
39, At 518'C, the rate of decomposition of a 39 518" C w, i1q6/ tq-."r.l(i tqrqt 363 Torr (,ii)
sample of gaseous acetaldehvde, initiallv vi, + .+t,1q.{ o,jfurcsltLds
{tlr{r Q'tz{-iL
at a pressure of 363 Torr, was [i 'Ari x[r{r iirii c'[Link] 1.00Torrs-1
5%
1.00 Tolr s 1 when 596 had reacted and [Link] .,ti o,,rri 339i, ).r&.(r 5iii cl,{ .{ri
0.5 Tort s-lwhen 33-"6 had reacted. The 0.5 Torr s_r tgdi. a x&{r ,r. sir_q:I.
orde! of the rcaction is :
(1) 2 (1) 2
(2) 3 (2) 3
(3) 1 (3) 1
(4) 0 (4) 0
40. How long ([Link]) should water b€ 40. \l2]
,k
ef,--e -: [3Ca3(POa)2'Ca(OH)21 to : i il{<rai i\in si 6 .} ritql.
.ffit' (r)
(2)
[CaEr]
13(CaF2).Ca(oH)2]
(1)
(2)
[CaFr]
[3(CaFr) Ca(OH)2]
v
18
60(" ,'l-oK
rl n**q'
5u al-,
1$ s\, q
iq'
olv ,4('J ,8
l1 1600
c [Link] c-
1
42. Which oI the following compounds lz. -[t{.deu {,{'ro/-r1{ 3{[Link] {€,i,i"/, ,,iq ("i{r)
contain(s) no covalent bond(s) ? .rdl ?
KCl, PHr, O., Bzlle H2s01 KCL PH3, O" B2H{' H2SO1
(1) KCl, B?H6/ PH3 (1) KCt, B2H' PH3
43 Which of the following are Lewis acids ? ls. .[t{ oat\c&i{l 3{ Sdri .1G61 E ?
44. Total number of lone Pair of electlons in 44. It r{r.{.i1{i udtr:ns dc\il.t Tltil g( ilu{t
It ion is I ril.r'r.
(1) 3 0) 3
(2) 6 (2) 6
(3) e (3) e
(4) 12 (4) 12
t
I
{5. l{hich of the fdlowing salts is the most ns. il{.,u\er fln'rri sql} ordk irqqr.{i l {l qqR
I
basic in aqueous solution ? "1,1J
t] ?
-+rt t
A/PaEe 79 SPACE FOR ROUGH WORK i/ ?T
t.
t
sf
4t Hvdrogcn peroxicle oxidises [fe(CN)u]l 46 dRls: .{r'-,{qqi,,it4ii.z.t iri*r:lr.
to IFe(CN),,]r in acidic medium but [Fe(CN)o]a 1 [FelCN),,1r 1i .lrGitjr 1
redtr, er I etC\r,, j1 to IFert NroJr rn ri o vgr --rr t't.i-r \...q.{ii lF, r( \, I
alkalinc medium. The other [Link] [Fe(CN),,]r ri lisa-r :i r]. qit
tt,-r q-t iL
(3) H,O and (H2O + 02) (3) HzO ,.ri (H2O + 02)
48. The compound that does not produce 4s. ri l"y-r] .i 6"d[,{ Ruz< ,r} -udqiv< .tq €.r--r
nitrogen gas by the thermal decornposition 3rAI {aii .} airq'I.
is:
N\'*:l'"'i5"J''
49 When metal 'M' is trcatcd with NaOtI, a 49. 6,{ri 'M'.r1 NaOH iusr xfu,1r 5?(i, ttE
white gelatinous prccipitate 'X' is obtained, 9'Ut-ttt( .{aft\ 'X' xfl '1t{ , I .) '{'-( \3
which is solublt, in excess of NaOH. Naol I 1ti ,r?1 qd .aq a. <itor-r t -t -rqn
1
Compound'X' when heated shongly gives rt?1i 5r(i oris rdi.r,i t] t i *'riiL,rqhi
r-rit
an oxide which is used in chromatograPhy .{[q{i\\5 (r1} [Link] qtt t!. i !.(r.l \,t [Link].
as an adsorbent. The metal 'M'is:
(2) Ca (2) Ca
(3) AI (3) AI
50. Consider the following reaction and so. ili ottq<.t *qA qi Aqr+li ,a<ri <rl.
statemcnts
iI
lCo(NH3)aBr2l+ + Br +[Co(NH3)38r3] + NH3 lCo(NH3)4Br2l+ + Br- rlco(NHj)3Bril + NH3
(l) Two isomers are produced if the (D 6;i x&q3 {r'[s[ .,uq.t fl?a itqqe3 ('t{
reactant complex ion is a cis-isomer. d, q 1q23l 6g11^r er.{ d.
(II) Two isomers are produced if the 0D 6irx0{r5 rirlql .rq-t (r-tr nl{irzr c'lir
reactant complex ion is a h4rs- A, q itltEtzs't 6.\-i ,uq d.
isomer.
([I) Only one isomer is produced if the oID 6I x&t{3 iig'[g[ o{,{-r 7-d ${1126 ('l{
reactant complex ion is a f/ais- a, li( + 6/ +[Link]., G\-{ ert.,L 0.
isomer.
l.\-1 (IV) Only one isomer is produced iJ the (IV) 6i rl&.rs rislel o{tq-r a?il rr{qa c'l{
reactant complex ion is a cirisomei. d 5&t qi n/ +t {'125 Gc\..t er{ d.
I l{t
51. Glucosc on prolonged heating $-ith HI 51. ,.1:jri ..riuu rir{ l1,ji Ht tr"l rrir :ini q,[Link]
gi'es: il.r.i rir4i.
52, The frals-alkenes are formeri by the sz. .ili<Lqis{ :'til u4 ,qLqsd-th [istt-reil 4r-a-
reduction oI alkynes ra,ith : ar(+l-i'r q-udL rBt{ r} ?
53. Which of the following compounds will 53. {d4'16/-t .{RrL,{-r qD-fl u}rsr{e ,{eq{A lrD
be suitable for Kjeldahl's method (or .r1 r ,4rqcrL riqlt"y{qiqil 3q1 t{3rd tral ?
nitrogen estimation ?
(1) (r)
o 2
(21 12)
o2
(3) (3)
+ +
N2Cl 2c1-
(1) (1)
o ()
CH: CH:
(1) (1)
co"H
o
CH: CH:
(2) (2)
D
co2lI co2H
() o ..o
(3) (3)
(4) (4)
c02H co2H
CH:r CH:
o o
I A/Page 23 SPACE FOR ROUGH WORK / ?1 t{t t
i
9H o'tJ^
0 4/*tt -:.l. Q
55 An alkali is titated against an acid $,ith ss. qrz-j.d1l.j rtqr.11 ARs +u{ {ii,-tLr!tr ,"rjt-or
methvl orange as indicak)r, 1'hich of the {$ xO xL{ i?(i ilii-u{ril i{ {.iin +rF
following is a correct combination ? d?
Base [Link] End point .jda ,jti{s ',ifrr E6
(1) Weak Strong Colourless to (1) Q4,ri ]rqq tLQdl-t .{ieil
pink Tnoil
(2) Strong Strong Pinkish red (2) xqq rqq ({teRr \s
to vellow :dqi[
U-tt'{i
tqll
(3) Weak Strong Yellow to (3) [Link] ]rorsr .[qr.{qil
pinkish red (ttqttt \sa
,!(1rd
coloutless i.G{t<
56 The predominant form of histamine so. {t<q <r'Ldl,{i 6vRra d[+ztud.t<i rilvt ues
present in human blood is (pK", tilql. (pK,, dltzlsl-r = e.o;
Histidine = 6.0)
n H
N N
NH2 NHz
(1) (, (l) (,
H H
N @ N @
(2)
(*.N NH:
(2)
(o
.N
NH:
H H
II 1J
N N
(3) (s (3)
(.*
NHz NHz
H H
H H
N @ N @
NH: NH:
(1) ( (4) (*
\
A/Page 24 sPACE FoR RoucH woRK / ?i l.{i +{'r
57. Phenol reacts with methyl chloroformate sz. Q<je-fl hqrde rtt'ir)[Link] att NuoH <'[
in the presence of NaOH to form Product owrl{ r&,{r r?d fi6/ A qi r}. e il ar,
A- A reacts with Br2 to form Product B. tuil x&,{L srdi -0v"r B mu qq d. a qi r
A arld B are respectively : .r$i littrl.
oH OH
ir
(1)
OCH:
(1) (Hr (r:
o
(2J
(2)
(3)
(3)
Bt
(4) ocHr
({)
o
Q'
58. The increasing order of basicity of the se. .{l{ o qqL ri {lo/- -{l AB:.u-t't o{ao'l *.t ltrql.
following compourds is :
2
(a) (r)
NH NH
(b) (b)
NH, NH"
t'
(c) (.)
-( Nri N}I
(d) (d) NHCH3
NHCH3
(1) (a)<(b)<(c)<(d) (1) (a) < (b) < (c) < (d)
I
I
(2) (b)<(a) < (c)<(d) (2) (b) < (a) < (c) < (d)
(3) (b)<(a)<(d)<(c) (3) (b) < (a) < (d) < (c)
(4) (d)<(b) < (a)<(c) (l) (d) < (b) < (a) < (c)
HI HI
Heirt Heat
OH OH
0) 0)
OH OH
I I
(2) (2)
I I
OH OH
(3) (3)
I I
I I
(4) (1)
OH OH
l\t Ilr
NaONle NaOMe
(, \4eOIl MeOH
OMe OMe
(1) 0)
(2) (2)
(3) (3)
OMe ON4e
(4) (1)
61. Two sets A and B aro as under: er. di ,ret a .{.i A -ip x.{r'91 0 :
63. If d, 13 € C are the distinct roots, of the 63. "i",p.C{ {rrct12-r+l=0.(t G(--r
equation ,2-r+1= 0, then cror + p1o7 is u{loy C'l { al, alo1 + p1o7 = _.
equal to :
(1) -1 (1) -1 l
(2) 0 (2) 0 i
l
(3) 1 (3) 1
(4) 2 (4) 2
A/PaEe 28 SPACE FOR ROUGH WORK / ei srdi i'{r
1L
-p x4r=t
.tt Lg -4'
I4 2x Ir -{ 2t 2r
64. lt 2:i )r = (A + B-rXx - A)2 , 64. a 2ii t-4 2\ = (A + Br)(r - A)2,
2r 2rx ,] 2x 2r
then the ordered pa (A, B) is equal to r A rr$fl "i.s (A, B)=_
(l) (-4, -s) (1) ( 4. -s)
(2) (-4, 3) (2) ( -4. 3)
5)'
(3) ( -.1, s) (3) ( 1, 5)
(4) (4, s) (4) (4, s)
65. If the system of linear equahons 6s. ") tl\,r rdlsr$ {cR
r+ky+32=0 r+ ky+32=0
3x +ky - 2z= 0 3, +k! -22=O
2t+4y-32=0 2t+4y-32=O
I:
has a non-zero solution (, y, z), then i tpiiar 61<r (r, y, z) al* nl
1-:
y2 v'
is equal to
(1) - 10 (1) 10
(2) 10 (2) 10
(3) - 30 (3) 30
(4) 30 (4) 30
66. From 6 different novels and 3 different 56. 6 [d(--r -rc{(!qr r4.i I Gt--t tr"[Link]
dictionaries, 4 novels and 1 dictionary are 4 -rc{Gqr ,uri 1 {rc€5\r \ri6 st.u.r d r{i
to be selected and aranged in a row on a sr"/dl \r {sl rlR{ q{l {a "ii6"rqr{i } I
shelf so that the dictionar) is always rn oisit rr,.sstL ddar -,{Llt1i r!. 4 rii6qeft }zdl
the middle. The number of such rli a{r, r t
arangements is :
0) -1 1t) 1
(2) 0 (2) 0
(3) 1 (3) 1
(4) 2 (4) 2
68. Let a1, al a, ....., au, be in A.P. such that 6u QR1) ar, ar, ar, ....., are lrti(i Aq[ (A.P.) 1i
72
(1\ 66 o) 66
(2) 68 (2) 68
(3) 34 (3) 34
(4) 33 (4) 33
(2)
-.
(2) 248 248
(3) 464 (3) 464
"1
.4
70. For each t € & let[t] be the greatest integer zo. x.{: t e R qD, trnl } 1tf iii +tat't .,tt-{ t
t
.r) lcss than or equal to t. Then rit -u-ti nu.r
1s[[Link] {{l . i letL ztG r:.
idt ir u-,[i.L]-131i' .lP x.,llll*[?lr
;,* \-.u' , , l.5
,r
\_o+ 1l \i Lrl, Lrl ] llr J
(4) does not exist (in R) 111 .aR..r qitq{ .tell (Rl{0.
:'i 71. I4tS=[t€ R:/(r)= r-trl (er-1) sinlrl 71. qril ] S={t€R:/(r)=lr-nl.(ei -1)sinri
'.)
is not differentiable at t]. Then the set S is
,ji t.,tpr.4 fucr-tl.{ <t11..ti "L\t s
utitci
5. 6) equal to :
72, ll the curves y2:6r, gt2+by2=16 72. o,:i a3l y2:6t, gx2+by2=10 "it "ftoai
trtersect each other at riSht an8les, then 5r\ciri dt dl b -[t &qd E,
the value o( b is :
ret1t
(1) 6 (1) 6
7 7
i (2)
i (2)
,
i
(3) 4 (3) 4
9 9
(4) (4)
2 ,
A/PaEe 37 SPACE FOR ROUGH WORK / et 3di rrlkt
ff '1(r b+r6
"o
Let /(r) r''
.I I qpr ] /tr) ,2r 1.,t-r n,,t.,
73. , an(l B(r)=r-. x
:x-
73 -l-,
0) 3 o) 3
(2) -3 (2) -3
(3) -2nO (3) 2A
(4) z"D Al ).1;
is equal to :
+c 1_
0) --l-
3(1 r tanJr) 0) 3(1 + tan'.r)
(2)
-1
-.............-_ +C (21 -------i- +C
3(1 + tanr.r) 3(1 + tanrr)
1 1
(3) +C (3) +C
1+ cot'r I +.ot l 1
i
1 -1 I
(4) +C (4) +C I
1 + cot3r 1--tq I
I
1r'
(4)
i (4)
4
76. Let g(t)=cos x2, 11x1=,[, and 75. qtrl ] g(r) = cos 12, /(r) = ,[ , "t'i
dr p (d < 0) be the roots of the quadratic d, p (ct < p) &tttd d{Ir?g 1812 - 9n r + rr = 0
",
equation 1812 - 9rr, *Tr2 = 0. Then the .
<i "il"r u. rr y = t3,/1(r) alu lqr.,ir :r . o.
area (in sq. units) bounded by the curve r=p qiy = o (Rr 1,r.r1( xi 1r1 +t15,4
ot ltra -,ar
it.'a -
(3) (3)
ltJz - t\ ,l
(4)
2" (4)
ittz
I
A/Page 33 SPACE FOR ROUGH WORK / ?i tqt t
77. Let y=y(x) be the solutiofl of the 77 t{ } y=y(r) d Osc-L {.ilsrct
dv
dilferential equation sinrf +Vcosr =4r,r ( (0,T) . Glq
E +[Link] =4t, r e (0,rr). If D. v(r) =
o. ar -\6J
"l1l =
^l "1,2)
,(;) = ,, v(|) r e""r . ,
-
"""
2 4 2
0) 1t (1)
16 9J3
(2)
-8 1I
2
(2)
-8 2
9J3 eJ3
8, 8z
(3)
9
(3) -nI
(4)
4. 42
(4)
9 9
78. A straight line through a fixed point (2, 3) 7E. RA( Gq 12, :1 ,ltieil \i1R q{dl lqr lt|lrtt|]i
intersects the coordinate axes at distinct R--r Grgul r ui q ai tlt d. o .l 6l"tat{g
'it
points P and Q. If O is the odgin and the Ci{ .,ri dq?iiin OpRe :i x1 strai ,,t4, .tl
rectangle OPRQ is completed, then the R -r:l [q5\s{ 6.
locus of R is :
E0. lf the tangent at (1, 7) to thecurve 80. w r2=y-6 A H5 1r,4 ,[Link]<) ttir
"i
,z=y-6 touches the circle q4,\ i+f +76x+72y+c=o i
t\ri cl c
f +f +16x+12y+c=0 then the value of -il t}ea L
cis:
(1) les 0) 195
(2) 18s (2) '185
(3) 8s (3) 85
(4) es (4) 95
[Link]
nqo{ 81. Tangent and normal are drawn at 81 \?q(lt 16r \l'{ [tE P(16, 16) ,,ttilul E'\iQ
y2 =
7 1 -
0) (1)
2 2
(2) 2 (2)
(3) (3) 3
14
4 4
(4) (4) b
3 3
83. lt' L1 is the line of intersection of the planes 83. 6,i Lr d aq.t(i 2t-2y+32-2=0,
2x - 2y +32 - 2= 0,, - y+z+1 =O and x.-y+z+1:o il 6elur clrt .t'l t, nl
I-2 is theline of intelsection of the planes ltlt((. r+2y-z-3= O, 3x -y + 22 -1= O
x + 2y - z -3 =O, 3, - y +22 -7= 0, the -{l Btl"u alq, .t1 iurd r, oai t, i rLu+.u
the distance of the origin from the plane, r.6nell 6t"rrt&51 .,i<p 0
.ontaining the lines I-1 and 12, is :
(1) 1
qTz (1)
4J'
1
I 1
(2) ,J1 (2)
3Ji
1
(3) il:z (3)
2J'
1
1 1
(4) T (4)
84. The length of the proiection of the line s4. [\5ot'l 1s, -1, a1 :,1.1 (4, - 1, 3) A 6]s(t
segment joining the points (5, -1,4) and l ',tt'isd +rr{(e r +y + z=7 qt<i nqi,{
(4, -1, 3) on the plane, x+v+z=7 is I ciquJ<1 r).
2 2
(1) 6 (1)
6
2 2
(2\ t (2)
5
1 1
(3) (3)
5 5
D
l- E
(1) (4)
1l \1,
A/Page 35 sPACE FoR RoucH woRK / ?t l{ii rau
--i-\ ?\|t
o'4)
, .-l +6 -l l-\0'1 )'
I
I
Ii-/r
t'',
,.h (r, r,) l-{r ',\) Kt,"
o
)
.t 6
85. Let u be a vector coplanar r^'ith the 85 trRi ! +dE u { xttlrl a -2r +]i-l
..3)
.{qi) vectors a -2i +3j k r,tt b- / + I {tetit{n(tt{tl 6.t u e,t a
b k If u is perpendicular to a n (1or €rq i,t.r u .b = 2a, 1i- lul-)2
=
_2 js ,t . .'!,4)
.tnd b = 24, then u equal to
., '. '11
(1) 336 (i) 336
o
(2) (2) )
t=0,
315 31s
r-,( (,'\,u\ lorl'\
-2 'l (3) 2s6 (3) 2s6
1=0 2
{qdt \*'L
(4) 84 (4) 84
86. A bag contains 4 red and 6 black balls. A 85. + iidlqi 4 ere ,i,ri d. qr &{l{{l
5 sruu €sr.,rl
ball is drawn at random from the ba& its r€ers ?'[a ,i-r ss'i vri.r sr1 i<'t i.L - qqr{
colour is observed and this ball along with i
.{A B ori .,{RqE or i.L.u qqRtu Q rsroal
two additional balls of the same colour are A rr Esl {dl,.{i \n r T,q{ rtQ E. u{
"i
retumed to the bag. lf now a ball is drawn r,u A(il{i?.il .{rr[fu5 r1A tr
es'i .{{s [Link]
at random from the bag, then the rara, r-i \rit 5l(r €s'l (r(r c),r iil iqrq<L
probabfity that this drawn ball is rcd, is : t)'
Ci 1{
[Link]
xql\
(1) 3
10
2
(r)
2
3
10
l9 '\| rrrx i "n'
,Or
(2) ; (2)
5 (\t
( lol
I
1 1
(3) 5
(3)
0
3 1
(4) t (4)
1
,
A / Page 37 SPACE FoR RoucH woRK / ri l{ u< 6
a 1t L )'1^236 yt+^J -11.-e o..'t-9 '' - t-lvl
(
q+2: Ltl- .BF._.#
1
)
t) "Lr,ir5-z,rry-^ Iii: f-0
\t+u)}. ^6 ,
lt: \ l-
99 99
87. rt iO, - 5) = e ancl t (., - s)'? = 4s, 87. "l1 I(ri . 5):9 r4:t l{*, -s12 =ts,
i=\ r:l ,= I ,:I
then the stalldard dc,viation of the 9 items n'L 9 ,,t'rtt\s-t't rr, rr, ....., tr.j :tetQta [Link].t-t
x7, tV ....., ,gis I rr.
(1) e (1)
(2\ 1 (,2) l
(3) 2 (3) l
(4) 3 (4) 3
(-"( 1):
)l
r 8cosn (-"( 1l:,
2)
)-"( 6 ) 6 6
in [0, n] is krr, then k is equal to i -{ "i(rra [0, ,'] qi [Link] 6]a1-ir {iqruii
"}
krr C'trr, ol k =
2
(1) (1)
5 5
13 l3
12) 9
12)
i
u q
(3)
i (3)
9
20 20
(4) (4) g
9
(1) -P (D -P
=1
(2) P (2) P
.?
.;r
(3) q (3) ,l
(1) -q (1) -q
-o0o- -o0o-
1- The candidat.s shoutd {ill in the requted parti(uldrs .{rltut{[Link] re {iui .,ti 6u \1 ("rLE-1) .ri [Link]
on the [Link] [Link] and Ansiler Shet (5ide-1) \',th "/ir1
alotk Bdll Poitt P.'L
o&,at \i ! M1 ,Aa ,1)&2 ia a'r [Link]'r,r *.ii
X For FritinS/marling [Link] on Si.r.-' .. rh" i
Answer Shet, use ah.t Adll Poittt P.n otly-
Gnr\i (utt3-2) ${.{r/A€ 4rt,il. 1ta a<l <ict
viriu 'i+<1 [Link],r :rqi.
3. Ihe candidates should not write their Roll Numbers
an!flhen' els. (except in the spsilied space) on the \rllq{r?il.;{.{ldHi .a$.{i, ){* :Qr5r/
Test Booklet/Answer Shet.
3. 6{i \1 rri ilF{( }.u-r
Q.4,r rr-.r tld rqt< ,{r $a.i {d[.
4. Out of the four optioff given for each question, onl!
one option is the correct atuwer.
4. ri! Ir{ .,uie r{rl fua.r]ltM i6(
rrD fuelr rld d.
5. For each [Link] response, * b@-fourtb mark' ot "U "y
th€ toLal marks allotted to the question (i.e. t hark) 5. x..t! \rjzr ./c{rq rri, )re rrD haittr 3<r ,19tai{
will be deducted from the total score. No [Link]
from the total score, however, will be made y' rd % i .1, qCqIfl) +A (1 ler) i g1 u1r{{l !r.r<ai .rur'I"
rrsr'ars, ts indicated for an i[em in the Aiswer Sheet. Grr ,ra"ri'il s)tl 6rri n* I {vdl, {qqqL g(t lgrriir]l
5. Handle the Test Bookl€t and Aiswer Sheet with care, . r1d 1!et rtv<r,[Link]
as unrl na citumstan.?s krftpt lot dtstftpa q n
Test Boovet Cod? and An$oet Sh?rt Code), anothtt sct o rr \f}.lfl \lt'l 5lqr qqll. lRql ), ,lthqr
.,r-r [Link]
zjill bc ptof idtd. ,{ftf*ra{i.{hhyt ir .a.{.{..ri<$ .rA {6trr,rI .rlu
7. The candidates a.e not allowed to do any rough worl
or writing worl on the A8wer Sheet AI calculations/
.{(}ur iL .{.1 G.Q ,{'( tI lq't [Link]
writing work are bo be done in the space prcvided for
this purpos€ in the Test Booldet itsef, ,narked 'Space 7. Gdi \i
\1 \r'lq$llii iU r1 rL.i ) cr"uet <rwj <dt. rrll
,or RouSh work'. This spac€ is given at the bottom of ,LgLnrl/ n ugL rd !g na Viupd Rrrihd 'q i${.j ra{L{'
each p.8e and in lour pag€6 (Pag€ 4G43) at dE md of lti !t.i .aL 8rr{ ei5 $rur iliiiou,Lri B. rr.l [Link]
the booller "/
6. On completion of dle test, lhe candidates must han4
rifli rr! \.ii (v.i 4G€) 4\1r{ r{.,( d.
over tlrc Arlswer Sheet to drc Invigilator on duty in the
Room/[Link]. Howe€r, th€ (ddidrl€r are allowed to a. .ritu 1ei tm vtr1, [Link] 3crlck Ai1tLri 6rtr .ri r]t
trlc en ay thi6 T€64 Bookl€twith then ii. rtltu{l r)'u+lm{ ra lCirr <rr! vtl rtr r}.
9. E chc [Link] m6t show m demand his/her Adrnit
o. sls ,r{lqur{l.l A,1qu-fl ,,i,r \t
Crrd to the Invigilaror. xaicr 5rl {ar.{i.
10. No candidate, without special permission of the ,i{l+u{[Link]{l
10. t0Q-s-a.{r"{ Qi'icrr.0 AiIc r",r..{,Lr itrt
Superintendenl or,nvigilalor, should leave his/her
s€al dle ols{t <d[.
IL The candidaDes 6hould nol ieave the Elamimtion Hall
11. [Link] \i Ai1qu.l 6(? .{1 nl.,rt .r"n .{rlqiL..[.i ,{rlq{l .is
without handing over their Answer Sheet to the
InviSilator on duty and siSn the [Link] Sheet o-I(;i ry.i <{l .,r:i [Link] [Link] tl{l it{t *.{1. nr.! ii.r1. t
again. Cas€s whe.e a candidate has not siSned the
Attendake Shet sond time B,ill be d<med not to
4c qLr 6{U(a rnzrindl qd d,{.iI6(r.{i Arla{rtri
have handed overlhe Atrwer Shet and dealt with as ril"j <tII ia at I iictai .,tnr1 ,i u{{< uaa<1 r,.r1"t
an un airltleans case. The [Link]€s de ilso required qr-r*{ rilz{ ,c{lqn'll.i .itar<
-rqjr- 6,rlEr['t sr"rL tpr<i
to put their left [Link] THUMB impression ir the spa.e riprj Aut< AISn rru.t.t r*r n{
provided in th€ Att€ndance She€t.
lZ Use of Electronic/Manual Calculato. and any 12. rrd*11fu .1ct(k,.lui.,rr.n.,er ikl riir{R: €uret
/d
Elertronic device like mobile phone, pager etc. is
prchibit€d-
i.r 1 e1t6<r fu \"n t!. <t [Link] r{ r<td 6.
[Link] .andidates are governed by all Rules and 13. \rlRr \,[Link] \llqutllqht .rci< ouq< .Q'lql risqr fuit
Regulations of $e Examination body with regard to qi
th€ir conduct in the Eramiiation Hall. AI cases of
rrLitqlt$ A.t. \t
<.[Link] taL nqAr .,rtnlai
unfair [Link] will be dealt with as per Rules and .{r1 .i!,ri.u fi,rt (rlr&her \i
1..,q 5r,i"udt sr"{d 4.{r\
[Link] of the Eramination body.
1d No part of the Test Booklet and Answer Sheet shall be ra. iirtrer Rrdt{ \r1q{ :tir$ or*q .reti [Link] qpti qi
[Link] und€r anv .[Link] grt '
,ru+t.d[.
15. Candidateb are not allowed to (arry any textual
material, printed or writteir bits of pap€.s, pager, 1s. \{lUi\/,t{rUrE r{qu{R rl$'tr"t usr lrl'dl,
Rqr,r
nobile phone, electronic devi.e or aitt other malerial
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