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Gas Properties and Equations of State

This document discusses gas properties and equations of state. It provides equations for calculating pseudocritical pressure and temperature using Sutton's method, accounting for gas composition. It also provides equations for calculating gas viscosity, formation volume factor, and using standard conditions of 14.7 psi and 520R.

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moji20067147
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95 views3 pages

Gas Properties and Equations of State

This document discusses gas properties and equations of state. It provides equations for calculating pseudocritical pressure and temperature using Sutton's method, accounting for gas composition. It also provides equations for calculating gas viscosity, formation volume factor, and using standard conditions of 14.7 psi and 520R.

Uploaded by

moji20067147
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd

Gas Properties

Equation of State
𝑚
𝑃𝑉 = 𝑧𝑅𝑇 = 𝑧 𝑅𝑇
𝑀

V volume occupied at PV by n moles of gas


m mass of gas considered
M molecular weight of the gas
R ideal gas constant 10.7 mol lb

Pseudocritical Pressure and temperature


𝑃𝑝𝑐 = ∑ 𝑦𝑖 𝑃𝑐𝑖
𝑇𝑝𝑐 = ∑ 𝑦𝑖 𝑇𝑐𝑖
Pci Tci critical pressure and temperature of ith component
yi mole fraction of the ith component
Sutton’s method of finding Pseudocritical Pressure and temperature
𝑝𝑝𝑐ℎ = 756.8 − 131.0𝛾ℎ − 3.6𝛾ℎ2
𝑇𝑝𝑐ℎ = 169.2 + 349.5𝛾ℎ − 74.0𝛾ℎ2
Valid if .57<h<1.68 and <12% CO2, <3% N2, no H2S
For gas with higher CO2 and N2 that is sour
𝑝𝑝𝑐 = (1 − 𝑦𝐻2𝑆 − 𝑦𝐶𝑂2 − 𝑦𝑁2 − 𝑦𝐻2𝑂 )𝑝𝑝𝑐ℎ + 1306𝑦𝐻2𝑆 +
1071𝑦𝐶𝑂2 + 493.1𝑦𝑁2 + 3200𝑦𝐻20

𝑇𝑝𝑐= (1 − 𝑦𝐻2𝑆 − 𝑦𝐶𝑂2 − 𝑦𝑁2 − 𝑦𝐻2𝑂 )𝑇𝑝𝑐 + 672.35𝑦𝐻2𝑆 +


547.58𝑦𝐶𝑂2 + 227.16𝑦𝑁2 + 1164.9𝑦𝐻2𝑂

𝛾𝑤 −1.1767𝑦𝐻2𝑆 −1.51𝑦𝐶𝑂2 −.9672𝑦𝑁2 −.622𝑦𝐻2𝑂


𝛾ℎ =
1−𝑦𝐻2𝑆 −𝑦𝐶𝑂2 −𝑦𝑁2 −𝑦𝐻2𝑂

∑(𝑦𝑖 𝑀𝑊𝑖 )
𝛾ℎ =
28.9

𝑀𝑊𝑔 = 28.9𝛾𝑔

Gas viscosity
𝑌1×𝑒 𝑌5
𝜇𝑔 =
104

(9.4+.02𝑀𝑊)𝑇 1.5
𝑌1 =
209+19𝑀𝑊+𝑇
986
𝑌2 = 3.5 + .01𝑀𝑊 +
𝑇

𝑌3 = 2.4 − .2𝑌2
𝑀𝑊
𝑌4 = .007532
𝐵𝑔
𝑌5 = 𝑌2(𝑌4)𝑌3

Formation volume factor

𝑧𝑅𝑃𝑠𝑐 𝑇
𝐵𝑔 =
𝑧𝑠𝑐 𝑅𝑃𝑇𝑠𝑐
𝑧𝑃𝑠𝑐 𝑇
𝐵𝑔 =
𝑃𝑇𝑠𝑐

If standard conditions are 14.7psi and 520R


𝑇
𝐵𝑔 = 5.035𝑧
𝑃

Also
𝑃𝑠𝑐 𝑇 𝑅𝐵
𝐵𝑔 = 𝑧
5.614∗1000∗𝑃∗𝑇𝑠𝑐 𝑚𝑠𝑐𝑓

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