SAFETY DATA SHEET:

NONYL PHENOL 9

IN CASE OF TRANSPORTATION EMERGENCY CONTACT:

CHEMTREC:(800) 424-9300
-----------------------
ALL OTHER INQUIRIES:
(770) 904-7042 // www.ciscochem.com
266 Rue Cezzan Lavonia, GA 30553

1. IDENTIFICATION
COMMON NAME:
TERGITOL NP-9, SUFACTANT

SYNONYM:
Poly(oxy-1,2-ethanediyl), .alpha.-(4-nonylphenyl)-.omega.-hydroxy-branched

CHEMICAL NAME:
NONYL PHENYL POLYETHYLENE GLYCOL ETHER

2. HAZARDS IDENTIFICATION
Potential Acute Health Effects:
Hazardous in case of eye contact (irritant). Slightly hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation.

Potential Chronic Health Effects:

CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
Repeated or prolonged exposure is not known to aggravate medical condition.

3. COMPOSITION
NAME CAS - NO % BY WEIGHT
1) Poly (oxy-1,2-Ethanediyl),
alpha-(4-nonyphenyl)-omega-hydroxy,
branched 127087-87-0 >97

2) Polyethylene Glycol 25322-68-3 <3

3) Dinonylphenyl Polyoxyethylene 9014-93-1 <2

Toxicological Data Tergitol NP-9, Surfactant:

on Ingredients
ORAL (LD50): Acute: 960-3980 mg/kg [Rat].
DERMAL (LD50): Acute: 2000-2991 mg/kg [Rabbit].

4. FIRST AID MEASURES

Eye Contact Skin Contact

SDS: NONYL PHENOL 9 Page: 1

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
Cold water may be used. Get medical attention if irritation occurs.

Skin Contact
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated
clothing and shoes. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical
attention.

Serious Skin Contact

Not available

Inhalation
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.

Serious Inhalation
Not available

Ingestion
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If
large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or
waistband.

Serious Ingestion
Not available

5. FIRE FIGHTING MEASURES

Flammability of the Product
May be combustible at high temperature

Auto-Ignition Temperature
not available

Flash Points
CLOSED CUP: 247°C (476.6°F). (Pensky-Martens.) OPE N CUP: 282°C (539.6°F) (Cleveland)

Flammable Limits
Not available

Products of Combustion
not available

Fire Hazards in Presence of Various Substances

Slightly flammable to flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks.

Explosion Hazards in Presence of Various Substances

Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of
static discharge: Not available.

Fire Fighting Media and Instructions

SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Special Remarks on Fire Hazards

Not available

Special Remarks on Explosion Hazards

not available

SDS: NONYL PHENOL 9 Page: 2

6. ACCIDENTAL RELEASE MEASURES
Small Spill
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Finish
cleaning by spreading water on the contaminated surface and dispose of according to local
and regional authority requirements.

Large Spill
Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.

7. HANDLING AND STORAGE

Precautions
Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe
gas/fumes/ vapor/spray. Wear suitable protective clothing. If ingested, seek medical advice immediately and show the container or
the label. Keep away from incompatibles such as oxidizing agents, acids, alkalis.

Storage
Keep container tightly closed. Keep container in a cool, well-ventilated area.

8. EXPOSURE CONTROLS AND PERSONAL PROECTION

Engineering Controls
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location

Personal Protection
Splash goggles. Lab coat. Gloves. Respiratory protection is not necessary for normal handling. Good room ventilation or use of local
exhaust (fume hood) is sufficient. Use a vapor respirator under conditions where exposure to the substance is apparent (e.g.
generation of high concentrations of mist or vapor, inadequate ventilation, development of respiratory tract irritation), and
engineering controls are not feasible. Be sure to use an approved/certified respirator or equivalent

Personal Protection in Case of a Large Spill

Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE
handling this product.

Exposure Limits
Not available

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state and appearance: Liquid

Odor: Mild

Taste: Not available

Color: Colorless to light yellow

Molecular Weight not available

pH (1% soln/water) 6 (Acidic)

Boiling Point Decomposition temperature: >250°C (482°F)

Melting Point Freezing point: 3.8°C (38.8°F) Pour Point: -1°C

Critical Temperature Not available

SDS: NONYL PHENOL 9 Page: 3

Specific Gravity 1.042-1.062 (Water = 1)

Vapor Pressure <0.001 kPa (@ 20°C)

<0.04mmHg @ 20 C

Vapor Density >1 (Air = 1)

Volatility Not available

Odor Threshold Not available

Water/Oil Distribution Coefficient Not available

Ionicity (in water) Non-ionic

Dispersion Properties See solubility in water

Solubility Soluble in cold water, hot water

10. STABILITY AND REACTIVITY

Stability The product is stable

Instability Temperature Not available

Conditions of Instability Avoid prolonged excess heat which may cause product decomposition.
Avoid incompatible materials such as strong bases strong acids, strong oxidizing agents and
materials reactive with hydroxyl compounds.

Incompatibility with various

substances Reactive with oxidizing agents, acids, alkalis

Corrositivity Not available

Special Remarks on Reactivity Normally un reactive. However, avoid strong bases at high temperatures, strong acids, strong
oxidizing agents, and materials reactive with hydroxyl compounds.

Special remarks on Corrositivity not available

Polymerization will not occur

11. TOXICOLOGICAL INFORMATION

Routes of Entry
Absorbed through skin. Eye contact. Ingestion

Toxicity to Animals:
Acute oral toxicity (LD50): 960-3980 mg/kg [Rat].
Acute dermal toxicity (LD50): 2000-2199 mg/kg [Rabbit].

Chronic Effects on Humans

Not Available

Other Toxic Effects on Humans

Hazardous in case of eye contact (irritant).
Slightly hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation.

Special Remarks on Toxicity to Animals

Not available

Special Remarks on Chronic Effects on Humans

SDS: NONYL PHENOL 9 Page: 4

May contain trace amounts of Ethylene oxide (<0.0010%),1,4-dioxane (<0.0020%) which can cause cancer. May contain trace
amounts of Ethylene oxide (<0.0010%) which may cause birth defects or other reproductive harm.
May cause adverse reproductive effects and birth defects based on animal studies.

Special Remarks on other Toxic Effects on Humans:

Acute Potential Health Effects:
Skin: May cause mild skin irritation.
Eyes: Causes eye irritation. May cause corneal injury.
Ingestion may cause abdominal discomfort, nausea, vomiting, and diarrhea.
Inhalation: Mist may cause irritation of the upper respiratory tract (nose, throat).
Chronic Potential Health Effects:
Skin: Prolonged or widespread contact is not likely to result in absorption of potentially harmful amounts. Ingestion: Prolonged or
repeated ingestion may affect the liver.

12. ECOLOGICAL INFORMATION

ECOTOXICITY
Ecotoxicity in water (LC50): 21.4 mg/l 48 hours [Daphnia]. 6.6 mg/l 96 hours [Daphnia]. 7.7 mg/l 96 hours [Fish (Fathead
Minnow)]. 4.8 mg/l 96 hours [Fish (Fathead Minnow)]. 6.6 mg/l 96 hours [Fish (Fathead Minnow)].

BOD5 AND COD

Not available

Products of Biodegradation
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation

Not Available

Special Remarks on the Products of Biodegradation

Not available

13. DISPOSAL CONSIDERATIONS

Waste Disposal
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

14. TRANSPORT INFORMATION

DOT CLASSIFICATION
Not a DOT controlled material (USA)

Identification
Not applicable

Special Provisions for Transport

Not applicable

15. REGULATORY INFORMATION

FEDERAL AND STATE REGULATIONS

California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer, birth
defects or other reproductive harm, which would require a warning under the statute: Ethylene oxide; 1,4-Dioxane
California prop. 65: This product contains the following ingredients for which the State of California has found to cause reproductive
harm (female) which would require a warning under the statute:
Ethylene Oxide
California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer
which would require a warning under the statute: Ethylene oxide; 1,4-Dioxane
Minnesota: Polyethylene glycol

SDS: NONYL PHENOL 9 Page: 5

TSCA 8(b) inventory: Poly(oxy-1,2-ethanediyl), .alpha.-(4-nonylphenyl)-.omega.-hydroxy-branched; Dinonylphenyl
Polyoxyethylene; Polyethylene Glycol
TSCA 8(a) PAIR: Poly(oxy-1,2-ethanediyl), .alpha.-(4-nonylphenyl)-.omega.-hydroxy-branched

CALIFORNIA PROPOSITION 65 WARNINGS

California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer
which would require a warning under the statute: Ethylene oxide; 1,4-Dioxane California prop. 65: This product contains the
following ingredients for which the State of California has found to cause birth defects which would require a warning under the
statute: No products were found.

OTHER REGULATIONS

For CAS no. 127087-87-0:

EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No. 500-045-0).
Canada: Listed on Canadian Domestic Substance List (DSL).
China: Listed on National Inventory.
Japan: Listed on National Inventory (ENCS).
Korea: Listed on National Inventory (KECI).
Philippines: Listed on National Inventory (PICCS).
Australia: Listed on AICS.

OTHER CLASSIFICATIONS

WHMIS (CANADA) CLASS D-28. Material causing other toxic effects (TOXIC)

DSCL (EEC) R36-Irritating to eyes

S26- In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice

PROTECTIVE EQUIPMENT

GLOVES, LAB COAT, SPLASH GOGGLES

16. OTHER INFORMATION

Other Special Considerations
Major Uses: in detergents and cleaners; in paper and textile processing; in paints and coatings; in agrochemicals; in metalworking
fluids; in dust control

Notice to Reader
All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to
the material as packaged. If this product is combined with other materials, deteriorates, or becomes contaminated, it may pose
hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods of handling and personal
protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, CISCO , assumes
no responsibility for the completeness or accuracy of the information contained herein.

Date Created: 5/15/2015

Date Updated: 6/22/2015

SDS: NONYL PHENOL 9 Page: 6

 Safety Data Sheet
EDTA Disodium, 0.5M

Section 1 Product Description

Product Name: EDTA Disodium, 0.5M
Recommended Use: Science education applications
Synonyms: Ethylenediamine Tetraacetic Acid aqueous, chelating solution
Distributor: Carolina Biological Supply Company
2700 York Road, Burlington, NC 27215
1-800-227-1150
Chemical Information: 800-227-1150 (8am-5pm (ET) M-F)
Chemtrec: 800-424-9300 (Transportation Spill Response 24 hours)

Section 2 Hazard Identification

Classification of the chemical in accordance with paragraph (d) of §1910.1200;

WARNING

Harmful if swallowed. Harmful to aquatic life.

GHS Classification:
Hazardous to the aquatic environment - Acute Category 3, Acute Toxicity - Oral Category 4

Other Safety Precautions: May cause irritation to skin.

May cause irritation.
May cause gastrointestinal discomfort.

Acute Toxicity Dermal Contains 18.6 % of the mixture consists of ingredient(s) of unknown toxicity
Acute Toxicity Inhalation Vapor 19.6 % of the mixture consists of ingredient(s) of unknown toxicity
Contains
Acute Toxicity Inhalation Dust/Mist 19.6 % of the mixture consists of ingredient(s) of unknown toxicity
Contains

Section 3 Composition / Information on Ingredients

Chemical Name CAS # %
Water 7732-18-5 80.4
Ethylenediaminetetraacetic Acid, Disodium Salt, Dihydrate (EDTA Sodium) 6381-92-6 18.6
Sodium Hydroxide 1310-73-2 1

Section 4 First Aid Measures

Emergency and First Aid Procedures
Inhalation: In case of accident by inhalation: remove casualty to fresh air and keep at rest.
Eyes: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Skin Contact: After contact with skin, wash immediately with plenty of water.
Ingestion: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

Section 5 Firefighting Procedures

Extinguishing Media: Use media suitable to extinguish surrounding fire.

EDTA Disodium, 0.5M Page 1 of 4

 Safety Data Sheet
Fire Fighting Methods and Protection: Firefighters should wear full protective equipment and NIOSH approved self-contained
breathing apparatus.
Fire and/or Explosion Hazards: Fire or excessive heat may produce hazardous decomposition products.
Hazardous Combustion Products: None Known

Section 6 Spill or Leak Procedures

Steps to Take in Case Material Is Exposure to the spilled material may be irritating or harmful. Follow personal protective
Released or Spilled: equipment recommendations found in Section 8 of this SDS. Additional precautions may be
necessary based on special circumstances created by the spill including; the material spilled,
the quantity of the spill, the area in which the spill occurred. Also consider the expertise of
employees in the area responding to the spill.
Isolate area. Keep unnecessary personnel away.
Prevent the spread of any spill to minimize harm to human health and the environment if safe
to do so. Wear complete and proper personal protective equipment following the
recommendation of Section 8 at a minimum. Dike with suitable absorbent material like
granulated clay. Gather and store in a sealed container pending a waste disposal evaluation.
Absorb the liquid and scrub the area with detergent and water. Pick up wash liquid with
additional absorbent and place in a disposable container. Contain the discharged material.

Section 7 Handling and Storage

Handling: Wash thoroughly after handling. Do no eat, drink or smoke when using this product. Avoid release to the
environment. Avoid contact with skin and eyes.
Storage: Suitable for any general chemical storage.
Storage Code: Green - general chemical storage

Section 8 Protection Information

ACGIH OSHA PEL
Chemical Name (TWA) (STEL) (TWA) (STEL)
EDTA, Disodium Salt, Dihydrate N/A N/A N/A N/A
Sodium Hydroxide N/A N/A 2 mg/m3 TWA N/A

Control Parameters
Engineering Measures: Local exhaust ventilation or other engineering controls are normally required when
handling or using this product to avoid overexposure. Good general room ventilation
should be sufficient to control airborne contaminates to safe levels.
Personal Protective Equipment (PPE): Lab coat, apron, eye wash, safety shower.
Respiratory Protection: No respiratory protection required under normal conditions of use.
Eye Protection: Wear chemical splash goggles when handling this product. Have an eye wash station
available.
Skin Protection: Avoid skin contact by wearing chemically resistant gloves, an apron and other protective
equipment depending upon conditions of use. Inspect gloves for chemical break-through
and replace at regular intervals. Clean protective equipment regularly. Wash hands and
other exposed areas with mild soap and water before eating, drinking, and when leaving
work.
Gloves: Butyl rubber, Nitrile, Neoprene, Polyvinyl chloride

Section 9 Physical Data

Formula: See Section 3 Vapor Pressure: N/A
Molecular Weight: N/A Evaporation Rate (BuAc=1): N/A
Appearance: Colorless Liquid Vapor Density (Air=1): N/A
Odor: No data available Specific Gravity: >1
Odor Threshold: No data available Solubility in Water: Soluble
pH: Approx. 8.0 Log Pow (calculated): No data available
Melting Point: 252 C Autoignition Temperature: No data available
Boiling Point: 100 C Decomposition Temperature: No data available
Flash Point: No data available Viscosity: No data available
Flammable Limits in Air: N/A Percent Volatile by Volume: N/A

Section 10 Reactivity Data

EDTA Disodium, 0.5M Page 2 of 4

 Safety Data Sheet

Reactivity: No data available

Chemical Stability: Stable under normal conditions.
Conditions to Avoid: Exposure to moisture
Incompatible Materials: Water-reactive materials, Strong oxidizing agents, Strong reducing agents, Acids,
Hydroquinone, Organic halides, Phosphorus, Alcohols, Metals, Aldehydes
Hazardous Decomposition Products: None Known
Hazardous Polymerization: Will not occur

Section 11 Toxicity Data

Routes of Entry Ingestion, skin and eye contact.
Symptoms (Acute):
Delayed Effects: No data available

Acute Toxicity:
Chemical Name CAS Number Oral LD50 Dermal LD50 Inhalation LC50
Water 7732-18-5 Oral LD50 Rat
90000 mg/kg
EDTA, Disodium Salt, Dihydrate 6381-92-6 Oral LD50 Rat
2000 mg/kg

Carcinogenicity:
Chemical Name CAS Number IARC NTP OSHA
EDTA, Disodium Salt, Dihydrate 6381-92-6 Not listed Not listed Not listed
Sodium Hydroxide 1310-73-2 Not listed Not listed Not listed

Chronic Effects:
Mutagenicity: No evidence of a mutagenic effect.
Teratogenicity: No evidence of a teratogenic effect (birth defect).
Sensitization: No evidence of a sensitization effect.
Reproductive: No evidence of negative reproductive effects.
Target Organ Effects:
Acute: No data available
Chronic: Not listed as a carcinogen by IARC, NTP or OSHA., To the best of our knowledge, the toxicological
properties of this mixture have not been thoroughly evaluated.

Section 12 Ecological Data

Overview: This material is not expected to be harmful to the ecology.
Mobility: No data
Persistence: Dissolved into water, Photodegradation
Bioaccumulation: No data
Degradability: No data
Other Adverse Effects: No data

Chemical Name CAS Number Eco Toxicity

Water 7732-18-5 No data available
EDTA, Disodium Salt, Dihydrate 6381-92-6
Sodium Hydroxide 1310-73-2 Aquatic LC50 (96h) Rainbow Trout 45.4 MG/L

Section 13 Disposal Information

Disposal Methods: Dispose in accordance with all applicable Federal, State and Local regulations. Always
contact a permitted waste disposer (TSD) to assure compliance.
Waste Disposal Code(s): Not Determined

EDTA Disodium, 0.5M Page 3 of 4

 Safety Data Sheet

Section 14 Transport Information

Ground - DOT Proper Shipping Name: Air - IATA Proper Shipping Name:
Not regulated for transport Not regulated for air transport by IATA.

Section 15 Regulatory Information

TSCA Status: All components in this product are on the TSCA Inventory.

Chemical Name CAS § 313 Name § 304 RQ CERCLA RQ § 302 TPQ CAA 112(2)
Number TQ

EDTA, Disodium Salt, Dihydrate 6381-92-6 No No No No No

Sodium Hydroxide 1310-73-2 No 1000 lb 1000lb (454kg) No No
RQ final RQ

Section 16 Additional Information

Revised: 09/03/2014 Replaces: 08/27/2014 Printed: 09-12-2014
The information provided in this (Material) Safety Data Sheet represents a compilation of data drawn directly from various sources
available to us. Carolina Biological Supply makes no representation or guarantee as to the suitability of this information to a particular
application of the substance covered in the (Material) Safety Data Sheet.

Glossary
ACGIH American Conference of Governmental NTP National Toxicology Program
Industrial Hygienists OSHA Occupational Safety and Health Administration
CAS Chemical Abstract Service Number PEL Permissible Exposure Limit
CERCLA Comprehensive Environmental Response, ppm Parts per million
Compensation, and Liability Act RCRA Resource Conservation and Recovery Act
DOT U.S. Department of Transportation SARA Superfund Amendments and Reauthorization Act
IARC International Agency for Research on Cancer TLV Threshold Limit Value
N/A Not Available TSCA Toxic Substances Control Act
IDLH Immediately dangerous to life and health

EDTA Disodium, 0.5M Page 4 of 4

 Material Safety Data Sheet
Sodium Lauryl Ether Sulfate
Section 1: Chemical Product and Company Identification
Product Name: Sodium Lauryl Ether Sulfate 70 Chemtrade International
Company Information: Rm. 201, Unit 3, Building 8, Shijia Garden, No. 93,
Chemical Name: Sodium Lauryl Ether Sulfate Xiangjiang Road, Qingdao Development Zone,
Customs Tariff No: 34021100 Qingdao, Shandong, China 266555
Synonym Name: Sodium Alkyl Ethoxy Sulphate, Tel: 0086-532-86893005
Sodium C10-16 Alkyl Ethoxy Sulphate Fax: 0086-532-86893005
(Predominantly C12-C14)
Chemical Formula: CH3-(CH2) n-(O-CH2-CH2) p
-OSO3Na n=9-15, p=2

Section 2: Composition and Information on Ingredients

Composition:
Name CAS No. EINECS No. %by weight
Sodium Lauryl Ether Sulfate 68585-34-2 no longer polymer 70

Section 3: Hazards Identification

May cause some irritation to the mouth and upper digestive tract.
May cause significant skin irritation especially if exposure is prolonged and/or repeated.
Contact with eyes can cause severe irritation. If not washed out promptly, will injure the tissue, and permanent
damage may result.

Section 4: First Aid Measures

Wash out mouth with water. Do not induce vomiting. Seek medical advice.
Wash the skin with soap and water. Seek medical attention if skin appears damaged.
Immediately wash out the eye with plenty of water for at least 15 minutes holding the eye open.
Seek medical attention urgently.

Section 5: Fire and Explosion Data

Fumes containing carbon dioxide, carbon monoxide and sulphur dioxide may be formed in large fire.
Use power, form, sand, water spray.
Avoid using large quantities of water.

In case of fire, self-contained breathing apparatus should be worn.

Section 6: Accidental Release Measures

Contain and collect spillage.

Absorb on to sand / kieselguhr.
Failure to contain release must be reported to the local authority and medical should be notified.

May make floor very slippery.

Wear impervious gloves/overalls and eye protection while clearing up the spillage.
Do not wash into the drains.
Place in plastic barrels for disposal.
Do not mix with other waster materials.
Dispose of in accordance with Federal State and local authority regulations.
Seek advice from the local waste authority or contact medical for guidance.
 Section 7: Handling and Storage
Store in plastic, plastic lined or stainless steel, tight closed containers at between 5 and 40 degrees Centigrade.
Do not store close to strong oxidizing agents which could aggravate any fire situation.

Section 8: Exposure Controls/Personal Protection

Avoid contact with eyes, skin or clothes.
Working procedures should be designed to minimize worker exposure to this product. When this is not possible, the
following personal protective equipment should be provided.

Skin protection: Protective overalls and shoes/boots recommended

Hand protection: Impervious gloves recommended.
Eye protection: Safety face shield must be worn.
Respiratory protection:

All personal protective equipment must comply with the appropriate EEC (CE) standards and should be maintained
and stored to ensure continued suitability for use. Where necessary workers should be trained in the effective use of
the personal protective equipment provided.
No exposure standards have been set for the substances present in this product.

Section 9: Physical and Chemical Properties

Appearance: viscous liquid pale straw
Odour: characteristic Set point (℃): ca. 7
Melting Point / Melting Range: 10-15℃
Boiling Point / Boiling Range: X
Relative Density (20℃): ca. 1.1
Viscosity (25℃): ca. 25000 m Pa.s. Brookfield RVT Spindle 4.R.P.M 100
Water Solubility (20℃): ca. 450 g/l
Solubility in lower alcohols: fully miscible @20℃
pH (20℃) (100 g/l): ca. 7.5
Flash Point (℃): X
“X”=Not Applicable

Section 10: Stability and Reactivity Data

If the pH fails an exothermic reaction may occur releasing sulphuric acid.
May react with strong oxidants.

Decomposition
May start to hydrolyse >50 degC.

Section 11: Toxicological Information

LD50(oral rat) >2000mg/Kg
Not classified as “Harmful if swallowed”. May cause some irritation of the mouth and upper digestive tract.
May produce significant skin irritation after prolonged contact.
May cause severe, possibly permanent eye damage.

Section 12: Ecological Information

Ecoloxicity: The product is toxic to aquatic organisms.

Ecological Overview: Not expected to cause significant environment impact.
Mobility: The product will dissolve in water.
Persistence / Degradability: This product is readily biodegradable with respect to EC criteria.
Bio-accumulation: Product is surface active, Log Pow inappropriate.
Do not release into surface waters.

Section 13: Disposal Considerations

When disposing of waste or surplus material avoid contact with the eye and skin. Impervious gloves/over all sand a
face shied must be worn.
Do not wash into the drains.
Do not mix with other waste materials.
Dispose of in accordance with Federal State and local authority regulations.
Seek advice from the local waste authority or contact medical for guidance.

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).

Identification: Not applicable.
Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

This preparation is classified according to the criteria laid down in the EEC Directives on the Control of Dangerous
Substances and Preparations.

Irritant
R41: Risk of serious damage to eyes.
R38: Irritating to skin.

S26: In case of contact with eyes, rinse immediately with plenty of water. Seek medical advice.
S39: Wear eye / face protection.
This product is classified on the basis of information compiled by CESIO on the toxicological properties of
surfactants.
No exposure standards have been set for the substances present in this product.

Wassergefahrdungsklasse (WGK): 2

Section 16: Other Information

A16.21 INVENTORY NAME(S): Poly(oxy-1,2-ethanediyl), alpha-sulfo-omega-hydroxy-, C10-16-alkyl

ethers, sodium salts (TSCA, DSL, AICS)
Sodium Laureth Sulphate (INCI) CAS / 68585-34-2 or 9004-82-8 or 3088-31-1

Uses and Restrictions-The uses of this product include the following: Surfactants. Cleaning.
Washing agents. Toiletries.
Dispersion agents. Foaming agents. Wetting agents.

MSDS Creation Date: 6/16/2000

Revision #4 Date: 3/15/2007
The information above is believed to be accurate and represents the best information currently available to us. However, we make
no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no
liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their
particular purposes. In no event shall Chemtrade International be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Chemtrade
International has been advised of the possibility of such damages.
 Citric Acid, Anhydrous
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 10/24/2007 Revision date: 04/04/2017 Supersedes: 06/19/2013 Version: 1.1

SECTION 1: Identification
1.1. Identification
Product form : Substance
Substance name : Citric Acid, Anhydrous
CAS No : 77-92-9
Product code : LC13140
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : For laboratory and manufacturing use only.
Recommended use : Laboratory chemicals
Restrictions on use : Not for food, drug or household use
1.3. Details of the supplier of the safety data sheet
LabChem Inc
Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court
Zelienople, PA 16063 - USA
T 412-826-5230 - F 724-473-0647
[email protected] - www.labchem.com

1.4. Emergency telephone number

Emergency number : CHEMTREC: 1-800-424-9300 or 011-703-527-3887

SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture
GHS-US classification
Serious eye damage/eye irritation Category 2A H319
Full text of H statements : see section 16

2.2. Label elements

GHS-US labeling
Hazard pictograms (GHS-US) :

GHS07
Signal word (GHS-US) : Warning
Hazard statements (GHS-US) : H319 - Causes serious eye irritation
Precautionary statements (GHS-US) : P264 - Wash exposed skin thoroughly after handling
P280 - Wear eye protection
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P337+P313 - If eye irritation persists: Get medical advice/attention

2.3. Other hazards

Other hazards not contributing to the : None.
classification
2.4. Unknown acute toxicity (GHS US)
Not applicable

SECTION 3: Composition/Information on ingredients

3.1. Substances
Substance type : Mono-constituent
Name Product identifier % GHS-US classification
Citric Acid, Anhydrous (CAS No) 77-92-9 100 Eye Irrit. 2A, H319
(Main constituent)

04/04/2017 EN (English US) Page 1

Citric Acid, Anhydrous
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Full text of hazard classes and H-statements : see section 16

3.2. Mixtures
Not applicable
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed
by warm water rinse.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : May cause respiratory irritation.
Symptoms/injuries after skin contact : Slight irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
Symptoms/injuries after ingestion : Nausea.
Chronic symptoms : Affection/discolouration of the teeth.
4.3. Indication of any immediate medical attention and special treatment needed
None.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Not flammable.
Explosion hazard : Not applicable.
Reactivity : None.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away
from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.

04/04/2017 EN (English US) 2/6

Citric Acid, Anhydrous
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation
of vapor.
Hygiene measures : Wash exposed skin thoroughly after handling.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : incompatible
materials. Keep container closed when not in use.
Incompatible products : Strong bases. Strong oxidizers.
Incompatible materials : Sources of ignition. Direct sunlight.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
No additional information available

8.2. Exposure controls

Appropriate engineering controls : Emergency eye wash fountains should be available in the immediate vicinity of any potential
exposure.
Personal protective equipment : Gloves. Safety glasses.

Hand protection : Wear protective gloves.

Eye protection : Chemical goggles or safety glasses.
Respiratory protection : Respiratory protection not required in normal conditions.
Other information : Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Solid
Appearance : White powder or lumps.
Color : white
Odor : Odorless
Odor threshold : No data available
pH : 1.7 10% solution
Melting point : 153 °C
Freezing point : No data available
Boiling point : 175 °C
Flash point : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Non flammable.
Vapor pressure : No data available
Relative vapor density at 20 °C : No data available
Relative density : No data available
Specific gravity / density : 1.665 g/cm³
Molecular mass : 192.12 g/mol
Solubility : Soluble in water. Soluble in ethanol. Soluble in ether.
Water: 59.2 %
Log Pow : No data available
Auto-ignition temperature : No data available

04/04/2017 EN (English US) 3/6

Citric Acid, Anhydrous
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Decomposition temperature : 175 °C

Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : No data available.
Oxidizing properties : None.
9.2. Other information
No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
None.
10.2. Chemical stability
Not established.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Likely routes of exposure : Inhalation; Skin and eye contact; Ingestion

Acute toxicity : Not classified
Citric Acid, Anhydrous (77-92-9)
LD50 oral rat 5400 mg/kg
ATE US (oral) 5400.000 mg/kg body weight
Skin corrosion/irritation : Not classified
pH: 1.7 10% solution
Serious eye damage/irritation : Causes serious eye irritation.
pH: 1.7 10% solution
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Based on available data, the classification criteria are not met
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Based on available data, the classification criteria are not met
Specific target organ toxicity – single exposure : Not classified
Specific target organ toxicity – repeated : Not classified
exposure
Aspiration hazard : Not classified

Potential Adverse human health effects and : Based on available data, the classification criteria are not met.
symptoms
Symptoms/injuries after inhalation : May cause respiratory irritation.
Symptoms/injuries after skin contact : Slight irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.
Symptoms/injuries after ingestion : Nausea.

04/04/2017 EN (English US) 4/6

Citric Acid, Anhydrous
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Chronic symptoms : Affection/discolouration of the teeth.

SECTION 12: Ecological information

12.1. Toxicity
Citric Acid, Anhydrous (77-92-9)
LC50 fish 1 440 mg/l
EC50 Daphnia 1 1534 mg/l

12.2. Persistence and degradability

Citric Acid, Anhydrous (77-92-9)
Persistence and degradability Not established.

12.3. Bioaccumulative potential

Citric Acid, Anhydrous (77-92-9)
Bioaccumulative potential Not established.

12.4. Mobility in soil

No additional information available

12.5. Other adverse effects

Other information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.
Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information

Department of Transportation (DOT)
In accordance with DOT
Not regulated

SECTION 15: Regulatory information

15.1. US Federal regulations
Citric Acid, Anhydrous (77-92-9)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic
Substances Control Act (TSCA) inventory

This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40
CFR §372.38(a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986
and 40 CFR Part 372.

15.2. International regulations

CANADA
Citric Acid, Anhydrous (77-92-9)
WHMIS Classification Class D Division 2 Subdivision B - Toxic material causing other toxic effects

EU-Regulations
No additional information available

National regulations
No additional information available

15.3. US State regulations

California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer,
developmental and/or reproductive harm
04/04/2017 EN (English US) 5/6
Citric Acid, Anhydrous
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 16: Other information

Revision date : 04/04/2017
Other information : None.
Full text of H-phrases: see section 16:
------ H319 Causes serious eye irritation
NFPA health hazard : 1 - Materials that, under emergency conditions, can cause
significant irritation.
NFPA fire hazard : 0 - Materials that will not burn under typical dire conditions,
including intrinsically noncombustible materials such as
concrete, stone, and sand.
NFPA reactivity : 0 - Material that in themselves are normally stable, even
under fire conditions.

HMIS III Rating

Health : 1 Slight Hazard - Irritation or minor reversible injury possible
Flammability : 0 Minimal Hazard - Materials that will not burn
Physical : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT
react with water, polymerize, decompose, condense, or self-react. Non-Explosives.
Personal protection : B
B - Safety glasses, Gloves

SDS US LabChem

Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this
SDS. The user must determine suitability of this information for his application.

04/04/2017 EN (English US) 6/6

 341 Christian Street, Oxford, CT 06478 USA
Tel: (203) 267-6061 Fax: (203) 267-6065
www.naturalsourcing.com [email protected]

MSDS
MATERIAL SAFETY DATA SHEET

ORGANIC VIRGIN COCONUT OIL

1. PRODUCT NAME AND COMPANY IDENTIFICATION

Product Name: VIRGIN COCONUT OIL --ORGANIC
Product Use: Personal Care Formulations
Company Name: Natural Sourcing
Company Address: 341 Christian Street, Oxford, CT 06478, USA
Date Issued: 10/28/2015
Emergency Telephone Number: Chemtrec Tel: (800) 262-8200

2. COMPOSITION/INGREDIENT INFORMATION
Ingredients:
Vegetable Oil Triglycerides 100% FROM COCONUT
Hazardous Components: None
CAS #: 8001-31-8

3. HAZARDS IDENTIFICATION
Routes of Entry
Eye Contact: No known hazard
May cause irritation in sensitive individuals with prolonged
Skin Contact:
exposure
Ingestion: Food Grade
Inhalation: Inhalation of fine mist may effect respiratory system

4. FIRST AID MEASURES

Flush with plenty of water or eye wash solution for 15 minutes.
Eyes:
Get medical attention if irritation persists.
Skin: Wash with soap and flush with plenty of water
Ingestion: Contact Physician if discomfort is encountered.
Inhalation: Remove to fresh air and seek medical attention
Inhalation of product may aggravate existing chronic respiratory
Medical Conditions Generally
problems such asthma, emphysema or bronchitis. Skin contact
Aggravated by Exposure:
may aggravate existing skin disease.

5. FIRE FIGHTING MEASURES

Flash Point (Method Used): 180˚C (direct ignition)
Flammable Limits
LEL: Not established
UEL: Not established
Extinguishing Media: Dry Chemical, Carbon Dioxide, Foam

Page 1 of 4
 Cool containers exposed to flame with water. Limit the spread of
Special Firefighting Procedures: oil. Treat as an oil (edible fat) fire. Use air supplied equipment
for fighting interior fires. DO NOT USE WATER TO EXTINGUISH.
As with all unsaturated fats and oils, some porous materials
such as rags, paper, insulation or clay when wetted with this
Unusual Fire & Explosion Hazards: product may undergo spontaneous combustion. Keep such
wetted materials well ventilated to prevent possible heat build
up.
Hazardous Decomposition Materials: CO, CO2

6. ACCIDENTAL RELEASE MEASURES (STEPS FOR SPILLS)

Absorb onto an inert, absorbent substrate and sweep up. Wash
Methods for Cleaning Up: area with soap and water. Floors will be slippery; take
precautions.

7. HANDLING AND STORAGE

Handling
Avoid direct or prolonged contact with skin and eyes. Avoid
Safe Handling:
breathing oil mist.

Storage
Requirements for Storage Areas and
Store in an area that is cool, dry, and well-ventilated.
Containers:

8. EXPOSURE CONTROL/PERSONAL PROTECTION

These recommendations provide general guidance for handling
this product. Because specific work environments and
material handling practices vary, safety procedures should be
developed for each intended application. While developing
Introductory Remarks:
safe handling procedures, do not overlook the need to clean
equipment and piping systems for maintenance and repairs.
Waste resulting from these procedures should be handled in
accordance to the section entitled Disposal Considerations.
Engineering controls are usually not necessary if good hygiene
practices are strictly followed. Respiratory protection is
generally not required during normal operations. Wear the
Exposures Guidelines:
following to prevent skin contact: work pants, long sleeve
work shirt, and work gloves. Where there is the danger of eye
contact, wear splash proof goggles.
Threshold Limit Value: Liquid: None; Oil Mist: 10 mg/m; total particulate.
Personal hygiene is an important work practice exposure
control measure and the following general measures should be
taken when working with or handling this material:

(1) Do not store, use, and/or consume foods, beverages,

Work Practice Controls: tobacco products, or cosmetics in areas where this material is
stored.
(2) Wash hands and face carefully before eating, drinking,
using tobacco, applying cosmetics, or using the toilet.
(3) Wash exposed skin promptly to remove accidental splashes
or contact with this material.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid oil

Page 2 of 4
Color: Creamy white
Odor: Characteristic, bland, coconut
Vapor Pressure (mm Hg.): N/A
Vapor Density (AIR = 1): >1
Boiling Point: N/A
Melting Point: 24-26°C
Cloud Point: 21-23°C
Specific Gravity (H2O = 1): 0.89390
Saponification Value: 255-263
pH: 5-8
Solubility in Water: Insoluble
Water Reactive: No

10. STABILITY AND REACTIVITY

This material is stable under normal conditions described in
Stability:
that section.
None
Incompatibility (Materials to Avoid):

Conditions to Avoid: None

Hazardous Decomposition or
CO, CO2
Byproducts:
Hazardous Polymerization: Will Not Occur

11. TOXICOLOGICAL INFORMATION

No Information

12. ECOLOGICAL INFORMATION

No information

13. DISPOSAL CONSIDERATIONS

Chemical additions, processing or otherwise altering this
material may make the waste management information
present in this MSDS incomplete, inaccurate or otherwise
inappropriate. Please be advised that state and local
Waste Disposal Methods:
requirements for waste disposal may be more restrictive or
otherwise different from federal laws and regulations. Consult
state and local regulations regarding the proper disposal of
this material.

14. TRANSPORT INFORMATION

This material is not considered hazardous for transport.
DOT Classification: Not Regulated - Not Dangerous Goods
ADR/RID: Not Regulated - Not Dangerous Goods
IATA: Not Regulated - Not Dangerous Goods
IMDG: Not Regulated - Not Dangerous Goods

15. REGULATORY INFORMATION

No information

Page 3 of 4
16. ADDITIONAL INFORMATION
This information is provided for documentation purposes only.
This product is not considered hazardous.

The complete range of conditions or methods of use are beyond our control therefore we do not
assume any responsibility and expressly disclaim any liability for any use of this product. Information
contained herein is believed to be true and accurate however, all statements or suggestions are made
without warranty, expressed or implied, regarding accuracy of the information, the hazards connected
with the use of the material or the results to be obtained from the use thereof. Compliance with all
applicable federal, state, and local laws and local regulations remains the responsibility of the user.

This safety sheet cannot cover all possible situations which the user may experience during
processing. Each aspect of your operation should be examined to determine if, or where, additional
precautions may be necessary. All health and safety information contained in this bulletin should be
provided to your employees or customers.

Page 4 of 4
 Material Safety Data Sheet (MSDS) – Asam Sulfat – H2SO4
Bagian 1. Identifikasi Bagian 7. Penanganan dan Penyimpanan
Nomor Kesehatan: 3 Simpan di tempat yang dingin, kering, dan
C2784
Produk: Kemungkinan terbakar 0 mempunyai ventilasi yang baik. Letakkan jauh di
Asam sulfat 93% Reaktivitas 0 material yang tidak cocok. Jangan lupa mencuci
Nama Produk: Persentase tangan setelah memegang.
kekentalan 2

Merek Dagang Bagian 8. Pengontrolan & Perlindungan Diri

Formula: H2SO4 Alat Bantu Pernapasan: tidak diperlukan
RTECS: WS5600000 Sarung tangan
Perlindungan
Mekanik: yang disetujui
tangan:
C.A.S CAS# 7664-93-9 Ventilasi: NIOSH
Proteksi Kacamata dan
Exhaust Lokal: mata: pelindung muka
Bagian 2. Komposisi Perlengkapan Proteksi lainnya: Gunakan pakaian yang
tepat untuk melindungi kulit.
Sara Batas
Komponen Nomor CAS % Dim
313 penggunaan: Bagian 9. Data Fisik dan Kimiawi
Informasi
Gravitasi yang
Water, Titik cair: tidak 1.84
Tidak digunakan
Deionized ASTM CAS# 7732-18-5 ~7% V/V tersedia
dimuat Informasi Informasi
Type II Persentase
Titik Didih: tidak tidak
Penguapan:
tersedia tersedia
OSHA TWA Tekanan 1mm Hg @ Tingkat
Sulfuric Acid 1 mg/mƒ, <1
CAS# 7664-93-9 ~93% V/V uap: 145.8°C Penguapan:
93% ACGIH STEL Kepadatan <0.3 @ Standar
3 ppm Uap: 25°C Penguapan:
Temperatur
Kelarutan Dapat
Bagian 3. Pengenalan Bahaya menyala Tidak ada
dalam Air: Larut
Dapat menyebabkan iritasi dan terbakar. Berbahaya jika otomatis:
teroles. Hindari uap ataupun asapnya. Gunakan dlm ventilasi Cairan
Jumlah
cukup. Hindari kontak dgn mata, kulit atau baju. Cuci tangan Bentuk bening
minimun di Tidak Ada
dengan bersih setelah memegang dan simpan rapat-rapat. dan bau: tidak
udara terbuka:
berbau
Bagian 4. Tata Cara Pertolongan Pertama informasi Jumlah
Titik
Pertolongan Pertama: Panggil dokter. tidak maksimum di Tidak ada
menyala:
tersedia udara terbuka:
KULIT: bila terjadi kontak, segera basuh kulit dengan air paling
sedikit 15 menit saat membersihkan pakaian dan sepatu yang Bagian 10. Stabilitas dan Reaktivitas
terkontaminasi. Bersihkan secara menyeluruh pakaian dan
Kondisi yang harus dihindari:
sepatu sebelum digunakan lagi.
Stabilitas: Stabil Hindari sentuhan dengan material
MATA: basuh mata dg air selama paling sedikit 15 menit, buka yang tidak cocok.
tutup pelupuk mata beberapa kali. Cari pertolongan medis. Material yang dihindari:
PERNAPASAN: Segera cari udara segar. Pengoksidasi, logam, bases, amines.
Jika tidak bisa bernapas, berikan pernapasan buatan, jika Produk Dekomposisi Berbahaya:
masih sulit bernapas, berikan oksigen. Asap beracun: Sulfur Oksida
TERTELAN: Berikan beberapa gelas susu atau air. Akan terjadi Bahaya Polimerisasi: Tidak akan terjadi
beberapa kali muntah, jangan memasukkan apapun kedalam Kondisi yang harus dihindari: Tidak diketahui
mulut orang yang tidak sadar. Bagian 11. Informasi Tambahan
Bagian 5. Tata Cara Penanggulangan Kebakaran Kondisi yang paling buruk:
• Karat !
Tipe Dicurigai sebagai penyebab kanker.
Semua jenis pemadam dapat digunakan •
Pemadam Apabila terpapar dapat berakibat fatal.
untuk memadamkan api. •
kebakaran:
• Bersifat menghancurkan jaringan tubuh.
Bahaya Dekomposisi pada kondisi panas
ledakan: menghasilkan banyak uap beracun. Akut: rasa terbakar hebat pada kulit, mata atau
Bereaksi dgn air, melepaskan panas dan saluran nafas, saluran pencernaan; kejang²;
Prosedur oksigen; jadi bila digunakan akan luber. edema saluran nafas dan paru².
terhadap api: Gunakan pakaian pelindung dan alat bantu Akibat kronis : infeksi kulit, kerusakan pada mata,
pernapasan. saluran pencernaan dan saluran pernafasan.
Klasifikasi DOT : Sulfuric Acid, 8, UN1830, PG II
Bagian 6. Tata Cara Penanggulangan Tumpahan
Regulasi DOT dapat berubah dari waktu ke waktu.
Serap tumpahan dengan lap basah, kemudian letakkan dalam Silahkan konsultasikan dg versi terbaru dr kondisi yg ada
tempat sampah kimia. Atau bisa juga dinetralkan dengan basa
Revisi Tanggal data masuk: Disetujui oleh:
lemah.
No:0 9/1/2006 WPF
Informasi yang terkandung disini dianggap dan akurat dan dibuat untuk kepentingan pertimbangan dan pemikiran pengguna. Tidak ada garansi yang dapat
diutarakan atau dinyatakan atas kelengkapan atupun keakuratan informasi ini, semuanya didapat dari Science Stuff, Inc. atau dari tempat lain. Pengguna materi
ini seharusnya melengkapi dirinya dengan investigasi pribadi dan informasi medis terkini, agar material ini dapat ditangani dengan aman.
Sumber: Science Stuff, Inc
http://www.sciencestuff.com/msds/C2784.html

Sept 2009 - From: www.itokindo.org (free pdf - Manajemen Modern dan Kesehatan Masyarakat)
 Material Safety Data Sheet (MSDS)
Bagian 1 – IDENTITAS BAHAN DAN PERUSAHAAN
(Chemical Product and Company Identification)

NAMA PRODUK NPK Pelangi (Pupuk Majemuk Peracikan Kering)

/ NAMA DAGANG

SYNONYM MSDS ini diterapkan pada semua

produk NPK Pelangi dibuat dari
peracikan pupuk kering yang
berisi kombinasi dari Ammonium
phosphat (MAP dan DAP) ,
Batuan Phosphat, Urea dan
Potash.

NAMA KIMIA Tidak diterapkan, merupakan produk racikan REVISI KE 1.0

MSDS disiapkan oleh Dept.

Keselamatan Kesehatan Kerja
FAMILY KIMIA Garam Ammonium dan Lingkungan Hidup pada 4
maret 2008.

FORMULA KIMIA Tidak diterapkan, merupakan produk racikan 24 JAM NOMER TELEPON
EMERGENCY
Transport: +62 548 41204
PENGGUNAAN digunakan di Industri pertanian pangan Medical: +62 548 4118
sebagai pupuk majemuk.

DIBUAT OLEH : DIPASOK OLEH :

PT. Pupuk Kalimantan Timur PT. Pupuk Kalimantan Timur
Jl James Simanjuntak 1, Jl James Simanjuntak 1,
Bontang 75313, Kalimantan timur, Bontang 75313, Kalimantan timur,
Indonesia. Indonesia.
Telepon : (0548) 41202, 41203 Telepon : (0548) 41202, 41203
Faks : (0548) 41616, 41626. Faks : (0548) 41616, 41626.

Halaman 1 dari 8
 NPK Pelangi Halaman :2 dari 8

Bagian 2 – KOMPOSISI BAHAN.

(Hazardous Ingredients)
Exposure Limits (ACGIH)
TLV-TWA TLV-TWA
NAMA BAHAN CAS # % Berat
mg/m3 ppm

Monoammonium phosphate 7722-76-1 ----

--- 0-70

Diammonium phosphate 7783-28-0 ---- 0-70

Potassium chloride 7447-40-7 ---- 0-30

Urea 57-13-6 ---- 0-70
Rock Phosphate 1306-05-04 ---- 0-70
Kieserite 14567-64-7 ---- 0-5
Dolomite 16389-88-1 ----- 0-5
ACGIH TLV notasi:
---- tidak terdapat TLV pada bahan ini

DATA TOXICOLOGI Monoammonium Phosphate (MAP) TFI Test Program:

PADA ISI BAHAN Oral (tikus) LD50, Prosedur OECD 425: >2,000 mg/kg. MAP tidak termasuk racun akut pada rute oral.
Dermal (tikus) LD50, , Prosedur OECD 402: >5,000 mg/kg. MAP tidak termasuk racun akut pada
route dermal.
Dibasic Ammonium phosphate (DAP)
TFI Test , OECD 402 toksisitas dermal akut: LD50: > 5,000 mg/kg tikus, tidak termasuk akut.

TFI Test, OECD 425 toksisitas oral akut: LD50: > 2,000 mg/kg rat, tidak termasuk racun akut.
TFI Test, OECD 201 Alga hijau akut toxicity test, tidak teramati sampai 97.1 mg/L (konsentrasi
Tertinggi) ; merangsang pertumbuhan pada 6.4 mg/L dan lebih tinggi.
Ecotoxicity:
Toksisitas akut pada Ikan, 96 jam LC50, ikan pelangi air tawar, prosedur OECD 203: >85.9 mg/L.
Toksisitas akut MAP pada ikan tosisitasnya rendah.

Potash TFI Test:

Toksisitas akut oral : 2,600 mg/kg tikus;
Ecotoxicity:
Toksisitas akut pada Ikan, species campuran 96 jam LC50 : 2,010 mg/L
Toksisitas akut pada invertibrates, Daphnia 48 jam TLm 337mg/L

TFI Test – Urea 46-0-0 :

Toksisitas akut oral : 14300 mg/kg tikus, 510 mg/kg ternak
Toksisitas kronis oral , NOAL : 20250 mg/kg tikus

Ecotoxicity
Toksisitas akut pada Ikan, Barilius Barna LC50, 96 jam >9.100 mg/L
Toksisitas akut pada vertebrata, Daphnia EC 50 (24 jam) >10.000 mg/l
Toksisitas akut pada burung, merpati, LDLo = 16.000 mg/kg subcutaneos.
Toksisitas pada Algae, Scenedesmus quadricauda, pembelahan sel terhambat
TT (192)jam > 10.000 Mg/L
NPK Pelangi Halaman :3 dari 8

Bagian 3 – IDENTIFIKASI BAHAYA

(Hazards Identification)

EFFEK POTENSI Produk ini dapat menyebabkan iritasi mata dan kulit pada kontak yang berulang
BAHAYA AKUT atau jangka panjang disebabkan oleh tindakan mekanis atau debu yang terserap
kulit. Paparan debu berlebih yang terhisap dapat menyebabkan iritasi saluran yang
berhubungan dengan pernapasan. Bila masuk di pencernaan dapat menyebabkan
iritasi di saluran gastrointestinal, yang yang ditandai dengan rasa terbakar dan
diarrhea.

EFFEK POTENSI CARCINOGENIC EFFECTS: NONE by ACGIH, EPA, IARC, NTP, OSHA.
BAHAYA KRONIS MUTAGENIC EFFECTS: NONE by ACGIH, EPA, IARC, NTP, OSHA.
TERATOGENIC EFFECTS: NONE by ACGIH, EPA, IARC, NTP, OSHA.

Bagian 4 – TINDAKAN P3K

( First Aid Measures)

Dapat menyebabkan iritasi mata. Periksa dan lepaskan setiap lensa kontak.
KONTAK MATA Dengan segera bilaslah mata dengan air mengalir untuk sedikitnya 15 menit,
kelopak mata dijaga membuka. Hubungi dokter jika gejala iritasi tidak hilang.

Dapat menyebabkan iritasi kulit. Cuci kulit yang terkena dengan sabun dan air.
KONTAK KULIT MINOR Tutuplah kulit yang teriritasi dengan lotion kulit yang kualitas baik. Jika iritasi
tidak hilang, hubungi dokter. Cuci pakaian yang terkena sebelum dipakai
kembali.

KONTAK KULIT LUAS

Tidak ada informasi tambahan.

TERHIRUP MINOR Penghisapan yang berulang atau jangka panjang terhadap debunya dapat
berakibat pada iritasi saluran pernapasan. Kendurkan pakaian ketat di sekitar
leher dan pinggang..Biarkan korban untuk beristirahat di suatu tempat yang
berventilasi baik. Hubungi dokter bila gejala tidak hilang.

TERHIRUP PARAH Di dalam situasi darurat gunakan perlindungan pernapasan yang tepat untuk
mengungsikan korban yang terkena ke tempat aman secepat mungkin.
Kendurkan pakaian ketat di sekitar leher dan pinggang orang itu.
Oksigen mungkin bisa diberikan jika sulit bernafas. Jika korban tidak bernafas,
lakukan napas buatan. Segera panggil bantuan medis.

Jangan dirangsang untuk muntah. Segera angkut korban ketempat fasilitas

TERTELAN SEDIKIT
tindakan darurat. Pengeluaran dari perut harus dilakukan oleh personil medis.
Jika memungkinkan, berikan tidak lebih daripada 1 gelas susu atau air (atau
1/2 gelas untuk anak-anak) untuk membilas mulut dan kerongkongan dan
mengencerkan isi perut.
Jika terjadi muntah secara spontan, turunkan kepala sehingga muntahan itu
tidak akan masuk kembali ke mulut dan kerongkongan. Bilas mulut dengan air

TERTELAN BANYAK Tidak ada informasi tambahan.

NPK Pelangi Halaman :4 dari 8

Bagian 5 – TINDAKAN PENANGGULANGAN KEBAKARAN & PELEDAKAN

(Fire and Explosion Data)

PRODUK INI Tidak dapat terbakar.

AUTO-IGNITION
TEMPERATURE Tidak dapat diterapkan
Tidak dapat diterapkan
FLASH POINT
Tidak dapat diterapkan
FLAMMABILITY LIMITS
Material ini tidak akan terbakar tetapi mengalami dekomposisi thermal pada
HASIL PEMBAKARAN temperatur yang tinggi akan mengeluarkan gas-gas mudah menyala dan
beracun: amoniak, oksida nitrogen, dan oksida-oksida belerang,
BAHAYAKEBAKARAN Tidak ada
DENGAN ADANYA
BERBAGAI SUBSTANSI
BAHAYA PELEDAKAN Bahan ini tidak dapat meledak
DENGAN ADANYA
BERBAGAI SUBSTANSI
Material tidak akan terbakar. mengalami dekomposisi thermal pada temperatur
MEDIA PEMADAM API yang tinggi akan mengeluarkan gas-gas mudah menyala dan beracun:
Pemadaman penggunaan media yang sesuai dengan bahan di lingkungannya..
Petugas pemadam kebakaran perlu memakai alat pernapasan brething
Apparatus (SCBA).

Tidak mudah menyala. Gas-gas Flammable/toxic akanterbentuk pada suhu

KETERANGAN yang meninggi (> 190 °C) disebabkan oleh dekomposisi panas (amoniak,
KHUSUS RESIKO
oksida-oksida belerang, oksida nitrogen, oksida-oksida fosfor). Suatu alat
KEBAKARAN
respirator dengan pasokan udara (SCBA) harus digunakan untuk menghindari
terhisap uap-uap yang beracun.

KETERANGAN Tidak ada informasi tambahan.

KHUSUS RESIKO
PELEDAKAN

Bagian 6 – TINDAKAN MENGATASI KEBOCORAN DAN TUMPAHAN

(Accidental Release Measures)

TUMPAHAN SEDIKIT Ambil bahan yang tertumpah dan taruh dalam suatu wadah khusus untuk
digunakan kembali atau dibuang.

Cegah tumpahan bertambah dan lakukan dengan hati-hati. Hindarkan tumpahan

TUMPAHAN BANYAK memasuki saluran pembuangan air, sumber air, sumur-sumur, dll. Produk akan
mempercapat pertumbuhan ganggang dan mungkin menurunkan tingkat kualitas
air dan rasa.
NPK Pelangi Halaman :5 dari 8

Bagian 7 – PENYIMPANAN DAN PENANGANAN BAHAN

(Handling and Storage)

PERHATIAN Hindari kontak dengan kulit dan mata. Setelah penanganan, selalu mencuci tangan-
tangan secara menyeluruh dengan sabun dan air. Jangan menghirup debu.
Singkirkan dari makanan, minuman dan makanan ternak. Jauhkan dari jangkauan
anak-anak.

PENYIMPANAN
Simpan di suatu tempat yang kering, yang berventilasi baik dan dingin.

Bagian 8 - PENGENDALIAN PEMAPARAN DAN ALAT PELINDUNG DIRI

(Exposure Controls/Personal Protection)

KONTROL
Gunakan seperti proses terlampir, ventilasi exhaust lokal, atau kendali teknik lain
ENGINEERING
untuk mejaga dibawah nilai ambang batas yang diijinkan.
Jika dalam pemakaian menghasilkan debu, gunakan ventilasi untuk menjaga zat-
zat pencemar yang naik di udara di bawah ambang batas paparan.

PERALATAN Pemilihan peralatan pelindung perorangan bervariasi, tergantung atas kondisi

PELINDUNG DIRI penggunaan. Gunakan pelindung pernapasan yang sesuai untuk dust/mist ketika
ventilasi tidak cukup. Masker debu dianjurkan digunakan. Di mana kontak kulit dan
mata akan terjadi sebagai akibat paparan berkala yang singkat, gunakan pakaian
berlengan, coveralls, sarung tangan tahan bahan kimia, dan kaca mata pengaman
berpenutup samping.

PELINDUNG DIRI BILA Tidak ada informasi tambahan.

ADA TUMPAHAN
BESAR
Fed OSHA PEL Permissible Exposure Limit:: 15 mg/m3 for Particulates Not
AMBANG PAPARAN Otherwise Regulated (nuisance particulates) as total dust.
Surat Edaran Menteri Tenaga Kerja Republik Indonesia No SE-01/MEN/1997
Tentang Nilai Batas Faktor Kimia di Udara Lingkungan Kerja : 10 mg/m3 Partikulat
selama jam kerja, 8 jam per hari atau 40 jam per minggu.

Bagian 9 – SIFAT FISIKA DAN KIMIA

(Physical and Chemical Properties)

PENAMPAKAN Padat (Racikan dari kristal granul)

FISIK
BERAT MOLEKUL Tidak diterapkan WARNA Putih dan/ atau coklat dan/atau
abu-abu dan/atau merah
pH (10% larutan) 5 - 8 BAU Tidak berbau
TITIK LELEH Tidak diterapkan RASA Asam (ringan)
Temperatur kritis Tidak tersedia Volatility Tidak diterapkan
SPECIFIC GRAVITY g/cc <1 (Water = 1) SOLUBILITY Mudah larut dalam air.
BULK DENSITY Tergantung Formulanya DISPERSION Lihat kelarutan di air.
kg/m 3 ; lbs/ft3 PROPERTIES
VAPOR PRESSURE Tidak diterapkan. WATER/OIL DIST. Not available.

VAPOR DENSITY Tidak diterapkan

NPK Pelangi Halaman :6 dari 8

Bagian 10 – STABILITAS DAN REAKTIFITAS BAHAN

(Stability and Reactivity Data)

STABILITAS Produk dianggap stabil

TEMPERATURE Tidak tersedia

KETIDAKSTABILAN

KONDISI Tidak ada catatan tambahan

KETIDAKSTABILAN

KETIDAKSTABILAN
DENGAN SUBSTANSI Sedikit reactive dengan oxidizing agents, metals, alkalis, and kelembaban..
LAIN
Korosif terhadap aluminum, seng dan tembaga.
Sedikit corrosive dengan baja, dan 304 stainless steel.
CORROSIVITAS
Tidak-corrosive terhadap 316 stainless steel.

CATATAN KHUSUS Hindari kontak dengan embun. Higroskopik. Bahan ini akan menyerap air. Hidrolisis
UNTUK REACTIVITY bahan ini pelan-pelan akan menghasilkan asam bersifat merusak logam.
Bahan ini tidak cocok terhadap material campuran tembaga. Bersifat korosif kepada
CATATAN KHUSUS
UNTUK CORROSIVITY
kuningan. Bersifat korosif kepada logam dan campuran logam yang mengandung
besi.

Bagian 11 – INFORMASI TOKSIKOLOGI

(Toxicological Information)

RUTE KERACUNAN Tertelan, terhirup

TOXICITY PADA HEWAN Lihat Bagian II.

Dalam air material ini akan melepaskan ion ammonium. Amoniak adalah bahan
CATATAN KHUSUS beracun untuk ikan. Hindari tercecer atau masuk ke anak sungai/air.
UNTUK TOXISITAS Mungkin berbahaya terhadap ternak dan kehidupan liar jika termakan. Bersihkan
PADA BINATANG
semua material yang tumpah, terutama terjadi pada saat pemuatan pupuk curah
dengan peralatan.
Produk itu sendiri dan produk-produk turunan nya tidaklah berbahaya di bawah
kondisi normal dalam kehati-hatian dan penggunaan yang bertanggung jawab.
.

EFFEK LAIN PADA Data base kita tidak ada tambahan mengomentari ketoksisan dari produk ini
MANUSIA

Bagian 12 – INFORMASI EKOLOGI

(Ecological Information)

ECOTOXICITY Keracunan rendah pada manusia atau binatang pada penggunaan normal. Mungkin
dapat berbahaya pada binatang dan ternak bila tertelan. Bersihkan ceceran, khususnya
ketika pemuatan pupuk untuk menghindari paparan terhadap binatang.
Produk itu sendiri tidaklah berbahaya di bawah kondisi normal dalam kehati-hatian
dan penggunaan yang bertanggung jawab. Dalam air akan melepaskan ion
ammonium. Amoniak adalah beracun untuk ikan. Hindari tercecer, pelepasan atau
masuk kepada anak sungai/air.
Material ini tidak termasuk dalam daftar pencemar air laut.
NPK Pelangi Halaman :7 dari 8

BOD and COD Tidak tersedia.

DEGRADASI DARI Nitrogen oxides (NO,NO2 ...), sulfur oxides (SO2, SO3 ...), phosphates, inorganic mineral salts
PRODUK and oxides.

TOXICITY PRODUK
YANG TERGRADASI Produk dari biodegradsi ini tidak berbahaya pada kondisi normal.

CATATAN KHUSUS Produk ini akan mempercepat pertumbuhan algae sehingga dapat menurunkan kualitas air dan
PADA PRODUK YANG rasanya.
TERGRADASI

Bagian 13 – PEMBUANGAN LIMBAH

(Disposal Considerations)

Kumpulkan dan tempatkan di suatu kontainer yang pantas untuk penggunaan atau
PEMBUANGAN LIMBAH
ATAU DAUR ULANG
pembuangan yang diharapkan. Pastikan pembuangan mematuhi persyaratan-
persyaratan pemerintah dan peraturan-peraturan lokal.

Bagian 14 – INFORMASI UNTUK PENGANGKUTAN BAHAN.

(Transport Information)

KLASSIFIKASI
Tidak diatur di bawah TDG (Canada) atau D.O.T. (U.S.A.).
Tidak termasuk dalam-persyaratan dari Peraturan Bahan Bahaya 49 CFR Parts
171-180 untuk pengangkutan.

KETENTUAN KHUSUS
UNTUK TRANSPORT Tidak ada.

Bagian 15 – INFORMASI PERUNDANG-UNDANGAN

(Other Regulatory Information)

INFO REGULASI Surat Edaran Menteri Tenaga Kerja Republik Indonesia No SE-01/MEN/1997 Tentang
Nilai Batas Faktor Kimia di Udara Lingkungan Kerja
TSCA (Toxic Substance Control Act): This product is listed on the TSCA Inventory.
CERCLA/SUPERFUND, 40 CFR 117,302: This product contains no Reportable Quantity
(RQ) Substances.
Produk ini tidak dipertimbangkan sebagai pollutan dalam Baku Mutu Air Bersih.
This material contains the following chemicals subject to the reporting requirements of
SARA 313 and 40 CFR 372:
Aqueous ammonia from water dissociable ammonium ions, 10% of which is reportable as
CAS#7783-20-2 and as CAS#7722-76-1 and/or 7783-28-0.

CLASSIFIKASI HCS (U.S.A.) HCS CLASS: Irritating substance.

LAINNYA DSCL (EEC) Not available.
NPK Pelangi Halaman :8 dari 8

Bagian 16 – INFORMASI LAIN YANG DIPERLUKAN

(Other Information)

REFERENSI
-American Conference of Governmental Industrial Hygienists, Threshold Limit Values for
Chemical Substances, 2006.
-NFPA 704, National Fire Codes Online, National Fire Protection Association, current edition
at time of MSDS preparation.
-Corrosion Data Survey, Sixth Edition, 1985, National Association of Corrosion
Engineers
-TOMES® System: Heitland G & Hurlbut KM (Eds) (electronic version): MICROMEDEX,
Greenwood Village, Colorado, USA. Available at: http://csi.micromedex.com (2006).
The TOMES® System includes MEDITEXT® Medical Management; HAZARDTEXT®
Hazard Management; INFOTEXT® Documents; ERG2000 Emergency Response
Guidebook Documents; REPROTEXT®: Heitland G & Hurlbut KM (Eds); CHRIS Hazardous
Chemical Data: U.S. Department of Transportation, U.S. Coast Guard, Washington, D.C.
(2006); HSDB: Hazardous Substances Data Bank. National Library of Medicine, Bethesda,
Maryland (2006); IRIS: Integrated Risk Information System. U.S. Environmental Protection
Agency, Washington, D.C. (2006); NIOSH: Pocket Guide to Chemical Hazards. National
Institute for Occupational Safety and Health, Cincinnati, Ohio (2006); OHM/TADS: Oil and
Hazardous Materials Technical Assistance Data System. U.S. Environmental Protection
Agency, Washington, D.C. (2006); REPROTOX®: Scialli A.R. Georgetown University Medical
Center and Reproductive Toxicology Center, Columbia Hospital for Women Medical Center,
Washington, D.C. (2006); RTECS®: Registry of Toxic Effects of Chemical Substances.
National Institute for Occupational Safety and Health, Cincinnati, Ohio (2006); and
SHEPARDS: Shepard T.H.: Shepard's Catalog of Teratogenic Agents (2006).
-The Fertilizer Institute Product Testing Program Results, March 2003

UNTUK INFORMASI PT. Pupuk Kalimantan Timur

LEBIH LANJUT TENTANG
PRODUK INI, HUBUNGI Jl James Simanjuntak 1,
Bontang 75313, Kalimantan timur,
Indonesia.
Telepon : (0548) 41202, 41203
Faks : (0548) 41616, 41626.

CATATAN :

Konsumen menerima semua resiko yang berhubungan dengan pemakaian produk ini. Konsumen
menerima semua tanggung jawab untuk menjamin bahwa produk digunakan dengan cara yang
aman yang sesuai dengan prosedur, peraturan dan kebijakan lingkungan, kesehatan dan
keselamatan yang berlaku. PT PKT tidak bertanggung jawab atas informasi yang tersedia di lembar
ini, termasuk untuk setiap kerusakan dan kecelakaan yang disebabkan oleh penggunaan yang tak
semestinya. PT. PKT tidak menjamin kecocokan produk untuk penggunaan yang tidak semestinya
dan tidak bertanggung jawab atas kecelakaan atau kerusakan yang secara langsung atau tidak
langsung berhubungan dengan penggunaan produk ini.
Segala informasi yang ada di lembar ini dikembangkan dari berbagai sumber yang akurat dan
dipercayai oleh PT. PKT dan disusun berdasarkan opini dan fakta fakta yang ada selama proses
penyusunannya.
 Methanol
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 07/03/2013 Revision date: 12/12/2017 Supersedes: 12/12/2017 Version: 1.3

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product form : Substance
Substance name : Methanol
CAS-No. : 67-56-1
Product code : VT430
Formula : CH4O
Synonyms : acetone alcohol / alcohol C1 / alcohol, methyl / carbinol / colonial spirits / columbian spirits /
green wood spirits / manhattan spirits / methyl alcohol / methyl hydrate / methyl hydroxide /
methylen / methylol / monohydroxymethane / pyroligneous spirit / pyroxylic spirit / wood alcohol
/ wood naphtha
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Solvent
1.3. Details of the supplier of the safety data sheet
Val Tech Diagnostics, A Division of LabChem Inc
Jackson's Pointe Commerce Park Building 1000
1010 Jackson's Pointe Court
Zelienople, PA 16063
T 412-826-5230
F 724-473-0647
1.4. Emergency telephone number
Emergency number : CHEMTREC: 1-800-424-9300 or +1-703-741-5970

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
GHS-US classification
Flam. Liq. 2 H225
Acute Tox. 3 (Oral) H301
Acute Tox. 3 (Dermal) H311
Acute Tox. 3 (Inhalation) H331
STOT SE 1 H370
Full text of H statements : see section 16

2.2. Label elements

GHS US labeling
Hazard pictograms (GHS US) :

GHS02 GHS06 GHS08

Signal word (GHS US) : Danger
Hazard statements (GHS US) : H225 - Highly flammable liquid and vapour
H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled
H370 - Causes damage to organs (liver, kidneys, central nervous system, optic nerve) (Dermal,
oral)
Precautionary statements (GHS US) : P210 - Keep away from heat, sparks, open flames, hot surfaces. - No smoking.
P233 - Keep container tightly closed.
P240 - Ground/bond container and receiving equipment.
P241 - Use explosion-proof electrical, ventilating, lighting equipment
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P260 - Do not breathe mist, vapors, spray.
P264 - Wash exposed skin thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P271 - Use only outdoors or in a well-ventilated area.
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Methanol
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

P280 - Wear protective gloves, protective clothing, eye protection, face protection.
P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower.
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P330 - If swallowed, rinse mouth
P361+P364 - Take off immediately all contaminated clothing and wash it before reuse.
P370+P378 - In case of fire: Use carbon dioxide (CO2), powder, alcohol-resistant foam to
extinguish
P403+P235 - Store in a well-ventilated place. Keep cool.
P405 - Store locked up.
P501 - Dispose of contents/container to comply with local, state and federal regulations

2.3. Other hazards

Other hazards not contributing to the : None.
classification
2.4. Unknown acute toxicity (GHS US)
No data available

SECTION 3: Composition/Information on ingredients

3.1. Substances
Substance type : Mono-constituent
Name Product identifier % GHS-US classification
Methanol (CAS-No.) 67-56-1 100 Flam. Liq. 2, H225
(Main constituent) Acute Tox. 3 (Oral), H301
Acute Tox. 3 (Dermal), H311
Acute Tox. 3 (Inhalation), H331
STOT SE 1, H370

Full text of H-phrases: see section 16

3.2. Mixtures
Not applicable

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures general : Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory
arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious
with labored breathing: half-seated. Victim in shock: on his back with legs slightly raised.
Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no
warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid
physical strain.
First-aid measures after inhalation : Remove the victim into fresh air. Immediately consult a doctor/medical service.
First-aid measures after skin contact : Wash immediately with lots of water. Soap may be used. Do not apply (chemical) neutralizing
agents. Remove clothing before washing. Consult a doctor/medical service.
First-aid measures after eye contact : Rinse with water. Remove contact lenses, if present and easy to do. Continue rinsing. Take
victim to an ophthalmologist if irritation persists.
First-aid measures after ingestion : Rinse mouth with water. Immediately after ingestion, give alcohol to drink. Give nothing to
drink. Do not induce vomiting. Immediately consult a doctor/medical service. Take the
container/vomit to the doctor/hospital. Call Poison Information Centre (www.big.be/antigif.htm).
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Coughing. Symptoms similar to those listed under
ingestion.
Symptoms/effects after skin contact : Symptoms similar to those listed under ingestion.
Symptoms/effects after eye contact : Redness of the eye tissue. Lacrimation.
Symptoms/effects after ingestion : Nausea. Vomiting. AFTER ABSORPTION OF LARGE QUANTITIES: FOLLOWING
SYMPTOMS MAY APPEAR LATER: Change in the blood composition. Headache. Feeling of
weakness. Abdominal pain. Muscular pain. Central nervous system depression. Dizziness.
Mental confusion. Drunkenness. Coordination disorders. Disturbed motor response.
Disturbances of consciousness. Visual disturbances. Blindness. Respiratory difficulties.
Cramps/uncontrolled muscular contractions.
Chronic symptoms : Red skin. Dry skin. Skin rash/inflammation. Headache. Disturbed tactile sensibility. Visual
disturbances. Sleeplessness. Gastrointestinal complaints. Cardiac and blood circulation effects.

03/08/2019 EN (English US) 2/10

Methanol
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

4.3. Indication of any immediate medical attention and special treatment needed
Immediately after ingestion, give a glass of strong drink, beer or wine to drink. Hospitalize at once for treatment with the right antidotes.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Quick-acting ABC powder extinguisher. Quick-acting BC powder extinguisher. Quick-acting
class B foam extinguisher. Quick-acting CO2 extinguisher. Class B foam (alcohol-resistant).
Water spray if puddle cannot expand.
Unsuitable extinguishing media : Water (quick-acting extinguisher, reel); risk of puddle expansion. Water; risk of puddle
expansion.
5.2. Special hazards arising from the substance or mixture
Fire hazard : DIRECT FIRE HAZARD. Highly flammable liquid and vapour. Gas/vapor flammable with air
within explosion limits. INDIRECT FIRE HAZARD. May be ignited by sparks.
Explosion hazard : DIRECT EXPLOSION HAZARD. Gas/vapour explosive with air within explosion limits.
INDIRECT EXPLOSION HAZARD. may be ignited by sparks. Reactions with explosion
hazards: see "Reactivity Hazard".
Reactivity : Violent to explosive reaction with (some) metal powders and with (strong) oxidizers. Violent
exothermic reaction with (some) acids and with (some) halogens compounds.
5.3. Advice for firefighters
Firefighting instructions : Cool tanks/drums with water spray/remove them into safety. Do not move the load if exposed to
heat. Take account of toxic fire-fighting water. Use water moderately and if possible collect or
contain it.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures : No flames, no sparks. Eliminate all sources of ignition. No naked lights. No smoking. Dike and
contain spill.

6.1.1. For non-emergency personnel

Protective equipment : Gas-tight suit.
Emergency procedures : Keep upwind. Mark the danger area. Consider evacuation. Close doors and windows of
adjacent premises. Stop engines and no smoking. No naked flames or sparks. Spark- and
explosion-proof appliances and lighting equipment. Keep containers closed. Wash
contaminated clothes.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Stop leak if safe to do so. Ventilate area.
6.2. Environmental precautions
Prevent soil and water pollution. Prevent spreading in sewers.
6.3. Methods and material for containment and cleaning up
For containment : Contain released substance, pump into suitable containers. Plug the leak, cut off the supply.
Dam up the liquid spill. Try to reduce evaporation. Measure the concentration of the explosive
gas-air mixture. Dilute combustible/toxic gases/vapours with water spray. Take account of
toxic/corrosive precipitation water. Provide equipment/receptacles with earthing. Do not use
compressed air for pumping over spills.
Methods for cleaning up : Take up liquid spill into a non combustible material e.g.: sand, earth, vermiculite slaked lime or
soda ash. Scoop absorbed substance into closing containers. Carefully collect the
spill/leftovers. Damaged/cooled tanks must be emptied. Do not use compressed air for
pumping over spills. Clean contaminated surfaces with an excess of water. Take collected spill
to manufacturer/competent authority. Wash clothing and equipment after handling.
6.4. Reference to other sections
No additional information available

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Methanol
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Use spark-/explosionproof appliances and lighting system. Take precautions against
electrostatic charges. Keep away from naked flames/heat. Keep away from ignition
sources/sparks. Measure the concentration in the air regularly. Work under local
exhaust/ventilation. Comply with the legal requirements. Remove contaminated clothing
immediately. Clean contaminated clothing. Handle uncleaned empty containers as full ones.
Thoroughly clean/dry the installation before use. Do not discharge the waste into the drain. Do
not use compressed air for pumping over. Keep container tightly closed.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with
mild soap and water before eating, drinking or smoking and when leaving work. Wash
contaminated clothing before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Incompatible products : Strong oxidizers. Strong bases. Strong acids. Acid anhydrides. Acid chlorides.
Incompatible materials : Direct sunlight. Heat sources. Sources of ignition.
Heat-ignition : KEEP SUBSTANCE AWAY FROM: heat sources. ignition sources.
Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: combustible materials. oxidizing agents. strong acids.
(strong) bases. halogens. amines. water/moisture.
Storage area : Store in a cool area. Store in a dry area. Keep container in a well-ventilated place. Fireproof
storeroom. Keep locked up. Provide for a tub to collect spills. Provide the tank with earthing.
Unauthorized persons are not admitted. Aboveground. Meet the legal requirements.
Special rules on packaging : SPECIAL REQUIREMENTS: closing. dry. clean. correctly labelled. meet the legal
requirements. Secure fragile packagings in solid containers.
Packaging materials : SUITABLE MATERIAL: steel. stainless steel. iron. glass. MATERIAL TO AVOID: lead.
aluminium. zinc. polyethylene. PVC.
7.3. Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Methanol (67-56-1)
USA ACGIH ACGIH TWA (ppm) 200 ppm
USA ACGIH ACGIH STEL (ppm) 250 ppm
8.2. Exposure controls
Appropriate engineering controls : Emergency eye wash fountains should be available in the immediate vicinity of any potential
exposure. Keep concentrations well below lower explosion limits.
Personal protective equipment : Safety glasses. Protective clothing. Gloves. Full protective flameproof clothing. Face shield.

Materials for protective clothing : GIVE GOOD RESISTANCE: polyethylene/ethylenevinylalcohol. styrene-butadiene rubber.
viton. GIVE LESS RESISTANCE: chloroprene rubber. chlorinated polyethylene. natural rubber.
nitrile rubber/PVC. GIVE POOR RESISTANCE: leather. neoprene. nitrile rubber. polyethylene.
PVA. PVC. polyurethane.
Hand protection : Protective gloves against chemicals (EN374).
Eye protection : Safety glasses.
Skin and body protection : Head/neck protection. Protective clothing.
Respiratory protection : Full face mask with filter type AX at conc. in air > exposure limit. High vapour/gas
concentration: self-contained respirator.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Liquid.
Molecular mass : 32.04 g/mol
Color : Colourless.

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Odor : Characteristic odour. Mild odour. Pleasant odour. Alcohol odour. Commercial/unpurified
substance: irritating/pungent odour.
Odor threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : 4.1
Relative evaporation rate (ether=1) : 6.3
Melting point : -97.8 °C
Freezing point : No data available
Boiling point : 64.7 °C (1013 hPa)
Flash point : 9.7 °C (Closed cup, 1013 hPa, EU Method A.9: Flash-Point)
Critical temperature : 240 °C
Auto-ignition temperature : 455 °C (1013 hPa, DIN 51794: Self-ignition temperature)
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapor pressure : 128 hPa (20 °C)
Vapor pressure at 50 °C : 552 hPa
Critical pressure : 79547 hPa
Relative vapor density at 20 °C : 1.1
Relative density : 0.79 - 0.80 (20 °C)
Relative density of saturated gas/air mixture : 1
Specific gravity / density : 790 - 800 kg/m³ (20 °C)
Solubility : Soluble in water. Soluble in ethanol. Soluble in ether. Soluble in acetone. Soluble in chloroform.
Water: 100 g/100ml (20 °C)
Ethanol: complete
Ether: complete
Acetone: complete
Log Pow : -0.77 (Experimental value)
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : 0.544 - 0.59 mPa·s (25 °C)
Explosive properties : No data available
Oxidizing properties : No data available
Explosion limits : 5.5 - 36.5 vol %
9.2. Other information
Minimum ignition energy : 0.14 mJ
Saturation concentration : 166 g/m³
VOC content : 100 %
Other properties : Clear. Hygroscopic. Volatile. Neutral reaction.

SECTION 10: Stability and reactivity

10.1. Reactivity
Violent to explosive reaction with (some) metal powders and with (strong) oxidizers. Violent exothermic reaction with (some) acids and with (some)
halogens compounds.
10.2. Chemical stability
Hygroscopic.
10.3. Possibility of hazardous reactions
No additional information available
10.4. Conditions to avoid
Direct sunlight. High temperature. Incompatible materials. Open flame. Sparks. Overheating.
10.5. Incompatible materials
Strong oxidizers. Strong bases. Strong acids. Peroxides. Acid anhydrides. Acid chlorides.
10.6. Hazardous decomposition products
Carbon dioxide. Carbon monoxide.

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SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

Methanol ( \f )67-56-1
LD50 oral rat 1187 - 2769 mg/kg body weight (BASF test, Rat, Male / female, Weight of evidence, Aqueous
solution, Oral, 7 day(s))
LD50 dermal rabbit 17100 mg/kg (Rabbit, Inconclusive, insufficient data, Dermal)
LC50 inhalation rat (mg/l) 128.2 mg/l air (BASF test, 4 h, Rat, Male / female, Experimental value, Inhalation (vapours))
ATE CLP (oral) 100 mg/kg body weight
ATE CLP (dermal) 300 mg/kg body weight
ATE CLP (gases) 700 ppmV/4h
ATE CLP (vapors) 3 mg/l/4h
ATE CLP (dust, mist) 0.5 mg/l/4h
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity – single exposure : Causes damage to organs (liver, kidneys, central nervous system, optic nerve) (Dermal, oral).
Specific target organ toxicity – repeated : Not classified
exposure
Aspiration hazard : Not classified
Potential Adverse human health effects and : Toxic in contact with skin. Toxic if swallowed. Toxic if inhaled.
symptoms
Symptoms/effects after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Coughing. Symptoms similar to those listed under
ingestion.
Symptoms/effects after skin contact : Symptoms similar to those listed under ingestion.
Symptoms/effects after eye contact : Redness of the eye tissue. Lacrimation.
Symptoms/effects after ingestion : Nausea. Vomiting. AFTER ABSORPTION OF LARGE QUANTITIES: FOLLOWING
SYMPTOMS MAY APPEAR LATER: Change in the blood composition. Headache. Feeling of
weakness. Abdominal pain. Muscular pain. Central nervous system depression. Dizziness.
Mental confusion. Drunkenness. Coordination disorders. Disturbed motor response.
Disturbances of consciousness. Visual disturbances. Blindness. Respiratory difficulties.
Cramps/uncontrolled muscular contractions.
Chronic symptoms : Red skin. Dry skin. Skin rash/inflammation. Headache. Disturbed tactile sensibility. Visual
disturbances. Sleeplessness. Gastrointestinal complaints. Cardiac and blood circulation effects.

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : Not classified as dangerous for the environment according to the criteria of Regulation (EC) No
1272/2008.
Ecology - air : Not included in the list of substances which may contribute to the greenhouse effect (IPCC).
Not included in the list of fluorinated greenhouse gases (Regulation (EU) No 517/2014). Not
classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009).
Ecology - water : Not harmful to crustacea. Not harmful to fishes. Groundwater pollutant. Inhibition of activated
sludge. Nitrification of activated sludge is inhibited. Not harmful to algae. Not harmful to
bacteria.
Methanol (67-56-1)
LC50 fish 1 15400 mg/l (EPA 660/3 - 75/009, 96 h, Lepomis macrochirus, Flow-through system, Fresh
water, Experimental value, Lethal)
EC50 Daphnia 1 18260 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 96 h, Daphnia magna, Semi-
static system, Fresh water, Experimental value, Locomotor effect)
ErC50 (algae) 22000 mg/l (OECD 201: Alga, Growth Inhibition Test, 96 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value)

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12.2. Persistence and degradability

Methanol (67-56-1)
Persistence and degradability Readily biodegradable in the soil. Readily biodegradable in water.
Biochemical oxygen demand (BOD) 0.6 - 1.12 g O ₂/g substance
Chemical oxygen demand (COD) 1.42 g O ₂/g substance
ThOD 1.5 g O ₂/g substance

12.3. Bioaccumulative potential

Methanol (67-56-1)
BCF fish 1 1 - 4.5 (72 h, Cyprinus carpio, Static system, Fresh water, Experimental value)
Log Pow -0.77 (Experimental value)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).

12.4. Mobility in soil

Methanol (67-56-1)
Surface tension 0.023 N/m (20 °C)
Log Koc 0.088 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Ecology - soil Highly mobile in soil.

12.5. Other adverse effects

No additional information available

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Waste disposal recommendations : Do not discharge into drains or the environment. Remove waste in accordance with local and/or
national regulations. Hazardous waste shall not be mixed together with other waste. Different
types of hazardous waste shall not be mixed together if this may entail a risk of pollution or
create problems for the further management of the waste. Hazardous waste shall be managed
responsibly. All entities that store, transport or handle hazardous waste shall take the
necessary measures to prevent risks of pollution or damage to people or animals. Recycle by
distillation. Incinerate under surveillance with energy recovery. Obtain the consent of pollution
control authorities before discharging to wastewater treatment plants.
Additional information : Hazardous waste according to Directive 2008/98/EC, as amended by Regulation (EU) No
1357/2014 and Regulation (EU) No 2017/997.

SECTION 14: Transport information

In accordance with DOT
Transport document description : UN1230 Methanol, 3, II
UN-No.(DOT) : 1230
DOT NA no. : UN1230
Proper Shipping Name (DOT) : Methanol
Transport hazard class(es) (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Hazard labels (DOT) : 3 - Flammable liquid

DOT Symbols : D - Proper shipping name for domestic use only, or to and from Canada
Packing group (DOT) : II - Medium Danger

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DOT Special Provisions (49 CFR 172.102) : IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T7 - 4 178.274(d)(2) Normal............. 178.275(d)(3)
TP2 - a. The maximum degree of filling must not exceed the degree of filling determined by the
following: (image) Where: tr is the maximum mean bulk temperature during transport, tf is the
temperature in degrees celsius of the liquid during filling, and a is the mean coefficient of
cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and
the maximum mean bulk temperature during transportation (tr) both in degrees celsius. b. For
liquids transported under ambient conditions may be calculated using the formula: (image)
Where: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 C
(59 F) and 50 C (122 F), respectively.
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
DOT Packaging Non Bulk (49 CFR 173.xxx) : 202
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Quantity Limitations Passenger aircraft/rail : 1 L
(49 CFR 173.27)
DOT Quantity Limitations Cargo aircraft only (49 : 60 L
CFR 175.75)
DOT Vessel Stowage Location : B - (i) The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) ‘‘On deck only’’ on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
DOT Vessel Stowage Other : 40 - Stow ‘‘clear of living quarters’’
Marine pollutant : -

Additional information
Other information : No supplementary information available.

ADR
Transport document description :
Hazard identification number (Kemler No.) : 336
Orange plates :

Tunnel restriction code : D/E

Transport by sea
UN-No. (IMDG) : 1230
Proper Shipping Name (IMDG) : methanol
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
EmS-No. (1) : F-E
MFAG-No : 19
EmS-No. (2) : S-D

Air transport
UN-No. (IATA) : 1230
Proper Shipping Name (IATA) : Methanol
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger

SECTION 15: Regulatory information

15.1. US Federal regulations
Methanol (67-56-1)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
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Methanol (67-56-1)
RQ (Reportable quantity, section 304 of EPA's 5000 lb
List of Lists)
SARA Section 311/312 Hazard Classes Physical hazard - Flammable (gases, aerosols, liquids, or solids)
Health hazard - Acute toxicity (any route of exposure)
Health hazard - Specific target organ toxicity (single or repeated exposure)

15.2. International regulations

CANADA
Methanol (67-56-1)
Listed on the Canadian DSL (Domestic Substances List)
WHMIS Classification Class B Division 2 - Flammable Liquid
Class D Division 2 Subdivision A - Very toxic material causing other toxic effects
Class D Division 2 Subdivision B - Toxic material causing other toxic effects

EU-Regulations
No additional information available

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Flam. Liq. 2 H225
Acute Tox. 3 (Inhalation) H331
Acute Tox. 3 (Dermal) H311
Acute Tox. 3 (Oral) H301
STOT SE 1 H370
Full text of H statements : see section 16

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]

Not classified
15.2.2. National regulations
No additional information available

15.3. US State regulations

Methanol(67-56-1)
U.S. - California - Proposition 65 - Carcinogens List No
U.S. - California - Proposition 65 - Developmental Yes
Toxicity
U.S. - California - Proposition 65 - Reproductive Toxicity No
- Female
U.S. - California - Proposition 65 - Reproductive Toxicity No
- Male

SECTION 16: Other information

Full text of H-phrases: see section 16:

------ H225 Highly flammable liquid and vapour
------ H301 Toxic if swallowed
------ H311 Toxic in contact with skin
------ H331 Toxic if inhaled
------ H370 Causes damage to organs

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NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 0 - Material that in themselves are normally stable, even
under fire conditions.

Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard
Physical : 0 Minimal Hazard
Personal protection : H

SDS US ValTech

Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this
SDS. The user must determine suitability of this information for his application.

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