Q.

1 Which of the following combination contains only isoelectronic series : [3]

(A) N3–, O2–, Cl–, Ne (B) F–, Ar, S2–, Cl–
3– 2– –
(C*) P , S , Cl , Ar (D) N3–, F–, O2–, Ar

Q.2 In crystal of which of the following ionic compound, would you expect the maximum distance between
centre of cation and anion. [3]
(A) CsF (B*) CsI (C) LiI (D) LiF

Q.3 The ionic radii of F, F–, O2– are in the order of : [3]
(A) O2– < F– < F (B) F– > O2– > F
2–
(C*) O > F > F– (D) O2– = F– > F

Q.4 The correct order of radii is : [4]

(A) N < Be < B (B*) <F– O2–
< N3–
(C*) Na > Li < K (D*) Fe > Fe3+ > Fe4+
2+

Q.5 Which among the following species has the same number of electrons in its outermost as well as penultimate
shell ? [3]
(A) Mg 2+ (B) O 2– (C) F– (D*) Ca 2+

Q.6 Which one of the following pair would have a large size : [6]
(i) K or K + (ii) Br or Br– 2–
(iii) O or F– +
(iv) Li or Na +

(v) P or As (vi) Na+ or Mg+2

[Ans. (i) K (ii) Br– (iii) O2– (iv) Na+ (v) As (vi) Na+ ]

Q.7 Arrange the following in increasing order of radii [8]

(i) I, I+, I–
(ii) C, N, Si, P
(iii) O2–, N3–, F–
(iv) Be+2, Cl–, S2–, Na+, Mg2+
(v) B, Be, Li, Na
(vi) Cl–, S2–, Ca2+
(vii) Mg2+, Al3+, Na+, O2–, F–
(viii) S, O, Se, F
[Ans. (i) I¯ > I > I+
(ii) C > N < P < Si
(iii) F¯ < O2– < N–3
(iv) Be+2 < Mg2+ < Na+ < Cl¯ < S–2
(v) B < Be < Li < Na
(vi) S2–>Cl–> Ca+2
(vii) O2– > F– > Na+ > Mg2+ > Al3+
(viii) Se > S > O > F]

Q.8 The ionic radii of N3–, O2– and F¯ are respectively given by: [3]
(A) 1.36, 1.40, 1.71 (B) 1.36, 1.71, 1.40
(C*) 1.71, 1.40, 1.36 (D) 1.71, 1.36, 1.40
Q.9 Arrange the following ions in order of their ionic radii Li+, Mg2+, K+, Al3+ [4]
[Ans. Al3+ < Mg2+ <Li+ < K+ ]

Q.10 A monoatomic anion of unit charge contain 45 neutrons and 36 electrons. What is atomic mass number
of element and in which group of periodic table does it lie. [4]
[Ans. Atomic mass No. 80, Group No. 17 ]

Q.11 Calculate Zeff for 3s electron in vanadium(23). [4]

[Ans.  = 11.25 Zeff = 11.75]

Q.12 Calculate Zeff for last valence shell electron in fluorine (F). [5]
[Ans.  = 3.8 Zeff = 5.2]
Q.1 Which transition involves maximum amount of energy (M is a metal) [3]
(A) M— (g)  M (g) + e (B) M (g)  M+ (g) + e
(C) M (g)  M (g) + e
+ +2 (D*) M+2 (g)  M+3 (g) + e

Q.2 Which one of the following electronic configuration of an atom has the highest ionisation energy [3]
(A) 1s22s22p3 (B) 1s22s22p63s1 (C*) 1s22s22p6 (D) 1s22s22p5

Q.3 The first five ionization energies of an element are 9.1, 16.2, 24.5, 35 and 205.7 eV respectively. Then
number of valence electron in the atom is [3]
(A) 2 (B) 3 (C*) 4 (D) 5

Q.4 Give the correct order of initials T (true) or F (false) for following statements. [3]
(I) Top positions of Lother-Mayer’s atomic volume curve are occupied by Alkali metals.
(II) Number of elements presents in the fifth period of the periodic table are 32.
(III) 2nd I.P. of Mg is less than the 2nd I.P. of Na.
(IV) A p-orbital can take maximum of six electrons.
(A*) TFTF (B) TFFT (C) FFTF (D) TTFF

Q.5 For the element X, student Surbhi measured its radius as 102 nm, Mr.Gupta as 113 nm and Mr. Agarwal
as 100 nm using same apparatus. Their teacher explained that measurements were correct by saying that
recorded values by three students were [3]
(A*) Crystal, vander Waal and covalent radii (B) Covalent, crystal and vander Waal radii
(C) Vander Waal, ionic and covalent (D) None is correct

Q.6 Choose the correct statement. [5]

(A*) Be and Al are not in same group.
(B*) All the transition metal correspond to d-block.
(C*) Be and Al are having lot of similarities in their properties.
(D) The atomic radius gradually decreases from Sc to Zn.

Q.7 Statement-1 : The ionisation potential of Sn is greater than Pb. [3]

Statement-2 : Usually ionisation energy decreases down the group.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D*) Statement-1 is false, statement-2 is true.

Q.8 Statement-1 : (I.E.)n of an atom is always greater than (I.E.)n–1 (n is integer number) [3]
Statement-2 : ne/Z ratio decreases on successive elimination of electrons.
(A*) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
Q.9 Arrange the following periodic properties with justification. [5]

(a) Increasing order of first ionization energy N, O, F [Ans. F > N > O]

(b) Increasing order of ionization energy Cl–, K+, S–2, Ca2+ [Ans. S–2 < Cl– < K+ < Ca+2]

(c) Increasing order of ionization energy Li+, Be+, B+, C+, N+, O+, F+
[Ans. Be+ < C+ < B+ < N+ < F+ < O+ < Li+]

(d) Increasing order of ionization energy Fe, Fe+2, Fe+3 [Ans. Fe < Fe+2 < Fe+3]

(e) Increasing order of first ionization potential Mg, Al, Si, Na [Ans. Na<Al<Mg<Si]

Q.10 How many neutrons are present in 180 mL water at (i) 4°C & (ii) 127°C & 0.821 atm pressure.
Can you predict the phase of H2O in these conditions. [3]
[Ans: 80 NA(Liquid), 0.036 NA (Gas)]
CLASS : XI (J & K) MARKS : 35 DATE : 27-28/07/2009 TIME : 30 MIN. DPP. NO.-10
Q.1 Which of the following relation is correct [3]
(A) 2 I.P. – E.A. – E.N. = 0 (B) 2 I.P. – E.N. + E.A. = 0
(C*) 2 E.N. – I.P. – E.A. = 0 (D) E.N. – I.P. – E.A. = 0

Q.2 The correct order of electron affinity for the different families is [3]
(A) Halogen > carbon > nitrogen > oxygen (B) Halogen > oxygen > nitrogen > carbon
(C) Halogen > nitrogen > carbon > oxygen (D*) Halogen > oxygen > carbon > nitrogen

Q.3 A0/2 atoms of X (g) are converted into X+ (g) by energy E1. A0/2 atoms of X (g) are converted into
X—(g) by energy E2. Hence ionisation potential and electron affinity of X (g) are [3]
2E1 2( E1  E 2 ) 2E1 , 2E 2 ( E1  E 2 ) 2E 2
(A) A . A0 (B*) A0 A0 (C) A0
.
A0 (D) None
0

Q.4 First, second and third I.P. values are 10 eV, 15 eV and 150 eV. Element can be [3]
(A*) Be (B) B (C) F (D) Na

Q.5 Find the highest ratio of IP values of given pair of elements : [3]
(A) He : Ne (B) Ne : Ar (C*) He : Xe (D) Kr : Xe

Q.6 Which of the following case the size ratio is minimum : [3]
(A) Li– / Li (B) H– / H (C*) Na– / Na (D) Can not be predicted

Q.7 The most acidic oxide is : [3]

(A) SO3 (B) P2O5 (C*) Cl2O7 (D) P2O3

Q.8 State True or False with explanation for the following questions [3]
(a) E.A. of M+(g) ion and I.E. of M(g) atom are equal.

(b) EA1 of sulphur is more than EA1 of oxygen.

(c) I.E. of Pb is more than Sn even though Pb is larger atom than Sn.
[Ans. (a) True, (b) True, (c) True]

Q.9 (a) Which has greater IE1 ? Na+ or Ne. Explain [3]
(b) Which has greater IE2 ? O or N. Explain
(c) Which has greater IE2? Li or Be. Explain [Ans. (a) Na+, (b) O, (c) Li]

Q.10 Three atoms have the following E.C. [4]

(i) A = 1s2 2s2 2p6 3s2 3p1 (ii) B = 1s2 2s2 2p6 3s2 3p5
(iii) C = 1s2 2s2 2p6 3s2 3p6 4s1
(a) which of the three has largest IE1
(b) Which has smallest IE4
(c) Stability of A+3, B+2, C+3. [Ans. (a) ii, (b) ii, (c) A+3 > B+2 > C+3]

Q.11 Solutions of equal strength of XOH & QOH are prepared. If the E.N. of X & Q are respectively 0.9 &
3.2 then comment on their acidic / basic nature of then solution. Why. [4]
[Ans. XOH is basic & QOH is acidic]
Q.1 According to Born-Haber's cycle, the enthalpy of formation of ionic compounds can be determined.
The formation of NaCl involves following steps: [3]

(I) Na(s)  S  Na(g) (II) Na(g)  I  Na+(g) + e–
Energy of sub lim ation Ionisation potential

H
 D  2Cl (g)
(III) Cl2(g) Bond (IV) Cl(g) + e–   Eg   Cl– (g)
dissociati on energy Electron gain enthalpy

(V) Cl–(g) + Na+(g)  U  NaCl (S)

Lattice energy

The enthalpy of formation of NaCl will be

D D
(A) Hf = S + I– –Heg–U (B*) Hf = S + I+ –Heg–U
2 2

H eg H eg
(C) Hf = –S – I–D+ +U (D) Hf = –S – I–D – –U
2 2

Q.2 The correct order of second ionization energy for elements C, N, O and F is _______. [3]
[Ans. O > F > N > C]

Q.3 Choose the correct order of the following: [3]

(A) N–H > P–H > As–H > Sb–H : Polarity order
(B*) Mg2+(aq) > Sr2+ (aq) > Ba2+ (aq) : Hydrated radius order
(C) Mg2+(aq) > Sr2+ (aq) > Ba2+ (aq) : Ionic mobility order
(D) NaF > MgO > SrO : Lattice energy order

Q.4 Which of the following process is associated with best possibility of the energy release. [3]
(A) Li  Li+ + e– (B) O¯ + e–  O2–
(C*) Cl ++ e–  Cl (D) Be + e–  Be¯

Q.5 Statement-1 : F¯ is having highest hydrated radius among the other halide ions [3]
Statement-2 : Electronegativity of fluorine (F) is maximum in the periodic table.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B*) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

Q.6 Statement-1: Nitrogen atom has higher ionization energy than fluorine atom. [3]
Statement-2: Nitrogen atom has extra stable electronic configuration due to half filled p-subshell.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D*) Statement-1 is false, statement-2 is true.
Q.7 Which of the following statement is not correct: [3]
(A) Ionic mobility of Na+(aq) is greater than Mg2+(aq)
(B*) The E.A. of 'F' atom is more than 'Cl' atom
(C) Second I.P. of 'B' atom is greater than that of 'C' atom
(D) I.E. of O¯ is less than that of 'O' atom.

Q.8 Which of the following species of Mn has lowest electronegativity? [3]

(A*) Mn(II) (B) Mn(IV) (C) Mn(VI) (D) Mn(VII)

Q.9 The E.N. of H, X, O are 2.1, 0.8 and 3.5 respectively comment on the nature of the compound
H–O–X, that is : [3]
(A*) Basic (B) Acidic (C) Amphoteric (D) Can't be predicted

Q.10 If X – Y – Z is a compound and X, Y, Z are of comparable size & electronegativity of X = 3.0 , Y = 3.5
, Z = 0.8 then the bond which will break first in gas phase. [3]
(A*) X – Y (B) Y – Z
(C) both simultaneously (D) Can’t be predicted.

Q.11 Prove that the formation of NaCl2 is highly endothermic and energetically unfavourable from the following
data using Born-Haber Cycle [5]
Heat of sublimation of Na = 109 kJ/mol
1st IE of Na = 494 kJ/mol
st
1 IE of Na + = 4563 kJ/mol
Bond Energy of Cl2 = 242 kJ/mol
Electron gain enthalpy of Cl = –347 kJ/mol
Lattice energy of NaCl2 = 2560 kJ/mol [Ans. 2154 kJ/mol]