Grotan® OX: Safety Data Sheet
Grotan® OX: Safety Data Sheet
47-224 Kędzierzyn-Koźle
POLAND
Telephone: +48 77 472 15 00
Telefax: +48-77 472 16 00
biuro@[Link]
[Link]
22851 Norderstedt
Germany
Telephone: +49 (0)40/ 52100-0
Telefax: +49 (0)40/ 52100318
mail@[Link]
[Link]
E-mail address of person : SAI/AT +49 40 52100 100 or S&M UK +44 114 254 3500
responsible for the sai-at@[Link]
SDS/Contact person
1.4 Emergency telephone number
Emergency telephone num- : UK Poisons Emergency number: 0870 600 6266
ber
Emergency telephone num- : +49 (0)40 / 52 100 –0
ber
Skin corrosion, Category 1B H314: Causes severe skin burns and eye damage.
Specific target organ toxicity - repeated H373: May cause damage to organs through pro-
exposure, Category 2, Gastrointestinal longed or repeated exposure.
tract, Respiratory Tract
Long-term (chronic) aquatic hazard, Cat- H411: Toxic to aquatic life with long lasting effects.
egory 2
Special labelling of certain : Use biocides safely. Always read the label and product infor-
mixtures mation before use.
3.1 Substances
Chemical nature : Liquid
(single substance)
Hazardous components
Chemical name Index-Number Classification Concentration
CAS-No. (% w/w)
EC-No.
Registration number
reaction products of paraformal- 612-290-00-1 Acute Tox. 4; H302 90 - 100
dehyde and 2- --- Acute Tox. 4; H332
hydroxypropylamine (ratio 3:2); --- Acute Tox. 3; H311
[MBO] --- Skin Corr. 1B; H314
Skin Sens. 1A; H317
Eye Dam. 1; H318
Muta. 2; H341
Carc. 1B; H350
STOT RE 2; H373
Aquatic Chronic 2;
H411
EUH071
For explanation of abbreviations see section 16.
In case of skin contact : In case of contact, immediately flush skin with plenty of water
for at least 15 minutes while removing contaminated clothing
and shoes.
Call a physician immediately.
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,
4.2 Most important symptoms and effects, both acute and delayed
Symptoms : No information available.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : No information available.
Skin and body protection : Body protection must be chosen depending on activity and
possible exposure, e.g. apron, protecting boots, chemical-
protection suit ( according to EN 14605 in case of splashes or
EN ISO 13982 in case of dust).
equipment.
Odour : amine-like
Solubility(ies)
Water solubility : in all proportions (20 °C)
Viscosity
Viscosity, dynamic : 176 mPa*s (-10 °C)
Method: OECD Test Guideline 114
10.1 Reactivity
Stable under recommended storage conditions.
10.2 Chemical stability
No decomposition if stored normally.
10.3 Possibility of hazardous reactions
Hazardous reactions : reaction with acids.
Acute toxicity
Product:
Acute oral toxicity : LD50 (Rat): 630 mg/kg
Assessment: Harmful if swallowed.
Components:
Skin corrosion/irritation
Product:
Species : Rabbit
Assessment : Causes severe skin burns and eye damage.
Method : OECD Test Guideline 404
Result : Corrosive after 3 minutes to 1 hour of exposure
Test substance : concentrate
Components:
Product:
Species : Rabbit
Assessment : Causes serious eye damage.
Method : OECD Test Guideline 405
Result : Risk of serious damage to eyes.
Test substance : concentrate
Species : Rabbit
Result : No eye irritation
Test substance : 0,2 % solution
Components:
Product:
Species : Guinea pig
Assessment : The product is a skin sensitiser, sub-category 1A.
Method : OECD Test Guideline 406
Result : May cause an allergic skin reaction.
Components:
Product:
Germ cell mutagenicity- As- : Mutagenic Category 2, Classified based on the conditions
sessment cited in Note 9 (Regulation (EC) 1272/2008, Annex VI, Part 3,
Note 9).
Components:
Germ cell mutagenicity- As- : Mutagenic Category 2, Classified based on the conditions
sessment cited in Note 9 (Regulation (EC) 1272/2008, Annex VI, Part 3,
Note 9).
Carcinogenicity
Product:
Carcinogenicity - Assess- : May cause cancer., Classified based on the conditions cited in
ment Note 8 (Regulation (EC) 1272/2008, Annex VI, Part 3, Note 8).
Components:
Reproductive toxicity
Product:
Reproductive toxicity - As- : Not classified based on available information.
sessment
Components:
Product:
Assessment : Not classified based on available information.
Components:
Product:
Target Organs : Respiratory Tract, Gastrointestinal tract
Assessment : May cause damage to organs through prolonged or repeated
exposure.
Components:
Product:
Species : Rat
NOAEL : 72 mg/kg
Application Route : Repeated dose (90 days) toxicity (oral)
Method : OECD Test Guideline, 408
Components:
Aspiration toxicity
No data available
12.1 Toxicity
Product:
Toxicity to fish : LC50 (Brachidanio rerio): 57,7 mg/l
Components:
Product:
Biodegradability : Result: Readily biodegradable.
Method: OECD Test Guideline 306
Components:
Components:
Product:
Distribution among environ- : Remarks: No data available
mental compartments
Product:
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher..
Product:
Adsorbed organic bound : Remarks: Product does not contain any organic halogens.
halogens (AOX)
Waste key for the unused : The waste producer itself must, in consultation with the ap-
product(Group) propriate authorities and a waste disposal company, obtain a
waste code from the EWC (European Waste Catalogue)
14.1 UN number
IMDG : UN 2922
IATA : UN 2922
14.2 UN proper shipping name
IMDG : 8
IATA : 8
14.4 Packing group
IMDG
Packing group : II
Labels : 8 (6.1)
EmS Code : F-A, S-B
IATA (Cargo)
Packing instruction (cargo : 855
aircraft)
Packing group : II
Labels : Corrosive, Toxic
IATA (Passenger)
Packing group : II
Labels : Corrosive
14.5 Environmental hazards
IMDG
Marine pollutant : yes
14.6 Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and var-
iations in regional or country regulations.
For personal protection see section 8.
14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable for product as supplied.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mix-
ture
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of
major-accident hazards involving dangerous substances.
E2 ENVIRONMENTAL
HAZARDS
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways; ADR - European Agreement concerning the International Carriage of Dangerous
Goods by Road; AICS - Australian Inventory of Chemical Substances; ASTM - American Society
for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regula-
tion; Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN
- Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Cana-
da); ECHA - European Chemicals Agency; EC-Number - European Community number; ECx -
Concentration associated with x% response; ELx - Loading rate associated with x% response;
EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx -
Concentration associated with x% growth rate response; GHS - Globally Harmonized System;
GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - In-
ternational Air Transport Association; IBC - International Code for the Construction and Equip-
ment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentra-
tion; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical
Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Mari-
time Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisa-
tion for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration
to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal
Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not
Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No
Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop-
ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu-
lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc-
es; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No
1907/2006 of the European Parliament and of the Council concerning the Registration, Evalua-
tion, Authorisation and Restriction of Chemicals; RID - Regulations concerning the International
Carriage of Dangerous Goods by Rail; SADT - Self-Accelerating Decomposition Temperature;
SDS - Safety Data Sheet; SVHC - Substance of Very High Concern; TCSI - Taiwan Chemical
Substance Inventory; TRGS - Technical Rule for Hazardous Substances; TSCA - Toxic Sub-
stances Control Act (United States); UN - United Nations; vPvB - Very Persistent and Very Bioac-
cumulative
Further information
Classification and procedure used to derive the classification for mixtures according to Regulation
(EC) No. 1272/2008
Acute Tox. 4, H302 : On basis of test data.
Acute Tox. 3, H311 : On basis of test data.
Acute Tox. 4, H332 : On basis of test data.
Skin Corr. 1B, H314 : On basis of test data.
Skin Sens. 1A, H317 : On basis of test data.
Eye Dam. 1, H318 : On basis of test data.
Muta. 2, H341 : REGULATION (EC) No 1272/2008
Carc. 1B, H350 : REGULATION (EC) No 1272/2008
STOT RE 2, H373 : On basis of test data.
Aquatic Chronic 2, H411 : REGULATION (EC) No 1272/2008
Changes since the last version are highlighted in the margin. This version replaces all previous
versions.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.









