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Grotan® OX: Safety Data Sheet

MSDS liquid Biocide

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100% found this document useful (2 votes)
2K views16 pages

Grotan® OX: Safety Data Sheet

MSDS liquid Biocide

Uploaded by

Nina
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

grotan® OX No Change Service!


Version Revision Date: Date of last issue: 06.06.2017
06.00 15.10.2018 Date of first issue: 20.01.2011

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier


Trade name : grotan® OX
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Sub- : Preservative
stance/Mixture

1.3 Details of the supplier of the safety data sheet


Supplier : Brenntag Polska Sp. z o.o.
ul. J. Bema 21

47-224 Kędzierzyn-Koźle
POLAND
Telephone: +48 77 472 15 00
Telefax: +48-77 472 16 00
biuro@[Link]
[Link]

Manufacturer/ Supplier : Schülke & Mayr GmbH


Robert-Koch-Str. 2

22851 Norderstedt
Germany
Telephone: +49 (0)40/ 52100-0
Telefax: +49 (0)40/ 52100318
mail@[Link]
[Link]

E-mail address of person : SAI/AT +49 40 52100 100 or S&M UK +44 114 254 3500
responsible for the sai-at@[Link]
SDS/Contact person
1.4 Emergency telephone number
Emergency telephone num- : UK Poisons Emergency number: 0870 600 6266
ber
Emergency telephone num- : +49 (0)40 / 52 100 –0
ber

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)


Acute toxicity, Category 4 H302: Harmful if swallowed.

Acute toxicity, Category 3 H311: Toxic in contact with skin.

Acute toxicity, Category 4 H332: Harmful if inhaled.

Skin corrosion, Category 1B H314: Causes severe skin burns and eye damage.

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

grotan® OX No Change Service!


Version Revision Date: Date of last issue: 06.06.2017
06.00 15.10.2018 Date of first issue: 20.01.2011

Skin sensitisation, Category 1A H317: May cause an allergic skin reaction.

Serious eye damage, Category 1 H318: Causes serious eye damage.

Germ cell mutagenicity, Category 2 H341: Suspected of causing genetic defects.

Carcinogenicity, Category 1B H350: May cause cancer.

Specific target organ toxicity - repeated H373: May cause damage to organs through pro-
exposure, Category 2, Gastrointestinal longed or repeated exposure.
tract, Respiratory Tract

Long-term (chronic) aquatic hazard, Cat- H411: Toxic to aquatic life with long lasting effects.
egory 2

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)


Hazard pictograms :

Signal word : Danger

Hazard statements : H302 + H332 Harmful if swallowed or if inhaled.


H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H373 May cause damage to organs (Respiratory Tract, Gas-
trointestinal tract) through prolonged or repeated exposure.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H411 Toxic to aquatic life with long lasting effects.

Supplemental Hazard : EUH071 Corrosive to the respiratory tract.


Statements
Precautionary statements : P261 Avoid breathing vapours.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protec-
tion/ face protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do
NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immedi-
ately all contaminated clothing. Rinse skin with water or show-
er.
P304 + P340 IF INHALED: Remove person to fresh air and
keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with wa-
ter for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

grotan® OX No Change Service!


Version Revision Date: Date of last issue: 06.06.2017
06.00 15.10.2018 Date of first issue: 20.01.2011

Special labelling of certain : Use biocides safely. Always read the label and product infor-
mixtures mation before use.

2.3 Other hazards


This substance/mixture contains no components considered to be either persistent, bioaccumula-
tive and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or
higher.

SECTION 3: Composition/information on ingredients

3.1 Substances
Chemical nature : Liquid
(single substance)

Hazardous components
Chemical name Index-Number Classification Concentration
CAS-No. (% w/w)
EC-No.
Registration number
reaction products of paraformal- 612-290-00-1 Acute Tox. 4; H302 90 - 100
dehyde and 2- --- Acute Tox. 4; H332
hydroxypropylamine (ratio 3:2); --- Acute Tox. 3; H311
[MBO] --- Skin Corr. 1B; H314
Skin Sens. 1A; H317
Eye Dam. 1; H318
Muta. 2; H341
Carc. 1B; H350
STOT RE 2; H373
Aquatic Chronic 2;
H411
EUH071
For explanation of abbreviations see section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures


General advice : Take off all contaminated clothing immediately.

If inhaled : If breathed in, move person into fresh air.


If symptoms persist, call a physician.

In case of skin contact : In case of contact, immediately flush skin with plenty of water
for at least 15 minutes while removing contaminated clothing
and shoes.
Call a physician immediately.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

grotan® OX No Change Service!


Version Revision Date: Date of last issue: 06.06.2017
06.00 15.10.2018 Date of first issue: 20.01.2011

for at least 15 minutes.


Call a physician immediately.

If swallowed : Do NOT induce vomiting.


Rinse mouth with water.
Give small amounts of water to drink.
Obtain medical attention.

4.2 Most important symptoms and effects, both acute and delayed
Symptoms : No information available.

Risks : No information available.

4.3 Indication of any immediate medical attention and special treatment needed
Treatment : No information available.

SECTION 5: Firefighting measures

5.1 Extinguishing media


Suitable extinguishing media : Water
Dry powder
Foam
Carbon dioxide (CO2)

Unsuitable extinguishing : No information available.


media

5.2 Special hazards arising from the substance or mixture


Specific hazards during fire- : No information available.
fighting

5.3 Advice for firefighters

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures


Personal precautions : Ensure adequate ventilation.
Use personal protective equipment.

6.2 Environmental precautions


Environmental precautions : Do not flush into surface water or sanitary sewer system.
Avoid subsoil penetration.

6.3 Methods and material for containment and cleaning up


Methods for cleaning up : Wipe up with absorbent material (e.g. cloth, fleece).
Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

grotan® OX No Change Service!


Version Revision Date: Date of last issue: 06.06.2017
06.00 15.10.2018 Date of first issue: 20.01.2011

6.4 Reference to other sections


see Section 8 + 13

SECTION 7: Handling and storage

7.1 Precautions for safe handling


Advice on safe handling : Use only in well-ventilated areas.
Handle and open container with care.

Advice on protection against : No special protective measures against fire required.


fire and explosion

Hygiene measures : Take off all contaminated clothing immediately.

7.2 Conditions for safe storage, including any incompatibilities


Requirements for storage : Store in original container.
areas and containers

Further information on stor- : Limited stability - see label on pack.


age conditions

Advice on common storage : Keep away from food and drink.

7.3 Specific end use(s)


Specific use(s) : none

SECTION 8: Exposure controls/personal protection

8.1 Control parameters


Hazardous decomposition products
8.2 Exposure controls

Personal protective equipment


Eye protection : Safety glasses with side-shields conforming to EN166

Hand protection : Impervious glovesSplash protection: disposable nitrile rubber


gloves e.g. Dermatril (layer thickness: 0.11 mm) made by KCL
or gloves from other manufacturers offering the same protec-
[Link] contact: Butyl rubber gloves e.g. Butoject
(>480 Min., layer thickness: 0.70 mm) made by KCL or gloves
from other manufacturers offering the same protection.

Skin and body protection : Body protection must be chosen depending on activity and
possible exposure, e.g. apron, protecting boots, chemical-
protection suit ( according to EN 14605 in case of splashes or
EN ISO 13982 in case of dust).

Respiratory protection : In case of insufficient ventilation, wear suitable respiratory

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

grotan® OX No Change Service!


Version Revision Date: Date of last issue: 06.06.2017
06.00 15.10.2018 Date of first issue: 20.01.2011

equipment.

Filter type : Filter type AB

Protective measures : Avoid contact with skin and eyes.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties


Appearance : Liquid

Colour : colourless, -, light yellow

Odour : amine-like

Odour Threshold : not determined

pH : ca. 10 (20 °C)


Concentration: 1,5 g/l

Melting point/range : < -35 °C


Method: Directive 92/69/EEC, A.1

Pour point -39 °C


Method: ASTM D6892

Boiling temperature : ca. 204 °C


Method: Directive 92/69/EEC, A.2

Flash point : > 100 °C


Method: ISO 2719

Evaporation rate : not determined

Flammability (solid, gas) : not auto-flammable

Upper explosion limit / Upper : Not applicable


flammability limit

Lower explosion limit / Lower : Not applicable


flammability limit

Vapour pressure : 0,014 hPa (25 °C)


Method: calculated

Vapour density : not determined

Relative density : 1,049 - 1,069 g/ml (20 °C)


Method: Tested according to Directive 92/69/EEC.

Solubility(ies)
Water solubility : in all proportions (20 °C)

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

grotan® OX No Change Service!


Version Revision Date: Date of last issue: 06.06.2017
06.00 15.10.2018 Date of first issue: 20.01.2011

Partition coefficient: n- : log Pow: ca. -0,3 (25 °C)


octanol/water Method: Directive 92/69/EEC, A.8

Auto-ignition temperature : not determined

Viscosity
Viscosity, dynamic : 176 mPa*s (-10 °C)
Method: OECD Test Guideline 114

19 mPa*s (20 °C)


Method: OECD Test Guideline 114

8 mPa*s (40 °C)


Method: OECD Test Guideline 114

Flow time : < 15 s at 20 °C


Method: DIN 53211

Explosive properties : Not explosive

Oxidizing properties : The substance or mixture is not classified as oxidizing.

9.2 Other information


Surface tension : 68,1 mN/m, 1 g/l, 20 °C, OECD Test Guideline 115

Refractive index : 1,469 - 1,479 at 20 °C

Self-ignition : not auto-flammable

SECTION 10: Stability and reactivity

10.1 Reactivity
Stable under recommended storage conditions.
10.2 Chemical stability
No decomposition if stored normally.
10.3 Possibility of hazardous reactions
Hazardous reactions : reaction with acids.

10.4 Conditions to avoid


Conditions to avoid : No data available

10.5 Incompatible materials


Materials to avoid : Acids

10.6 Hazardous decomposition products


formaldehyde

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

grotan® OX No Change Service!


Version Revision Date: Date of last issue: 06.06.2017
06.00 15.10.2018 Date of first issue: 20.01.2011

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Product:
Acute oral toxicity : LD50 (Rat): 630 mg/kg
Assessment: Harmful if swallowed.

Acute inhalation toxicity : LC50 (Rat): 2 mg/l


Exposure time: 4 h
Test atmosphere: dust/mist
Method: OECD Test Guideline 436
GLP: yes
Assessment: Harmful if inhaled.

Acute dermal toxicity : LD50 (Rat): 760 mg/kg


Method: OECD Test Guideline 402
Assessment: Toxic in contact with skin.

Components:

reaction products of paraformaldehyde and 2-hydroxypropylamine (ratio 3:2); [MBO]:


Acute oral toxicity : LD50 (Rat): 630 mg/kg
Method: OECD Test Guideline 423
Assessment: Harmful if swallowed.

Acute inhalation toxicity : LC50 (Rat): 2 mg/l


Exposure time: 4 h
Test atmosphere: dust/mist
Method: OECD Test Guideline 436
GLP: yes
Assessment: Harmful if inhaled.

Acute dermal toxicity : LD50 (Rat, female): 760 mg/kg


Assessment: Toxic in contact with skin.

Skin corrosion/irritation

Product:
Species : Rabbit
Assessment : Causes severe skin burns and eye damage.
Method : OECD Test Guideline 404
Result : Corrosive after 3 minutes to 1 hour of exposure
Test substance : concentrate

Components:

reaction products of paraformaldehyde and 2-hydroxypropylamine (ratio 3:2); [MBO]:


Species : Rabbit
Assessment : Causes severe skin burns and eye damage.
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

grotan® OX No Change Service!


Version Revision Date: Date of last issue: 06.06.2017
06.00 15.10.2018 Date of first issue: 20.01.2011

Method : OECD Test Guideline 404


Result : Corrosive after 3 minutes to 1 hour of exposure
Test substance : concentrate

Serious eye damage/eye irritation

Product:
Species : Rabbit
Assessment : Causes serious eye damage.
Method : OECD Test Guideline 405
Result : Risk of serious damage to eyes.
Test substance : concentrate

Species : Rabbit
Result : No eye irritation
Test substance : 0,2 % solution

Components:

reaction products of paraformaldehyde and 2-hydroxypropylamine (ratio 3:2); [MBO]:


Species : Rabbit
Assessment : Causes serious eye damage.
Method : OECD Test Guideline 405
Result : Risk of serious damage to eyes.
Test substance : concentrate

Respiratory or skin sensitisation

Product:
Species : Guinea pig
Assessment : The product is a skin sensitiser, sub-category 1A.
Method : OECD Test Guideline 406
Result : May cause an allergic skin reaction.

Components:

reaction products of paraformaldehyde and 2-hydroxypropylamine (ratio 3:2); [MBO]:


Species : Guinea pig
Assessment : The product is a skin sensitiser, sub-category 1A.
Method : OECD Test Guideline 406
Result : Causes sensitisation.

Germ cell mutagenicity

Product:
Germ cell mutagenicity- As- : Mutagenic Category 2, Classified based on the conditions
sessment cited in Note 9 (Regulation (EC) 1272/2008, Annex VI, Part 3,
Note 9).

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

grotan® OX No Change Service!


Version Revision Date: Date of last issue: 06.06.2017
06.00 15.10.2018 Date of first issue: 20.01.2011

Components:

reaction products of paraformaldehyde and 2-hydroxypropylamine (ratio 3:2); [MBO]:


Genotoxicity in vivo : Test Type: Mutagenicity (in vivo mammalian bone-marrow
cytogenetic test, chromosomal analysis)
Species: Mouse
Method: OECD Test Guideline 475
Remarks: Did not show mutagenic effects in animal experi-
ments.

Germ cell mutagenicity- As- : Mutagenic Category 2, Classified based on the conditions
sessment cited in Note 9 (Regulation (EC) 1272/2008, Annex VI, Part 3,
Note 9).

Carcinogenicity

Product:
Carcinogenicity - Assess- : May cause cancer., Classified based on the conditions cited in
ment Note 8 (Regulation (EC) 1272/2008, Annex VI, Part 3, Note 8).

Components:

reaction products of paraformaldehyde and 2-hydroxypropylamine (ratio 3:2); [MBO]:


Carcinogenicity - Assess- : May cause cancer., Classified based on the conditions cited in
ment Note 8 (Regulation (EC) 1272/2008, Annex VI, Part 3, Note 8).

Reproductive toxicity

Product:
Reproductive toxicity - As- : Not classified based on available information.
sessment

Components:

reaction products of paraformaldehyde and 2-hydroxypropylamine (ratio 3:2); [MBO]:


Reproductive toxicity - As- : Not classified based on available information.
sessment

STOT - single exposure

Product:
Assessment : Not classified based on available information.

Components:

reaction products of paraformaldehyde and 2-hydroxypropylamine (ratio 3:2); [MBO]:


Remarks : Based on available data, the classification criteria are not met.

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

grotan® OX No Change Service!


Version Revision Date: Date of last issue: 06.06.2017
06.00 15.10.2018 Date of first issue: 20.01.2011

STOT - repeated exposure

Product:
Target Organs : Respiratory Tract, Gastrointestinal tract
Assessment : May cause damage to organs through prolonged or repeated
exposure.

Components:

reaction products of paraformaldehyde and 2-hydroxypropylamine (ratio 3:2); [MBO]:


Target Organs : Gastro-intestinal system, Respiratory system
Assessment : May cause damage to organs through prolonged or repeated
exposure.

Repeated dose toxicity

Product:
Species : Rat
NOAEL : 72 mg/kg
Application Route : Repeated dose (90 days) toxicity (oral)
Method : OECD Test Guideline, 408

Components:

reaction products of paraformaldehyde and 2-hydroxypropylamine (ratio 3:2); [MBO]:


Species : Rat
: < 100 mg/kg
Application Route : Repeated dose (90 days) toxicity (oral)
Method : OECD Test Guideline 408

Aspiration toxicity
No data available

SECTION 12: Ecological information

12.1 Toxicity

Product:
Toxicity to fish : LC50 (Brachidanio rerio): 57,7 mg/l

Toxicity to daphnia and other : EC50 (Daphnia magna): 37,9 mg/l


aquatic invertebrates Exposure time: 48 h

Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): 5,7 mg/l


Exposure time: 72 h

Toxicity to daphnia and other : NOEC: 1,3 mg/l


aquatic invertebrates (Chron- Exposure time: 21 d
ic toxicity) Species: Daphnia magna (Water flea)
Method: OECD Test Guideline 211

Toxicity to microorganisms : EC50 : 44 mg/l


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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

grotan® OX No Change Service!


Version Revision Date: Date of last issue: 06.06.2017
06.00 15.10.2018 Date of first issue: 20.01.2011

Method: OECD 209

Components:

reaction products of paraformaldehyde and 2-hydroxypropylamine (ratio 3:2); [MBO]:


Toxicity to fish : LC50 (Brachidanio rerio): 57,7 mg/l

Toxicity to daphnia and other : EC50 (Daphnia magna): 37,9 mg/l


aquatic invertebrates Exposure time: 48 h

Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): 5,7 mg/l


Exposure time: 72 h

Toxicity to microorganisms : EC50 : 44 mg/l


Method: OECD Test Guideline 209

12.2 Persistence and degradability

Product:
Biodegradability : Result: Readily biodegradable.
Method: OECD Test Guideline 306

Result: Readily biodegradable, according to appropriate


OECD test.
Biodegradation: 89,8 %
Exposure time: 28 d
Method: OECD Test Guideline 301B

Chemical Oxygen Demand : 17.887 mg/g


(COD) Test substance: 1 % solution

Components:

reaction products of paraformaldehyde and 2-hydroxypropylamine (ratio 3:2); [MBO]:


Biodegradability : Result: Readily biodegradable.
Method: OECD Test Guideline 306

Result: Readily biodegradable, according to appropriate


OECD test.
Biodegradation: 89,8 %
Exposure time: 28 d
Method: OECD Test Guideline 301B

12.3 Bioaccumulative potential

Components:

reaction products of paraformaldehyde and 2-hydroxypropylamine (ratio 3:2); [MBO]:


Partition coefficient: n- : log Pow: -0,3
octanol/water

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

grotan® OX No Change Service!


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12.4 Mobility in soil

Product:
Distribution among environ- : Remarks: No data available
mental compartments

12.5 Results of PBT and vPvB assessment

Product:
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher..

12.6 Other adverse effects

Product:
Adsorbed organic bound : Remarks: Product does not contain any organic halogens.
halogens (AOX)

SECTION 13: Disposal considerations

13.1 Waste treatment methods


Product : Dispose of as special waste in compliance with local and na-
tional regulations.
Can be disposed of as a solid waste or burned in a suitable
installation subject to local regulations.

Contaminated packaging : Empty containers should be taken to an approved waste han-


dling site for recycling or disposal.

Waste key for the unused : The waste producer itself must, in consultation with the ap-
product(Group) propriate authorities and a waste disposal company, obtain a
waste code from the EWC (European Waste Catalogue)

SECTION 14: Transport information

14.1 UN number

IMDG : UN 2922
IATA : UN 2922
14.2 UN proper shipping name

IMDG : CORROSIVE LIQUID, TOXIC, N.O.S.


(reaction products of paraformaldehyde and 2-
hydroxypropylamine (ratio 3:2); [MBO])
IATA : CORROSIVE LIQUID, TOXIC, N.O.S.
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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

grotan® OX No Change Service!


Version Revision Date: Date of last issue: 06.06.2017
06.00 15.10.2018 Date of first issue: 20.01.2011

(reaction products of paraformaldehyde and 2-


hydroxypropylamine (ratio 3:2); [MBO])
14.3 Transport hazard class(es)

IMDG : 8
IATA : 8
14.4 Packing group

IMDG
Packing group : II
Labels : 8 (6.1)
EmS Code : F-A, S-B
IATA (Cargo)
Packing instruction (cargo : 855
aircraft)
Packing group : II
Labels : Corrosive, Toxic
IATA (Passenger)
Packing group : II
Labels : Corrosive
14.5 Environmental hazards

IMDG
Marine pollutant : yes
14.6 Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and var-
iations in regional or country regulations.
For personal protection see section 8.
14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable for product as supplied.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mix-
ture
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of
major-accident hazards involving dangerous substances.
E2 ENVIRONMENTAL
HAZARDS

Volatile organic compounds : none, Directive 2010/75/EC on the limitation of emissions of


volatile organic compounds

15.2 Chemical safety assessment


Not applicable

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

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06.00 15.10.2018 Date of first issue: 20.01.2011

SECTION 16: Other information

Full text of other abbreviations

ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways; ADR - European Agreement concerning the International Carriage of Dangerous
Goods by Road; AICS - Australian Inventory of Chemical Substances; ASTM - American Society
for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regula-
tion; Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN
- Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Cana-
da); ECHA - European Chemicals Agency; EC-Number - European Community number; ECx -
Concentration associated with x% response; ELx - Loading rate associated with x% response;
EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx -
Concentration associated with x% growth rate response; GHS - Globally Harmonized System;
GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - In-
ternational Air Transport Association; IBC - International Code for the Construction and Equip-
ment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentra-
tion; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical
Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Mari-
time Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisa-
tion for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration
to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal
Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not
Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No
Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop-
ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu-
lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc-
es; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No
1907/2006 of the European Parliament and of the Council concerning the Registration, Evalua-
tion, Authorisation and Restriction of Chemicals; RID - Regulations concerning the International
Carriage of Dangerous Goods by Rail; SADT - Self-Accelerating Decomposition Temperature;
SDS - Safety Data Sheet; SVHC - Substance of Very High Concern; TCSI - Taiwan Chemical
Substance Inventory; TRGS - Technical Rule for Hazardous Substances; TSCA - Toxic Sub-
stances Control Act (United States); UN - United Nations; vPvB - Very Persistent and Very Bioac-
cumulative

Further information

Classification and procedure used to derive the classification for mixtures according to Regulation
(EC) No. 1272/2008
Acute Tox. 4, H302 : On basis of test data.
Acute Tox. 3, H311 : On basis of test data.
Acute Tox. 4, H332 : On basis of test data.
Skin Corr. 1B, H314 : On basis of test data.
Skin Sens. 1A, H317 : On basis of test data.
Eye Dam. 1, H318 : On basis of test data.
Muta. 2, H341 : REGULATION (EC) No 1272/2008
Carc. 1B, H350 : REGULATION (EC) No 1272/2008
STOT RE 2, H373 : On basis of test data.
Aquatic Chronic 2, H411 : REGULATION (EC) No 1272/2008

Z11021_03 ZSDB_P_ALL EN Page 15/16


SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

grotan® OX No Change Service!


Version Revision Date: Date of last issue: 06.06.2017
06.00 15.10.2018 Date of first issue: 20.01.2011

Changes since the last version are highlighted in the margin. This version replaces all previous
versions.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

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