Extended Safety Data Sheet

in accordance to Regulation (EC) No 1907/2006 (as amended by Commission Regulation (EU) No 453/2010)
STERLITAMAK
PETROCHEMICAL EC No. 204-881-4 eSDS: v.1.00
PLANT AGIDOL-1 CAS No. 128-37-0 Date: 01/01/2011

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Trade name: Agidol-1
Chemical name: 2,6-di-tert-butyl-p-cresol
Synonyms: Butylated hydroxytoluene
BHT
EC Name: 2,6-di-tert-butyl-p-cresol
Index No: Not available
(Annex VI to Regulation (EC)
No 1272/2008)
EC No: 204-881-4
CAS No: 128-37-0
Registration No: 01-2119480433-40-0000
(assigned under Article 20(3) of
Regulation (EC) No 1907/2006)

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses: BHT is a registered antioxidant, licensed for food and animal feed
products, cosmetics, packaging materials.
Because of its chemical-physical properties, BHT is used as an
antioxidant/stabiliser in a wide variety of products, including petroleum
products, synthetic rubbers, plastics, elasomers, oils, waxes, soaps,
paints, inks, etc.
BHT as such is used at industrial settings only. It is not available to
consumers as such.
BHT is present in the end-use products as a substance bound into or onto
matrix.
The CSR defines the following uses of BHT:

IU0 [importation and storage –INDUSTRIAL USE];

IU1 [Use as a stabilizing (antioxidant) component substance in
manufacture of other (any, not specified) products–
INDUSTRIAL USE]

IU2 [General Use as a stabilizing (antioxidant) component
substance within other (any, not specified) products –
INDUSTRIAL, PROFESSIONAL, CONSUMER USE ]
Uses advised against: BHT shall not be available to general public/consumers as such.
BHT shall not be used in contradiction to all relevant national/regional
restrictions applied to this substance, including, but not limited to, those
prescribed by REACH regulation.
Exposure scenario(s): For detailed information on exposure assessment, please, refer Annex I
to this eSDS.

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 Extended Safety Data Sheet
in accordance to Regulation (EC) No 1907/2006 (as amended by Commission Regulation (EU) No 453/2010)
STERLITAMAK
PETROCHEMICAL EC No. 204-881-4 eSDS: v.1.00
PLANT AGIDOL-1 CAS No. 128-37-0 Date: 01/01/2011

1.3. Details of the supplier of the eSDS

Company Contact Details: Open Joint-Stock Company «Sterlitamak Petrochemical Plant» (JSC
SPP)
10, Technicheskaya ulitsa, Sterlitamak
The Republic of Bashkortostan, 453110
The Russian Federation
Contact person: Oksana [Link]
Tel: +7 (3473) 20-75-24 Fax: +7 (3473) 21-65-36
e-mail: kovalenko@[Link]
Only Representative Contact Angefero Limited LLC
Details: Office12, 1 Agiou Neofitou
P.O. 6015, Larnaca, Cyprus
Contact person: Roman M. Shumiazki
Tel: +357 24665907/08 Fax: +357 24665906
e-mail: angefero@[Link]
1.4. Emergency telephone number
Company +007 3473 20-75-24
OR Emergency number: +357 2466 5907/08
European Country Emergency Please, refer to Annex II of this eSDS for the list of Emergency
Number: telephones of European Poisons Centers
NOTE: The list of emergency telephone numbers is provided here for
reference only. It may not be complete or correct. Please, consult with
your local/national competent authorities for the emergency number in
your country.

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to the Not available
criteria of Regulation (EC) No
1272/2008 (CLP Regulation) (as
listed in Annex VI, table 3.1):
Classification according to the Not available
DSD/DPD criteria of Annex I of
Directive 67/548/EEC and as
reported in Regulation (EC) No
1272/2008 (Annex VI, table 3.2):
Self classification (according to for physical-chemical properties: Not classified
the GHS criteria of Regulation
(EC) No 1272/2008 (CLP for health hazards: Not classified
Regulation)
Corresponds to the GHS criteria:
for environmental hazards:
Hazards to the aquatic environment: Chronic Category 1
H410: Very toxic to aquatic life with long lasting effects.

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 Extended Safety Data Sheet
in accordance to Regulation (EC) No 1907/2006 (as amended by Commission Regulation (EU) No 453/2010)
STERLITAMAK
PETROCHEMICAL EC No. 204-881-4 eSDS: v.1.00
PLANT AGIDOL-1 CAS No. 128-37-0 Date: 01/01/2011

2.2. Label elements

Labelling according to the GHS Signal word: Warning
criteria of Regulation (EC) No
Hazard pictograms:
1272/2008 (CLP Regulation)
Corresponds to the GHS criteria:

GHS09: environment
Hazard statements:
H410: Very toxic to aquatic life with long lasting effects.
Precautionary statements:
Prevention:
P273: Avoid release to the environment.
Response:
P391: Collect spillage.
Disposal:
P501: Dispose of contents/container in accordance with local/ regional/
national/ international regulation.
Labelling according to the Not applicable.
DSD/DPD criteria of Annex I of
Directive 67/548/EEC and as
reported in Regulation (EC) No
1272/2008 (Annex VI, table 3.2):
2.3. Other hazards
Physical Chemical Hazards: Fire and Explosion Hazards:
• Fire Potential: Slight.
• Hazardous Decomposition: When heated to decomposition,
this substance emits toxic fumes.
Chemical Hazard:
• The substance decomposes on burning and on contact with
oxidizing materials.
Human Health Hazards: Eye and Skin Contact:
• May cause skin and eye redness.
Inhalation:
• Respiratory irritation effects (i.e. cough, sore throat) may
occur on inhalation to dust particles of BHT.

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 Extended Safety Data Sheet
in accordance to Regulation (EC) No 1907/2006 (as amended by Commission Regulation (EU) No 453/2010)
STERLITAMAK
PETROCHEMICAL EC No. 204-881-4 eSDS: v.1.00
PLANT AGIDOL-1 CAS No. 128-37-0 Date: 01/01/2011

SECTION 3: Composition/information on ingredients

3.1. Substances
Main constituent(s): CAS No Chemical name % (mass) EC No
128-37-0 2,6-di-tert-butyl-p- ≥ 99% 204-881-4
cresol
Stabilizer(s): Not used
Other Hazardous Components/ Absent
Impurities:

SECTION 4: First aid measures

4.1. Description of first aid measures

Eye and Skin Contact: • Eyes: First rinse with plenty of water for several minutes. If
irritation occurs, get medical attention.
• Skin: Remove contaminated clothes. Rinse and then wash
skin with water and soap. If irritation occurs, get medical
attention.
Inhalation: • If a person breathes in large amounts of this chemical, move
the exposed person to fresh air at once. Keep the affected
person warm and at rest. Get medical attention.
Ingestion: • If affected person is in conscious state, then rinse mouth.
Keep the affected person warm and at rest. Get medical
attention.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation: • Inhalation to high concentration of dust may cause irritation
symptoms to respiratory apparatus.
Skin/Eye contact: • May cause skin or eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Acute exposure: • For special medical treatment please, refer to medical
professionals.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Extinguishing media: • Extinguish with Carbon dioxide and powdered fire
extinguisher.
5.2. Special hazards arising from the substance or mixture
Fire and Explosion Hazards: • Not Flammable.
• Combustible.
• Flash point 114 deg C.
• Self-ignition temperature 425 deg C

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 Extended Safety Data Sheet
in accordance to Regulation (EC) No 1907/2006 (as amended by Commission Regulation (EU) No 453/2010)
STERLITAMAK
PETROCHEMICAL EC No. 204-881-4 eSDS: v.1.00
PLANT AGIDOL-1 CAS No. 128-37-0 Date: 01/01/2011

Unusual fire and explosion • When heated to decomposition, this substance emits toxic
hazards: fumes
5.3. Advice for firefighters
Special fire fighting procedures: • Avoid unnecessary run-off of fire-prevention media and of
extinguishing media (water cooling, fighting a fire with
water and foam) which may cause pollution at contact with
BHT.
Personal protection: • Use corresponding protective clothes, individual means of
eye protection, self contained breathing apparatus.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel
Precautionary measures: • Avoid direct contact with eyes, skin, and inhalation of dust.
• Use corresponding protective clothes, individual means of
eye protection, self contained breathing apparatus.
• Eliminate sources of ignition and sparks.
• If appropriate, provide ventilation of premises
6.1.2. For emergency responders
• Similarly to sub-paragraph 6.1.1. of the eSDS
6.2. Environmental precautions
Accidental Spills and Releases: • Do NOT let this chemical enter the environment, keep away
from drains, surface and ground water.
6.3. Methods and material for containment and cleaning up
If BHT is spilled, the following • Sweep spilled substance into containers; if appropriate,
steps should be undertaken: moisten first to prevent dusting.
• Do NOT wash away into sewer.
• Do NOT let this chemical enter the environment.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Training: • Any person who comes into contact with BHT needs to be
trained in proper handling and safety per applicable federal,
state and local laws and regulations.
• Employers must advise employees of all areas and
operations where exposure to BHT might occur.
Handling: • Avoid dust generation.
• Avoid inhalation of dust, ingestion, and contact with eyes
and skin.
• Do not eat, drink, or smoke during work. Wash hands before
eating.

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 Extended Safety Data Sheet
in accordance to Regulation (EC) No 1907/2006 (as amended by Commission Regulation (EU) No 453/2010)
STERLITAMAK
PETROCHEMICAL EC No. 204-881-4 eSDS: v.1.00
PLANT AGIDOL-1 CAS No. 128-37-0 Date: 01/01/2011

7.2. Conditions for safe storage, including any incompatibilities

Storage: • Store separated from food and feedstuffs. Store in covered
dry storehouses at a distance of 1 meter from heating body
at the temperature from minus 300C to plus 40 0C protecting
from direct sunlight and humidity.
Substances, incompatible in joint • Strong oxidizers
storage
7.3. Specific end use(s)
Influence of the identified uses, • For more detailed information on risks, RMM and control
specified in sub-paragraph 1.2. measures, please, refer to Section 8 and Annex I of the
of the eSDS, to the human eSDS.
health:
Influence of the identified uses, • BHT is classified as very toxic to aquatic life with long
specified in sub-paragraph 1.2. lasting effects. Do NOT let this chemical enter the
of the eSDS, to the environment: environment.
• For more detailed information, please, refer to Sections 8,
12 and Annex I of the eSDS.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

International Occupational Organization Limit value -8-hour Limit value–
Exposure Limit values: Short-term
ppm mg/m3 ppm mg/m3
American Conference of - 2 mg/m3, - -
Governmental and
Inhalable particulate and
Industrial Hygienists -
vapor
ACGIH (TLV) [TWA]
EU Occupational Exposure Limit No harmonized OEL values are established for BHT in the EU.
values:
DNEL/DMEL from the CSR in The following critical DN(M)ELs are proposed for occupational
accordance with REACH inhalation exposure:
regulation:
• DMEL=2 mg/m3 (inhalable particulate and vapour)
(Note: These values are not legally binding and are referred here for
recommendation purpose only. All currently adopted by the
national/regional competent authority levels on safe exposure to this
chemical shall apply):
PNECs from the CSR in PNEC (water) = 0.004 mg/L;
accordance with REACH PNEC (sediment) = 0.731 mg/kg;
regulation: PNEC (soil) = 0.350 mg/L.
(Note: These values are not legally binding and are referred here for
recommendation purpose only. All currently adopted by the
national/regional competent authority levels on safe exposure to this
chemical shall apply):

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 Extended Safety Data Sheet
in accordance to Regulation (EC) No 1907/2006 (as amended by Commission Regulation (EU) No 453/2010)
STERLITAMAK
PETROCHEMICAL EC No. 204-881-4 eSDS: v.1.00
PLANT AGIDOL-1 CAS No. 128-37-0 Date: 01/01/2011

8.2. Exposure controls

Occupational Exposure Controls:
Engineering controls and good • Taking into account the information presented in sub-
work practices: paragraph 8.1 of the eSDS the organization of
manufacturing processes, connected with use of BHT, shall
provide dust and vapors content of the substance at
workplaces below permissible level established by
company’s inner requirements.
• Periodic analytical control of air condition at workplaces,
engineering control of used equipment condition shall be
carried out according to federal / national / local legislation
in force.
Respiratory Protection: • Personal Protective Equipment/ Respiratory Protection:
Respiratory protection should be used in accordance with
federal / national / local legislation requirements.
• Respiratory protection is recommended to use to supplement
the engineering controls and work practices as individual
protective equipment of respiratory apparatus.
• Persons should not be assigned to tasks requiring the use of
individual protective equipment of respiratory apparatus
unless it has been determined they are physically able to
perform the work and are trained to use the equipment.
Chemical Protective Clothing: • The level of protection selected should be based on the
potential BHT concentration and likelihood of contact.
• Corresponding protective clothes, gloves of tight dust-proof
material are recommended as routine protection means from
contact with the substance.
Eye and Face Protection: • Appropriate eye and face protection may be necessary to
prevent contact with this substance.
• If there is a potential that this chemical can come in contact
with eye or face, eye googles and face masks shall be used.
Hazard communication: • The transmittal of hazard information to workers is to be
accomplished by such means as container labelling and
other forms of warning, material safety data sheets, and
employee training.
Housekeeping and Hygiene • The workplace should be kept clean, orderly, and in a
Facilities: sanitary condition. Adequate washing facilities shall be
provided and maintained in a sanitary condition.
• Do not eat, drink, or smoke during work. Wash hands before
eating.
Environmental Exposure controls:
Emission sources:
Controlled emissions: Emissions of substance to the atmosphere
and sewage waters, appearing during manufacturing processes
connected with its usage.

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 Extended Safety Data Sheet
in accordance to Regulation (EC) No 1907/2006 (as amended by Commission Regulation (EU) No 453/2010)
STERLITAMAK
PETROCHEMICAL EC No. 204-881-4 eSDS: v.1.00
PLANT AGIDOL-1 CAS No. 128-37-0 Date: 01/01/2011

Uncontained emissions: Release of the substance to the

environment at emergency cases during manufacturing
processes connected with usage of BHT, as the results package
integrity damage connected with violation of handling operation,
transportation, storage requirements.
Summary of RMM relevant to
BHT is classified as very toxic to aquatic life with long lasting
environment: effects. To reduce the risks connected with release of BHT to the
environment the measures of Good Manufacturing Practice,
engineering control of production equipment condition,
corresponding organization of handling operations,
transportation, storage shall be adopted.

If the substance is present in emissions to air and sewage waters
the limits of its concentration shall not exceed the limits
established by federal / state and local legislation.

Waste-related: The transportation, storage, treatment, and
disposal of this waste material must be conducted in compliance
with local regulations for hazardous wastes. Disposal can occur
only in properly permitted facilities. Check state and local
regulation of any additional requirements for disposal
conditions.

For detailed information on estimation of influence of BHT to
the environment, please, refer to Section 12 of the eSDS.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance: Solid substance (in flakes, crystals)
Odour: -
Odour threshold: -
pH: -
Melting point/freezing point: 70oC
Initial boiling point and boiling 265oC
range:
Flash point: 114oC
Flammability: Not Flammable
Upper/lower flammability or -
explosive limits:
Vapour pressure: 0.00177 mm Hg ; 0.236 Pa (estimated, at 25 °C)
Relative density: 1.04 (relative density at 20 deg C)
Solubility(ies): Water: <1 mg/L (at 25 °C)
Partition coefficient: n- log Kow/ log Pow =5 (calculated)
octanol/water:
Auto-ignition temperature: 425°C

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 Extended Safety Data Sheet
in accordance to Regulation (EC) No 1907/2006 (as amended by Commission Regulation (EU) No 453/2010)
STERLITAMAK
PETROCHEMICAL EC No. 204-881-4 eSDS: v.1.00
PLANT AGIDOL-1 CAS No. 128-37-0 Date: 01/01/2011

Explosive properties: Not explosive, Contains no groups associated with explosive properties.
Oxidising properties: Not oxidizing
9.2. Other information
Henry’s law constant (HLC): BHT dissolves in etanol, acetone, ecetic ether, methylene chloride,
carbon tetrachloride, benzol, benzene, fats.
0.342 Pa-m3/ mole (estimated, at 25 ºC)

SECTION 10: Stability and reactivity

10.1. Reactivity
Chemical dangers: • The substance decomposes on burning and on contact with
oxidizing materials.
10.2. Chemical stability
Stability conditions: • Stable if stored and applied as directed
10.3. Possibility of hazardous reactions
Special precautions: • Store separated from strong oxidants.
10.4. Conditions to avoid
Conditions contributing to • Keep away from heat and sources of ignition
instability:
10.5. Incompatible materials
Incompatibilities: • The substance decomposes on burning and on contact with
oxidizing materials.
10.6. Hazardous decomposition products
Hazardous decomposition • When heated to decomposition, this substance emits toxic
products: fumes.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Toxicokinetics (absorption, The toxicokinetics of BHT have been comprehensively reviewed and
metabolism, distribution and reported elsewhere (WHO, 1964, 1986, 1995; OECD, 2005).
elimination): The uptake, metabolism, distribution and elimination of BHT were
investigated in a number of in vivo and in vitro studies in animals
providing similar results. Experiments in animal test systems
demonstrated that BHT was readily absorbed via the gastrointestinal
tract and metabolised in test animals.
Higher concentrations of BHT were observed in the adipose tissue and
liver. However, no bioaccumulation was seen for BHT.
BHT is metabolized by cytochrome P450 (CYP) enzymes. The
metabolites observed include ester glucuronide and ether glucuronide.
BHT is excreted with urine (main elimination route) and faeces.

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 Extended Safety Data Sheet
in accordance to Regulation (EC) No 1907/2006 (as amended by Commission Regulation (EU) No 453/2010)
STERLITAMAK
PETROCHEMICAL EC No. 204-881-4 eSDS: v.1.00
PLANT AGIDOL-1 CAS No. 128-37-0 Date: 01/01/2011

Acute toxicity: Experimental data:

Oral LD50 (rats)>2000 mg/kg;
Dermal LD50 (rats) >2000 mg/kg.
Discussion:
BHT is a non volatile solid substance with low water solubility and low
vapour pressure. It can be absorbed via gastrointestinal tract and via skin
contact.
Available experimental data on acute toxicity of BHT include studies by
oral and dermal exposure routes performed in rodents. The data on oral
and dermal exposure to BHT are above the threshold for classification of
BHT for acute toxicity (i.e. > 2000 mg/kg b.w.).
There are no data on acute toxicity of BHT in humans.
Given, that BHT is used in industry for a long time, the lack of reports
on serious adverse acute toxicity effects (e.g., death) of BHT support the
low acute toxicity of BHT.
In conclusion, BHT is considered to be of low acute toxicity.
Skin corrosion/irritation: BHT was slightly irritating to the skin of rabbits. The irritating effects
observed were mild and reversible within 72 hours (OECD, 2005).
Exposure to BHT may cause skin redness (ICSC 0841).
Serious eye damage/irritation: BHT was slightly irritating to the eye of rabbits. The irritating effects
observed were mild and completely reversible within 72 hours (OECD,
2005).
Exposure to BHT may cause eye redness (ICSC 0841).
Respiratory irritation: BHT is a solid substance in a form of flakes or crystals and, therefore,
respiratory irritation to dust particles may occur on inhalation of BHT.
Respiratory or skin sensitization: Skin sensitisation:
In humans, contact dermatitis were reported in few cases. The OECD
High Production Volume chemicals evaluation programme (OECD
SIDS, 2005) of BHT suggests that though BHT was tested negative in
great numbers of workers or patients, sensitization reactions cannot be
fully excluded in single cases.
In accordance with the CLP criteria, skin sensitizer is defined as “a
substance that will lead to an allergic response following skin contact”.
To be classified as a skin sensitiser (Category 1) there must be evidence
of chemicals’s sensitizing effects observed in substantial number of
people.
In humans, contact dermatitis associated with BHT were reported for
some individuals. Therefore, based on the data summarised here, BHT is
likely to cause allergy in susceptible individuals.
However, taken the small number of possibly affected, it is not sufficient
to classify BHT in Category 1 Skin Sensitiser.

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 Extended Safety Data Sheet
in accordance to Regulation (EC) No 1907/2006 (as amended by Commission Regulation (EU) No 453/2010)
STERLITAMAK
PETROCHEMICAL EC No. 204-881-4 eSDS: v.1.00
PLANT AGIDOL-1 CAS No. 128-37-0 Date: 01/01/2011

Respiratory sensitisation:
In accordance with the CLP criteria, respiratory sensitizer is defined as
“a substance that will lead to hypersensitivity of the airways following
inhalation of the substance”. Generally, a substance is classified as
respiratory sensitizer if there is evidence in humans that the substance
can lead to specific respiratory hypersensitivity and/or if there are
positive results from an appropriate animal test.
Currently, no recognized animal models for the testing of respiratory
hypersensitivity are available.
Therefore, evidence that a substance can induce specific respiratory
hypersensitivity will normally be based on human experience. However,
no hypersensitivity reactions associated with exposure to BHT were
reported in humans.
In conclusion, based on the respiratory sensitization data summarized
here and taking into account that there have been no reports of
respiratory sensitization caused by BHT, it is not considered to be a
respiratory sensitizer.
Germ cell mutagenicity: BHT showed no potential to cause point mutations in bacterial and
mammalian test systems (WHO, 1986; OECD, 2005).
Additionally, BHT was estimated for mutagenic properties with the
currently available QSAR/SAR model for this endpoint (CAESAR
QSAR model for Mutagenicity v.[Link]) with overall result: Non-
Mutagen.
There are no data on genotoxicity of BHT in humans.
Based on the data, summarised in this section, BHT is not considered as
being genotoxic/ mutagenic.
Carcinogenicity The NTP 2-year study of carcinogenicity of BHT in rats and mice
observed no treatment-related neoplastic lesions. The study authors
concluded that BHT was not carcinogenic for F344 rats or B6C3F1 mice
under applied test conditions (NTP, 1979).
The International Agency on Research of Cancer (IARC) provides the
following evaluation of carcinogenicity of BHT (IARC, 1986, 1987):
• Overall evaluation BHT: is not classified as carcinogen
(Group 3).
Overall, BHT is not considered to be carcinogenic.
Reproductive toxicity: In general, there is no clear evidence for a direct effect of BHT on
fertility/ fetal development, in the absence of systemic toxicity.

STOT-single & repeated Repeated dose oral toxicity studies:

exposure:
BHT was reported to affect liver as a target organ in animal repeated
dose toxicity studies (WHO, 1995). BHT has been shown to induce
hepatocellular necrosis and proliferation in male Wistar rats at doses
which exceeded the maximum tolerated dose (sublethal oral doses of
1000 -1250 mg/kg bw/day).

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 Extended Safety Data Sheet
in accordance to Regulation (EC) No 1907/2006 (as amended by Commission Regulation (EU) No 453/2010)
STERLITAMAK
PETROCHEMICAL EC No. 204-881-4 eSDS: v.1.00
PLANT AGIDOL-1 CAS No. 128-37-0 Date: 01/01/2011

The Joint FAO/WHO Expert Committee on Food Additives considers

enzyme induction as the most sensitive index of toxicity effects of BHT
on liver (WHO, 1995). This evaluation report also conclude that a well
defined threshold was demonstrated at a dose of 100 mg/kg bw/day in a
long-term study with a NOEL of 25 mg/kg bw/day.

SECTION 12: Ecological information

12.1. Toxicity
Aquatic environment: BHT is not considered to degrade fast in the environment. The
BCF/BAF values estimated for BHT are above the cut-off values for
bioaccumulation (<500 L/kg wet-w) suggesting that BHT may have
some potential for bioaccumulation in aquatic life.
The ecotoxicity data on BHT are summarised as follows:
• Acute toxicity: LC50(EC50) <1 mg/L (published data and
estimated with ECOSAR v.1.00);
• Chronic toxicity: NOEC <1 mg/L (published data and
estimated with ECOSAR v.1.00).
This corresponds to Chronic Category 1 toxicity classification for BHT.
Acute toxicity: L(E)C50 0.464 mg/L fish, ECOSAR estimated
0.386 mg/L invertebrates, ECOSAR estimated
0.84 mg/L invertebrates, measured
0.577 mg/L green algae, ECOSAR estimated
Chronic toxicity: L(E)C50 0.096 mg/L invertebrates, measured

Chronic toxicity:NOEC 0.053 mg/L fish, measured

0.041 mg/L fish, ECOSAR estimated
0.061 mg/L invertebrates, ECOSAR estimated
0.363 mg/L green algae, ECOSAR estimated

Terrestrial environment: There are no data on toxicity of BHT to terrestrial (soil) organisms.
BHT is a non volatile solid substance which is insoluble in water. The
value for soil organic carbon-water partition coefficient calculated using
KOCWIN v. 2.0 (log Koc = 3.91 -4.17) suggests that BHT has some
potential to adsorb onto soil and sediment.
In the absence of ecotoxicity data for soil organisms, the PNEC soil is
calculated using the equilibrium partitioning method (EPM) as follows
(in accordance with ECHA Guidance on Information Requirements, Part
B):
PNEC soil =(0.174 + 0.0104 x Koc) x PNEC water.
Estimated Koc for BHT =8183 -14750 L/kg (by following a
precautionary approach, the lowest estimated Koc value of 8183 L/kg
will be used in the calculation); PNEC water =0.004 mg/L.
Therefore, PNEC soil= 0.350 mg/kg is calculated for BHT.

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 Extended Safety Data Sheet
in accordance to Regulation (EC) No 1907/2006 (as amended by Commission Regulation (EU) No 453/2010)
STERLITAMAK
PETROCHEMICAL EC No. 204-881-4 eSDS: v.1.00
PLANT AGIDOL-1 CAS No. 128-37-0 Date: 01/01/2011

12.2. Persistence and degradability

Hydrolysis: BHT is a solid substance which is poorly soluble in water. It contains
functional groups with weak potential for dissociation. Based on the
dissociation constant data and assuming poor solubility of BHT, this
substance is not likely to dissociate significantly in water under normal
environmental conditions.
Phototransformation/ photolysis: Photooxidation of BHT can be estimated using a computer model
accepted by the US EPA. The Atmospheric Oxidation Program for
Microsoft Windows (AOPWIN, v.1.92) estimated the following data:
Reaction with hydroxyl radicals at 25oC:
Overall OH Rate Constant: =18.2887 x 10-12 cm3/molecule-sec
Half Life: =0.585 days, 7.018 hours (12-hour day; 1.5x106 OH/cm3)
Thus, a half life of 0.585 days is estimated for reaction of BHT with
hydroxyl radicals in the atmosphere at 25oC [AOPWIN Program,
v.1.92].
Biodegradation: BHT is a non volatile solid substance which is almost insoluble in water.
The environmental fate of BHT in water and sediment will be
determined by biotic and abiotic transformation.
The QSARs estimated half-lives for biodegradation of BHT in water and
sediment based upon BIOWIN Ultimate Biodegradation are 900 hours
(37.5 days) and 8100 hours (337.5 days), respectively. Whereas the half-
lives of BHT for volatilization from water are estimated as 10.78 days
(for a river) and 122.8 days (for a lake) using EPI Suite software.
The QSAR models predict timeframe within weeks for primary
biodegradation of BHT and weeks-months for its ultimate degradation.
Overall ready biodegradability prediction provided by a number of
BIOWIN (v.4.10) models suggests that BHT is not ready biodegradable
in the environment.
12.3. Bioaccumulative potential
Aquatic bioaccumulation: The Bioconcentration Factor (BCF), Bioaccumulation factor (BAF) as
well as Biotransformation Rate in fish were estimated by the BCFBAF
software using the Arnot-Gobas method. This method model estimates
steady-state BCF (L/kg) and BAF (L/kg) values for non-ionic organic
chemicals in three general trophic levels of fish (i.e. lower, middle and
upper) in temperate environments (default temperature is 10oC).
The modeling results are summarized as follows:
• Log BCF =2.81; BCF =646 L/kg wet wt (regression-based
estimate)
• Biotransformation half-life =1.15 days (normalized to 10 g
fish)
• Log BAF =2.91 BAF =820 L/kg wet-wt (Arnot-Gobas
upper trophic)

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Generally, a BCF/BAF in fish of ≥ 500 is indicative of the potential to

bioconcentrate for classification purposes in accordance with CLP/GHS
criteria.
The BCF/BAF values estimated for BHT are above the cut-off values for
bioaccumulation indicating some potential to bioaccumulate in aquatic
organisms.
Terrestrial bioaccumulation: There is no experimental data on terrestrial bioaccumulation of BHT.
BHT is not considered to degrade fast in the environment. Moreover, the
estimated log Kow and BCF/BAF values for this chemical suggest that it
is likely to exhibit some bioconcentration and biomagnification
potential.
BHT is not soluble in water. In addition, BHT was not reported to
bioaccumulate in experimental animals.

12.4. Mobility in soil

Environmental distribution: BHT is a solid, poor water soluble substance with low vapour pressure.
QSAR modeling predicts that BHT will volatize slowly from surface
water with estimated TD50 = 10.48 days (river) and 122.8 days (lake).
Once in air, BHT will react with hydroxyl radicals with half-life of 7
hour.
The value for soil organic carbon-water partition coefficient (logKoc =
3.91 -4.17) suggests that BHT has some potential to adsorb onto soil and
sediment and, therefore, it is not likely to contaminate groundwater.
The data on environmental distribution of BHT obtained from the level
III fugacity model (EPI Suit v.4.00) confirms that BHT does not degrade
fast and depending on various emission scenarios, most of BHT will be
in water, soil and sediment.
12.5. Results of PBT and vPvB assessment
Persistence Assessment: The half life of BHT in water, sediment and soil are 37.5 days, 337.5
days and 75 days, respectively.
Therefore, BHT meets the Persistence criteria for PBT and vPvB
substances.
Bioaccumulation Assessment: BCF/BAF (estimated values) = 646 -1669 L/kg wet-wt.
Therefore, BHT does not meet Bioaccumulation criteria for PBT
substance and does not meet Bioaccumulation criteria for vPvB
substance.
Toxicity Assessment: The lowest reliable predicted/measured long-term aquatic NOECs for
BHT of 0.04/0.05 mg/L are above the cut off level of 0.01 mg/L.
BHT is not classified as to its chronic toxicity to mammals.
Therefore, BHT does not meet the criteria for Toxicity.
Conclusions on PBT or vPvB BHT is considered as persistent substance.
Properties: However, it is not considered bioaccumulative/ very bioaccumulative or
toxic substance.
Therefore, BHT is not a PBT or vPvB substance.

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12.6. Other adverse effects

Secondary poisoning: BHT is of low acute and chronic toxicity. It does not bioaccumulate in
mammals and, therefore, secondary poisoning to BHT via food chain is
of no concern.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Disposal: This substance, when discarded or disposed of, is a hazardous waste.
The transportation, storage, treatment, and disposal of this waste
material must be conducted in compliance with local regulations for
hazardous wastes.
Disposal can occur only in properly permitted facilities. Check state and
local regulation of any additional requirements for disposal conditions.
Disposal of containers: Please, refer your local/national/regional requirements on disposal.

SECTION 14: Transport information

14.1. UN number
UN No: 3077
14.2. UN proper shipping name
UN Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
2,6-di-tert-butyl-p-cresol

14.3. Transport hazard class(es)

UN Class: 9
14.4. Packing group
UN Packing Group: III
14.5. Environmental hazards
Environmental Hazards Self-classification (in accordance with GHS/CLP classification criteria):
• Hazards to the aquatic environment: Chronic Category 1
• H410: Very toxic to aquatic life with long lasting effects.
14.6. Special precautions for user
Note: A number of restrictions may apply to materials subject to local/
national/regional classifications requirements. Please refer to the
appropriate regulation for specific details regarding classification
requirements and restrictions.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
- -

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SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture
Export and Import of Dangerous This substance is not listed in the Annex I of Regulation (EC) No
Chemicals (Regulation (EC) No 689/2008.
689/2008) Information:
CLP Regulation (EC) No This substance is not listed in Annex VI (tables 3.1 and 3.2) to CLP
1272/2008: regulation.
REACH Regulation (EC) No This substance is registered in accordance with provisions of REACH
1907/2006: regulation. For registration number, please refer section 1.1 of this
eSDS.
15.2. Chemical safety assessment
CSA: Chemical Safety Assessment has been carried out for this chemical in
accordance with provisions of REACH regulation.

SECTION 16: Other information

Abbreviations and acronyms:

BAF Bio Accumulation Factor
BCF Bio Concentration Factor
CAS No Chemical Abstracts Service number
CLP Classification Labelling Packaging Regulation ; Regulation (EC) No 1272/2008
CSA Chemical Safety Assessment
CSR Chemical Safety Report
DMEL Derived Minimal Effect Level
DNEL Derived No Effect Level
DPD Dangerous Preparation Directive 1999/45/EEC
DSD Dangerous Substances Directive 67/548/EEC
EC European Commission
EC50 Half maximal effective concentration
ECHA European Chemicals Agency
EC-Number EINECS and ELINCS Number (see also EINECS and ELINCS)
EINECS European Inventory of Existing Commercial Substances
ELINCS European List of notified Chemical Substances
ES Exposure Scenario
e-SDS Extended Safety Data Sheet (SDS with ES attached)
EU European Union
GHS Globally Harmonized System
IUPAC International Union for Pure Applied Chemistry
LC50 Lethal concentration, 50 %
LD50 Median Lethal Dose
OEL Occupational Exposure Limit
PBT Persistent, Bioaccumulative and Toxic substance
PNEC(s) Predicted No Effect Concentration(s)
PPE Personal Protection Equipment
(Q)SAR Qualitative Structure Activity Relationship

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PLANT AGIDOL-1 CAS No. 128-37-0 Date: 01/01/2011

REACH Registration, Evaluation, Authorisation and Restriction of Chemicals

Regulation (EC) No 1907/2006
RMM Risk Management Measure
STOT Specific Target Organ Toxicity
(STOT) RE Repeated Exposure
(STOT) SE Single Exposure
TLV Threshold Limit Values
UN United Nations
vPvB Very Persistent and Very Bioaccumulative
Key Literature References and Sources for data:
IARC Monographs on the Evaluation of Carcinogenic Risks to Humans, Volume 40, Some Naturally
Occurring and Synthetic Food Components, Furocoumarins and Ultraviolet Radiation
WORLD HEALTH ORGANIZATION, INTERNATIONAL AGENCY FOR RESEARCH ON CANCER,
1986
IARC MONOGRAPHS ON THE EVALUATION OF CARCINOGENIC RISKS TO HUMANS
OveraIl Evaluations of Carcinogenicity: An Updating of IARC Monographs Volumes 1 to 42
SUPPLEMENT 7, WORLD HEALTH ORGANIZATION INTERNATIONALAGENCY FOR RESEARCH
ON CANCER, 1987
ICSC: 0841 BUTYLATED HYDROXYTOLUENE, International Programme on Chemical Safety (IPCS),
Prepared in the context of cooperation between the International Programme on Chemical Safety and the
Commission of the European Communities IPCS, CEC 2001
OECD SIDS (2005) 2,6-di-tert-butyl-p-cresol (BHT) CAS No 128-37-0 UNEP Publications, 2005
US EPA EPI Suite v.4.00 2009
World Health Organization/ International Programme on Chemical Safety; WHO/Food Additives Report
38A Butylated Hydroxytoluene (1964)
WHO (1995) WHO Technical Report Series 859. Evaluation of certain food additives and contaminants.
Forty-fourth report of the Joint FAO/WHO Expert Committee on Food Additives. World Health
Organisation, Geneva 1995.
Document History:
Created: 01.01.2011
Document version: v.1.00
Last revision: 01.01.2011
Disclaimer:
The information contained herein is accurate and is based on the present state of our knowledge. Although
reasonable care has been taken in the preparation of this document, we extend no warranties and make no
representations as to the accuracy or completeness of the information contained herein, and assume no
responsibility regarding the suitability of this information for the user’s intended purposes or for the
consequences of its use. Each individual should make a determination as to the suitability of the information
for their particular purpose(s). All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.

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Annex I

Exposure Scenario addressing uses carried out by workers

1. Stabilizing (antioxidant) component substance in manufacture of other (any, not

specified) products–INDUSTRIAL USE [ES1]
Free short title: ES1: Use as a stabilizing (antioxidant) component substance in
manufacture of other (any, not specified) products (industrial uses)
Systematic title based on use Sectors of Use:
descriptor
SU 3: Industrial uses: Uses of substances as such or in preparations at
industrial sites
SU 10: Formulation [mixing] of preparations and/or re-packaging
(excluding alloys)
Product category:
Any, Not specified
Processes, tasks activities PROC1: Use in closed process, no likelihood of exposure
covered PROC2: Use in closed, continuous process with occasional controlled
exposure
PROC3: Use in closed batch process (synthesis or formulation)
PROC4: Use in batch and other process (synthesis) where opportunity for
exposure arises
PROC5: Mixing or blending in batch processes for formulation of
preparations and articles (multistage and/or significant contact)
PROC6: Calendering operations
PROC7: Industrial spraying
PROC8a: Transfer of substance or preparation (charging/discharging)
from/to vessels/large containers at non-dedicated facilities
PROC8b: Transfer of substance or preparation (charging/ discharging)
from/to vessels/large containers at dedicated facilities
PROC9: Transfer of substance or preparation into small containers
(dedicated filling line, including weighing)
PROC10: Roller application or brushing
PROC11: non industrial spraying
PROC14: Production of preparations or articles by tabletting,
compression, extrusion, pelletisation
PROC19: Hand-mixing with intimate contact and only PPE available
PROC21:Low energy manipulation of substances bound in material and
or articles
PROC24: High (mechanical) energy work-up of substances bound in
materials and/or articles
Assessment Method Qualitative Risk Assessment (Tier I Risk Assessment):

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2. Operational conditions and risk management measures

Occupational Exposure:
OELs: OELs currently adopted by the national/regional competent authority shall apply.
DN(M)ELs recommended by the CSR (not legally binding, recommendation purpose only):
• DMEL=2 mg/m3 (inhalable particulate and vapour)
Environmental Release Characterization:
ERC1:Manufacture of substances
ERC2: Formulation of preparations
ERC3: Formulation of materials
ERC5: Industrial use resulting in inclusion into or onto matrix
2.1 Control of workers exposure
Product characteristic: Physical state: non water soluble, non volatile solid substance
(flakes, crystals)
Risk management measures related
Avoid inhalation to dust particles, skin and eye contact.
to the design of product:
Use Personal Protective Equipment as required.
Amounts used: Not specifically defined
Frequency and duration of 8-hour work shift, Not specifically defined
use/exposure
Human factors not influenced by Respiration volume under conditions of use: Heavy work,
risk management respiration volume = 30 m3/8h-day; Light work, respiration
volume = 10 m3/8h-day - Default values (ECHA Guidance on CSA
Chapter R.15, Section R 8.4.2)
Other given operational conditions
Local Exhaust Ventilation relevant to industrial work
affecting workers exposure environment.
Technical conditions and measures
Engineering controls and good work practices;
at process level (source) to prevent
Regular monitoring for leak detection.
release:
Technical conditions and measures
Engineering controls and good work practices;
to control dispersion from source
General Local Exhaust Ventilation relevant to industrial
towards the worker: work environment;

Regular monitoring for leak detection;

Use of Respiratory Protection;

Protective clothing and equipment;

Hazard communication;

Housekeeping and Hygiene Facilities.
Note: Workers exposure to BHT may arise at operations where
BHT is used, including storage, loading/unloading areas.
Occupational exposure to BHT may arise at operations where BHT
is used, including storage, loading/unloading areas, leaks in the
conveyor systems, loading mixers, maintenance and cleaning
operations.

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2.2 Control of environmental exposure

Product characteristics Physical state: non water soluble, non volatile solid substance
(flakes, crystals)
Amounts used Not specifically defined
Frequency and duration of use Not specifically defined
365 d/y Assuming continuous industrial process.
Technical conditions and measures
Engineering controls and good work practices;
at process level (source) to prevent
Regular monitoring for leak detection;
release
Hazard communication;

Housekeeping and Hygiene Facilities.
Technical onsite conditions and Use related measures:
measures to reduce or limit

Do NOT let this chemical enter the ground;
discharges, air emissions and
releases to soil
Do NOT exceed the permitted levels of the substance
concentration in air and sewage waters established by
federal / state / local legislation.
Waste related measures:
This substance, when discarded or disposed of, is a hazardous
waste. The transportation, storage, treatment, and disposal of this
waste material must be conducted in compliance with local
regulations for hazardous wastes.
Disposal can occur only in properly permitted facilities. Check
state and local regulation of any additional requirements for
disposal conditions.
3. Exposure estimation and reference to its source
Workers exposure: Workers exposure to BHT may arise at operations where BHT is
used, including storage, loading/unloading areas. Occupational
exposure to BHT may arise at operations where BHT is used,
including storage, loading/unloading areas, leaks in the conveyor
systems, loading mixers, maintenance and cleaning operations.
4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES
Workers exposure: Use in industrial process. Applying all necessary RMM to reduce
exposure to BHT.

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Annex II

IPCS directory of poison centres: European Region

Info from the International Programme on Chemical Safety (IPCS) publicly available at
[Link] (data retrieved on 28 June 2010)

AUSTRIA Vienna Wien

Vergiftungsinformationszentrale (Poisons Information Centre)
Telephone: +43 1 40 400 2222 Allgemeines KrankenhausWaehringer Geurtel 18-20
Vienna 1090
BELGIUM Brussels Bruxelles
Centre Anti-Poisons/Antigifcentrum
Emergency telephone: +32 70 245 245 Hôpital Militaire Reine Astrid
Rue Bruyn
Brussels B -1120
BULGARIA Sofia
National Toxicological Information Centre
Emergency telephone: +359 2 9154 National Clinical Toxicology Centre
409 Emergency Medical Institute "Pirogov"
21 Totleben Boulevard
1606 SOFIA
Information Centre: Telephone: +359 2 950 0975
CROATIA Zagreb
Poisons Control Centre
Emergency telephone: +385 1 234 Institute of Medical Research & Occupational Health
8342 Ksaverska Cesta 2
P.O. Box 291
Zagreb HR-10000
CZECH REPUBLIC Prague Praha
Poisons Information Centre
Emergency telephone: +42 2 2491 Clinic For Occupational Medicine, 1st Medical Faculty,
9293 or +42 2 2491 5402 Charles University
Na Bojisti 1
128 00 Prague 2
DENMARK Copenhagen
Poison Information Centre
Emergency telephone, health sector: Bispebjerg Hospital
+45 35 31 55 55 Bispebjerg Bakke 23, 60, 1
DK-2400 Copenhagen NV
Emergency telephone, public: +45 82 12 12 12
FINLAND Helsinki
Poison Information Centre
Emergency telephone: +358 9 471 977 P.O.B 790 (Tukholmankatu 17)
SF - 00029 HUS
Helsinki
FRANCE Paris
Centre Antipoison et de Toxicovigilance de Paris
Emergency telephone: +33 1 40 05 48 Hôpital Fernand Widal
48 200 rue du Faubourg Saint-Denis
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75475 Paris Cedex 10

GERMANY Giftnotruf Berlin
Berliner Betrieb für Zentrale Gesundheitliche Aufgaben
Institut für Toxikologie
Emergency telephone: +49 30 19240 Klinische Toxikologie und Giftnotruf Berlin
Oranienburger Strasse 285
13437 Berlin
GREECE Athens Athinai
Poisons Information Centre
Emergency telephone: +30 10 779 Children's Hospital "Aglaia. Kyriakou"
3777 Athens 11527
HUNGARY Budapest
Országos Kémiai Biztonsági Intézet (National Institute of
Chemical Safety)
Emergency telephone number: +36 80 Egészségügyi Toxikológiai Tájékoztató Szolgálat (Health
20 11 99 Toxicological Information Service)
1097 Budapest, Nagyvárad tér 2.
1437 Budapest PO Box 839

ICELAND Reykjavik
Iceland Poisons Information Centre
Emergency telephone: +354 525 111, Landspitali University Hospital
+354 543 2222 Fossvogi
Reykjavik 108
IRELAND (REPUBLIC OF) Dublin
National Poisons Information Centre
Emergency telephone: +353 1 Beaumont Hospital
8379964 P.O. BOX 1297
Beaumont Road
Dublin 9
ISRAEL Haifa
Israel Poisons Information Centre
Rambam Medical Centre
Emergency telephone: +972 4 854 PO Box 9602
1900 Haifa 31096
ITALY Rome Roma
Centro Antiveleni (Poisons Centre)
Dipartimento di Tossicologia Clinica
Emergency telephone: +39 06 305 Universita Cattolica del Sacro Cuore
4343 Largo Agostino Gemelli 8
I-00168 Roma

LATVIA Riga
Latvian Poisons Information Centre
Emergency telephone: +371 704 2468 Clinical Hospital "Gailezers"
2 Hipocrate Street
Riga LV 1038
LITHUANIA Vilnius
Poisons Control and Information Bureau
Emergency telephone: +370 2 36 20 Siltnamiu 29

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52, +370 2 36 20 92 2043 Vilnius

NETHERLANDS Bilthoven
this service is only available to health professionals
Emergency telephone: +31 30 274 88 National Poisons Information Centre
88 National Institute for Public Health and the Environment
P.O. Box 1
Bilthoven 3720 BA
NORWAY Oslo
Poisons Information
Emergency telephone: +47 22 591300 Directorate of Health and Social Affairs
P.O. Box 7000
St. Olavs Plass
0130 Oslo
POLAND Warsaw Warszawa
Warsaw Poison Control and Information Centre
Emergency telephone: +48 22 619 66 Praski Hospital
54; +48 22 619 08 97 Al. Solidarnosci 67
P-03 401 Warszawa
PORTUGAL Lisbon Lisboa
Centro de Informação Antivenenos – Dra Arlinda Borges
Emergency telephone: 808 250 143 Instituto Nacional de Emergência Médica (INEM)
(for use only in Portugal), +351 21 Rua Almirante Barroso, 36
330 3284 1000-013 Lisboa
ROMANIA Department of Clinical Toxicology
Spitalul de Urgenta Floreasca
Emergency telephone: +40 21 230 Calea Floreasca
8000 Bucharest
SLOVAKIA Bratislava
National Toxicological Information Centre
Emergency telephone: +421 2 54 77 4 University Hospital Bratislava
166 Limbová 5
833 05 Bratislava
SLOVENIA Ljubljana
Poison Centre
Emergency telephone: + 386 41 650 Division of Internal Medicine
500 University Clinical Centre Zaloska 7,
1525 Ljubljana
SPAIN Madrid
Servicio de Información Toxicológica
Instituto Nacional de Toxicología
Emergency telephone: +34 91 562 04 Departamento de Madrid
20 Calle Luis Cabrera 9
E-28002 Madrid
SWEDEN Stockholm
Giftinformationscentralen (Swedish Poisons Information Centre)
Karolinska Hospital
Emergency telephone: +46 8 33 12 31 SE-171 76 Stockholm
(International) 112 (National)
SWITZERLAND Zurich

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Centre Suisse d'Information Toxicologique

Emergency telephone: +41 1 251 51 (Swiss Toxicological Information Centre)
51 Freiestrasse 16
Postfach CH-8028
Zurich
UNITED KINGDOM London
London Guy's & St Thomas' Poisons Unit
Emergency telephone: 0870 243 2241 Medical Toxicology Unit
Guy's & St Thomas' Hospital Trust
The UK National Poisons Emergency Avonley Road
number is 0870 600 6266 (Outside the London SE14 5ER
UK: +44 870 600 6266)
NB these services are only available to
health professionals

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