Chemical Bonding: Ionic & Covalent Explained
Chemical Bonding: Ionic & Covalent Explained
M. Heyworth Rex, & J G R Briggs. (2013). All About Chemistry 'O' Level. Malaysia: Pearson
Education South Asia Pte Ltd., pages 84 to 93
Learning Outcomes:
(a) describe the formation of ions by electron loss/gain in order to obtain the electronic configuration of
an inert gas
(b) describe, using 'dot and cross' diagrams, the formation of ionic bonds between metals and non-
metals, e.g. in NaCl, MgCl2.
(a) describe the formation of a covalent bond by the sharing of a pair of electrons in order to gain the
electronic configuration of an inert gas.
(b) describe, using 'dot and cross' diagrams, the formation of covalent bonds between non-metallic
elements, e.g. H2 , O2, H2O, CH4, CO2.
(c) deduce the arrangement of electrons in other covalent molecules
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CHAPTER 2.3
STRUCTURE AND PROPERTIES
Covalent
Ionic Compounds
Metals Substances
Giant Metallic
Giant Ionic Giant Covalent Simple Molecular
Structures
Structures Structures Substances
M. Heyworth Rex, & J G R Briggs. (2013). All About Chemistry 'O' Level. Malaysia: Pearson
Education South Asia Pte Ltd., pages 94 to 97
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Learning Outcomes:
Pupils are expected to:
(a) relate the physical properties (including electrical property) of ionic compounds to their lattice
structure
(b) relate the physical properties (including electrical property) of covalent substances to their structure
and bonding
(c) relate the physical properties (including electrical property) of metals to their structure and bonding
(d) compare the structure of simple molecular substances, e.g. methane; iodine, with those of giant
molecular substances, e.g. sand (silicon dioxide); diamond; graphite in order to deduce their
properties
(e) compare the bonding and structures of diamond and graphite in order to deduce their properties such
as electrical conductivity, lubricating or cutting action (students will not be required to draw the
structures)
(f) deduce the physical and chemical properties of substances from their structures and bonding and
vice versa
(g) describe metals as a lattice of positive ions in a ‘sea of electrons’
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Electron structure and chemical bonding
We have previously looked at the first twenty elements in the periodic table.
When elements react we now know that they try to gain, lose or share electrons in order
to get a more stable electron structure. In many cases, this more stable electron
structure is the same as that of a noble gas.
When elements react we now know that they try to gain, lose or share electrons in order to get a
more stable electron structure. In many cases, this more stable electron structure is the same
as that of a noble gas.
The simple ideas expressed in this statement form the basis of the electronic theory of chemical
bonding.
Look carefully at the table below. This shows the electron structures of the atoms and ions of
elements in period 3.
1. The first three elements in period 3 (sodium, magnesium and aluminium) lose the electrons
in their outer shell to form positive ions (Na+, Mg2+, Al3+) with an electron structure like the
previous noble gas, neon.
2. Elements in groups VI and VII (sulphur and chlorine), which are near the end of period 3,
gain electrons to form negative ions (S2-, Cl-) with an electron structure like the next noble
gas, argon.
3. Elements in the middle of the period (silicon and phosphorus) do not usually form ions. They
get stable electron structures when they react by sharing electrons with other atoms instead
of gaining them or losing them. This sharing of electrons results in covalent bonds between
atoms which is the usual type of bonding in compounds of non-metals.
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Why do atoms bond?
Noble gases, such as helium, neon and argon, are monoatomic because their valence shells
are fully occupied by electrons. Thus, noble gases are stable and do not undergo bonding with
other atoms.
Since atoms with electronic configurations of noble gases are stable, atoms bond to achieve
electronic configuration of a noble gas. Atoms do so by transfer or sharing of electrons with
other atoms.
- When you have 2 electrons in the 1st shell, you have a duplet structure.
- When you have 8 electrons in the rest of the shells, you have an octet structure.
Chemical bonds
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2.1 Ionic Bonding
Ionic (electrovalent) bonds result from the transfer of electrons from metal atoms to non-metal
atoms forming positive and negative ions. The electrical forces between these oppositely
charged ions produce strong ionic bonds.
The sodium atom loses one electron to form a positive ion (cation) in order to obtain an octet
structure. The chlorine atom gains the electron from sodium atom to form a negative ion
(anion) in order to obtain an octet structure. The ions have opposite charges and therefore
attract each other to form an ionic compound known as sodium chloride. This attraction force
is called ionic bond.
In a sodium atom, there are 11 protons and 11 electrons. In a sodium ion, there are 11 protons
and 10 electrons. Therefore, the sodium ion carries an overall positive charge of 1+ and is
written as Na+.
In a chlorine atom, there are 17 protons and 17 electrons. In a chloride ion, there are 17
protons and 18 electrons. Therefore, the chloride ion carries an overall positive charge of 1-
and is written as Cl-.
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In figure 2, the magnesium atom gives up two electrons to form a magnesium ion, Mg2+. These
two electrons are transferred to two chlorine atoms to form two chloride ions, Cl-. The
magnesium chloride has the formula MgCl2.
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‘Dot-and-cross’ diagrams of ionic compounds
Steps:
1. Draw the valence electrons of the elements using ‘Dot and Cross’ only.
2. Electron(s) is/are transferred from the valence shell of the metal to the valence shell of
the non-metal.
3. The anion that has gained electron(s) from the cation will now have two type of electrons
– one originally from its valence shell, another one from the cation – differentiated by
‘dots’ and ‘crosses’.
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2.2 Covalent Bonding
Some atoms form bonds by sharing electrons to gain electronic configuration of a noble gas.
The bonds formed are known as covalent bonds.
A covalent bond is formed by the sharing of a pair of electrons between two atoms. Each
atom contributes one electron to the bond.
Generally, covalent bonds are formed between atoms of non-metal. Covalent bonds can be
formed between atoms of same elements or between atoms of different elements. Compounds
which contain covalent bonds are known as covalent compounds.
Single covalent bond - One pair of shared electrons between two atoms
Double covalent bond - Two pair of shared electrons between two atoms
Triple covalent bond - Three pair of shared electrons between two atoms
• Hydrogen molecules, H2
A hydrogen atom has 1 valence electron. It requires one more electron to obtain the electronic
configuration of a noble gas.
In order to obtain the electronic configuration of helium, two hydrogen atoms can share a pair of
electrons between themselves to form hydrogen molecules, H2 (figure 5). In order to
differentiate the two electrons, the electron of one atom is represented by a ‘cross’ while the
other electron of another atom is represented by a ‘dot’.
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• Oxygen molecules, O2
In order to obtain the electronic configuration of a noble gas, each oxygen atom requires two
more electrons. Instead of sharing a pair of electrons, two oxygen atoms can share two pairs of
electrons to form a double bond and obtain an octet structure.
The carbon atom has four valence electrons and it needs four more electrons to gain an octet
structure. The carbon atom can share its four electrons with four other hydrogen atoms, forming
a single covalent bond with each of the hydrogen atom.
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Valency
The number of electrons an atom uses to form bonds is called its valency.
Element Valency
Hydrogen 1
Oxygen 2
Aluminium 3
Carbon 4
When a chemical reaction occurs, one substance changes to another. This means that bonds in
the reactants must first be broken and then new bonds must be made in the products.
Now breaking bonds involves pulling atoms apart and this requires energy. On the other hand,
making bonds helps to make atoms more stable and this gives out energy. So,
• bond breaking is endothermic,
• bond making is exothermic.
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2.3 Structure and Properties
Look at the crystals of sodium chloride in this
photograph. What do you notice about all the salt
crystals?
All the salt crystals are roughly the same cubic shape.
Further studies show that all the crystals of one
substance have similar shapes. This suggests that the
particles in the crystals are always packed in a regular
fashion to give the same overall shape. Sometimes,
crystals grow unevenly and their shapes become
distorted. Even so, it is usually easy to see their
general shape. Solid substances which have a regular
packing of particles are described as crystalline. The
particles may be atoms, ions or molecules.
The figure below shows how cubic crystals and hexagonal crystals can form. If the particles are
always placed in parallel lines or at 90o to each other, the crystal will be cubic. If the particles
are placed at 120° in the shape of a hexagon, the final crystal will be hexagonal.
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Using X-rays to study crystals (Optional)
Look through a piece of thin stretched cloth at a small bright light. The pattern you see is due to
the deflection of the light as it passes through the regularly spaced threads of the fabric. This
deflection of the light is called diffraction and the patterns produced are diffraction patterns. If
the cloth is stretched so that the threads in the fabric get closer, then the pattern spreads further
out. From the diffraction pattern which we can see, we can work out the pattern of the threads in
the fabric which we cannot see. The same idea is used to work out how the particles are
arranged in a crystal.
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copper atoms can slide over each other in the close-packed structure.
In turn, the properties of a substance lead to its uses. Copper, for example is used for electrical
wires and cables because it is a good conductor and it can be drawn into wires.
Notice that the structure and bonding of a substance determine its properties and, in turn,
the properties determine its uses.
So the links from structure and bonding to properties help us to explain the uses of materials -
why metals are used as conductors, why graphite is used in pencils and why clay is used to
make bricks.
Earlier, you have learnt that all substances are made up from only three different types of
particle - atoms, ions, and molecules.
The table below shows the particles in these four structures, the types of substances formed
and examples of these substances.
The four types of solid structure and the particles they contain
Types of
Particles in the structure Types of substance Examples
structure
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If you look carefully at the surface of some
galvanised iron (iron coated with zinc), you will see
irregular shaped areas separated from each other
by clear boundaries.
X-ray analysis shows that the atoms in metal grains - packed in a regular fashion, but the grains
themselves are irregular-shaped crystals pushed tightly together.
Metals usually have a high density. This suggests that the atoms are packed close together. In
fact, X-ray studies show that the atoms of most metals are packed as close together as possible.
This arrangement is close packing. The figure above shows a few atoms in layer of a metal
crystal.
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The properties of metals
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This diagram shows the positions of
atoms before and after slip. This is what
happens when a metal is bent or
hammered into different shapes.
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Giant Ionic Structures
In solid ionic compounds, the ions are held together by the attraction between positive ions
and negative ions. The figures below show how the ions are arranged in one layer of sodium
chloride and a three-dimensional model of the structure of sodium chloride. Notice that Na+ ions
are surrounded by Cl- ions and vice versa.
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Giant covalent structures
• Diamond is very hard because its carbon atoms are linked by very strong covalent bonds.
Another reason for its hardness is that the atoms are not arranged in layers so they cannot
slide over one another like the atoms in metals. In fact, diamond is the hardest known
natural substance. Most of its industrial uses depend on this hardness.
• Diamond has a very high melting point because of the strong covalent bonds linking
carbon atoms in a giant structure. This means that the atoms cannot vibrate fast enough to
break away from their neighbours until very high temperatures are reached.
• Diamond does not conduct electricity. Unlike metals, diamond has no free electrons
because all four electrons in the outer shell of each carbon atom are held firmly in covalent
bonds. So in diamond there are no free electrons to form an electric current.
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Simple molecular substances
For example, hydrogen is H2, chlorine is Cl2, iodine is I2, carbon dioxide is CO2 and
tetrachloromethane is CCl4. Sugar (C12H22O11) has much larger molecules than these
substances, but it still counts as a simple molecule.
In these simple molecular substances, the atoms are held together in each molecule by
strong covalent bonds. But there are only weak forces between the separate molecules.
These weak forces between the separate molecules are called intermolecular bonds or Van der
Waals forces.
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The properties of simple molecular substances
The properties of simple molecular substances can be explained in terms of their structure. The
molecules in these substances have no electrical charge (unlike ions in ionic compounds or
electrons in metals). So there are no electrical forces holding them together. But some simple
molecular substances, like iodine, sugar. tetrachloromethane and water do exist as liquids and
solids so there must be some intermolecular forces holding their molecules together.
They have no mobile electrons like metals. They do not have any ions either. This means
that they cannot conduct electricity as solids, as liquids or in aqueous solution.
Notice the following key points from the last four ions.
• Substances with giant structures are often hard with high melting points and boiling
points.
• Substances with simple molecular structures are usually soft with low melting points and
boiling points.
• There are three types of strong force between particles in giant structures; metallic
bonds between metal atoms, covalent bonds between non-metal atoms, ionic bonds
between positive metal ions and negative non-metal ions.
• In simple molecular substances there are relatively weak forces between the separate
molecules.
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Common ions and formulae of ionic compounds
You are not expected to know all the names and symbols of common ions, but you should be
able to work out the formulae of ionic compounds. The names and symbols of some ions are
shown below.
Ionic compounds contain positive and negative ions. The number of positive charges must
equal the number of negative charges so that the compound has no charge overall. When the
positive ion has the same number of charges as the negative ion, it is easy to work out the
formula of the compound formed. Sodium chloride contains sodium ions, Na+, and chloride ions,
Cl-. As both ions have single charges, the formula is simply written as NaCl, i.e. the positive ion
followed by the negative ion with no charges written.
Similarly, ammonium chloride is NH4Cl; magnesium oxide is MgO, and so on. The fun starts
when the number of charges is different, as in magnesium chloride.
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Additional Reading: The Nuclear Age
On the 6th of August, 1945, weeks before the end of the World War II,
an atomic bomb code-named "Little Boy" was detonated over the
Japanese city of Hiroshima.
Three days later, a second bomb, code-named "Fat Man", was dropped
on the city of Nagasaki.
What is certain, however, is that the events of 1945 marked the start of the nuclear age for
mankind.
In this chapter, we shall explore the science behind nuclear weapons and find out why atomic
bombs are so devastatingly powerful.
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Atomic Bombs and Nuclear Weapons
An example is shown.
The mass of the nucleus is about 1 percent smaller than the mass of its individual protons and
neutrons. This difference is called the mass defect. The mass defect arises from the energy
released when the nucleons (protons and neutrons) bind together to form the nucleus. This
energy is called the binding energy. The binding energy determines which nuclei are stable
and how much energy is released in a nuclear reaction.
The hydrogen-2 nucleus, for example, composed of one proton and one neutron, can be
separated completely by supplying 2.23 million electron volts (MeV)* of energy. Conversely,
when a slowly moving neutron and proton combine to form a hydrogen-2 nucleus, 2.23 MeV are
liberated.
*1eV = 1.602×10−19J
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Because the speed of light is a large number and thus c2 is huge, a small amount of matter
can be converted into a tremendous amount of energy. This equation is the key to the
power of nuclear weapons and nuclear reactors.
During fission, more neutrons are produced. These neutrons cause fission in other uranium
atoms. This is repeated over and over again. This repeated process is called a chain reaction.
A lot of heat energy is produced in a nuclear fission chain reaction.
In a nuclear reactor, this heat energy is used to produce steam which is then used to drive a
turbine and dynamo to generate electricity.
When the chain reaction in nuclear fission is allowed to get out of control, an explosion can
occur. This is done deliberately in explosions produced by nuclear weapons. The explosion is
produced by uncontrolled fission of uranium-235 or plutonium-239.
As we see earlier, a small amount of matter can be converted into a tremendous amount of
energy in a nuclear reaction. Therefore nuclear weapon is far more powerful than any
conventional weapon. The atomic bomb dropped on Hiroshima, the “Little Boy”, released
between 54 and 75 TJ (Tera- = 1012) of energy, which is equivalent to 13 to 18 kilotons of TNT.
The modern nuclear weapon is even more devastating, as a weapon weighing a little more than
1,100kg is capable of releasing energy equivalent to more than 1.2 Megatons of TNT.
Health Risks
Most of the immediate damage caused by nuclear weapons is due to the energy released. This
takes the form of intense heat as well as shock waves which destroys both living things and
structures.
There are many long-term health effects of nuclear weapons as well. Radiation and radioactive
fallout affect those cells in the body that actively divide (hair, intestine, bone marrow,
reproductive organs). Some of the resulting health conditions include:
These conditions often increase the risk of leukemia, cancer, infertility and birth defects.
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References
http://www.atomicarchive.com/Physics/Physics1.shtml
http://energyfromthorium.com/2010/08/06/loveswu1/
http://science.howstuffworks.com/nuclear-bomb8.htm
http://en.wikipedia.org/wiki/Nuclear_weapon
Picture references
en.wikipedia.org (3), p3
archives.govt.nz, p3
en.wikipedia.org, p15
craighill.net, p41
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