COPPER AND ITS ALLOYS
Melting point of copper – 10830C
Main properties of copper:
High electrical and thermal conductivity
Good corrosion resistance, Machinability,
strength
Ease of fabrication
Non magnetic
Has a pleasing colour
Can be welded, brazed, and soldered
Easily finished by plating and lacquering
Electrical conductors- 99.9% Cu and identified as
Electrolytic Tough Pitch (ETP) copper or Oxygen
Free High Conductivity (OFHC) copper.
Arsenical copper - ≈ 0.3% Arsenic – improved
resistance to special corrosive conditions
Free cutting copper - ≈ 0.6% Tellurium – excellent
machining properties
Silver bearing copper – 7 to 30 oz/ton silver –
Silver raises the recrytallization of copper
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TEMPER DESIGNATION: Cu and most of its
alloys are homogeneous single phases, there are not
susceptible to heat treatment and t heir strength
may be altered only by cold working.
Two general classes of temper for non heat
treatable wrought copper alloys : cold worked and
soft or annealed.
The different cold worked tempers are obtained by
cold working the annealed material a definite
amount.
COPPER ALLOYS:
Brasses – essentially alloys of cu and Zn.
Some of the alloys may contain small amounts
of Pb, Sn, Al
Variations in composition will result in desired
colour, strength, ductility, machinability, corrosion
resistance, or a combination of such properties
Best combination of strength and ductility 70Cu-
30Zn
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Commercial Brass
Brasses for cold worked (Alpha brasses)
Brasses for hot working (Alpha Plus Beta
Brasses)
A. Alpha brasses – containing up to 36% Zn
Relatively good corrosion resistance and good
working properties.
1 Yellow α brasses – 20-36% Zn
Good strength with high ductility
Suitable for drastic cold working
Common practice to stress relief anneal these
bronzes after cold working to prevent stress
corrosion cracking
Subjected to selective leaching which can be
minimized by small amount of tin or antimony
0.5-3% lead improves machinability
Admiralty metal (71Cu-28Zn-1Sn)- improved
strength and corrosion resistance
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Aluminium brass (76 Cu-22Zn-2Al)- better
corrosion resistance form tenacious and self
healing film
2 Red brasses – 5 to 20 % Zn
Better corrosion resistance than yellow brasses and
not susceptible to stress corrosion cracking and
dezincification.
Gliding metal (95Cu-5Zn),
Commercial bronze (90Cu-10Zn),
Red brass (85Cu-15Zn),
Low brass (80 Cu-20 Zn)
B. Alpha Plus Beta Brasses – 54 to 62 % Cu
Consist of two phases - α + β1
β1 harder and more brittle than α at room
temperature therefore more difficult to cold work.
At elevated temperatures- single phase β becomes
very plastic, hence excellent hot working
properties.
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Muntz Metal – 60Cu-40Zn – has high tensile
strength and excellent hot working properties
Free cutting brass (61.5Cu-35.5Zn-3Pb)
Forging brass (60Cu-38Zn-2Pb)
Architectural Bronze – (57Cu-40Zn-3Pb)
Naval Brass – (60Cu-39.25Zn-0.75Sn)
Manganese bronze – (58.5Cu-39Zn-1.4Fe-1.5Sn-0.1Mn)
Bronzes – up to 12 % alloying elements.
Alloys of Cu and Sn, Al, Si, Be, in addition may
contain P, Pb, Zn, or Ni
A. Tin bronzes (Phosphor bronzes)
B. Silicon bronzes
C. Aluminum bronzes
D. Beryllium bronzes
Cupro-Nickels – Alloys of Copper and
Nickel
Nickel Silvers - alloys of Copper, Nickel
and Zinc
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