SAFETY DATA SHEET

Revision Date 11-Jul-2018 SDS Number 888100004794 Revision Number 3

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY

Product Name Gas Oil, Virgin
Synonyms Straight Run, Virgin Gas Oil, VGO, FCC Charge, Desulfurized Gas Oil, GAS OIL,
Vacuum Straight Run, Hydrodesulfurized Gas Oil, Cutter Stock, Light Coker Gas Oil,
Light Thermocracked Distillate (C10-C22), RS201, RS307

Recommended Use Fuel

Uses advised against All others

Manufacturer
Emergency Chemtrec: 1-800-424-9300
Tesoro Refining & Marketing Co.
Telephone Tesoro Call Center: 1-877-783-7676
19100 Ridgewood Parkway
San Antonio, TX 78259
E-mail address ProductStewardship@[Link]

2. HAZARDS IDENTIFICATION
Classification

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Flammable liquids Category 4

Acute Oral Toxicity Category 4
Acute dermal toxicity Category 3
Serious eye damage/eye irritation Category 2B
Carcinogenicity Category 1B
Chronic Aquatic Toxicity Category 2
Aspiration toxicity Category 1

Label elements

Danger

Combustible liquid Harmful if swallowed Toxic in contact with skin Causes skin irritation Causes eye irritation May cause cancer
Toxic to aquatic life with long lasting effects May be fatal if swallowed and enters airways

888100004794 Gas Oil, Virgin Page 1 / 11

 Appearance Liquid Physical State @20°C Liquid Odor Characteristic petroleum or
kerosene-like

Precautionary Statements - Prevention

Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Avoid release to the environment
Keep away from heat/sparks/open flames/hot surfaces. - No smoking

Precautionary Statements - Response

IF exposed or concerned: Get medical advice/attention
Specific treatment (see .? on this label)
Specific treatment (see .? on this label)
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF ON SKIN: Wash with plenty of soap and water
Call a POISON CENTER or doctor/physician if you feel unwell
Remove/Take off immediately all contaminated clothing
Wash contaminated clothing before reuse
If skin irritation occurs: Get medical advice/attention
Rinse mouth
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
Do NOT induce vomiting
In case of fire: Use CO2, dry chemical, or foam for extinction
Collect spillage

Precautionary Statements - Storage

Store locked up
Store in a well-ventilated place. Keep cool

Precautionary Statements - Disposal

Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC)

Not applicable

Other Information
Causes mild skin irritation. Toxic to aquatic life.

3. COMPOSITION/INFORMATION ON INGREDIENTS
General Composition Statement Gas oils are variable and complex substances of hydrocarbons, predominantly having
carbon chains from C9 to C30, containing variable amounts of alkanes, cycloalkanes,
olefins, and aromatics.
Chemical Name CAS-No Percent
Residues (petroleum), heavy coker gas oil 68478-17-1 0-100
Gas oils (petroleum), straight-run 64741-43-1 0-100
Distillates (petroleum), light thermal cracked; 64741-82-8 0-100
Cracked gasoil
 Polycyclic Aromatic Hydrocarbons 130498-29-2 0-7
Sulfur 7704-34-9 0-3
Naphthalene,2-Methyl- 91-57-6 0-1
Phenanthrene 85-01-8 0-0.2

4. FIRST AID MEASURES

Description of first aid measures

General advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is
required. Remove from exposure, lie down. In case of accident or if you feel unwell, seek
medical advice immediately. When symptoms persist or in all cases of doubt, seek medical
advice. Never give anything by mouth to an unconscious person. Take off all contaminated
clothing immediately and thoroughly wash material from skin.

Inhalation Remove from exposure, lie down. If breathing has stopped, give artificial respiration.
Get medical attention immediately. If breathing is difficult, administer oxygen. If
symptoms persist, call a physician.

Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Keep eye wide open while rinsing. Do not rub affected area. Remove contact lenses, if
present and easy to do. Continue rinsing. Get immediate medical advice/attention.

Skin contact Wash off immediately with soap and plenty of water while removing all
contaminated clothes and shoes. Get immediate medical advice/attention.

Ingestion Do NOT induce vomiting. Clean mouth with water and drink afterwards plenty of water.
Never give anything by mouth to an unconscious person. Get immediate medical
advice/attention.

Self-protection of the first aider Remove all sources of ignition. Ensure that medical personnel are aware of the material(s)
involved, take precautions to protect themselves and prevent spread of contamination.
Wear personal protective clothing (see section 8). Avoid direct contact with skin. Use
barrier to give mouth-to-mouth resuscitation.

Most important symptoms and effects, both acute and delayed

Symptoms Inhalation of high vapor concentrations may cause symptoms like headache, dizziness,
tiredness, nausea and vomiting. Prolonged contact may cause redness and irritation.
Hydrogen sulfide can cause respiratory paralysis and death, depending on
concentration and duration of exposure. The "rotten egg" odor of hydrogen sulfide is not
a reliable indicator of exposure, since olfactory fatigue (loss of smell) will occur.

Indication of any immediate medical attention and special treatment needed

Note to physicians Treat symptomatically.

5. FIRE-FIGHTING MEASURES
Small Fire Any extinguisher suitable for Class B fires, dry chemical, CO2, foam (AFFF/ATC), or
water spray can be used.

Large Fire Water spray, fog or alcohol-resistant foam. CAUTION: Use of water spray when fighting fire
may be inefficient. Cool containers with flooding quantities of water until well after fire is
out.

Unsuitable extinguishing media Do not use straight streams.

Specific hazards arising from the

Keep product and empty container away from heat and sources of ignition. In the event of
chemical
fire, cool tanks with water spray.
Hazardous combustion products Smoke, CO, and other products of incomplete combustion.

Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge Yes.

Special protective equipment for

Firefighters should wear self-contained breathing apparatus and full firefighting turnout
fire-fighters
gear. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible
withdraw from area and let fire burn.

Further information ALWAYS stay away from tanks engulfed in fire. Fight fire from maximum distance or use
unmanned hose holders or monitor nozzles. Withdraw immediately in case of rising sound
from venting safety devices or discoloration of tank. Do not direct water at source of leak or
safety devices; icing may occur. Cool containers with flooding quantities of water until well
after fire is out. Do not allow run-off from fire-fighting to enter drains or water courses.

NFPA Health hazards 0 Flammability 2 Stability 0

Physical and chemical
properties -

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions Evacuate personnel to safe areas. Use personal protective equipment as required. See
section 8 for more information. Take precautionary measures against static discharges.
Do not touch or walk through spilled material. Avoid contact with skin, eyes or clothing.
Ensure adequate ventilation.

Other Information Refer to protective measures listed in Sections 7 and 8.

Environmental precautions

Environmental precautions Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage
if safe to do so.

Methods and material for containment and cleaning up

Methods for containment Stop leak if you can do it without risk. Do not touch or walk through spilled material. Dike far
ahead of liquid spill for later disposal.

Methods for cleaning up Take precautionary measures against static discharges. Dam up. Soak up with inert
absorbent material. Pick up and transfer to properly labeled containers.

Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.

7. HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Use personal protection equipment. Do not breathe vapor or mist. Keep away from
heat/sparks/open flames/hot surfaces. - No smoking. Take precautionary measures against
static discharges. Use with local exhaust ventilation. Handle in accordance with good
industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Take off
contaminated clothing and wash before reuse.

Hydrocarbon liquids including this product can act as a non-conductive flammable liquid (or
static accumulator), and may form ignitable vapor-air mixtures in storage tanks or other
containers. Precautions to prevent static initiated fire or explosion during transfer, storage
or handling, include but are not limited to these examples: (1) Ground and bond containers
during product transfers. Grounding and bonding may not be adequate protection to
prevent ignition or explosion of hydrocarbon liquid and vapors that are static accumulators.
 (2) Special slow load procedures for "switch loading" must be followed to avoid the static
ignition hazard that can exist when higher flash point material (such as fuel or diesel) is
loaded into tanks previously containing low flash point products (such as gasoline or
naphtha). (3) Storage tank level floats must be effectively bonded. For more information on
precautions to prevent static-initiated fire or explosion, see NFPA 77 Recommended
Practice on Static Electricity and API Recommended Practice 2003 Protection Against
Ignitions Arising Out of Static, Lightning, and Stray Currents.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from
heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static
electricity). Keep in properly labeled containers. Store in accordance with the particular
national regulations. Store in accordance with local regulations. Keep out of the reach of
children. Store locked up.

Keep away from flame, sparks, excessive temperatures and open flame. Use approved
containers. Keep containers closed and clearly labeled. Empty or partially full product
containers or vessels may contain explosive vapors. Do not pressurize, cut, heat, weld or
expose containers to sources of ignition. Store in a well-ventilated area. The storage area
should comply with NFPA 30 "Flammable and Combustible Liquid Code". The cleaning of
tanks previously containing this product should follow API Recommended Practice (RP)
2013 "Cleaning Mobile Tanks In Flammable and Combustible Liquid Service" and API RP
2015 "Cleaning Petroleum Storage Tanks". Emergency eye wash capability should be
available in the near proximity to operations presenting a potential splash exposure.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Chemical Name ACGIH TLV OSHA PEL
Naphthalene,2-Methyl- TWA: 0.5 ppm -
91-57-6 S*
Phenanthrene - TWA: 0.2 mg/m3
85-01-8
S* - Potential exposure by cutaneous route

NOTE: Limits shown for guidance only. For additional information, OSHA’s 1989 air contaminants standard exposure limits
provided even though the limits were vacated in 1992. State, local or other agencies or advisory groups may have established
more stringent limits. Follow applicable regulations.

Appropriate engineering controls

Engineering controls Showers

Eyewash stations
Ventilation systems.

Individual protection measures, such as personal protective equipment

Eye/face protection Use goggles or face-shield where there is a possibility of splashing.

Hand Protection Wear suitable gloves. Polyvinyl alcohol. Nitrile rubber. Neoprene gloves. Ensure that the
breakthrough time of the glove material is not exceeded. Refer to glove supplier for
information on breakthrough time for specific gloves.

Skin and body protection Wear suitable protective clothing.

Respiratory protection When workers are facing concentrations above the exposure limit they must use
appropriate certified respirators. Use a NIOSH approved respirator when there is a potential
for airborne concentrations to exceed occupational exposure limits. Refer to OSHA 29 CFR
1910.134, ANSI Z88.2, NIOSH Respirator Decision Logic, and the respirator manufacturer
for additional guidance on respiratory protection selection. A Self-Contained Breathing
 Apparatus (SCBA) should be used for fire fighting. Use a NIOSH approved
positive-pressure supplied air respirator if there is a potential for uncontrolled release,
exposure levels are unknown, in oxygen deficient (less than 19.5% oxygen), or any other
circumstance where an air-purifying respirator may not provide adequate protection.

General hygiene considerations Do not eat, drink or smoke when using this product. Contaminated work clothing should not
be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is
recommended. Wash hands before breaks and immediately after handling the product.
Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection.
Remove and wash contaminated clothing and gloves, including the inside, before re-use.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Physical State @20°C Liquid
Appearance Liquid
Odor Characteristic petroleum or kerosene-like
Color Yellow Brown
Odor threshold No data available

Property Values Remarks • Method

pH Not applicable
Melting point / freezing point -26 °C / -15 °F Gel point can be about -15°F; freezing requires
laboratory conditions
Boiling range 175 - 175 to 390 °C
Flash point > 61 °C / 142 °F
Evaporation rate No data available
Flammability (solid, gas) Flammable vapor released by liquid
upon heating
Flammability Limit in Air %
Upper flammability limit: 6.5
Lower flammability limit: 1.0
Vapor pressure 4 hPa @ 40°C
Vapor density No data available
Relative density 0.83
Water solubility Negligible
Solubility in other solvents No data available
Partition coefficient 3.9 to 6
Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity 3.35 cSt @ 40°C
Dynamic viscosity No data available
Explosive properties No data available
Oxidizing properties No data available
Minimum Ignition Energy (mJ) No data available
K st (bar.m/s) No data available
Softening point No data available
VOC Content (%) No data available
Density No data available
Bulk density Not applicable
Conductivity Hydrocarbon liquids such as atmospheric gas oil without static dissipater additive may have
conductivity below 1 picoSiemens per meter (pS/m). The highest electro-static ignition risks
are associated with ”ultra-low conductivities” below 5 pS/m. See Section 7 for sources of
information on defining safe loading and handling procedures for low conductivity products

10. STABILITY AND REACTIVITY

Reactivity This product is non-reactive under normal conditions.

Chemical stability Stable under recommended storage conditions.

Possibility of hazardous reactions None under normal processing.

Conditions to avoid Heat, flames and sparks.

Incompatible materials Oxidizing or reducing agents. Acids. Alkali.

Hazardous decomposition products None under normal use conditions.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Inhalation Specific test data for the substance or mixture is not available.

Eye contact Specific test data for the substance or mixture is not available.

Skin contact Specific test data for the substance or mixture is not available. Toxic in contact with
skin. (based on components).

Ingestion Specific test data for the substance or mixture is not available. Harmful if swallowed.
(based on components).

Information on toxicological effects

Symptoms No information available.

Numerical measures of toxicity

Acute toxicity

The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 1,892.00 mg/kg
ATEmix (dermal) 986.00 mg/kg

Chemical Name Oral LD50 LD50/dermal/rat - NO UNITS Inhalation LC50

(Wizards mg/kg)
Gas oils (petroleum), = 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) = 1.72 mg/L ( Rat ) 4 h
straight-run
64741-43-1
Distillates (petroleum), light = 3200 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) = 4.65 mg/L ( Rat ) 4 h
thermal cracked; Cracked gasoil
64741-82-8
Sulfur > 3000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 9.23 mg/L ( Rat ) 4 h
7704-34-9
Naphthalene,2-Methyl- = 1630 mg/kg ( Rat ) - -
91-57-6
Phenanthrene = 1.8 g/kg ( Rat ) - -
85-01-8

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Chemical Name
Gas oils (petroleum), straight-run Gas oils and distillate fuels may be fatal if they are swallowed and enter the airway. If
inhaled, short-term overexposure can cause disorientation, nausea, vomiting, signs of
central nervous system effects such as headache or disorientation, immediate
unconsciousness and death. In animal studies, gas oil streams and distillate fuels
demonstrated minimal acute toxicity by the oral, dermal and inhalation routes, minimal eye
irritation, moderate to severe skin irritation with 24 hours exposure, and no dermal
sensitization. Generally, results suggest that the degree of toxicity is associated with the
concentrations and ring distributions of aromatic constituents in the fuels. When dermal
exposures last 24 hours or longer, moderate to severe skin irritation, but not sensitization,
has been reported in animal studies. Repeated dermal exposures have been reported to
 cause systemic effects in animals, including changes in liver and thymus weight and blood
chemistry. Some gas oil streams and distillate fuels can cause gene mutations in studies
using bacteria and animal tissue. Results of developmental studies with gas oils
demonstrate that some gas oils induce developmental effects and others do not. Effects
observed include reduced litter size through resorptions, lower body weights, and fetal
malformations were reported for 2 members of the category. Studies in animals indicate
that gas oils and distillate fuels are potential skin carcinogens after repeated skin
application, but are not associated with tumors in other parts of the body (systemic tumors).
The carcinogenicity of individual petroleum streams varies due to factors such as source
and processing; IARC and ECHA C&L Inventory reports individually on the carcinogenicity
of these substances.

Health hazard and classification information

Skin Corrosion/Irritation Category No information available.

Serious eye damage/eye irritation No information available.

No information available.

Germ cell mutagenicity No information available.

Carcinogenicity Classification based on data available for ingredients. Contains a known or suspected
carcinogen.

The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical Name ACGIH IARC NTP OSHA
Phenanthren - Group 3 - -
e 85-01-8

Reproductive toxicity No information available.

Target Organ Systemic Toxicant -

No information available.
Single Exposure

Target Organ Systemic Toxicant -

No information available.
Repeated Exposure

Aspiration hazard No information available.

12. ECOLOGICAL INFORMATION

Additional Ecological Information Release of this product should be prevented from contaminating soil and water and from
entering drainage and sewer systems. U.S.A. regulations require reporting spills of this
material that could reach any surface waters. The toll free number to the U.S. Coast Guard
National Response Center is (800) 424-8802
Marine pollutant.

Ecotoxicity Toxic to aquatic life with long lasting effects.

Chemical Name Algae/aquatic plants Fish Toxicity to Crustacea

microorganisms
Distillates (petroleum), - 7.3: 96 h Brachydanio - -
light thermal cracked; rerio mg/L LC50
Cracked gasoil semi-static
64741-82-8
Sulfur - 14: 96 h Lepomis - -
7704-34- macrochirus mg/L LC50
9 static 866: 96 h
Brachydanio rerio mg/L
LC50 static 180: 96 h
 Oncorhynchus mykiss
mg/L LC50 static

Persistence and degradability No information available.

Bioaccumulation There is no data for this

product. Component Information

Chemical Name Partition coefficient
Naphthalene,2-Methyl- 3.86
91-57-6
Phenanthrene 4.5
85-01-8

Other adverse effects No information available.

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Waste from residues/unused Dispose of in accordance with local regulations. Dispose of waste in accordance with
products environmental legislation.

Contaminated packaging Do not reuse empty containers.

Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes
Polycyclic - Included in waste stream: - -
Aromatic K022
Hydrocarbons
130498-29-2
Phenanthren - Included in waste stream: - -
e 85-01-8 F039

14. TRANSPORT INFORMATION

DOT
UN/ID no UN1993
Proper Shipping Name Flammable liquids, n.o.s.
Hazard Class 3
Packing group III
Special Provisions B1, B52, IB3, T4, TP1, TP29
Marine pollutant Marine pollutant.
Emergency Response Guide 128
Number

TDG
UN/ID no UN1993
Proper Shipping Name Flammable liquid, n.o.s.
Hazard Class 3
Packing group III
Marine pollutant Marine pollutant.

MEX
UN/ID no UN1993
Proper Shipping Name Flammable liquid, n.o.s.
Hazard Class 3
Special Provisions 223, 224
 Packing group III

UN/ID no UN 1993
Proper Shipping Name Flammable liquid, n.o.s.
Hazard Class 3
Packing group III
ERG Code 3L

IMDG
UN/ID no UN1993
Proper Shipping Name Flammable liquid, n.o.s.*
Hazard Class 3
Packing group III
EmS No. F-E, S-E
Special Provisions 223, 274, 955
Marine pollutant Marine pollutant

15. REGULATORY INFORMATION

International Inventories
TSCA Not Listed
DSL/NDSL Not Listed
ENCS Not Listed
IECSC Not Listed
KECL Not Listed
PICCS Not Listed
AICS Not Listed

Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances

US Federal Regulations

SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.

SARA 311/312 Hazard Categories

Acute health hazard Yes
Chronic Health Hazard Yes
Fire hazard Yes
Sudden release of pressure hazard No
Reactive Hazard No

CWA (Clean Water Act)

This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42).

Chemical Name CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Quantities Substances
Polycyclic - X - -
Aromatic
Hydrocarbons
130498-29-2
Phenanthren - - X -
e 85-01-8
CERCLA
The CERCLA definition of hazardous substances contains a “petroleum exclusion” clause which exempts crude oil, fractions of
crude oil, and products (both finished and intermediate) from the crude oil refining process and any indigenous components of
such from the CERCLA Section 103 reporting requirements. However, other federal reporting requirements, including SARA
Section 304, as well as the Clean Water Act may still apply.

US State Regulations

California Proposition 65
This product does not contain any Proposition 65 chemicals.

U.S. State Right-to-Know Regulations

US State Regulations

Chemical Name New Jersey Massachusetts Pennsylvania

Polycyclic Aromatic X - X
Hydrocarbons
130498-29-2
Sulfur X X X
7704-34-9
Naphthalene,2-Methyl- X - -
91-57-6

16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION

Revision Date 11-Jul-2018

Revision Note No information available.

Disclaimer
Tesoro Companies, Inc. (Tesoro) provides the information on this Safety Data Sheet (SDS) in order to meet its obligations
under 29 CFR 1910.1200, and does not hereby make any guarantee of product specifications or suitability for any
particular purpose. Tesoro does not assume any liability arising out of the use of Tesoro’s product or the use of
information provided on this SDS. The end user of the product has the responsibility for evaluating the adequacy of the
data under the conditions of use, determining the safety, toxicity and suitability of the product under these conditions,
and obtaining additional or clarifying information where uncertainty exists. No guarantee expressed or implied is made as
to the effects of such use, the results to be obtained, or the safety and toxicity of the product in any specific application.
Furthermore, the information herein is not represented as absolutely complete, since it is not practicable to provide all
relevant information in the format of this document, since additional information may be necessary under exceptional
conditions of use, and since Tesoro prepared this SDS based on information available on the date of its publication.

1014, 1016, 2228, 2229

End of Safety Data Sheet