Shimazdu AA6800 Tech
Shimazdu AA6800 Tech
*1
*2
MAC ASC
Manual Atomizer Autosampler
Changing kit
GFA
Graphite Furnace Dual Atomizer System
Atomizer Manual switching between Flame and Furnace
Flame Selection
Monochromator
Detector
D2 lamp
Sample beam
Beam splitter
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Advantages of the Double-Beam System
Long-term stability High sensitivity A
The graph shows the results of The graph shows the direct b
s
Absorbance
measurements on 2 ppm copper (Cu) measurement results for 0.1
conducted over at least one hour. ppm lead (Pb).
(The plot shows mean values for 11
repeated measurements.) Over the
course of more than 600
Measurement time
measurements, the instrument Conc(ppm)
Data Showing Long-Term Stability for 0.1 ppm to 0.4 ppm Calibration Curve for Lead (Pb)
achieved a relative standard Flame Cu Measurements
deviation within 1%.
Multi-element analysis of small sample volumes 1. Sample injected into 2. Solenoid valve opens to inject sample
No blockage of burner slot with samples having a high salt concentration micro sampling port. in one shot into the flame.
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World-Class High-Sensitivity Furnace
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High-Performance Autosampler
Mix and inject up to four sample types (diluted solution, standard solution,
sample, matrix modifier, etc.). (Unmixed samples can also be injected.)
Select a fluororesin tube or pipette tip as the injection nozzle.
Automatic dilution and re-analysis if the calibration curve concentration is exceeded.
Digital temperature control and electronic gas flow control enhance stability
Combination of a high-sensitivity optical sensor and unique digital temperature control
technology achieves highly accurate temperature control in all temperature regions from
drying to atomization. An electronic flow controller can precisely control the inner gas
flow rate in 0.01 L/min units. These control techniques significantly enhance both the
sensitivity and the data stability.
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$$ Quickly and easily switch between flame and
Employs a quick, tool-less switching mechanism, making it as easy and effortless as shown in the photo.
From flame...
...to flame
All that is involved in switching from flame to furnace is to remove the burner head and put in place the furnace
section. No tools are needed, making this a quick, easy process.
Furthermore, one autosampler can be used for both flame and furnace, which negates the need to prepare
the autosampler for each analysis method.
* Depending on the state of the sample, some other combinations may be appropriate.
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furnace
... to furnace
From furnace...
AA-6300
1080mm(W) × 545(D) ×460(H)
* Dimensions do not include the ASC-6880. Height (H) does not include protrusions.
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$$ Power Supply, for Unique
High-Performance Boosted Hollow
Cathode Lamp Included as Standard
Air - Ac et y l ene Ai r - Ac et y l en e G ra p h i te G ra p h i te
Fla m e Anal y s i s F l am e Anal y si s F u rn a ce A n a l y si s F u rn a ce A n a l y si s
Pb and Zn: Comparison Table for Typical Detection Limits of the High-Performance Boosted Hollow Cathode Lamp and the Ordinary
Hollow Cathode Lamp
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Advanced Safety Technology
Comprehensive Safety Functions in Every System
Safety is an extremely important consideration for flame atomic absorption
spectrophotometers using acetylene gas.
The AA-6880 Series instruments incorporate a comprehensive range of safety
mechanisms, including gas leak detectors.
Safety-Conscious Design
Flame-retardant materials Safe ignition switches
UL 94V-0-rated flame-retardant materials The switches perfectly fit finger contours and are positioned
are used for the instrument external near the window.
covers and atomizer unit. This superior To prevent inadvertent operation, both switches must be
design pays due consideration to safety. pressed simultaneously to start ignition.
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$$ Dual-Background Correction Functions
The optimal background correction methods are installed as standard:
high-speed self-reversal method (SR method) and deuterium lamp method (D2 method).
Samples suitable for the SR method Samples suitable for the D 2 method
Samples with a complex matrix Purified water, tap water, environmental water, etc.
(Containing a large quantity of a specific element as the main component) Samples with a relatively simple matrix
IH spectrum
Background absorption
Principle
Background A small current IL (approx. 10 mA) and a large current IH (approx. 500
Atomic absorption mA) are alternately passed through the hollow cathode lamp. The
Atomic lamp emission spectrum when the large current flows has a depression
Lamp current
IH absorption
in the center (self-reverse), due to self-absorption of the large number
of sputtered atoms in the atom cloud, as shown in the diagram to the
Wavelength Wavelength Atomic
Absorption absorption left. No significant atomic absorption is apparent and background
IL layer
IL spectrum absorption mainly occurs. Conversely, the lamp emission spectrum
Background
when the small current flows comprises a single narrow peak resulting
Time
Atomic absorption from both atomic absorption and background absorption. By
determining the difference between the two types of absorption, it is
possible to accurately correct for the background absorption and
(Lamp energy) (Sample measurement) (Energy component ratio)
measure the true atomic absorption.
Examples suitable for SR method (where differences result between SR and D2 methods)
Example: Measurement of trace levels of zinc in iron (analysis of Zn in Fe solution)
BGC-SR method BGC-D 2 method
Zn 0.25ppm
Atomic absorption signal
Atomic absorption signal Zn 0.50ppm
Background signal
Background signal
Fe 0.1%
Fe 0.5%
Fe 0.5% Zn 0.25ppm
Fe 0.5% Zn 0.5ppm
Fe 0.75% Zn 0.3ppm
The identical 0.5 ppm Zn solution is accurately corrected to Due to inadequate correction, the absorbance is higher at
the same absorbance at (2) and (6). (6) than at (2) for the identical 0.5 ppm Zn solution.
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Examples of elements and wavelengths causing spectral
interference problems due to neighboring lines
Measured Element Analytical Line (nm) Coexisting Element Absorption Line (nm)
Al 309. 28 Mg 3 0 9 .3 0
As 193. 76 Fe 1 9 3 .7 3
Ca 422. 67 Fe 4 2 2 .6 4
Cd 228. 80 Ni 2 2 8 .8 4
Cu 324. 75 Fe 3 2 4 .7 3 The SR method is suitable for samples containing elements that cause
Ga 294. 36 Ni 2 9 4 .3 9 problems with spectral interference, as shown in the table to the left.
Mg 285. 21 Fe 2 8 5 .1 8
Ni 232. 00 Fe 2 3 2 .0 4
Pb 217. 00 Fe 2 1 6 .9 5
Sb 217. 58 Fe 2 1 7 .5 5
Se 196. 03 Fe 1 9 6 .0 5
Si 251. 61 Fe 2 5 1 .6 9
Zn 213. 856 Fe 2 1 3 .8 5 8 9
Examples suitable for D2 method (where no difference results between SR and D2 methods)
Example: Measurement of trace levels of lead in 2% NaCl solution by molecular absorption (analysis of Pb in 2% NaCl solution)
Background signal
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Clear, Easy-to-Use Software
Features of the WizAArd Software
The WizAArd software used with the AA-6880 runs under Windows 7.
Wizard Functions Make Setting the Conditions So Simple That Even a Novice Can Do It.
Just set the measurement conditions using WizAArd to
complete the general settings.
Start Wizard.
Select element.
Connect to instrument.
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Software Provides Comprehensive Information Displays and Flexible Settings
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$$ Supports System Management and Accuracy
FDA 21 CFR Part 11 Compliance
Userr Management
Use Mana
Managem
gement
ent
User management restricts the users of Log Br
Brows
Browser
owser
er
the system. It registers each user to The log browser easily displays a variety of logs to check the
determine how each one uses the system modification history and other log information.
software.
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Management
Accuracy Management (QA/QC) Functions Permit User Level Management, Audit Trail, and Electronic Signatures
QA/QC compatibility
The QA/QC functions permit accuracy
management.
* Data from all Shimadzu analytical instruments can be centrally managed by CLASS-Agent.
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$$ Installation Conditions
Dimensions
Wall
Table
200
150
465
588
870
200 max.
280
ø150 to ø200
Exhaust fan
Damper
417
1100 to 1200
Unit: mm
AA-6880 S=1: 2 0
Above dimensions do not include PC or printer.
702
GFA-6880
ASC-6880
390
340
702
960
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Make sure all required equipment is available before starting instrument installation. See the installation guidelines for details.
Example of recommended piping for the atomic absorption system Operating Temperature range 10 to 35 °C
environment Humidity range 20 to 80% (less than 70% when temperature is higher than 30 °C)
Stainless steel piping 1500 mm min. (W) × 700 mm min. (D)
(inner diameter greater than 7 mm) Testing bench
Withstand load: 200 kg *1, 2
Stop cock Stop cock Setting pressure 0.11 MPa Material Stainless *3
Gas tube
Dimensions 7 mm min. I.D. × 80 mm min. (L)
Cylinder: 0.11 MPa
Acetylene
Pressure regulator
Lab: 0.09 MPa
Compressor: 0.4 MPa
Acetylene gas
Gas supply Air
Pressure range 0.3 MPa pressure Lab: 0.35 MPa
Setting pressure 0.09 MPa Setting pressure 0.4 MPa (set secondary Cylinder: 0.4 MPa
pressure) Dinitrogen oxide
Lab: 0.35 MPa
Cylinder: 0.4 MPa
Argon
Lab: 0.35 MPa
Material Stainless
Setting pressure 0.4 MPa
Dinitrogen For flame: Approx. 500 mm W × 500 mm D
oxide gas Dimensions
Pressure range 1 MPa Exhaust duct For furnace: ø150 mm to ø200 mm
Setting pressure 0.35 MPa
For flame: 600 to 1200 m3/hr
Intake capacity
For furnace: 10 to 180 m3/hr
Argon gas
Pressure range 1 MPa Cooling water (GFA-6880) Cooling water circulation unit or tap-water equipment *4
Setting pressure 0.35 MPa
*1 Atomic absorption spectrophotometer stand recommended
Setting pressure 0.4 MPa
Mist separator *2 Maintain a free maintenance space of 150 to 200 mm to the sides and rear of the instrument.
*3 Do not use pipes containing copper, silver, gold, or mercury (or alloys containing these metals)
Pressure range 1 MPa as pipes for acetylene.
Setting pressure 0.35 MPa *4 If tap-water equipment is used, ensure that it meets the specifications below.
Lab Outdoor
Compatible faucet Faucet 13 or 12 to 15 mm O.D. rimmed faucet
80 mm max. Air compressor
Water temperature 10 to 30 °C
Water flow rate 0.6 to 1.5 L/min
Supply pressure 0.08 to 0.15 MPa *5
Supply port 7 mm min.
*5 If the supply pressure exceeds 0.17 MPa, use the optional Regulator ASSY.
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AA-6880 Series
The contents of this publication are provided to you “as is” without warranty of any kind, and are subject to change without notice. Shimadzu
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