The Feasibility of Peanut (Arachis Hypogaea) Shells As Alternative Glue
The Feasibility of Peanut (Arachis Hypogaea) Shells As Alternative Glue
Glue
Submitted to:
Submitted by:
Arnaiz, Robinson C.
Sibayan, Lea L.
March 2020
Table of Contents
Abstract ............................................................................................... i
Acknowledgement ................................................................................ ii
ChapterI. Introduction........................................................................... 1
Objectives .................................................................................. 2
Hypothesis ................................................................................. 2
Flowchart .................................................................................... 5
Summary .................................................................................. 22
Conclusion................................................................................. 22
Recommendation ....................................................................... 23
Appendices ........................................................................................ 24
Bibliography....................................................................................... 51
Table 1 ..................................................................................... 16
Table 2 ..................................................................................... 17
Table 3 ..................................................................................... 18
Table 4 ..................................................................................... 19
Table 5 ..................................................................................... 20
Table 6 ..................................................................................... 21
Figure 1 .................................................................................... 16
Figure 2 .................................................................................... 18
Figure 3 .................................................................................... 20
The alternative glue was made by extracting lignin from the peanut
(Arachis hypogaea) shells. The said lignin was extracted by pulverizing the
peanut shells and adding 1.5 gram of sodium hydroxide into the mixture.
The extracted lignin was then mixed with flour to obtain the glue-like texture
of the substance.
come out with the conclusions. Based on the computed mean of the
to commercially-available glue.
i
Acknowledgement
The completion of the study would not have been possible without the
appreciation to all of them. The researchers would like to extend our sincere
classmates, teachers and our school, Valenzuela National High School for
Above all, we are grateful to our Almighty God, for supplying us with
knowledge and wisdom, thus letting us complete and finish our study.
ii
Chapter I
Introduction
are thrown away because they have less uses, like the peanut shells.
Nowadays, waste are scattered all around. Burning them is one of the ways
to hasten waste but it can only add pollution to our environment and burning
waste can produce carbon dioxide (CO2) which is one of the so-called
global warming hence, it will later cause climate change which will affect not
out of peanut (Arachis hypogaea) shell’s lignin. . This will benefit the
1
Objectives
a) odor
b) color
c) stickiness
Hypothesis
2
Significance of the Study
hypogaea’s lignin, which will be beneficial to the environment for it will give
This research will also compare the alternative and commercial glue in
terms of odor, color, and stickiness. The ultimate goal of this study is to
create a more environmentally friendly glue that does not contain as much
toxic components than the ones available in the market. This way, the study
(Arachis hypogaea) shells and to test the product in terms of color, odor,
and stickiness. The effects of alternative glue to the paper after a long
period of time are beyond the scope of the study. The research will be
3
Definition of Terms
together
chemicals
4
Flowchart
5
Chapter II
about the lignin in straw and its application in the industry is scattered and
scarce compared to the wood lignin. This study of related literature has
natural and renewable product has been widely used in the past. Studies
also showed that there is a great potential for many applications across
chemicals. The type of lignin differs not only from one to another species but
bio-based polymers which are discarded as waste in the pulp and paper
production of such compounds have also been explained along with common
6
As stated in the study of Sen, T. et. al (2016), natural fibers are a
renewable resource and have several advantages associated with them, they
impart the composite with high stiffness and strength. Moreover, it proves
that they have a desirable fiber aspect ratio, biodegradable, readily available
from natural sources, and more importantly, have a low cost per unit
volume.
shells for a variety of purposes: fuel, mulch, carrier for chemicals and
fertilizers, bedding for livestock and poultry, pet litter, soil conditioners, etc.
Peanut hulls are also fed to livestock, particularly ruminants and rabbits,
although their high fibre content does not make them suitable for most
monogastric species.
other things. Scientist and educator George Washington Carver extolled the
value of peanuts and their shells at the beginning of the 20th century. In the
7
Based from the literature of Somayyeh, K. (2017), lignin, a
in the world. This generic term lignin describes a large group of aromatic
accounts for approximately 30% of wood weight while conferring rigidity and
lignin (HMKL) indicated that about 0.36 mole of the - CH2OH/C9 unit was
introduced into the lignin under the optimal reaction conditions, of which
about 0.33 mole was introduced into C-5 of guaiacyl moieties via Lederer-
gum flakes.
8
for the manufacture of exterior grade wood particleboard. The formulations
relative proportion of reactive points yield better results than the higher
molecular mass lignin used in the past. These lignin allow a higher
Based from the study of Akgül M. et. al (2008), the main objective of
this study was to investigate the potential of peanut husk (Arachis hypogaea
alcohol–benzene, hot and cold water, and dilute alkali (1% NaOH) solubility,
studied as an adhesive for more than 100 years, but there are only a few
industrial applications. The reason for the current interest is the high
availability and low price of lignin. Lignin is the main by-product of paper
pulping processes and is typically burned as fuel. Being the natural glue in
mainly of lignin has yet to be developed. Lignin has less reactive sites in the
9
aromatic ring than phenols, and the steric effects caused by the
lignin sulfonate with formaldehyde under the influence of caustic and heat
and then to combine the resulting compound with phenol formaldehyde resin
Based from the literature of Qiming (2005), a modified lignin and gum
cooled to room temperature, the solid content of 30-50% was obtained for
modified lignin plastic, the content of each component is: lignin 20-30wt%,
vegetation pigment
10
According to Songbai Z. et. al (2013), one method for preparing
method which uses lignin-based adhesive after the formation of gum waste
paper acetylated lignin particles in the air with the use of artificial stalks
extracting lignin from peanut. The method comprises the following steps:
crushing peanut shells into powder with granularity of 30-50 meshes; drying
the crushed peanut shell in an microwave; putting the dried powder into a
reaction kettle, adding solid sodium hydroxide in a ratio of 20:1, mixing and
wherein the ratio of water and powder is 2:1; further raising the
to obtain lignin.
11
Chapter III
Methodology
Materials
Microwave
10 grams flour
Procedure
Pulverize the peanut shells using mortar and pestle, crush into 30-50
mesh powder. Dry the pulverized peanut shells for 1 minute with a low
the dried pulverized peanut shells. Add 100 ml of tap water then put it back
obtained after the cooling separation. To obtain the lignin, let the insoluble
portion dry at between 30-40°C. Pour out the mixture into its final container.
12
Table 1: Comparison of Alternative Peanut Shell Glue and
Respondents
1 2 3 4 5 6 7 8 9 10
Alternative
Peanut Shell
Glue
Commercially
Available
Glue
Legend:
5 Fabric Conditioner
4 Soy Sauce
3 Vinegar
2 Fish Sauce
1 Bagoong
13
Respondents
1 2 3 4 5 6 7 8 9 10
Alternative
Peanut Shell
Glue
Commercially
Available
Glue
Legend:
1 2 3 4 5 6 7 8 9 10
Alternative
Peanut Shell
Glue
Commercially
Available
Glue
Legend:
force used
15
Chapter IV
2.2 3.7
of Color
This table shows that the alternative glue got an average of 2.2 while
the commercial glue got an average of 3.7, signifying that the alternative
glue’s color is similar to chocolate’s color while the commercial glue’s color is
similar with pale brown color. According to Schenk (1991), peanut shells
contain tannins, which diffuse from mechanical layer of peanut shell and are
4
3.5
3
2.5
2 Commercial Glue
1
0.5
0
Alternative Glue Commercial Glue
16
Figure 1: Graph showing the comparison of the mean between
of the shell interior is the tannins. The extent of browning depends on the
amount of tannin produced by the shell and also the growth pressure of the
seed.
Sources Degree
of of Sum of Mean Computed Tabular Decision Interpretation
Degrees Squares F F
Variation Freedom
(0.05)
Total 19 30.56
17
Alternative Glue Commercially Available Glue
2.7 5
of Odor
This table shows that the alternative glue got an average of 2.7 while
commercial glue got an average of 5. The odor of the alternative glue, which
strong acid with a pungent smell that can overwhelm other substances.
3 Commercial Glue
Alternative Glue
2
0
Alternative Glue Commercial Glue
18
According to Pelletier (2011), vinegar contains acetic acid that gives
Sources Degree
of of Sum of Mean Computed Tabular Decision Interpretation
Degrees Squares F F
Variation Freedom
(0.05)
Total 19
19
Alternative Glue Commercially Available Glue
3.1 3.5
of Stickiness
The alternative glue got an average of 3.1 while commercial glue got
glue can be compared to the stickiness of fingers being separated with great
force exerted while the stickiness of the commercial glue can be compared
3.5
2.5
2 Commercial Glue
0.5
0
Alternative Glue Commercial Glue
20
Figure 3: Graph showing the comparison of the mean between
their mixture.
Sources Degree
of of Sum of Mean Computed Tabular Decision Interpretation
Degrees Squares F F
Variation Freedom
(0.05)
Total 19
21
Chapter V
Summary
wastes such as peanut husks, which will also be helpful to students who use
glue because of its low price and can be made at home. The researchers
made an alternative glue using peanut husks, sodium hydroxide and water.
The researchers gathered the data that led to reject the null hypothesis. In
terms of color, alternative glue got an average of 2.2 while the commercially
available glue got an average of 3.7. In terms of odor, alternative glue got
Conclusion
drawn:
22
2. In terms of color, the alternative glue made out of peanut shells is
Recommendation
23
Appendix A
Plate no.1
Plate no.2
24
Plate no.3
Water
Plate no. 4
Flour
25
Plate no.5
Plate no.6
Microwave
26
Plate no.7
Weighing Scale
Plate no.8
27
Plate no.9
Plate no.10
Mixing the pulverized peanut shells with a 1.5 g sodium hydroxide flakes
28
Plate no.11
Adding and mixing of 100 ml water to the pulverized peanut shells with
sodium hydroxide
Plate no.12
Put the pulverized peanut shells with the sodium hydroxide flakes and water
29
Plate no.13
Mixing of the extract of the pulverized peanut shells and the 10 g flour
Plate no.14
Comparing the appearance and color of alternative glue (A) and the
30
Plate no.15
Comparing the appearance and color of alternative glue (A) and the
Plate no.16
Comparing the odor of alternative glue (A) and the commercially available
glue (B)
31
Plate no.17
Comparing the odor of alternative glue (A) and the commercially available
glue (B)
Plate no.18
available glue (B
32
Appendix B
Respondents
1 2 3 4 5 6 7 8 9 10
Alternative
Peanut Shell 2 3 2 1 1 3 2 3 4 1
Glue
Commercially
3 4 4 4 4 4 4 4 2 4
Available
Glue
Legend:
5 Fabric Conditioner
4 Soy Sauce
3 Vinegar
2 Fish Sauce
1 Bagoong
33
Table 2: Comparison of Alternative Peanut Shell Glue and
Respondents
1 2 3 4 5 6 7 8 9 10
Alternative 3 3 2 2 2 3 4 3 2 3
Peanut Shell
Glue
Commercially 5 5 5 5 5 5 5 5 5 5
Available
Glue
Legend:
34
Table 3: Comparison of Alternative Peanut Shell Glue and
Respondents
1 2 3 4 5 6 7 8 9 10
Alternative 4 4 3 3 2 3 3 2 3 4
Peanut Shell
Glue
Commercially 4 3 5 4 4 4 3 1 4 3
Available
Glue
Legend:
force used
35
Appendix C
36
37
38
CURRICULUM VITAE
dlamador21@gmail.com
09079095768
Personal Information:
Age : 14
Sex : female
Height : 4’9 ft
Weight : 94 lbs
Educational Background:
39
Awards/Honors Received:
Character References:
Valenzuela City
09218973491
Valenzuela City
09451080282
City
09156424471
40
CURRICULUM VITAE
ARNAIZ, ROBINSON C.
libag.master@gmail.com
09218973491
Personal Information:
Age : 14
Sex : Male
Height : 5’4 ft
Religion : Catholic
Educational Background:
41
Awards/Honors Received:
Character References:
09667780757
Valenzuela City
09079095768
City
09156424471
42
CURRICULUM VITAE
bradecindarylle@gmail.com
09156424471
Personal Information:
Age : 15
Sex : Female
Height : 5’ ft
Religion : Catholic
Educational Background:
43
Awards/Honors Received:
(RSPC)
Character References:
Valenzuela City
09218973491
Valenzuela City
09079095768
09451080282
44
CURRICULUM VITAE
Cherriemaebulahan1@gmail.com
09451080282
Personal Information:
Age: 14
Sex: Female
Height: 4’9 ft
Weight: 99 lbs
Educational Background:
45
Awards/Honors Received:
Character References:
Valenzuela City
09218973491
Valenzuela City
09079095768
City
09156424471
46
CURRICULUM VITAE
Criszafaye30@gmail.com
09667780757
Personal Information:
Age : 14
Sex : Female
Height : 150 cm
Weight : 44 kg
Religion : Catholic
Educational Background:
47
Awards/Honors Received:
Character References:
Valenzuela City
09218973491
Valenzuela City
09499792769
City
09156424471
48
CURRICULUM VITAE
yrlyel02@gmail.com
09499792769
Personal Information:
Age : 14
Sex : Female
Height : 5’2 ft
Religion : Catholic
Educational Background:
49
Awards/Honors Received:
Participant
Character References:
09451080282
Valenzuela City
09079095768
City
09156424471
50
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