Magmatic Cu-Au Hydrothermal Models
Magmatic Cu-Au Hydrothermal Models
Introduction
Discussion
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Ore Deposit Model
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Critical elements for a genetic model
Trap
(maximum disequilibrium)
• chemistry
• structure
Transport
(water, gas or magma)
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Tectonic Setting and Brief Magmatic
Hydrothermal System
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Regional Tectonic Framework (Waters, 2010)
Sundaland Craton
Continental fragment
Australian Craton
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Porphyry provinces
• In any given province, porphyry
deposits are typically emplaced
within a time interval of a few
million years
• Similar magma suites
characterise individual provinces
• Similar metal suite characterise
each metallogenic event
• There is a general relationship to
subduction environment
• Specific relationship to tectonic
change
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Favourable geodynamic settings
Island arc
Andean arc
Diagramcourtesy
Accreted arc
of Jorge Skasrmeta,
Post orogenic belt
CODELCO
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Behind-belt magmatic centres (shoshonitic)
Architecture of an oceanic island arc
• Porphyry deposits
form at discrete
moments in the
evolution of
magmatic arcs
• What are the
tectonic triggers?
Reproduced from
Richards (2011)
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Volcanism and porphyry
deposits
• Active volcanism is the antithesis
of porphyry ore formation
• When shallow crustal magma
chambers erupt, H2O is exsolved
as steam under hydrostatic load
• There is no capacity for the
magma to exsolve metal-rich
brine
• Low P conditions inhibit vapour
transport of copper and gold,
thereby preventing any
significant mineralisation
Plinian ash column, Mt St Helens, May, 1980.
Source: Murck et al., 1997
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Geodynamics: Mankayan 200 km
Philippine
Plate
Eurasian
Plate
200 km
Subducted part of
Scarborough Ridge
Uplift
Crustal-scale arc-transverse fault system occurs in the arc above a kink, or tear, in the subducting
slab
Rapid rise of asthenospheric melts and efficient release of mineralizing fluids at high crustal-levels
associated deposit
types magma sources
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Hydrothermal system
Hydrothermal system
associated deposit
types
convection
fluid sources
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Hydrothermal system
(continued)
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Intrusive system and magma sources
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Hydrothermal system in perspective
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Associated and related deposits
Epithermal systems:
Au Ag (Cu,Pb,Zn,As,Sb,Hg)
Cu Pb Zn Ag Au (As,Sb) veins & dissseminations
breccias & diatremes replacements
Mesothermal systems: Ag Au (F,B)
Zn Pb
Disseminated Cu skarns
“orogenic” gold
Au Sn
W skarns
Cu
I.O.C.G. systems
Iron Oxide Copper Gold
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Intrusive system in perspective
Richards, J.P. (2003): Tectono-Magmatic Precursors for Porphyry Cu-(Mo-Au) Deposit Formation;
Economic Geology, vol. 98, no. 8, pp. 1515-1533. 23
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Magma sources in perspective
Richards, J.P. (2003): Tectono-Magmatic Precursors for Porphyry Cu-(Mo-Au) Deposit Formation;
Economic Geology, vol. 98, no. 8, pp. 1515-1533.
*MASH: Melting Assimilation storage and Homogenization
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Where do porphyry copper deposits form
(geotectonic setting)
Richards, J.P. (2003): Tectono-Magmatic Precursors for Porphyry Cu-(Mo-Au) Deposit Formation;
Economic Geology, vol. 98, no. 8, pp. 1515-1533. 25
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Porphyry (+Skarn) and Epithermal
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Porphyritic intrusions
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Multi-phase intrusions
LEGEND
LP3
Alluvium
Post-Mineralization
Porphyry
N Northwest Porphyry
LA
100 m
LP3 Late P3 Porphyry
P2
EP3 Early P3 Porphyry
-66°36’15
LP3
Northeast Porphyry
B veins:
• Continuous planar quartz veins
• May contain molybdenite
• Lack K-feldspar and any obvious alteration halos “B” veins
D veins:
• Late sulfide veins
• pyrite ± bornite, chalcopyrite, enargite,
tennantite, sphalerite and/or galena
• Quartz – anhydrite ± carbonate gangue
• Phyllic alteration halos “D” veins
Hypogene mineralisation
Main ore minerals: chalcopyrite, bornite, gold, molybdenite
0.5 – 1 % Cu
+ +
+ + +
• Outer pyrite-rich halo + +
+ + +
• Cu-Au rich core may be + +
surrounded by Mo annulus + + +
+ + +
+
+
+
+
200 m
+ + + +
E27
E22
E48
E28
E37 E31
E26
Jurassic marine
sedimentary rocks
Permo-Triassic
crystalline Metamorphic
basement Basement
20
10
0
0 100 200 300 400 500 0 100 200 300 400 500
Age (Ma) Age (Ma)
Continental arc
Calc-alkalic Island arc
High-K calc-alkalic Collision zone
Alkalic Arc of unknown type
DataJsource:
ResourcesKirkham & Dunne, 1999
Genetic Model For Porphyry
From Corbett
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From Corbett
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The porphyry Cu model
Geology
Sillitoe (2010)
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The porphyry Cu model
Alteration
Sillitoe (2010)
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Lepanto mine
Actinolite-cemented
Quartz-chalcopyrite veins
Prehnite-calcite-pyrite
Biotite-magnetite hydrothermal
inorthoclase-
vein
and orthoclase-
in chlorite-
From Holiday and Cooke (2007), with inspiration from Biotite-magnetite-altered hornblende-
altered
Bladed
Epidote dacite
veins and Vuggy breccia,
quartz,
porphyry,
calcite-cemented
altered
alteration,
Mankayan
altered El
basalt,Teniente,
Lepanto,
Ampucao,
breccia,
Mankayan,
lithocap,
trachyandesite, Chile
Philippines
Philippines
Kelian, Indonesia
Ridgeway, NSW
Philippines
E27, NSW
Sillitoe and Thompson (2006) quartz diorite porphyry, Philex, Philippines
Summary
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SW Pacific porphyry and epithermal deposits
Monywa: Far South East:
2 Gt @ 0.38% Cu 329 Mt @ 0.72% Cu, 1.14 g/t Au
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Unconventional Settings
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Epithermal deposit classification
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To simplify discussion we will consider two end-
members:
Gold is the dominant economic metal in
• deposits associated with neutral pH,
dominantly meteoric fluids (low-
sulfidation)
• in most aspects intermediate-
sulfidation deposits are very similar to
low-sulfidation
• deposits associated with acid pH,
dominantly magmatic fluids (high-
sulfidation)
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Agynski, Kamchatka, Russia: high-grade ore with needle adularia
Geothermal systems
– modern analogues for LS – IS deposits
• Peripheral
bicarbonate waters
Neutral chloride
waters
400°C
• Steam-heated acid
sulfate waters
2 km
2 km
Magma
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Volcanic-hydrothermal systems
– modern analogues for HS deposits
• Magmatic heat and
volatile source
acid sulfate waters crater lake
solfatara
• Acid alteration in
acid chloride upflow & lateral
waters / brines
200ºC outflow zones
300ºC
400ºC 300ºC
• Volcanism may
disrupt or destroy
hydrothermal system
2 km
Magma
2 km
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Where do they occur?
Low-Sulfidation High-Sulfidation
Low-Sulfidation High-Sulfidation
Pyrite ubiquitous (abundant) ubiquitous (abundant)
Sphalerite common (variable) common (very minor)
Galena common (variable) common (very minor)
Chalcopyrite common (very minor) common (minor)
Enargite-Luzonite rare (very minor) ubiquitous (variable)
Tennantite-Tetrahedrite common (very minor) common (variable)
Covellite uncommon (very minor) common (minor)
Stibnite uncommon (very minor) rare (very minor)
Orpiment rare (very minor) rare (very minor)
Realgar rare (very minor) rare (very minor)
Arsenopyrite common (minor) rare (very minor)
Cinnabar uncommon (minor) rare (very minor)
Electrum uncommon (variable common (minor)
Native Gold common (very minor) common (minor)
Tellurides-Selenides common (very minor) uncommon (variable)
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Hydrothermal Alteration
Low-Sulfidation High-Sulfidation
pH Alunite
Mineral 100 Mineral
200 300
Mineral
Jarosite
Halloysite
Kaolinite
Stability Stability
A c idi c
Dickite
Pyrophyllite
Diaspore
Zunyite, topaz
Anatase
Rutile
Mineral assemblages
Cristobalite Sinter
lithostatic
allow us to estimate
Quartz
Pyrite
temperature and acidity
200
Marcasite
N eutr al
Smectite
Depth, m
Illite/smectite 400
Chlorite/smectite
Illite
600 hydrostatic
Chlorite (water + 1 wt% CO2 )
Epidote
Biotite 800
Adularia
A l k alin e
Mordenite
Laumontite
Wairakite
Chlorite
Illite
calcite
chlorite
epidote
calcite
pyrite
epidote
quartz, chalcedony, quartz residual quartz Quartz, illite / chlorite
adularia, pyrite, adularia (vuggy & massive), alunite, alunite
base metal sulfides, illite sulfides, sulfosalts, Au-Cu-
carbonates, Au-Ag pyrite (Ag)
Modified from Sillitoe, 1993
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Geochemical Associations
Low-Sulfidation High-Sulfidation
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Low-sulfidation schematic model
Silicified blanket
Illite ± adularia
0
Cool meteoric
(km) water Ores
Alteration Mixing with
envelope shallow meteoric
Acid sulfate water
with low Au solubility
water
Absorption of high-P Meteoric water
vapor produces transports gold
reduced, acid as AuHS(aq)??
Heated ground-
low salinity water Heated
1 water with high Au
ground-water
solubilities as
AuHS(aq) convective cell
Magmatic vapors Alteration Heated
(incl. SO,2 HCl) ground-water
Vuggy quartz
Acid brine
Alunite
Gas phase transports gold
Kaolinite metal transport as AuCl2- ??
Magmatic Sericite Magmatic
2 brine
brine
K-silicate
Modified after White (1991), Arribas (1995) and Heinrich et al. (2004)
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GAS PHASE
low density
high SO2, HCl
low NaCl, metals
LIQUID PHASE
higher density
low SO2, HCl
At shallow depths (< 4 km)
high NaCl, metals
aqueous magmatic fluids
split into two separate phases
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White, 1990
Lepanto-FSE, Philippines
SE NE SW
NW b v
v
v v
v v v v v v v
v v v 1200
v
1200 v v v v Breccia pipe v v
v v (m)
v v
(m) v v v
v v
Lepanto v
800 Epithermal ore 1000
>2.5 wt% Cu equiv.
v v
v
Main breccia ore
400
Porphyry ore 800
>1.0 wt% Cu equiv. FSE
+ 200 m
+ +
0 400 m
a b Stratabound ore
+ + +
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LOW SULPHIDATION
EPITHERMAL (LSE)
- Gosowong
- Pongkor
- Toka Tindung
- Hishikari, Japan
- Martha, NZ
- Cracow, Australia
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Evidence of boiling
Hydrothermal eruption breccia, Yellowstone, USA Co-existing L- and V-rich fluid inclusions,
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Intermediate Sulphidation
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Intermediate sulfidation deposits
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Intermediate sulfidation deposits
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From Corbett 2002
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FSE-LEPANTO-VICTORIA
Fe-rich sphalerite +
chalcopyrite veins in
sericite-carbonate Sphalerite-galena-
altered andesite carbonate fill
breccia
Kelian, Indonesia
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Overprinting
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Porphyry – epithermal superposition
J Resources Vuggy quartz with dickite infill, Lepanto, Philippines Reproduced from Sillitoe, 2010
Telescoping Mechanisms
Progressive uplift and erosion during magmatic-hydrothermal activity promotes
transition from lithostatic to hydrostatic load and epithermal overprinting
Rosario HS
vein
LS Epithermal
Rosario overprint
Porphyry Seaward-directed
sector collapse
Biotite
alteration
1 km
1 km
1 km 1 km
propylitic propylitic
• Phyllic alteration is
phyllic typically magmatic-
hydrothermal in
origin (not meteoric)
wall • It may relate to
rocks
potassic periods when
magmatic gases
dominate the system
Lowell and Guilbert (1970) model
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Tumpangpitu Type Section 11060mN
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AA overprint at Bujang,
AA overprint atTumpangpitu Photo by Rachel
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LOCATION OF PRINCIPAL EPITHERMAL DEPOSITS
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IOCG
Iron Oxide Copper Gold Deposit
(IOCG deposits consist of predominant magnetite or haematite, one or more copper sulphides
And (MINOR) pyrite within silicate alteration dominated by K-feldspar or sericite or by albite and biotite
or by biotite and chlorite-actinolite. DW. Haynes)
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Tectonic Setting IOCG (Hitzman, 2000)
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Alternative Models based on Principal Fluid Sources
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Conceptual Model (Barton and Johnson, 2000)
Conceptual model (Barton and Johnson, 2000) that contrasts igneous-related mineral deposits dominated by: (1)
magmatic hydrothermal fluids (on right, = porphyry type) with (2) those dominated by non-magmatic (external) brines
(on left, = IOCG type).
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Schematic Cross-Section of Alteration Zoning Related to Typical Fe-
oxide Cu-Au ±REE / U Deposits
(after Hitzman et al. 1992)
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Anatomy of an MH-IOCG system showing variable depth of emplacement of the source
batholith in the mid- to upper crustal environment, spatial associations of proximal and distal
alteration and mineralization styles, and possible fluid and metal sources. Sources: Hitzman et
al. (1992), Naslund et al. (2002), Richards (2005, 2011), Mumin et al. (2007, 2010), Groves et
al. (2010), Corriveau et al. (2010a,b).
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Genetic Link and Secular Differences Between PCD and Magmatic
Hydrothermal IOCG
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Genetic Link and Secular Differences Between PCD and Magmatic
Hydrothermal IOCG
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Genetic Link and Secular Differences Between PCD and Magmatic
Hydrothermal IOCG
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Olympic Dam
97
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Location
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SELESAI–SATU
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Volcanogenic Massive Sulphides
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VMS
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VMS
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Benar-benar S E L E S A I . .
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