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be dedined aa a eee HI Folly
) cRemscal bovd
a molkeade.
dogether He constisuend alone ™
PM) doolal chile 14 one efablle Roo a unbooded s Side.
Stor) (on ay © dleo Frown as elechonic
Reouy oS voleasy
Mole can orbibe HReary x
aes ded by Hund ond Mulliken rn’ 19324
Theory was pad dora YS
Atow ki onbidal fo to adomic on bi fal
Moleale Kr ombifal fo fo maleeslor on bital.
ylestyfollee of, MoT x
LCOAO '- Linear Combination of ofomie Onbitete
Ddomic on bite (Do)t 4 <— ho} ey
on ear
Mbecten o bite io
ce
as
=
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om,
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gre
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we
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ad
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e(7 Simvilon, eneryy:-Combintion 1 Poterble whew afomrt
Onbrfed's fave simu coergy devel.
a4
L»Tb pk ye energy pup wheya
Err Jb IK ood Joswchonnkr Ro Payegg.
Biles sla [Hip herd
ft
ry Reedisto, bibion of energy ons
Formed meleudan onbifals = Combined afom'e onbitalls
no. of Mo® x0. of IDN.0
* Lowen energy bonding Modecilan onbiged (8M0)
@ Higher er bonding Molecular onbs fel O8mo)
Ww Configurabion t=
Lighter maleude een of €Lt4
%
Hi, othe weds, rahe wah, wh TA a=W sp ot
4 a den of enenpyW's
l i (A8BN®
7; ans ~
ee Sak ey
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7 rors
yt st
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= ee 2
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= Wate MF
oo
é
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BL) Heavrour malecule ¥ no: ode hd
e 1g jot on 2Ge ts yr oP, Th = Th » wabu= Tok,
= ee
—
increas ing i
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reetrereer
ail
r
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oe = if unpaired ere Preseod
fase magne dic ore a
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tawagmedirc *
6. Bood andes.
Bood onde» sa
Measure mend ou boo! Sneogh Oo»
bond SH bilidy,
$0=Mh-m%
<
My = Mo of boodn e
Na= No. of ands bending 6
Bow Coat Bond
STobiliy “ Aoeoght ae
Jeogf
Be a
Di pa Onding
\os
o -
~ Latan flee
ae
ee @ Ho wm ollecle © Me
t :
= Hs if Rea es
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ae ts
ent 8 os Sr =
_ i 4 1s wm 146
ets
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eno ois §.6= 2:29 S69
5
Sees fo=2= Ont
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2 H Fs Hence cbimagne dite
— eace divnapoehe 7 he
cu9
Hug D Mr moleule
ae a9) oe
peel a
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Kno
nme
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iy 1
cs
cn»
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Fi Poy Tal ;
Av
PoP,
BVTAR
Sof,
§.ozto-t 2 3
7
Nv
=.
Fae
Hen ce diqnagnedic in
Tae
aoo
oO. =. Ore sang
ED
Hence tf 18 0 Para magne die th adhuneee z
Hence Saas feeds
pe
o>
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s
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HE moleade
AY:
(sh)
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Hence sf fo iop magne brs me (eaen
RPP PPAR PPRARPPOREARASSASAY LEAVY IDwep
|
r 109C0 Bon ding
I ydeay 2 7
pe
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i. When an Rydnogeo ofom 16 il) Wh Am
~ elecdina aegchive ofom ond o Fgh edec Ino atgahve thes
FHP faving Lone Poin Je dy ing do make bond with
3 ao own
= Rydrogen fom Hon Hel bond 8 Frown 06 Fydnopey
oo Cae
~~ : d Doak
~ a He 6
— Covdleed
~~
bond
— Sfnenghh of fy dnayen bond
fon'c oF
SS eet AE Cosi
- Nod t
a H-bond x E- ‘trary -
: He bowdr'n
— ge itt es 4
=m 9) inbrwoleallr H- booding Ui) obra male clon H-boetiy
“ eblu duo 7 mane tan duo + Tn 0 maleate
el moleudes . Rong ike Stu dune
ato Chelah'on (Wosv'ng) Oye
O-H ~ Ve 0. Ui]
US 0
a
Ss
*
Nes
. Le
Rr modeede m
ee E :c
oobke, basi ab evtyy
ye
a
Syme Bnical H-bonding
© Shooy
_ Solubilid,» TRe Prttecce af fy thoy ee bonding bl,
Deg a Subsfince tinditade Hof the mabhases one
PEPSI) IIL I¢0042
Elect, vidy .~ TRe elemend &
i Snontgahividy . y he tlemend fering mane electo
Jorms fydroven bondix 0, ef
yop oy bd eben deed
ding De,” ne
deze bonding
=JMolewles Ravi
1 Fydrozen bondin
mole, 7 Ee ovyy Rave Spe
FJ Mohkules Toning dees aof Rave 4 ‘
Lowen ile, Sey me
—epaige
Wiscosity, and Surface tension
ods, have trgher
1 doom stoong Rydrogee bo ler
ae %, vne ae
values oF vis cocity ond : ’
Fh Due Fo & drogen bonding waber 6 mane vI'8Coud Shap
offer — angani'e Liquids:
a Medetc ooding g :
WRen a met) docs © 80 © do vat ged od o
Bod oder asp here Foor the metalic tye 10M bez De
Game dhe bly re ll eens and & daom bond
week we Collled anedallse bond
canteaseetsites
ech ong)
rome ti @ ®
Lond & @ @ ©
e@ @ @
Tteamves of eflle bonding,
sp The Sree & Fe ony ] Electron sea Meory| Davee —lonente Heo
si) Me valence bend Kec | Resonance. HReory
ee If
ze
a
jis) Fe mcloolen orbital HReory | fond eorywlll ihe oe
Also Known ag Fllec tron bea
o “@e @e
Jr oY Sy
Oe @e@e
cree eae
G wn
AE}
Fae tan Mecon ding fo ie free € PReony Keone ts
Enovgh mo. of & tn ary Pond abe anand fhe
Keanal( Purse von), Pe & fnavelr tm a wave
WP feems Ike we fave a sea of er-
o TRe Posendiad enengy of Pte so Aa Pe cays ball
Han in de Tioleded ator .
e Hence dis 9.F 16 mes Pong; ble for swefallle bond.
Limidabione 5.
TRe only Qrniehion io Hof dR Heo eee
devs od quablifafive Arnall ug wees, aa a
quend'debrv e Onaly 6 Bron Res Keo, o fess
Soccesstul +aes Valence, Bond, Theory
, md © This Heong 6 also Known a6
omer Necon ding fo Ris Heory , He sdrucdne of medals
be descnibed to Snr af covalent
Resonnne Heony.
ere or abla “y
ow 9” a
Sea bonds Rad mesonafle amongs4 He Memnafe inderalorc
eee Positions Mm medals
mm
—
—
mm
—
~~
a ybinifabions
Boe TRe VET amncf explain dermal conductivity 5 metallic
=e Justine amd decneage Cooducstvid, with RmPrcdunre-
eer, 3 36 also nod Pooo'hle fo carp $e nedent'on oh
medalfirc properties te He Uquid. stk on tn sdldron.
So
Nes
ie)* Mole cutak ORBI Tal THEORY »
SY AR6 oknon One tory
ee
+ Bars on mebabe
o TR
o. af atoms y He M9
tag
Heong Ore acl
Ms vnedtlls ComPosed of very fonge
(bot Povey ond aud born) formed becomes 60 Sorige i)
Rot Here is vino aly na ent ipy ore nence fom One
Oxide Jo nee ¥ Ond He onbifals merge inf & band
of allow ed cvengy Levee, ond Bra ta He onigrn of
Bond Peony.
Volence band. 2 band Jooming by abowdling mao
nding m,
16 Kown a8 valence bond and ry
Sele d wih em + ‘a
HHH
CondbucSon bod. ‘
aa B bond Sooming by andl boedbiny ny
16 Known gg Conduction band ond of i
=
re Compe el, ene
TYSaaY,
E mes '-
ay ga’ TRe gop bly dh
du Ay m
Valence band 15 Known Qs ie és 9
Jop: ey gp 001 band
—fa" and Heosy of bin
Lez is” ast ae?
Lag 42 a8 °°
a
3
Cittrery
mW 5 full Filled om bvdal
ath HO
CeHERELILICLILLtetiee
a
Ff
&ome ©)
a -
SOLL@ STATE — *
On He basis of extrnd Sahnes, Crystal Con PO =
eacpain by Jalllowning poinds ~~
is +
peels Poe. Sucre Barat ot Ory Crystal OF void cell eee
rs Called face. i oe
yy We assocrasion of 6 Jaces Sexe vs a Sormcbvoo of
unit cell on Cory stall. > fo
ce
Ok
Bl
A) tafe “TRe Tolniag beet ofc iiee ee 16 Called eye
In one uetd cell Hene one 40 edge Gre Pregenf
BenF
E dye
HHEEEH TELL
“=cell
vof
EeEECEELLICCEIUIIC1NN000 000001
©) Tnderducied ary - When wo Jace a6 sociodes , ten
He Angle formed inarde de face oF soled v9 cabled
Tofortecrad angle.
5 Tafendacial ong le
d) Zove Ond Tone oxti's:~ Wken a Unid cell io
Hen if known a6
s
Q6 o0cioe bby Comele o bel®
Tone.
Tr $e cendne of, Zone»
do edge den Wig 16 Knows ap Zone aoxie-
when Omy dine Passes Ponalel
unit, oh
tk ony Josfrce due do whre f
Fre smolles# Ponficlle
os untd cell.
a Nedice uit Sonn —¢4 Known
Shed by $e ans ociahion od und
Pod we Com Say
Sommatton oo a Cyst Sfoocdune,
ce tet flene is a“ce Com bine
TRe sfape of 09 geore dry af vy See
70m 0 unil cell.
> united
Unit cell Can be vary in sire deproding on de Lath ce.
Arie of Spon fe
When a Sine is Pass Kraay f He centre of vat
Cel SucR of He ne pedadion of same Sdrucdune 1a
Jos many dimes Hen Ia 1s Known ag ars of
Spamedy,
y fais oS Speedin 2 oF folaaiog pes
D Pais of Foun Sal ee
WRenicline, (i. Poe, soug fi We cendne
Im Suck a way Here epedeb on
66 form foun simes +
of Qny cube
DF same Soucbng
EHH EHH tttPeCOLII(CLILIICL1NECtisitte
2
TRen ne pedation v6 done On ae? Qc
1) Daca oF S20 Sold Symmred
WRen a fine Pass Boo ugh He cevdne of ony dothice
Sock of v0 Same sdrucdune 16 ve feadeded ly Sorrmed
Do nofobion » PRs Symmedtiny ia krourm as foro Jodh
ii) Yody centined cubic y atice_( 80)
8 odor o7 Point one
He pe od dedttce tow,
ie commen nd oleo of She cendne of
dd
a
Qneseat of ie
Dody.
ody corer A ¥6 Sas
cece 7 1'V) Nuwbery of tory in aid cedly
Jallvoing Soon yae 6 used.
No- oF adom im unig cel) > Ne + Tp
§ im
jf ee
Rene 2
Ner7 No. od odom of Comes
NFP no. of afom off fue cendne
Nino. oF ado inside de Cube
on
Centne of body
y Simple cubic Jadhice
We Knoo in simple Cubic oSfice ofoms ong on
Point ane resent onky of commen .
a Nombes oF afom in untd Cell & +o yo
ie eS
Th Ony unit call Jo confine JRe num ben of fom,
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