SAFETY DATA SHEET
1. Identification
Product identifier NACCONOL 90G
Other means of identification
Product code 0533
Recommended use Surfactant
Recommended restrictions For industrial use only.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Company name Stepan Company
Address 22 West Frontage Road
Northfield, IL 60093
USA
Telephone General 1-847-446-7500
E-mail Not available.
Emergency phone number Medical 1-800-228-5635
Chemtrec 1-800-424-9300
Chemtrec Int'l +1 703-527-3887
2. Hazard(s) identification
Physical hazards Not classified.
Health hazards Acute toxicity, oral Category 4
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 1
Environmental hazards Hazardous to the aquatic environment, acute Category 2
hazard
Hazardous to the aquatic environment, Category 3
long-term hazard
OSHA defined hazards Combustible dust
Label elements
Signal word Danger
Hazard statement Harmful if swallowed. Causes skin irritation. Causes serious eye damage. Toxic to aquatic life.
Harmful to aquatic life with long lasting effects. May form combustible dust concentrations in air.
Precautionary statement
Prevention Keep container tightly closed. Prevent dust accumulation to minimize explosion hazard. Keep
away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and
receiving equipment. Wear eye/face protection. Wash thoroughly after handling. Do not eat, drink
or smoke when using this product. Avoid release to the environment. Wear protective gloves.
Response If swallowed: Call a poison center/doctor if you feel unwell. If on skin: Wash with plenty of water. If
in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Immediately call a poison center/doctor. Specific treatment (see this
label). Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated
clothing and wash before reuse.
Storage Store away from incompatible materials.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise May form combustible dust concentrations in air.
classified (HNOC)
Supplemental information None.
Material name: NACCONOL 90G SDS US
Material ID: 430 Product code: 0533 Version #: 08 Revision date: 03-22-2018 Print date: 03-22-2018 1/8
3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
Sodium (C10-16) benzenesulfonate 68081-81-2 90 - 93
(Alternate CAS: 25155-30-0;
68411-30-3)
Sodium sulfate 7757-82-6 5
Water 7732-18-5 1.5
Sodium chloride 7647-14-5 <1
Other components below reportable levels 1-<3
4. First-aid measures
Inhalation If dust from the material is inhaled, remove the affected person immediately to fresh air. Call a
physician if symptoms develop or persist.
Skin contact Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off
contaminated clothing and wash before reuse.
Eye contact Do not rub eyes. Immediately flush eyes with plenty of water for at least 15 minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately.
Ingestion Rinse mouth. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
Do not induce vomiting without advice from poison control center.
Most important Dusts may irritate the respiratory tract, skin and eyes. Symptoms may include stinging, tearing,
symptoms/effects, acute and redness, swelling, and blurred vision. Permanent eye damage including blindness could result.
delayed Skin irritation. May cause redness and pain.
Indication of immediate Provide general supportive measures and treat symptomatically. In case of shortness of breath,
medical attention and special give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.
treatment needed
General information In the case of accident or if you feel unwell, seek medical advice immediately (show the label
where possible). Ensure that medical personnel are aware of the material(s) involved, and take
precautions to protect themselves.
5. Fire-fighting measures
Suitable extinguishing media Water spray. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Apply extinguishing
media carefully to avoid creating airborne dust.
Unsuitable extinguishing None known.
media
Specific hazards arising from Explosion hazard: Avoid generating dust; fine dust dispersed in air in sufficient concentrations and
the chemical in the presence of an ignition source is a potential dust explosion hazard. During fire, gases
hazardous to health may be formed.
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting In case of fire and/or explosion do not breathe fumes. In the event of fire, cool tanks with water
equipment/instructions spray. Move containers from fire area if you can do so without risk.
Specific methods Cool containers exposed to flames with water until well after the fire is out.
General fire hazards May form combustible dust concentrations in air.
6. Accidental release measures
Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Dust
protective equipment and deposits should not be allowed to accumulate on surfaces, as these may form an explosive
emergency procedures mixture if they are released into the atmosphere in sufficient concentration. Use only non-sparking
tools. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged
containers or spilled material unless wearing appropriate protective clothing. Avoid inhalation of
dust from the spilled material. Ensure adequate ventilation. Local authorities should be advised if
significant spillages cannot be contained.
Material name: NACCONOL 90G SDS US
Material ID: 430 Product code: 0533 Version #: 08 Revision date: 03-22-2018 Print date: 03-22-2018 2/8
Methods and materials for Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take
containment and cleaning up precautionary measures against static discharge. Use only non-sparking tools. This product is
miscible in water.
Large Spills: Collect spillage. If sweeping of a contaminated area is necessary use a dust
suppressant agent which does not react with the product. Sweep up or vacuum up spillage and
collect in suitable container for disposal. Collect dust using a vacuum cleaner equipped with HEPA
filter. Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air). Minimize
dust generation and accumulation. Prevent entry into waterways, sewer, basements or confined
areas. Following product recovery, flush area with water.
Environmental precautions Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic
environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid
discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect
material from direct sunlight. Ground/bond container and receiving equipment. Minimize dust
generation and accumulation. Provide appropriate exhaust ventilation at places where dust is
formed. Do not get this material in contact with eyes. Do not get this material in contact with skin.
Avoid breathing dust. Do not get this material on clothing. Wear personal protective equipment.
Wash thoroughly after handling. Avoid release to the environment.
Conditions for safe storage, Keep away from heat, sparks and open flame. Dry powders can build static electricity charges
including any incompatibilities when subjected to the friction of transfer and mixing operations. Provide adequate precautions,
such as electrical grounding and bonding, or inert atmospheres. Store in original tightly closed
container. Store in a well-ventilated place. Guard against dust accumulation of this material.
Routine housekeeping should be instituted to ensure that dusts do not accumulate on surfaces.
8. Exposure controls/personal protection
Occupational exposure limits This mixture has no ingredients that have PEL, TLV, or other recommended exposure limit.
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Ventilation should be sufficient to effectively remove and prevent buildup of any dusts or fumes
controls that may be generated during handling or thermal processing. Eye wash facilities and emergency
shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles) and a face shield. Use tight fitting goggles if
dust is generated.
Skin protection
Hand protection Wear appropriate chemical resistant gloves.
Other Wear appropriate chemical resistant clothing.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
considerations as washing after handling the material and before eating, drinking, and/or smoking. Routinely
wash work clothing and protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Physical state Solid.
Form Powder.
Class II Dust for National Electric Code (NFPA 70)
Pmax = 6.4bar
Kst = 56 bar m/s
Minimum Ignition Energy (MIE) = > 1000 mJ
Minimum Explosible Concentration (MEC) = 74 g/m3
Minimum Autoignition Temperature (MAIT Cloud) = 460 C
Limiting Oxygen Concentration (LOC) = 15 vol. %
Mean particle size = 218 (11% < 75) micrometer
Color Cream
Odor Not available.
Odor threshold Not available.
pH 6 - 7.5 (1% aqueous)
Material name: NACCONOL 90G SDS US
Material ID: 430 Product code: 0533 Version #: 08 Revision date: 03-22-2018 Print date: 03-22-2018 3/8
Melting point/freezing point > 572 °F (> 300 °C)
Initial boiling point and boiling Not available.
range
Flash point > 201.0 °F (> 93.9 °C)
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 0.0002 hPa estimated
Vapor density Not applicable, powder
Relative density Not available.
Solubility(ies)
Solubility (water) Soluble
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Partition coefficient log Kow = 0.45 (HSDB, 2000)
(oil/water)
Specific gravity 0.53
10. Stability and reactivity
Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Keep away from heat, sparks and open flame. Avoid temperatures exceeding the flash point.
Contact with incompatible materials. Avoid dispersal of dust in the air (i.e., clearing dust surfaces
with compressed air). Minimize dust generation and accumulation.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition Upon decomposition, this product may yield sulfur dioxide and oxides of sulfur.
products
11. Toxicological information
Information on likely routes of exposure
Inhalation Inhalation of dusts may cause respiratory irritation.
Skin contact Causes skin irritation.
Eye contact Causes serious eye damage. Dust in the eyes will cause irritation.
Ingestion Harmful if swallowed.
Symptoms related to the Not available.
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicity Harmful if swallowed.
Material name: NACCONOL 90G SDS US
Material ID: 430 Product code: 0533 Version #: 08 Revision date: 03-22-2018 Print date: 03-22-2018 4/8
Product Species Test Results
NACCONOL 90G
Acute
Dermal
LD50 Rabbit > 2000 mg/kg
Oral
LD50 Rat 1080 - 1980 mg/kg
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Causes serious eye damage. Dust in the eyes will cause irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not available.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)
Not regulated.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - Not applicable.
single exposure
Specific target organ toxicity - Not applicable.
repeated exposure
Aspiration hazard Not applicable.
12. Ecological information
Ecotoxicity Toxic to aquatic life. Harmful to aquatic life with long lasting effects.
Product Species Test Results
NACCONOL 90G
Aquatic
Algae EC50 Algae 29 mg/l, 72 hours
Crustacea EC50 Daphnia 1.62 - 9.3 mg/l, 48 hours
Fish LC50 Fish 3 mg/l, 96 hours
Persistence and degradability Expected to be readily biodegradable.
Bioaccumulative potential No data available.
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
Material name: NACCONOL 90G SDS US
Material ID: 430 Product code: 0533 Version #: 08 Revision date: 03-22-2018 Print date: 03-22-2018 5/8
14. Transport information
General DOT Non-Bulk: Not Regulated
The following transportation classifications are for bulk shipments only:
DOT
UN number UN3077
UN proper shipping name Environmentally Hazardous Substance, Solid, N.O.S. (Alkylbenzenesulfonic Acid), MARINE
POLLUTANT
Transport hazard class(es)
Class 9
Subsidiary risk -
Packing group III
Environmental hazards
Marine pollutant Yes
Special precautions for user Not available.
IATA
UN number UN3077
UN proper shipping name Environmentally Hazardous Substance, Solid, N.O.S. (Alkylbenzenesulfonic Acid)
Transport hazard class(es)
Class 9
Subsidiary risk -
Packing group III
Environmental hazards Marine Pollutant
Special precautions for user Not available.
IMDG
UN number UN3077
UN proper shipping name Environmentally Hazardous Substance, Solid, N.O.S. (Alkylbenzenesulfonic Acid), MARINE
POLLUTANT
Transport hazard class(es)
Class 9
Subsidiary risk -
Packing group III
Environmental hazards
Marine pollutant Yes
EmS Not available.
Special precautions for user Not available.
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78 and
the IBC Code
DOT; IATA; IMDG
Marine pollutant
Material name: NACCONOL 90G SDS US
Material ID: 430 Product code: 0533 Version #: 08 Revision date: 03-22-2018 Print date: 03-22-2018 6/8
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)
Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
Classified hazard Combustible dust
categories Acute toxicity (any route of exposure)
Skin corrosion or irritation
Serious eye damage or eye irritation
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Clean Water Act (CWA) Hazardous substance
Section 112(r) (40 CFR
68.130)
Safe Drinking Water Act Not regulated.
(SDWA)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Japan Inventory of Existing and New Chemical Substances (ENCS) Yes
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory (NZIoC) Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
Taiwan Taiwan Inventory (TCSI) Yes
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date 06-30-2014
Revision date 03-22-2018
Version # 08
Further information Refer to NFPA 654, Standard for the Prevention of Fire and Dust Explosions from the
Manufacturing, Processing, and Handling of Combustible Particulate Solids, for safe handling.
Material name: NACCONOL 90G SDS US
Material ID: 430 Product code: 0533 Version #: 08 Revision date: 03-22-2018 Print date: 03-22-2018 7/8
Disclaimer Terms and Conditions. This SDS is designed only as guidance for the products to which it applies.
To the greatest extent permitted by applicable law, nothing contained herein creates any legal
obligation including contractual obligations, expressed or implied warranties, including any
warranties of merchantibility or fitness for particular purpose; or confers any intellectual property
rights, including rights to use trademarks or a license to use patents, issued or pending. The
information contained herein is based on the manufacturer's own study and the work of others, and
is subject to change at any time without further notice. There is no warranty, expressed or implied,
as to the accuracy, completeness or adequacy of the information contained herein, and neither the
provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of
either) are liable to any party for any damages of any nature, including direct, special or
consequential damages arising out of or in connection with the accuracy, completeness, adequacy
or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this
SDS. The receipt and use of this information constitutes consent to these terms and conditions.
Revision information Identification: Recommended restrictions
Hazard(s) identification: Supplemental information
Composition / Information on Ingredients: Ingredients
Physical & Chemical Properties: Multiple Properties
Transport information: General
HazReg Data: International Inventories
Material name: NACCONOL 90G SDS US
Material ID: 430 Product code: 0533 Version #: 08 Revision date: 03-22-2018 Print date: 03-22-2018 8/8
