Bimetal Production and Applications: A. A. Bykov
Bimetal Production and Applications: A. A. Bykov
Original Russian Text © A.A. Bykov, 2011, published in “Stal’,” 2011, No. 9, pp. 61–69.
Abstract—Production methods for rolled bimetallic structures are briefly reviewed, along with their applica
tions in the manufacture of certain metal products. Applications of bimetals of different type are outlined.
DOI: 10.3103/S096709121109004X
At present, multilayer metals—including bimetals— methods may be classified in terms of common char
constitute a large group of industrial materials with a wide acteristics. Thus, in terms of processes at the layer
range of properties. In bimetal rolling, the cheaper metal boundaries, three combinations may be identified in
is generally chosen as the base. The applied layer is char the contact zone: liquid + liquid; solid + liquid; and
acterized by high performance, depending on the specific solid + solid.
requirements (corrosion resistance, wear resistance,
electrical conduction, etc.). For different applications,
bimetals may be produced as sheet, strip, wire, pipe, Cast Surfacing
complex profiles, etc. In other words, their range practi An important method based on the interaction of
cally matches that of individual steels and alloys. liquid and solid metals is cast surfacing. This method
In applications, multilayer metals may be divided into is mainly used to produce bimetal blanks for subse
corrosionresistant, wearresistant, or tool materials, quent pressure treatment. In the production of two or
thermal bimetals, electricalengineering, wire, contact, threelayer sheet, the initial blank is obtained by cast
or antifrictional materials, materials for deep extrusion, ing liquid metal with one or two plates fixed in the
for heat exchangers, or for domestic appliances, and so mold (Fig. 1). The number of plates and their position
on. Bimetals significantly improve the production effi correspond to the number of layers in the final product
ciency of components in various branches of industry. and the subsequent production technology [1]. This
Technology benefits from the development of method is most effective in the manufacture of corro
effective production methods for bimetals and expan sionresistant and wearresistant bimetal sheet [2, 3].
sion of their range. Despite long experience in the cre Although it is simple and economical, cast surfac
ation of bimetals, they still occupy a secondary status ing has a number of limitations: the narrow gaps
among structural and functional materials, perhaps between the walls of the mold and the plates cannot be
because practical considerations lag behind experi satisfactorily filled with liquid steel; and the plates
mental and theoretical research in the field. melt if their melting point is below the temperature of
In the production of bimetals and multilayer met the liquid metal. It is difficult to use cast surfacing in
als, the goal is to ensure a strong bond between the lay the production of bimetal blanks when the plates are
ers over the whole contact surface, with specified sensitive to cracking on introducing the liquid metal.
thickness ratios of the layers; the formation of the In addition, this method is unsuitable for the produc
required structure and properties of each layer and the
bimetal as a whole; and further expansion of applica
bility. The latter factor must be based on analysis of the (a) (b) (c)
existing and prospective demand for bimetals of spe
cific quality and size and the capabilities of existing
equipment. The existing research and production
capabilities of metallurgical plants are sufficient to
meet Russian demand for multilayer metals, which
offer high efficiency at low cost.
METHODS OF PRODUCTION
Fig. 1. Installation of corrosionresistant steel plates in
The production technology for bimetals is largely mold for the production of a twolayer plate (a), a three
determined by the combination of metals. Existing layer plate (b), and two twolayer plates (c).
778
BIMETAL PRODUCTION AND APPLICATIONS 779
Continuous Casting 1
A promising approach is the continuous casting of 5
plane or round bimetallic blanks for subsequent plastic
deformation [4, 5]. The successive casting of two dif 2
ferent liquids ensures stronger bonding of the layers
than in the previous case and also considerably
increases the productivity, reduces the cost of the final
products, and creates favorable conditions for mecha A–A
nization and automation of the production processes.
The casting of threelayer blanks for rolling in the pro
duction of plow moldboards is illustrated in Fig. 2.
The upper mold 1 shapes the basic metal supplied
from casting ladle 3; the lower mold 2 shapes the coat
ing metal. In casting, the solidifying blank of basic
metal 5 is sent to the lower mold, where the coating
metal from mold 4 solidifies. The interaction of the
coating metal with the slightly oxidized hot surface of A A
the basic metal forms a bimetal blank, which is subse
quently processed in the same way as in an ordinary
Fig. 2. Producing a gapfree threelayer blank in a contin
continuouscasting machine. uouscasting machine: (1, 2) upper and lower molds;
The range of components produced from continu (3) casting ladle with basic metal; (4) ladle with coating
metal; (5) solidifying basic metal.
ouscast bimetallic blanks is relatively broad. Note,
however, that the continuous casting of bimetallic (b)
blanks is not yet widely used. (a)
2 1
Centrifugal Casting 3
Centrifugal casting is used to produce bimetallic G G
blanks with subsequent hot or cold plastic deformation
in pipe and rod production. In the casting of molten
metal and slag in a rotating mold, the metal for the
external layer is first introduced, followed by the slag. Fig. 3. Application of coating layer by wire (a) and strip
After solidification of the metal, with a slag coating, (b) electrodes: (1) cold wire; (2) conducting electrode;
the second metal is introduced, and the slag rises to its (3) current source.
surface. As a result of the washing and mixing of the
metals, a sufficiently strong bond is formed.
In multilayer surfacing, the chemical composition
of the first coating layers is changed by mixing, which
Multilayer Surfacing depends on how much the basic layer melts. In coating
Multilayer surfacing is widely used for the direct by two electrodes (Fig. 3), when the melting of the
coating of sheets and also forged and stamped parts of cold wire in the arc between the conducting electrode
carbon and lowalloy steel. This method may be used and the basic metal consumes some of the arc energy,
to produce large bimetal blanks for subsequent rolling the melting of the basic metal is reduced. To ensure the
into twolayer sheets [6]. In this method, the bond of required thickness and composition of the coating,
the coating layer and the base is formed in the liquid several layers are applied to the wire. However, this
state, thanks to melting of the basic layer to a certain considerably complicates the process and does not
depth and mixing of the coating metal with the molten ensure the required surface quality. The next step in
base metal. This ensures high binding strength of the the development of this method is to use a strip elec
layers. trode (Fig. 3b).
+
num, copper, nickel, and titanium. The production of (b)
multilayer materials by cold surfacing consists of sev
eral steps: preparation of the initial components; cold 2 3 4
+
surfacing; heat treatment; final cold rolling; and heat 1 + 5
+
treatment and trimming [1, 11]. In comparison with
piecewise stack rolling, cold surfacing is significantly +
+ +
+
faster, requires less labor and less metal, permits
mechanization and automation of the process, and (c)
+
improves working conditions.
The initial blanks, in the form of coiled strip, are 2 2 4
+
degreased and etched; their contact surfaces are 1 +
+ 5
cleaned. The initial blanks (strips of the basic and sur +
facing materials) are fed into the rollers of the mill and +
+ +
+
subjected to cold deformation (Fig. 10). The resulting
multilayer strip is wound into a coil. In cold surfacing, +
a sufficiently strong bond between the layers may be +
2 3
formed when only the more plastic component is
deformed. In rolling asymmetric strip, the nonunifor Fig. 10. Production of twolayer (a), threelayer (b), and
mity of laminar deformation leads to flexure of the fivelayer (c) strip by cold rolling and subsequent coiling:
bimetal on leaving the rollers. Such flexure may be (1) unwinding system with coil of basic material;
(2) unwinding system with coil of surfacing material;
prevented by specifying different roller speeds or (3) guide wheels; (4) working rollers of mill; (5) winding
by using rollers of different diameter. system with coil of multilayer strip.
In the production of wearresistant and tool bimet
als, joint rolling with local surfacing is employed.
Electrical contacts are produced by banded surfacing ing, mixing of the basic and coating steels is not per
(rolling of a stepped laminar stack in smooth rollers), mitted since the corrosion resistance of the coating is
so as to ensure flatness of the bimetallic strip. lost as its alloying elements pass to the base.
The ability of bimetals—in particular, the coating
layers—to resist corrosion in particular media deter
APPLICATIONS mines their application. Twolayer steels with chrome,
As already noted, multilayer metals may be used for chromonickel, and chromiumnickel–molybdenum
many different purposes. coatings are most widely used in industry. Two layer
sheets with a coating of chromonickel steel are used
for the manufacture of equipment operating in most
CorrosionResistant Bimetals organic compounds and in solutions of nitrates, sul
Corrosionresistant bimetals are mainly employed fates, and chlorides, dry chlorine, sulfur dioxide,
to replace corrosionresistant steel and nonferrous nitrogen oxides, and carbon dioxide. Sheet coated
metal or to extend the working life of ferrous metals with chromiumnickel–molybdenum steel is used to
[9]. Important properties of corrosionresistant steel manufacture equipment operating in very aggressive
include the possibility of combining the corrosion media: hot solutions of sulfuric and phosphoric acid;
resistance of the coating and the strength of the base boiling solutions of acetic, oxalic, and formic acids;
within a single material. Moreover, the thermal con and sulfuricacid solutions at high temperatures. In
ductivity of corrosionresistant bimetals is 2–3 times especially aggressive media, when the corrosion resis
that of corrosionresistant steel, which is important in tance of the steel is insufficient, it is expedient to use
heatexchanger manufacture. Manufacturing experi twolayer steel with an alloy coating based on nickel,
ence shows that the use of bimetallic sheet in the man titanium, and other nonferrous metals.
ufacture of equipment does not complicates processes In the chemical industry, twolayer steel with a
such as straightening, layout, stamping, bending, and coating of 08X18H10T and 08X13 steel is used in the
rolling, although it interferes with pressure treatment manufacture of molds, vacuum equipment, condens
and welding. In pressure treatment, the difference in ers, reactors, heat exchangers, digesters, washing
physicomechanical properties, strength, plasticity, tanks, reaction columns, autoclaves, and other com
and linearexpansion coefficients of the basic and ponents. In the oil industry, twolayer steel is used in
coating materials must be taken into account. In weld the manufacture of mixers, reactors for extracting gas
oline from raw petroleum, refining reactors, heat loads and speeds. However, these materials were used
exchangers, settling tanks, pumps, rectification and in fragile cast inserts.
boiling columns, coke chambers, and other equip Extensive research on inexpensive bearing materi
ment operating in sulfurbearing oil, fuel oils, heavy als has shown that, besides good antifrictional proper
oils, mixtures of gaseous raw materials, and gaseous ties, the alloy must have sufficient structural strength.
products containing hydrogen and hydrogen sulfide. It wasn’t until World War II that aluminum alloys were
In the oil industry, 70% of the twolayer steel has a widely adopted as antifrictional coatings in the manu
coating of 08X13 steel. This steel, despite its corrosion facture of bearing inserts on the basis of steelbased
resistance in some media, is unusable as a structural bimetals. The successful bearinginsert material is a
material on account of the low impact strength and bimetal whose upper layer consists of soft antifric
brittleness of the weld seams. This bimetal is mainly tional aluminum alloy, while the lower layer is low
used to replace carbon steel, which permits the main carbon steel, providing sufficient mechanical strength.
tenance of sufficient corrosion resistance without the The antifrictional coating must run in well and
need for special linings, with decrease in system mass, must be characterized by low friction with poor lubri
and with considerable increase in working life. cation, the ability to absorb solid particles, high ther
In the paper industry, bimetals are used in the man mal conductivity, high resistance to compression and
ufacture of digesters, waste tanks, heat exchangers, creep at operating temperatures, relatively high fatigue
mixers, decker housings and baths, and tanks for vari strength, high corrosion resistance, and so on. Low
ous liquids. carbon steel provides the basis in Russian bimetals for
In ship building, corrosionresistant bimetals are bearings.
used in the manufacture of various components in dis In Russia, antifrictional bimetals with a coating of
tillation units, tanks, and housings. ASM, AO201, AO61, AMO120, and AO92 alumi
In light industry and in the food industry, corro num alloys are widely used. Besides aluminum alloys,
sionresistant bimetals may be used in dairy equip such bimetals may also employ babbitt metals, bronze,
ment, fermentation tanks, vats, production lines, dis brass, or copper.
tillation equipment, and drying drums. Antifrictional bimetals are used to manufacture
Recently, corrosionresistant bimetals have been bearing inserts in cars, trucks, tractor, and combine
used increasingly in metallic structures operating in engines. As a rule, the inserts are produced on auto
rigorous Arctic conditions. matic lines by stamping coiled bimetal strip.
Bimetals are used in electrical engineering and temperature regulators, compensators, signals, and
electronics for the production of wires and electronic safety relays. The main characteristic of thermal
components. These bimetals, with high strength and bimetals is the ability to change shape on heating
good electrical characteristics, require minimum con (thermal sensitivity). To achieve maximum flexure of
sumption of expensive conducting materials (copper, the bimetal plate, components with the maximum dif
aluminum, silver, etc.) and are light and corrosion ference in linearexpansion coefficients must be
resistant. selected. The physicomechanical properties of the
The use of bimetals for unbreakable contacts in components must ensure strong bonding of the layers
electric circuits is very promising. Such contacts over the whole contact surface and permit subsequent
account for most of the power losses in conducting technological operations such as stamping, cutting,
systems. In electrical engineering, contact bimetals and bending. In addition, in the course of operation,
with local coatings consisting of silver and silver alloys the thermal bimetal must not acquire residual defor
and of copper, nickel, cadmium and other metals with mation and must not change its thermal activity or
added silver are used to meet the requirements regard electrical resistance. At present, thermal bimetals are
ing electrical resistance and scorch resistance. produced in the form of strip with a layerthickness
Threelayer strip (thickness 0.3–0.5 mm) consist ratio close to 1 : 1. The layer with the higher linear
ing of nickel + steel + nickel or copper + steel + nickel expansion coefficient is said to be active; the other
is used for battery casings and is characterized by high layer is said to be passive.
strength and convenience, good shape retention in We may divide thermal bimetals into five categories
cyclic loading, and high electrical conduction, espe in terms of their physicomechanical properties: those
cially at elevated temperatures. with high, aboveaverage, average, belowaverage, and
In electronics, multilayer metal strip combines low properties. They must have stable physicome
high strength and electrical conduction, low thermal chanical properties. Therefore, the chemical compo
expansion, technological convenience, and high cor sition of the two components is strictly regulated.
rosion resistance. Thus, for the manufacture of anodes The sensitivity of thermal bimetals is directly pro
in electrovacuum instruments, thermal measuring portional to the difference in linearexpansion coeffi
instruments, screens, and other components, we use cients of the active and passive layers. Invar alloys are
two,three, four, and fivelayer strip such as Fe + Al, chosen for the passive layer, and Mn, Ni, Cr, or Cu
Al + Fe + Al, Al + Fe + Ni, Cu + Ni, Fe + Ni, Cu + Fe, alloys for the active layer. In some cases, the compo
Ni + Cu + Ni, Ti + Fe + Al, Al + Fe + Cu + Ni, Al + nents of the bimetal must be nonmagnetic, so as to rule
Fe + Cu + Fe + Al, etc. out reaction of the thermal bimetal to the electromag
netic fields induced in the course of operation. For this
Bimetals for Deep Extrusion purpose, nonmagnetic bimetals with active and pas
sive layers consisting of BrB2 beryllium bronze have
Bimetals for deep extrusion combine high strength, been developed.
adequate plasticity, thermal conductivity, and good
corrosion resistance. In particular, bimetals consisting
of steel and copper alloys or of steel and nickel yield CONCLUSIONS
components with the required properties and perfor
mance. These bimetals perform well in stamping, The high performance of bimetals has stimulated
bending, welding, and heat treatment and hence are their production and use in various branches of indus
widely used in machine parts and system components. try. Despite the drop in output of bimetals in the past
The base in such bimetals provides the required tensile decade, their production and consumption seem to be
plasticity, strength, and impact resistance. The coating rebounding at present. As shown by experience in
ensures high corrosion resistance and sufficient plas Russia and around the globe, bimetals offer the pros
ticity in stamping. In addition, the coating serves a pect for improving the performance of traditional
lubricant function in stamping. Low carbon 11кп, products.
18кп, 11ЮA, and 18ЮA steel is recommended as the
base in bimetals for deep extrusion. The coating most REFERENCES
often consists of copper, singlephase brass, or nickel.
For deep extrusion, it is customary to use threelayer 1. Kobelev, A.G., Lysak, V.I., Chernyshev, V.N., et al.,
strip manufactured by cold surfacing, such as brass + Proizvodstvo metallicheskikh sloistykh kompozitsionnykh
steel + brass, tombac alloy + steel + tombac alloy, or materialov (Production of Laminar Metallic Composites),
nickel + steel + nickel. Moscow: Intermet Engineering, 2002.
2. Braunshtein, R.A., Production of TwoLayer Sheet Steel,
Chern. Metall.: Byull. NTI, 1958, no. 7, pp. 25–27.
Thermal Bimetals
3. Bykov, A.A., Chernyshev, O.G., Fedorov, V.N., et al.,
Thermal bimetals are used in the manufacture of Production of WearResistant Bimetals for Agriculture
sensitive elements for thermal instruments, automatic by Casting, Stal’, 1984, no. 8, pp. 41–43.
4. Manokhin, A.I., Doroshev, Yu.F., Rovenskaya, T.V., 8. Medovar, B.I., Medovar, L.B., Chernets, A.V., et al.,
et al., Production of Bimetal Blanks by Continuous Electroslag Surfacing by Liquid Metal: A New Method
Casting, Stal’, 1978, no. 12, pp. 1087–1088. of Producing HighQuality Composite Roller Blanks,
Trudy tret’ego kongressa prokatchikov (Proceedings of
5. Bykov, A.A., Doroshev, Yu.F., Bulat, S.I., and Third Congress of Rolling Specialists), Moscow:
Solov’ev, V.S., Continuous Casting of TwoLayer and OAO Chermetinformatsiya, 2000, pp. 369–372.
Multilayer Blanks: Review Information, Chern. Metall.,
Ser. Staleplavil. Proizv. (Inst. Chermetinform.), 1981, 9. Konnov, Yu.P., Kissel’man, M.A., Konnova, I.Yu.,
issue 3. et al., Electroslag Surfacing with a Vertical Blank to
Produce CorrosionResistant Bimetals, Stal’, 1993,
6. Meandrov, L.V., Dvukhsloinye korrozionnostoikie stali no. 5, pp. 26–30.
(TwoLayer CorrosionResistant Steel), Moscow: 10. Konon, Yu.A., Pervukhin, L.B., and Chudnovskii, A.D.,
Metallurgiya, 1970. Svarka vzryvom (Explosive Welding), Moscow: Mashi
7. Paton, B.E., Sterenbogen, Yu.A., Mosendz, N.A., nostroenie, 1987.
et al., New Production Process for Bimetals with a 11. Kobelev, A.G., Potapov, I.N., and Kuznetsov, E.V.,
CorrosionResistant Coating, Stal’, 1983, no. 7, Tekhnologiya sloistykh metallov (Technology of Lami
pp. 16–17. nar Metals), Moscow: Metallurgiya, 1981.