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0% found this document useful (0 votes)
58 views7 pagesSample Paper 2
Uploaded by
Jayshree SinghCopyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
ime allowed: 3 hours Maximum marks: 70
General Instructions: Same as CBSE Sample Question Paper-2023 (Solved),
SECTION-A
‘he following questions are multiple-choice questions with one correct answer. Each question carries
mark. There is no internal choice in this section.
L
Lower molecular mass of alcohols are:
(a) miscible in limited amount of water.
(b) miscible in excess of water.
() miscible in water in all proportions,
(@ immiscible in water.
Major product obtained on reaction of 3-Phenyl propene with HBr in presence of organic
peroxide will be
(a) 3-Phenyl-1-bromopropane (6) 1-Phenyl-3-bromopropane
(c) 1-Phenyl-2-bromopropane (d) 3-Phenyl-2-bromopropane
Transition elements show magnetic moment due to spin and orbital motion of electrons.
Which of the following metallic ions have almost same spin only magnetic moment?
@ Co* (i) Cr*
(ii) Mn* (i) Cr*
(@) (and (ii) (©) (i and (iii)
(© @and (iv) (@) (iii) and (iv)
In the reaction, A —— B, the rate of reaction increases two times on increasing the
concentration of A four times, the order of reaction is
(2 (b) 0
o> @3
Which of the following relationship is correct for A,, and A;, for strong electrolytes?
(b) Am = An x VE
@ Ay =A’ + AVE
(d) Ay = Ay AYE
(c) An = N°, Gl
* Identity the order of reaction, if k = 3 x 10's
(b) Pseudo first order
(d) Third order
(@) First order
(9) Second order 2
10.
il.
12,
13,
‘The most reactive amine towards dilute hydrochloric acid fs
HC.
® | WyCONH
NH,
HC
© ye ON—CHs @ O
The formula of the coordination compound Tetranmmineaquachloridocobat ayy ey
(a) CH;—NH,
; =
@ [Co(NH,),(H,O)CIICI, (© ICo(NH,),(H,0)CIIC1,
(©) [Co(NH;),(H,0)CHCh, (@) [Co(NH;),(H,0)CIICI
Reaction of phenol with CCI, and NaOH followed by hydrolysis is likely to give
ou al
Cl O-H
(a) wo
Ha
0
°
OH
CHO | oon
o & o&
Benzylamine may be alkylated as shown in the following equation:
CHgCH,NH, + R-X > C,H,CH,NHR
‘Which of the following alkylhalides is best suited for this reaction through Sy1 mechanism?
(a) CH,Br (0) CoHsBr
(0) CgHsCH,Br @ GH,Br
A carbonyl compound react with HCN to form a cyanohydrin which on hydrolysis forms
racemic mixture of a-hydroxy acids. The carbonyl compound is
(a) acetone © diethyl ketone
(©) acetaldehyde (@) formaldehyde 4
in a reaction, 2A —> Products, the concentration of A decreases from 0.5 mot L'®
04 mol Lin 10 minutes. The rate during this interval will be
reece ee
in @) 0.105 mol L*! min .
cemimber Of ons produced per formuta unit in an aqueous solution of [Colen)IC®
(c) 6 oe
@2 nich of the following compounds is most ,
sa, Which ol ° ost reactive towards nucleophiie addition reactions?
(@ CH;—C—H (b) CH, — d —CH,
9
9
Il
o C—H (@) (©)-¢—cn,
in these questions (Q. No. 15 t0 18), two statements are given - one labelled as Assertion (A) and the
“ther labelled Reason (R). Select the most appropriate answer from the options given below:
(a) Both Aand R are true and R is the correct explanation of A.
(6) Both A and R are true but R is not the correct explanation of A.
(¢) Ais true but R is false.
(@) Ais false but R is true.
15. Assertion (A) : Treatment of anisole with HI at 373 K gives phenol and methyl iodide.
Reason (R)_: Due to resonance O—C,H, bond is stronger than O—CH, bond.
16. Assertion (A): D (+)-Glucose is dextrorotatory in nature.
Reason (R) = ‘D’ represents its dextrorotatory nature.
17. Assertion (A) + In transition elements ns orbital is filled up first and (n ~ 1)d afterwards,
during ionization ns electrons are lost prior to (n-1)d electrons.
Reason (R) : The effective nuclear charge felt by (m— 1)d electrons is higher as comn~
to that by ns electrons.
18, Assertion (A) : Acylation of amines gives a monosubstituted product »* “
amines gives polysubstituted product.
Reason (R) : Acyl group sterically hinders the approach groups.
SECTION-B
This section contains 7 questions with internal choice in two questions. The following questions are
very short answer type and carry 2 marks each.
19. ‘The rate constant for a first order reaction is 60 s~'. How much time will it take to reduce the initial
: 1 Ppa
concentration of the reactant to 7 > th of its initial value?
10
20. Differentiate between globular and fibrous proteins.
oR
(a) Name the linkage that hold together the amino acid molecules in a protei
(©) Name the unit formed by attachment of nucleoside to phosphoric acid
moiety.
21, What will be the product formed when chlorobenzene reacts with magnesium in presence of dry
in.
at 5! position of sugar
ther? Give equation also. OR
a seart it aan towards the Sy! reaction.
ee a «optically active but I-bromobutane is optically inactive,
b) 2-bromobutane
2, ta Predict the geometry of [N(CN
(b) Caleutate the spin only magnetic m
23, Define molar conductivity. _
24, Write the two conditions for collisions to bs
ve bi
IN) 2
joment of [Cu(NH;)4}* ion.
1¢ effective collisions.
25, Write the major products) n the followings
©
(a) CH,—CH=CH—CH,—CN hn oe
C10,
(0) CH,—CH,—OH
SECTION-C
This section contains 5 questions with internal choice in two questions. The following questions are
short answer type and carry 3 marks each.
26. Convert any three of the following:
(@) Phenol to o-hydroxybenzaldehyde. (b) Methanal to ethanol.
(). Phenol to phenyl ethanoate. (@) Propene Propan-2-ol
(©) Methyl magnesium bromide 2-Methylpropan-2-ol
27. (a) Write the hybridisation type and structure of the complex [Cr(NH),Cl.]*.
(®) Calculate the spin only magnetic moment of [CoF,]*- ion.
28, When 19.5 g of F—CH,—COOH (Molar mass = 78 g mol) is dissolved in 500 g of wate, the
depression in freezing point is observed to be 1°C. Calculate the degree of dissociation of
F—CH,—COOH.
(Given: K; for water = 1.86 K kg mol]
29. (a) Give a chemical tes to distinguish between N-methylethanamine and N,N-dimethyl ethanamine.
(b) Write the reaction for catalytic fi it
lytic reduction of nitroben, action of product
fae zene followed by reaction of pt
(©) Out of butan-I-ol and butan-
amine, which will be more soluble in water and why?
30. Give reasons:
‘i .
4) Alkyl halides, though polar, are immiscible with water?
(6) Syl reactions a i
e accompanied by racemisation in optically active alkyl halides. Why?
oe OR
©) Give teasons forthe following:
(0 Ethyl iodide undergoes §,
2 react
(i) CX pond agian a te han ethyl bromide
lobenzene is smaller than CX bond length in CHs—%: reatment of alkyl chloride with aqueous KOH leads to the formation of alcohol but in the
f alcoholic KOH, alkene is the major product.
SECTION-D
sng questions are case-based questions. Each question has an internal choice and carries
iy each. Read the passage carefully and answer the questions that follow.
‘The t
presence ©
When solution does not ‘obey Raoult’s law over entire range of concentration, then itis called non-
+ eal solution. The vapour pressure of such solution is either higher or lower than that predicted
ipaoul’s WI ts higher, the solution exhibits positive deviation andi tis lower i exhibits
negative deviation from Raoult’s law. The cause of these deviations lie in the nature of interactions
at the molecular level. In case of positive deviation from Raoult’s law, A-B interactions are
weaker than those between AA or B—B, ice.
, the intermolecular attractive forces between the
Totue-solvent molecules are weaker than those between the solute-solute and solvent-solvent
molecules. ‘This means that in such solutions, the molecules of A(or B) will find it easier to escape
than in pure state. This will increase the vapour pressure resulting in positive deviation. In case of
negative deviations from Raoult’s law, the intermolecular atractive forces between A—AandB—B
sre weaker than those between A-B and leads to decrease in vapour pressure resulting in negative
deviations.
‘Answer the following questions:
(a) Suggest the type of interaction present in NaCIO3 and water.
(b) Which type of deviation will be shown by the solution, if Yap
