UNIVERSITY "POLITEHNICA" BUCHAREST
DEPARTMENT OF PHYSICS
Laboratory experiments
BN 119
THERMOCOUPLE
(SEEBECK EFFECT)
2020
Scopes
1/ To calibrate a thermocouple such that to be able to measure temperatures.
2/ To find the Seebeck coefficient.
Phenomenon
Thermo-electric effect, or Seebeck effect: it
consists in the apparition of an electric voltage
across a material subjected to a temperature
gradient, i.e. a temperature difference.
The circuit configured as shown in figure. The
materials (metals, alloys or semiconductors) are
acting as generators helping each other. They are
converting directly heat in electric energy.
Each voltage depends on the temperature
gradient T1T2 and on the material constant
that can be either positive or negative:
UA=A(T1T2)
UB=B(T2T1) (h axis reversed)
Therefore
U=UA+UB or U=A(T1T2) + B(T2T1) or U=(AB) (T1T2),
or, finally
U=AB (T1T2), (1)
where AB=AB is the Seebeck coefficient that depends on both materials. If U=0 at
T2=273.15K=0C then the device indicates the temperature in degrees Celsius:
U=AB . (2)
Experimental setup
There are two thermocouples, one already
calibrated and graded in Celsius degrees, the
other must be calibrated.
Both of them are functioning between in the
same environments.
Data
Calibrate U=0 at T1=T2=273.15K (0C).
(C) U (mV), heating U (mV), cooling
30 1.4 1.5
40 1.8 2.0
50 2.3 2.5
60 2.9 3.0
70 3.4 3.5
80 3.8 4.0
90 4.4 4.5
100 5.1 5.0
110 5.4 5.5
120 5.9 6.0
130 6.6 6.5
140 6.9 7.0
150 7.4 7.5
160 7.8 8.0
170 8.3 8.5
180 8.9 9.0
190 9.6 9.6
200 10.1 10.0
210 10.4 10.4
220 10.9 11.0
230 11.5 11.6
240 11.9 12.1
250 12.4 12.5
260 12.9 12.9
270 13.4 13.6
280 13.9 14.0
290 14.5 14.4
300 14.9 14.9
Data processing
1/ Represent the graphs of the heating and cooling processes U() on millimeter paper (or Excel) in
the same coordinates and draw the straight lines that approximate at best each dot set (one for
heating and one for cooling).
2/ For each approximating line calculate the slope by choosing two distinct points M(M,UM),
U M −U N
N(N,UN); the slope is m= ❑ −❑ .
M N
3/ Compute the coefficients Seebeck according to Eq.(2) separately at heating and cooling
respectively. Are they the same?
Question
Explain why the effect is used only for measuring devices, and not to obtain electric energy for
commercial purposes.
Further study
https://sciencing.com/calibrate-thermocouple-2659.html