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Hess's Law Calculations Worksheet

The document contains 5 chemistry problems involving calculating enthalpy changes (ΔH) from standard enthalpy of formation values. The problems involve using Hess's law to determine the ΔH for different chemical reactions. Standard enthalpy of formation values are provided for reference reactions used in the calculations.

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Drech Lanado
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816 views2 pages

Hess's Law Calculations Worksheet

The document contains 5 chemistry problems involving calculating enthalpy changes (ΔH) from standard enthalpy of formation values. The problems involve using Hess's law to determine the ΔH for different chemical reactions. Standard enthalpy of formation values are provided for reference reactions used in the calculations.

Uploaded by

Drech Lanado
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Hess's Law Worksheet NAME:__________________________PER:___

1. Calculate H for the reaction: C2H4 (g) + H2 (g) → C2H6 (g) from the following Data.
C2H4 (g) + 3 O2 (g) --> 2 CO2 (g) + 2 H2O (l) H = -1411. kJ

C2H6 (g) + 3½ O2 (g) --> 2 CO2 (g) + 3 H2O (l) H = -1560. kJ

H2 (g) + ½ O2 (g) --> H2O (l) H = -285.8 kJ

2. Calculate H for the reaction 4 NH3 (g) + 5 O2 (g) → 4 NO (g) + 6 H2O (g) from the
following Data.

N2 (g) + O2 (g) --> 2 NO (g) H = -180.5


kJ
N2 (g) + 3 H2 (g) --> 2 NH3 (g) H = -91.8 kJ

2 H2 (g) + O2 (g) --> 2 H2O (g) H = -483.6


kJ

3. Find H° for the reaction 2H2 (g) + 2C (s) + O2(g) → C2H5OH (l), using the following
thermochemical data:

C2H5OH (l) + 2 O2 (g) --> 2 CO2 (g) + 2 H2O (l) H = -875. kJ

C (s) + O2 (g) --> CO2 (g) H = -394.51 kJ

H2 (g) + ½ O2 (g) --> H2O (l) H = -285.8 kJ

4. Calculate H for the reaction CH4 (g) + NH3 (g) → HCN (g) + 3 H2 (g) given:
N2 (g) + 3 H2 (g) --> 2 NH3 (g) H = -91.8 kJ

C (s) + 2 H2 (g) --> CH4 (g) H = -74.9 kJ

H2 (g) + 2 C (s) + N2 (g) --> 2 HCN (g) H = +270.3 kJ

5. Calculate H for the reaction 2 Al (s) + 3 Cl2 (g) → 2 AlCl3 (s) from the data:
2 Al (s) + 6 HCl (aq) --> 2 AlCl3 (aq) + 3 H2 (g) H = -1049. kJ

HCl (g) --> HCl (aq) H = -74.8 kJ

H2 (g) + Cl2 (g) --> 2 HCl (g) H = -1845. kJ

AlCl3 (s) --> AlCl3 (aq) H = -323. kJ


Solutions

1. 

C2H4 (g) + 3 O2 (g) --> 2 CO2 (g) + 2 H2O (l) H = -1411. kJ

flip 2 CO2 (g) + 3 H2O (l) --> C2H6 (g) + 3½ O2 (g) H = +1560. kJ

H2 (g) + ½O2 (g) --> H2O (l) H = -285.8 kJ

C2H4 (g) + H2 (g) --> C2H6 (g) H = -137. kJ

2.

x2 2 N2 (g) + 2 O2 (g) --> 4 NO (g) H = 2 (-180.5 kJ)

flip x2 4 NH3 (g) --> 2 N2 (g) + 6 H2 (g) H = -2 (-91.8 kJ)

x3 6 H2 (g) + 3 O2 (g) --> 6 H2O (g) H = 3 (-483.6 kJ)

4 NH3 (g) + 5 O2 (g) --> 4 NO (g) + 6 H2O (g) H = -1628. kJ

3.

flip 2 CO2 (g) + 2 H2O (l) --> C2H5OH (l) + 2 O2 (g) H = -1(-875. kJ)

x2 2 C (s) + 2 O2 (g) --> 2 CO2 (g) H = 2 (-394.51 kJ)

x2 2 H2 (g) + O2 (g) --> 2 H2O (l) H = 2 (-285.8 kJ)

2H2(g) + 2C(s) + O2(g) --> C2H5OH(l) H° = -486. kJ

4.

flip x½ NH3 (g) --> 1/2 N2 (g) + 3/2 1H2 (g) H = -½(-91.8 kJ)

flip CH4 (g) --> C (s) + 2 H2 (g) H = -1(-74.9 kJ)

x½ 1/2 H2 (g) + C (s) + 1/2 N2 (g) --> HCN (g) H = ½(270.3 kJ)

CH4 (g) + NH3 (g) --> HCN (g) + 3 H2 (g) H = +256.0 kJ

5. 

2 Al (s) + 6 HCl (aq) --> 2 AlCl3 (aq) + 3 H2 (g) H = -1049. kJ

x6 6 HCl (g) --> 6 HCl (aq) H = 6 (-74.8 kJ)

x3 3 H2 (g) + 3 Cl2 (g) --> 6 HCl (g) H = 3 (-1845. kJ)

flip x2 2 AlCl3 (aq) --> 2 AlCl3 (s) H = -2 (-323. kJ)

2 Al (s) + 3 Cl2 (g) --> 2 AlCl3 (s) H = -6387. kJ

Hess's Law Worksheet NAME:__________________________PER:___ 1. Calculate H for the reaction: C2H4 (g) + H2 (g) → C2H6
Solutions 1. C2H4 (g) + 3 O2 (g) --> 2 CO2 (g) + 2 H2O (l)  H = -1411. kJ flip 2 CO2 (g) + 3 H2O (l) --> C2H6 (g) +

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