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Langmuir isotherm models typically apply to the adsorption of a single molecule layer on completely
homogeneous surfaces, with negligible interaction between adsorbed molecules.
‘There are three standard sub-options for the pure component Langmuir isotherms supported in Aspen
Adsorption:
Langmuir 1. The isotherm is a function of a partial pressure or concentration:
RR
14JPE (partial pressure)
or
Ie,
y=
1+JF; (concentration)
Langmuir 2. The isotherm is a function of temperature, and one of partial pressure or concentration:
__ mein
TBAT B
? (partial pressure)
or
_ eM,
Te Tg
? (concentration)
Langmuir 3. The isotherm is a function of temperature, and one of partial pressure or concentration.
Unlike Langmuir2, the maximum loading, expressed by (Auer) is a function of temperature, so
reflects more accurately the physical reality of numerous adsorption processes:
URIBE) Re B
TA
14 Te 8 (partial pressure)
or
(A A IBT,) Ie Me,
TAT,
bedie 4 (concentration)
