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Thermodynamic Process

Thermodynamics processes can be isometric, isobaric, isothermal, isentropic, or polytropic. For each process, the summary provides the key relationships between pressure (P), volume (V), and temperature (T) as well as expressions for work (W), heat (Q), internal energy (U), enthalpy (H), and entropy (S).

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Satoru Fujinuma
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420 views12 pages

Thermodynamic Process

Thermodynamics processes can be isometric, isobaric, isothermal, isentropic, or polytropic. For each process, the summary provides the key relationships between pressure (P), volume (V), and temperature (T) as well as expressions for work (W), heat (Q), internal energy (U), enthalpy (H), and entropy (S).

Uploaded by

Satoru Fujinuma
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Thermodynamics

ENGR. CHRISTIAN BLAS


ISOMETRIC PROCESS
A. P,V AND T (V=C)

P1 P2
=
T1 T2

B. NON FLOW WORK

Wn = PdV ; where: dV=0 @ V=C

Wn = 0
ISOMETRIC PROCESS
D. STEADY FLOW WORK G. HEAT TRANSFERRED
2 Q = U + Wn
Ws = - VdP = V (P1-P2) Wn = 0 V =C
1
Q = U
E. CHANGE IN INTERNAL ENERGY
U = m Cv T H. CHANGE IN ENTROPY

F. CHANGE IN ENTHALPY from : dS = dQ


T
H = m Cp T
S = m Cv ln T2
T1
ISOBARIC PROCESS
A. P,V AND T (P=C)

V1 V2
=
T1 T2

B. NON FLOW WORK


2
Wn = PdV
1
Wn = P(V2-V1)
ISOBARIC PROCESS
D. STEADY FLOW WORK
G. HEAT TRANSFERRED
2 Q = U + Wn
Ws = - VdP ; where: dP=0 @P=C Q = U + H
1
Ws=0 Q = H

H. CHANGE IN ENTROPY
E. CHANGE IN INTERNAL ENERGY
U = m Cv T from : dS = dQ
T
F. CHANGE IN ENTHALPY
S = m Cp ln T2
H = m Cp T T1
ISOTHERMAL PROCESS
A. P,V AND T (T=C)
D. STEADY FLOW WORK
P1 V1 = P2 V2
2
Ws = - VdP ; where: V= C/P
B. NON FLOW WORK 1
2
Ws = -P1 V1 ln (V2/V1)
Wn = PdV ; where P =c/v Ws = -mRT1 ln (V2/V1)
1
Wn = P1 V1 ln (V2/V1)
Wn = mRT ln (V2/V1) Ws = Wn
ISOTHERMAL PROCESS
G. HEAT TRANSFERRED
E. CHANGE IN INTERNAL ENERGY Q = U + Wn
U = 0 Q = Wn (for U=0)
F. CHANGE IN ENTHALPY
H = 0
H. CHANGE IN ENTROPY

from : dS = dQ
T

S = m Cp ln V2
V1
ISENTROPIC PROCESS k
A. P,V AND T (S=C OR PV = C )
k k
P1 V1 = P2 V2 PRESSURE-VOLUME
D. STEADY FLOW WORK
T1 k-1
= V2 2
TEMPERATURE-VOLUME C
T2 V1 Ws = - VdP ; where: V= P k
k-1
T1 P1 k
1
= TEMPERATURE-PRESSURE
T2 P2
Ws = k(P2V2-P1V1)
B. NON FLOW WORK 1-k
2 = kmR(T2-T1)
C
Wn = PdV; where P = V k 1-k
1
Wn = P2V2-P1V1 = mR(T2-T1) Ws=kWn
1-k 1-k
ISENTROPIC PROCESS
G. HEAT TRANSFERRED
E. CHANGE IN INTERNAL ENERGY
Q = 0
U = m Cv T =-Wn Q = U + Wn
F. CHANGE IN ENTHALPY U = - Wn

H = m Cp T H. CHANGE IN ENTROPY

S = 0
POLYTROPIC PROCESS
n
A. P,V AND T (PV = C )
n n
P1 V1 = P2 V2 PRESSURE-VOLUME
D. STEADY FLOW WORK
T1 n-1
= V2 2
TEMPERATURE-VOLUME C
T2 V1 Ws = - VdP ; where: V= P n
n-1
T1 P1 n
1
= TEMPERATURE-PRESSURE
T2 P2
Ws = n(P2V2-P1V1)
B. NON FLOW WORK 1-n
2 = nmR(T2-T1)
C
Wn = PdV; where P = V n 1-
1
Wn = P2V2-P1V1 = mR(T2-T1) Ws=nWn
1-n 1-n
POLYTROPIC PROCESS
G. HEAT TRANSFERRED
E. CHANGE IN INTERNAL ENERGY Q = m Cn T
U = m Cv T k-n
where; Cn = Cv
F. CHANGE IN ENTHALPY 1-n

H = m Cp T H. CHANGE IN ENTROPY

from : dS = dQ
T

S = m Cn ln T2
T1

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