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TARGET : PRE-MEDICAL 2024 PHYSICAL CHEMISTRY
SOLID STATE
1. fyfFk;e lajpuk esa fØLVfyr gksrk gSA ;fn
BCC 8. 916°C ls Åij xeZ djus ij yksgk fcuk ijek.kq
bZdkbZ lsy dh Hkqtk dh yEckbZ 350 pm gks rks dh f=kT;k esa ifjorZu ds bcc lajpuk ls fcc esa
fyfFk;e dh ijekf.od f=kT;k gksxh :- ifjofrZr gks tkrk gSA rks fØLVy ds fy, xeZ
(1) 303.1 pm (2) 606.2 pm djus ls igys rFkk ckn esa ?kuRo dk vuqikr gksxk
(3) 151.5 pm (4) 123.7 pm (1) 1.069 (2) 0.918 (3) 0.725 (4) 1.231
2. ?kuh; bZdkbZ lsy dh izR;sd Hkqtk dh yEckbZ 400 9. Qsjl vkWDlkbM ?kuh; lajpuk j[krk gS rFkk Hkqtk
pm gSA rRo dk ijek.kq Hkkj 120 rFkk bldk dh yEckbZ 5.0 Å gSA ;fn Qsjl vkWDlkbM dk
?kuRo 6.25 g/cm gks rks fØLVy tkyd gksxk :
3 ?kuRo 3.84 g/cm ekuk tk;s rks izR;sd lsy esa
3

(N A = 6 × 10 )
23 mifLFkr Fe rFkk O vk;uks dh la[;k gksxh
2+ 2–

23
(N A = 6 × 10 )
(1) ljy ?kuh; (2) dk; dsfUæ;
(1) 4 Fe rFkk 4 O
2+
(2) 2 Fe rFkk 2 O
2– 2+ 2–

®
(3) Qyd dsfUæ; (4) vUr dsfUæ;
(3) 1 Fe rFkk 1 O (4) 3 Fe rFkk 4 O
2+ 2– 2+ 2–

3. ,d rRo Qyd dsfUær ?kuh; lajpuk esa 10. ,d fcc tkyd esa, A, B, C rFkk D ijek.kq Øe'k%
fØLVyhd‘r gksrk gS rFkk Hkqtk dh yEckbZ 0.5 nm fdukjs ij] Qyd dsUæ ij] v"BQydh; vUrjky
gSA ;fn fØLVy dk ?kuRo 3.2 g/cm gks rks 3
rFkk prq"Qydh; vUrjky ij mifLFkr gS rks ?ku
ijek.kq Hkkj gksxk ? fod.kZ ij gksaxs :-
(1) 100 (2) 80 (3) 40 (4) 60 (1) 2A, C, 2D (2) 2A, 2B, 2C
4. ,d rRo X (ijek.kq æO;eku = 80 g/mol) FCC (3) 2A, 2B, 2D (4) 2A, 2D
11. ,d fØLVy X, Y rFkk Z d.kks ls cuk gSA X, fcc
lajpuk j[krk gS rks blds 8 g esa mifLFkr bZdkbZ
ladqy esa Y lHkh v"BQydh; vUrjky esa rFkk Z
lsy gksxh
lHkh prq"Qydh; vUrjky esa mifLFkr gSA ;fn
(1) 0.4 × N A (2) 0.1 × N A
(3) 4 × N A (4) 0.025 × N A lHkh d.k] ,d ?ku fod.kZ ds lkis{k gVk fy;s x;s
5. ,d Bksl ;kSfxd esa vkWDlkbM vk;u ?kuh; fufcM+ rks fØLVy dk laHkkfor lw=k gksxk :-
(1) XYZ (2) X 2 YZ 2
ladqyu esa tcfd A vk;u 1/8 prq"Qydh; 2+

(3) X 8 Y 4 Z 5 (4) X 5 Y 4 Z 8
vUrjky esa rFkk B vk;u 1/2 v"BQydh; +3
12. KCl fØLVy esa CdCl dh v'kqf) feykus ij
2

vUrjky esa mifLFkr gks rks ;kSfxd dk ljyre mRiUu gksaxs

lw=k Kkr dhft, : (1) 'kkWVdh nks"k
(1) A 2 B 2 O 4 (2) AB 2 O 4 (2) Ýsady nks"k
(3) A 2 B 4 O 2 (4) A 4 B 2 O 2 (3) foLFkkfir /kuk;u fjfDr
6. lksfM;e DyksjkbM ds fØLVy esa] izR;sd Na vk;u +
(4) F-dsUæ dk fuekZ.k
ds f}rh; fudVLFk vk;uksa dh la[;k gksxh 13. ,d vk;fud ;kSfxd AB ¶yksjkbV izdkj dh
(1) 8 Cl vk;u (2) 12 Na vk;u
– +
lajpuk j[krk gSA ;fn B dh f=kT;k 200 pm gks
–

(3) 12 Cl vk;u
–
(4) 24 Cl vk;u
–
rks A dh f=kT;k gksxh
+

7. Cu vk;uksa dh mifLFkfr ds dkj.k D;wizl

2+ (1) 82.8 pm (2) 146.4 pm
(3) 40 pm (4) 45 pm
lYQkbM ds izfrn'kZ dk la?kVu Cu S gS] tkyd 1.8
14. ;fn ,d ijek.kq izR;sd dksus ij rFkk nks ijek.kq
esa Cu dk eksy izfr'kr gksxk\
2+
izR;sd dk; fod.kZ ij mifLFkr gks rks ?kuh;
(1) 99.8% (2) 11.11% ,dkdh dksf"Bdk ds dqy ijek.kqvksa dh x.kuk djsa
(3) 88.88% (4) buesa ls dksbZ ugha (1) 8 (2) 9 (3) 6 (4) 3

H Your Target is to secure Good Rank in Pre-Medical 2024 [ 19 ]



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PHYSICAL CHEMISTRY TARGET : PRE-MEDICAL 2024
15. ;fn A CCP vo;o ds :i esa] B 50% 20. fdlh Bksl esa vkWDlkbM vk;u ccp esa O;ofLFkr
v"VQydh; fjfDr;ksa ij rFkk C, 50% 1
gSA vk;u A prq"Qydh; fjfDr;ksa dk rFkk
prq"Qydh; fjfDr;ksa ij gks rks A, B rFkk C ls 6

cusa ;kSfxd dk lw=k gksxk vk;u B v"VQydh; fjfDr;ksa dk 1/3 LFkku

(1) AB 3 C (2) A 2 BC 4 ?ksjrk gks rks ;kSfxd dk lEHkkfor lw=k crk,s :-
(3) AB 4 C (4) A 2 BC 2 (1) ABO 3 (2) AB 2 O 3 (3) A 2 BO 3 (4) A 2 B 2 O 3
16. dksjUMe esa] O "kV~Qydh; rFkk Al vk;u
2– 3+
21. ,d yo.k ftldk lw=k AB gS] ?kuh; fufcM 2

v"VQydh; fjfDr;ksa dk 2/3 Hkkx ?ksjrk gS rks ladqyu dk tkyd cukrk gS ftlesa A ijek.kq
dksjUMe dk lw=k D;k gksxk ?kuh; fufcM+ ladqyu ds tkyd fcUnqvksa ij gSA
(1) Al 6 O 4 (2) Al 2 O 3 (3) AlO 2 (4) Al 2 O vr% A rFkk B dh leUo; la[;k gS :-
17. ,d Bksl ABC esa A, B rFkk C dh O;oLFkk fuEuor (1) 4, 8 (2) 4, 4 (3) 8, 8 (4) 8, 4
gS rks Bksl dk lw=k gS :- 22. MgO (jkWd lkYV izdkj) rFkk ZnS (ftad CysUM) ds
C ,dkdh dksf"Bdk esa mifLFkr lw=k bdkbZ;ksa dh

®
⊕ la[;k Øe'k% gS :-
B (1) 4, 3 (2) 1, 3 (3) 4, 4 (4) 4, 2
23. 10 g NaCl esa mifLFkr ,dkdh dksf"Bdkvksa dh
A
la[;k gS
10 N A 2.5
⊕ (1) (2) × NA
58.5 58.5
5.6 5.6
(3) × NA (4) × NA × 2
(1) ABC (2) AB 2 C 2 (3) A 2 BC (4) AB 8 C 2 58.5 58.5
18. Qyd dsfUnzr ?kuh; O;oLFkk esa A rFkk B ijek.kqvksa 24. AB Bksl NaCl lajpuk esa fØLVyhd‘r gksrk gSA
esa A ijek.kq ,dkdh dksf"Bdk ds dksuksa ij rFkk _.kk;u B fcc tkyd dk fuekZ.k djrk gS rFkk
–

ijek.kq B Qyd dsUnz ij gSA A ijek.kqvksa esa ls /kuk;u A lHkh v"VQydh; fjfDr ij mifLFkr
+

,d ijek.kq dksus ls vuqifLFkr gS rks ;kSfxd dk gSA ;fn fp=k esa iznf'kZr lHkh d.kksa dks gVk fn;k
lk/kkj.k lw=k gksxk tk,s rks Bksl dk lw=k gksxk :-
(1) A 7 B 3 (2) AB 3 (3) A 7 B 24 (4) A 7/8 B 3
19. fdlh vk;fud fØLVy esa A ?kuh; fufcM ladqyu
esa rFkk B izR;sd prq"Qydh; fjfDr;ksa esa mifLFkr
gSA ;fn fdlh fØLVy esa B ds 'N' ijek.kq gS rks
mlesa A ds ijek.kqvksa dh la[;k gksxh :-
(1) AB (2) A 5 B 7 (3) A 7 B 5 (4) AB 2
N
(1) N (2) (3) 2 N (4) 2N
2

ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. 3 2 4 4 2 2 2 2 1 1 4 3 4 2 4
Que. 16 17 18 19 20 21 22 23 24
Ans. 2 1 3 2 1 4 3 2 1

[ 20 ] Your Target is to secure Good Rank in Pre-Medical 2024 H