SAFETY DATA SHEET

1. Identification
Product identifier V1R10Series
Other means of identification
Synonyms HP 3D HR PA12 Powder
Recommended use Materials to be processed in HP 3D MJF equipment only.
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
HP Inc.
1501 Page Mill Road
Palo Alto, CA 94304-1112
United States
Telephone 650-857-5020

HP Inc. health effects line

(Toll-free within the US) 1-800-457-4209
(Direct) 1-760-710-0048
HP Inc. Customer Care
Line
(Toll-free within the US) 1-800-474-6836
(Direct) 1-208-323-2551
Email: hpcustomer.inquiries@hp.com

2. Hazard(s) identification
Physical hazards Not classified.
Health hazards Not classified.
Environmental hazards Not classified.
OSHA defined hazards Not classified.

Label elements
Hazard symbol None.
Signal word Warning
Hazard statement May form combustible dust concentrations in air.
Precautionary statement
Prevention Take precautionary measures against static discharge. Use with adequate ventilation. Avoid
generation or accumulation of dust.
Response If inhaled, remove to fresh air. Get medical attention if symptoms persist. IN CASE OF FIRE, use
water spray or fog, foam, dry chemical or CO2. Collect in a chemical waste container. Use only
vacuum cleaners approved for combustible dust collection.
Storage Not available.
Disposal Not available.
Hazard(s) not otherwise May form combustible dust concentrations in air.
classified (HNOC) Risk of skin burns caused by hot melt.
Supplemental information This material is considered hazardous under the OSHA Hazard Communication Standard criteria,
based on hazard(s) not otherwise classified.

3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
Polyamide Proprietary 90-100

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Composition comments This product has been evaluated using criteria specified in 29 CFR 1910.1200 (Hazard
Communication Standard).

4. First-aid measures
Inhalation If dust from the material is inhaled, remove the affected person immediately to fresh air.

Move to fresh air in case of accidental inhalation of vapors or decomposition products. If breathing
is difficult, give oxygen. Oxygen or artificial respiration if needed. Consult a physician for specific
advice.
Skin contact Wash the skin immediately with soap and water. In case of contact with molten product, cool
rapidly with water and seek immediate medical attention. Do not attempt to remove molten product
from skin because skin will tear easily.
Eye contact Dust: Wash well-open eyes immediately, abundantly and thoroughly with water. Remove particle
remaining under the eyelids. If irritation persists, consult a doctor.
On contact with hot product: Cool eyes rapidly with cold water after contact with molten polymer.
Continue to rinse for at least 15 minutes. Get medical attention immediately.
Ingestion If swallowed, do NOT induce vomiting. Get medical attention. Never give anything by mouth to an
unconscious person.
Most important No experiences of acute or chronic damages in humans have been made yet.
symptoms/effects, acute and
delayed
General information Risk of skin burn caused by hot melt.
Do not leave the victim unattended.
Remove victim immediately from source of exposure.
Victim to lie down in the recovery position, cover and keep him warm.

5. Fire-fighting measures
Suitable extinguishing media Water spray, foam, dry powder or carbon dioxide.
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from May be released in case of fire: carbon monoxide, carbon dioxide, nitric oxides, organic products
the chemical of decomposition. Under certain fire conditions, traces of other toxic products may occur.
Special protective equipment As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH
and precautions for firefighters (approved or equivalent) and full protective gear.
Fire fighting Do not use a solid stream of water. A solid stream of water can cause a dust explosion. Fire
equipment/instructions fighting equipment should be thoroughly decontaminated after use.
General fire hazards Dust clouds generated during handling and/or storage can form explosive mixtures with air. Check
that all equipment is properly grounded and installed to satisfy electrical classification
requirements. As with any dry material, pouring this material or allowing it to free-fall or to be
conveyed through chutes or pipes can accumulate and generate electrostatic sparks, potentially
causing ignition of the material itself, or of any flammable materials which may come into contact
with the material or its container.

6. Accidental release measures

Personal precautions, In case product dust is released: Dust mask
protective equipment and
emergency procedures
Methods and materials for Sweep up or vacuum up spillage and collect in suitable container for disposal. If a vacuum is used,
containment and cleaning up the motor must be rated as dust explosion-proof. Dispose of in compliance with federal, state, and
local regulations.
Environmental precautions Prevent further leakage or spillage. Do not let product enter drains. Do not flush into surface water
or sanitary sewer system.

7. Handling and storage

Precautions for safe handling Avoid contact with skin and eyes Avoid breathing dust. Prevent dust accumulation to minimize
explosion hazard. Inside and outside the equipment should be cleaned regularly with an
explosion-protected vacuum cleaner to avoid dust accumulation. Do not sweep the dust or or try to
remove it with a compressed-air gun. Remove contaminated clothing and wash the skin thoroughly
with soap and water after work.
Conditions for safe storage, Store away from moisture and heat to maintain the technical properties of the product. Eliminate
including any incompatibilities sources of ignition. Do not expose to heat or store above 60C.

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8. Exposure controls/personal protection
Occupational exposure limits
Also see Exposure guidelines.
ACGIH
Material Type Value Form

V1R10Series TWA 10 mg/m3 Inhalable particles

(ACGIH)
Comments: Inhalable particles
Biological limit values No biological exposure limits noted for the ingredient(s).
Exposure guidelines Exposure Limit For Dust

ACGIH (TWA/TLV): 3 mg/m3 (Respirable Particulate)

US CA OEL (TWA/PEL): 10 mg/m3 (Total dust)
US CA OEL (TWA/PEL): 5 mg/m3 (Respirable fraction)
US OSHA (TWA:Z-3): 15 mg/m3 (Total dust)
US OSHA (TWA:Z-3): 5 mg/m3 (Respirable fraction)
US OSHA (TWA:Z-3): 50millions of particles per cubic foot of air (Total dust)
US OSHA (TWA:Z-3): 15millions of particles per cubic foot of air (Respirable fraction)

Appropriate engineering HP recommends the use of HP accessories for unpacking 3D parts and refilling the build chamber.
controls If other methods are used, read the following: Dust clouds generated during handling and/or
storage can form explosive mixtures with air. Dust explosion characteristics vary with the particle
size, particle shape, moisture content, contaminants, and other variables. Check that all equipment
is properly grounded and installed to satisfy electrical classification requirements. As with any dry
material, pouring this material or allowing it to fall freely or be conveyed through chutes or pipes
can accumulate and generate electrostatic sparks, potentially causing ignition of the material itself,
or of any flammable materials which may come into contact with the material or its container.

Investigate engineering techniques to reduce exposures below airborne exposure limits or to

otherwise reduce exposures. Provide ventilation if necessary to minimize exposures or to control
exposure levels to below airborne exposure limits. If practical, use local mechanical exhaust
ventilation at sources of air contamination such as open process equipment. Ensure that
dust-handling systems (such as exhaust ducts, dust collectors, vessels, and processing
equipment) are designed in a manner to prevent the escape of dust into the work area (i.e., there
is no leakage from the equipment). Consult ACGIH ventilation manual, NFPA Standard 91 and
NFPA Standard 654 for design of exhaust system and safe handling.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields.
Skin protection
Hand protection Wear impermeable gloves. Protective heat-insulating gloves are to be used during thermal
processing. Any areas of skin covered with dust must be washed immediately with soap and water
as the powder draws out natural moisture from the skin. Use barrier cream regularly.
Other Processing of this product releases vapors or fumes which may cause skin irritation. It is a good
industrial hygiene practice to minimize skin contact. Wash thoroughly after handling.
Respiratory protection Avoid breathing dust. Avoid breathing processing fumes or vapors. Where airborne exposure is
likely or airborne exposure limits are exceeded, use NIOSH approved respiratory protection
equipment appropriate to the material and/or its components and substances released during
processing.
Thermal hazards In thermal processing: Risk of skin burns. Wear appropriate thermal protective clothing, when
necessary.
General hygiene Always observe good personal hygiene measures, such as washing after handling the material
considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.

9. Physical and chemical properties

Appearance Powder.
Solid.
Physical state Not available.
Form Powder.
Color White.
Odor Not available.

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Odor threshold Not available.
pH Not available.
Melting point/freezing point 363.2 - 368.6 °F (184 - 187 °C)
Initial boiling point and boiling Not available.
range
Flash point Not available.
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure Not available.
Vapor density Not available.
Solubility(ies)
Solubility (water) insoluble
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature > 752 °F (> 400 °C)
Decomposition temperature > 662 °F (> 350 °C)
Viscosity Not available.
Other information
Explosive properties Dusts might form explosive mixtures with air.

Powder explosivity data:

Minimum Ignition Energy (MIE) “dust cloud” w/ Inductance >30mJ.

Layer Ignition Temperature (LIT) “dust layer” >400degC.
Minimum Ignition Temperature (MIT) “dust cloud” >360degC.
Auto Ignition Temperature (AIT) >400degC.
Flammability (flash back) This product is not flammable.
Oxidizing properties Not oxidizing.
Specific gravity 0.42 g/cm3

10. Stability and reactivity

Reactivity Under normal conditions: stable.
Chemical stability The product is stable under normal handling and storage conditions.
Possibility of hazardous Will not occur.
reactions
Conditions to avoid Take measures to mitigate material spillage and avoid potential ignition sources such as ESD
(ElectroStatic Discharges), flames, and sparks. Do not smoke nearby. Avoid wet/humid
environment. Recommended working humidity 50-70%. Avoid dust formation.
Incompatible materials Oxidizing materials, acids, strong bases, water and high humidity.
Hazardous decomposition Decomposition products on thermal decomposition, carbon monoxide, carbon dioxide, Nitrogen
products oxides (NOx), organic products of decomposition.

11. Toxicological information

Information on likely routes of exposure
Inhalation At high temperature, products of thermal decomposition can be irritating to respiratory system.
Skin contact May be considered as comparable to a similar product for which experimental results are: Non
irritating to skin.
Eye contact May be considered as comparable to a similar product for which experimental results are: Not
irritating to the eyes.
Material name: V1R10Series SDS US

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 Ingestion May be considered as comparable to a similar product for which experimental results are: Slightly
harmful by ingestion.
Symptoms related to the Not available.
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicity Based on available data, the classification criteria are not met.
Skin corrosion/irritation Based on available data, the classification criteria are not met.
Serious eye damage/eye Based on available data, the classification criteria are not met.
irritation
Respiratory or skin sensitization
Respiratory sensitization Based on available data, the classification criteria are not met.
Skin sensitization Based on available data, the classification criteria are not met.
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity Based on available data, the classification criteria are not met.
Specific target organ toxicity - Based on available data, the classification criteria are not met.
single exposure
Specific target organ toxicity - Based on available data, the classification criteria are not met.
repeated exposure
Aspiration hazard Based on available data, the classification criteria are not met.
Further information Complete toxicity data are not available for this specific formulation

12. Ecological information

Ecotoxicity No ecotoxicity data noted for the ingredient(s).
Persistence and degradability Not available.
Bioaccumulative potential Not available.
Mobility in soil Not available.
Other adverse effects Not available.

13. Disposal considerations

Disposal instructions Do not allow this material to drain into sewers/water supplies.
Dispose of waste material according to Local, State, Federal, and Provincial Environmental
Regulations.

14. Transport information

DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
ADR
Not regulated as dangerous goods.
Further information Not a dangerous good under DOT, IATA, ADR, IMDG, or RID.

Material name: V1R10Series SDS US

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15. Regulatory information
US federal regulations US EPA TSCA Inventory: All chemical substances in this product comply with all rules or orders
under TSCA.
All ingredients are listed or exempt
US TSCA 12(b): Does not contain listed chemicals.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous No
chemical
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations Not Listed
Regulatory information All chemical substances in this HP product have been notified or are exempt from notification
under chemical substances notification laws in the following countries: US (TSCA), EU
(EINECS/ELINCS), Switzerland, Canada (DSL/NDSL), Australia, Japan, Philippines, South Korea,
New Zealand, and China.

16. Other information, including date of preparation or last revision

Issue date 11-Sep-2016
Revision date 25-Jan-2019
Version # 07
Other information This SDS was prepared in accordance with USA OSHA Hazard Communications regulation (29
CFR 1910.1200).
Disclaimer This Safety Data Sheet document is provided without charge to customers of HP. Data is the most
current known to HP at the time of preparation of this document and is believed to be accurate. It
should not be construed as guaranteeing specific properties of the products as described or
suitability for a particular application. This document was prepared to the requirements of the
jurisdiction specified in Section 1 above and may not meet regulatory requirements in other
countries.

This safety data sheet is meant to convey information about HP inks (toners) provided in HP
Original ink (toner) supplies. If our Safety Data Sheet has been provided to you with a refilled,
remanufactured, compatible or other non-HP Original supply please be aware that the information
contained herein was not meant to convey information about such products and there could be
considerable differences from information in this document and the safety information for the
product you purchased. Please contact the seller of the refilled, remanufactured or compatible
supplies for applicable information, including information on personal protective equipment,
exposure risks and safe handling guidance. HP does not accept refilled, remanufactured or
compatible supplies in our recycling programs.

Material name: V1R10Series SDS US

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Explanation of abbreviations

ACGIH American Conference of Governmental Industrial Hygienists

CAS Chemical Abstracts Service
CERCLA Comprehensive Environmental Response Compensation and Liability Act
CFR Code of Federal Regulations
COC Cleveland Open Cup
DOT Department of Transportation
EPCRA Emergency Planning and Community Right-to-Know Act (aka SARA)
IARC International Agency for Research on Cancer
NIOSH National Institute for Occupational Safety and Health
NTP National Toxicology Program
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
RCRA Resource Conservation and Recovery Act
REC Recommended
REL Recommended Exposure Limit
SARA Superfund Amendments and Reauthorization Act of 1986
STEL Short-Term Exposure Limit
TCLP Toxicity Characteristics Leaching Procedure
TLV Threshold Limit Value
TSCA Toxic Substances Control Act
VOC Volatile Organic Compounds

Material name: V1R10Series SDS US

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