OT - 3 (ADV) C3 - ICON

[Link] : 180
Class : C2 - ICON
OBJECTIVE TEST - 3 Time: 3 Hrs
Subjects : Mathematics, Physics, Chemistry Date : 27.08.21

SYLLABUS
Maths : Binomial Theorm
Physics : Centre of Mass (Complete)
Chemistry : [Link] Kinetics Molecularity & order

Name of the Student ...................................................................... Roll No .......................................

MATHEMTICS
SECTION - I
(Straight objective type questions(+3,–1)

1. For natural numbers m, n if (1 − y) m (1 + y) n = 1 + a1 y + a2 y2 + ........, and a1=a2=10, then (m,n)is

a) (35, 20) b) (45, 35) c) (35, 45) d) (20, 45) [ ]
2. The coefficient of x5 in the expansion of (x2 – x – 2)5 is [ ]
a) –83 b) –82 c) –81 d) 0
3. If the coefficients of rth, (r+1)th and (r+2)th terms in the binomial expansion of (1+y)m are in A.P.
then m and r satisfy the equation [ ]
a) m 2 − m ( 4r − 1) + 4r 2 + 2 = 0 b) m 2 − m ( 4r + 1) + 4r 2 − 2 = 0
c) m 2 − m ( 4r + 1) + ( 4r 2 + 2) = 0 d) m 2 − m ( 4r − 1) + 4r 2 − 2 = 0

300 300 300

= ∑ ar x , ∑ ar = a. Then ∑ ra =
r
2 3 100
4. If (1 + x + x + x ) r [ ]
r =0 r =0 r =0

a) 300a b) 100a c) 150a d) 75a

5. The coefficient of x12 in the expansion of (1 + 2x2 – x3)8 is [ ]
a) 6340 b) 6342 c) 6344 d) 6346

SECTION - II
(One or more than one correct answer type questions(+3,–1))
5
⎛1 ⎞ 2 4
6. If in the expansion of ⎜ + x tan x ⎟ the ratio of 4th term to the 2nd term is π then the value
⎝x ⎠ 27
of x can be [ ]
−π −π π π
a) b) c) d)
6 3 3 12
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( )
20
7. Let R = 8 + 3 7 and [R] = the greater integer less than or equal to R. Then [ ]
a) [R] is even b) [R] is odd

1
c) R − [ R ] = 1 − d) R + R [ R] = 1 + R 2
(8 + 3 7 )
20

8. If C0 , C1, C2 , C3 , ...., Cr , ......, Cn are binomial Coefficients such that C n− 3 , C n− 2 , C n−1 are in
Arithmetic progression (where Cr = nCr , n ∈ N ) , then [ ]

a) C1 , C2 , C3 are in Arithmetic progression b) C1 , C2 , C3 are in HP

c) n = 14 d) n = 7

( )
5
9. If it is known that the third term of the binomial expansion x + x log10 x is 106, then x is equal to
−5
a) 10 b) 10 2 c) 100 d) 5 [ ]
10. If (1 + 2x + 3x2)10 = a0 + a1x + a2x2 + ..... + a20x20, then [ ]
a) a1 = 20 b) a2 = 210 c) a19 = 20. 37 d) a20 = 310

SECTION - III
(Passage type questions(+3, –1))

Passage : I

( )
n
If 1 + px + x 2 = 1 + a1 x + a2 x 2 + ...... + a2n x 2n , where n ∈ N, p ∈ R , ar = Co -efficient
of xr.
11. If n = 40, p = 3, r = 5 then which of the following is true. [ ]
a) 135a5 = 6 a6 + 4 a4 b) 105a5 = 6a6 − 76 a4
c) 105a5 = 6a6 − 36 a4 d) 135a5 = 6a6 − 36 a4

12. The remainder obtained when a1 + 5a2 + 9 a3 + 13a4 + ....... + (8n − 3) a2 n is divided by (p + 2) is
a) 1 b) 2 c) 3 d) 0 [ ]

13. If p = –3 and n is even number, the value of a1 + 3a2 + 5a3 + 7a4 + ...... + (4 n − 1) a2 n is
a) n b) 2n – 1 c) 2n – 2 d) 2n [ ]

Passage : II

(1 + x)n = C0 + C1x + C2x2 + C3x3 + ....+ +Cnxn _____(1)

14. Values of x, we should substitute in (1) to get the sum of the series C0 + C3 + C6 + ..... are
a) 1, – 1, w b) w, w2, w3 c) w, w2, – 1 d) w, w2, w4 [ ]
15. If n is a multiple of 3, then C0 + C3 + C6 + ... is equal to [ ]
2 n + 2 ( −1) 2 n − 2 ( −1)
n n
2n + 2 2n − 2
a) b) c) d)
3 3 3 3
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16. The sum of values of x, which we should substitite in (1) to give the sum of the series C0 + C4 + C8
+ C12 + .... is [ ]
a) 2 b) 2(1 + i) c) 2(1 – i) d) 0

SECTION - IV
(Matrix Matching type questions(+3, –1))
Column - I Column - II
17. The remainder, when (1523 + 2323) is a) 00 17 a b c d
divided by 19, is c d
18 a b
18. If (11)27
+ (21)27
when divided by b) 01 c
19 a b d
16 leaves the remainder
20 a b c d
19. Last Two digits of the number c) 15
N = 7100 – 3100 are
20. The last two digits of the number 3400 are d) 10

PHYSICS

SECTION - I
(Straight objective type questions(+3, –1))
21. Four particles of masses 1 kg, 2 kg, 3 kg and 4 kg are placed at the four vertices A, B, C and D of
a square of side 1 m. Find the position of centre of mass of the system. [ ]
Y
a) 0.5m, 0.7 m

b) 0.5 m, 0.5 m
D m3 C
m4
c) 0.7 m, 0.7 m

d) 0.7 m, 0.5 m m2
A m1 B X
22. The velocity of the centre of mass of the system of particles shown in figure is [ ]
1m/s
a) 0.2 ms–1 0.4m/s
1kg
370 370
b) 0.3 ms–1 1.5 kg
1.5m/s 1.2 kg
c) 0.4 ms–1 1kg
0.5 kg 3m/s 370
d) 0.5 ms–1 2m/s

23. Two spheres of masses 4 kg and 8 kg are moving with velocities 2 ms–1 and 3 ms–1 away from
each other along the same line. Find the velocity of centre of mass. [ ]

3 4 –1 5 –1 2
a) ms–1 b) ms c) ms d) ms–1
2 3 2 3

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24. A thin uniform rod of length L is bent at its mid point as shown in the figure. The distance of centre
of mass form the point ‘O’ is [ ]
L θ L θ
a) cos b) sin
2 2 4 2 G

L θ L θ O
c) cos d) sin
4 2 2 2
25. A rod of length L is placed along the x -axis between x = 0 and x = L. The linear density (mass/
length) ρ of the rod varies with the distance x from the origin as ρ = a + bx. Here a and b are
constants. Find the position of centre of mass of this rod. [ ]
P Q

x=0 x=L
dx

⎡ 3aL + 2bL2 ⎤ ⎡ 2aL + 3bL2 ⎤ ⎡ 3aL + 3bL2 ⎤ ⎡ 6aL + 2bL2 ⎤

a) ⎢ , 0, 0 ⎥ b) ⎢ ,0,0 ⎥ c) ⎢ 3a + 6bL ,0,0 ⎥ d) ⎢ 2a + 3bL ,0, 0 ⎥
⎣ 6a + 3bL ⎦ ⎣ 6a + 3bL ⎦ ⎣ ⎦ ⎣ ⎦
SECTION - II
(One or more than one correct answer type questions(+3, –1))
26. Four identical bricks, each of length l, are put on the top of one another in such a way that part of
each extends beyond the one beneath. The largest equilibrium extensions are [ ]
l
a) Top brick over hanging the one below by l/2
I
b) Second brick from top over hanging the one below l/4 II
III
c) Third brick from top over hanging by bottom one by l/6 IV

11
d) The total over hanging length from the edge of the bottom brick is l
12
27. A disc of radius ‘r’ is removed from the disc of radius ‘R’ then [ ]
a) The minimum shift in centre of mass is zero
r2
b) The maximum shift in centre of mass cannot be greater than
( R + r)
r2
c) Centre of mass must lie where mass exists d) The shift in centre of mass is
( R + r)
28. Three particles each of mass m are welded to a rigid frame consisting of three massless rods, each
of length L. The rods are welded to each other at point O. The frame is placed on a smooth
horizontal floor. Three forces start acting as shown in the figure. Then, just at the initial moment
2F ˆ
a) acceleration of O is ao = i F A
[ ]
3m Y
X
5F ˆ 1200 O 1200
b) acceleration of A is aA = i
6m 1200
3F C B 2F

7F ˆ F ˆ
c) acceleration of B is a B = i− j
12m 4 3
d) Magnitudes of accelerations of B and C are equal
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29. Among the following statements are correct from Shift in Centre of Mass [ ]
a) A square portion of diagonal equal to radius is removed from a uniform circular plate of radius
R
R as shown in figure. Then shift in centre of mass is, xshift = .
2 ( 2π − 1) a a
R
R 2

b) A uniform square of side 2L is divided into four equal quadrants. If one of the quadrent is
L
removed, then shift in centre of mass is x shift = L L2
.
3 2 x

c) From a uniform square plate of side 2L, a circular portion is removed from one of the quadrant
πL L/2

L/ 2
then shift in centre of mass is xshift = 2 (16 − π )
2L
x

d) When a triangular portion is removed from one edge of a square plate of side ‘a’ as shown in the
a

a c1 c2
figure then shift in centre of mass is given by xshift = a
9 a
2 3

30. A light rope passes over a light frictionless pulley attached to the ceiling. An object with a large
mass is tied to one end and an object with a smaller mass is tied to the other end Both masses are
released from rest. Which of the following statement(s) is /are false for the system consisting of the
two moving masses while string remains taut. [ ]
a) The centre of mass remains at rest
b) The net external force is zero
c) The velocity of the centre of mass is a constant
M m
d) The acceleration of the centre of mass is g downward
SECTION - III
(Passage type questions (+3,–1))
Passage - I :
A block of mass m moves with velocity V0 toward a stationary block of mass M on a smooth
horizontal surface.
V0
m M

31. Velocity of centre of mass of the system is : [ ]

mv0 mv0 mv 0 v0
a) b) c) d)
M+m M M−m 2
32. Initial velocity of block of m w.r.t centre of mass of the system: [ ]
Mv 0 mv0 v0 vo
a) b) c) d)
m+M M+m 2 3

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33. Maximum compression in the spring of stiffness constant k is : [ ]

1 ⎛ mM ⎞ 1⎛ M ⎞ 1 m
b) vo
k ⎜⎝ M + m ⎟⎠
a) v o c) v o
k ⎜⎝ m + M ⎟⎠
d) None of these
k (M + m)

Passage - II:
A horizontal frictionless string is threaded through a bead of mass m. The string is tied to two
vertical opposite sides of a cart of mass M. The length of the cart is L and the radius of the bead is
r [r << L]. Initially the bead is at the right edge of the cart. The cart is struck and as a result moves
with a velocity v0. Assuming that no energy is lost in any collision.
L

M m Smooth

34. The velocity of centre of mass of the cart and the bead is [ ]
mv0 Mv 0 Mv 0 mv 0
a) b) c) d)
m+M m+M M−m M−m
35. The first collision of the bead with the wall of the cart takes place after a time t1 given by
L L 2L L
a) v b) v c) v d) 2v [ ]
0 COM COM 0

36. The velocity of the bead after the first collision in the centre of mass frame is [ ]
2Mv0 2mv 0 mv0 Mv 0
a) b) c) d)
m+M m+M m+M m+M
SECTION - IV
(Matrix matching type questions(+3, –1))
Column - I Column - II
R
37. Distance of centre of mass of a)
2
semicircular ring from centre 37 a b c d
3R 38 a b c d
38. Distance of centre of mass of b)
4
semicircular disc from centre 39 a b c d
4R 40 a b c d
39. Distance of centre of mass of c)
3π
solid cone from vertex
2R
40. Distance of centre of mass of hemi d)
π
spherical shell from centre

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CHEMISTRY
SECTION - I
(Straight objective type questions(+3, –1))
41. Rate law for 2A + B → C + D from following data: [ ]
[Link] [A] (M) [B] (M) Rate (M/s)
1. 0.01 0.01 2.5
2. 0.01 0.02 5
3. 0.03 0.02 45
a) r = K[A]1/3[B] b) r = K[A]2[B] c) r = K[A][B]1/3 d) r = K[A]2/3 [B]1/3
42. Sucrose decomposes in acid solution into glucose and fructose according to the first order rate
law, with t½ = 3.00 hours. What fraction of sample of sucrose remains after 8 hours? [ ]
a) 1.158 b) 0.518 c) 0.158 d) 3.182
43. Half life period for a first order reaction is 20 minutes. How much time is required to change
the concentration of the reactants from 0.08 M to 0.01M [ ]
a) 20 minutes b) 60 minutes c) 40 minutes d) 50 minutes
44. The reaction A → B follows first order kinetics. The time taken for 0.8 mole of A to produce 0.6
moles of B is 1 hour. What is the time taken for conversion of 0.9 mole of A to produces 0.675
moles of B?
a) 1 hour b) 0.5 hour c) 0.25 hours d) 2 hours [ ]
45. 20% first order reaction is completed in 50 minutes. Time required for the completion of 60% of
the reaction is [ ]
a) 100 min b) 150 min c) 262 min d) 205 min
SECTION - II
(One or more than one correct answer type questions(+3, –1))
46. A 2 litre container contains 4 moles of N2O5. On heating to 1000C, N2O5 undergoes complete
dissociation to NO2 and O2. If rate constant for decomposition of N2O5 is 6.2 × 10-4 sec–1, select
the correct statements
a) The mole ratio before and after dissociation is 4 : 2 [ ]
b) The time required to complete 40% of reaction is 824 sec
c) t1/2 of N2O5 is 1117.7 sec and it is independent of temperature.
d) If volume of container is doubled, the rate of decomposition becomes half of the intial rate
47. Select the correct statement(s) [ ]
a) The rate law of the elementary reaction 2 A → B + C ; must be Rate = K[A] . 2

b) The rate law for the complex reaction A + B → C , might not be Rate = K[A] [B]
c) If the partial orders differ from the coefficients in the balanced reaction, the reaction must be
complex.
d) If the partial orders equal to corresponding coefficients in the balanced reaction, the reaction
must be elementary.
48. In case of 1st order reactions [ ]
a) t 75% = 2t1/ 2 b) t 99.9% = 10t1/ 2 c) t100% = infinity d) t100% = 2t1/ 2

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49. Incorrect statements in the following [ ]
a) Unimolecular reactions always 1st order
b) Order does not change with pressure and temperature
c) In case of free radical combination reactions, order is equal to molecularity
d) In 1st order reactions rate decreases with increase of time
50. For a reaction, A + B → products, the rate of reactions is increased by 8 times when the concen-
tration of A & B are doubled. The rate of reaction is doubled when the concentration of A alone
is doubled. Then [ ]
a) Order of reaction with respect to A is 1 b) Order of reaction with respect to B is 2
c) Rate = K [ A][ B]
2
d) Units of rate constant are mole-2 lit2 time-1
SECTION - III
(Passage type questions (+3,–1))
Passage - I
For the overall reaction between A and B to yield C and D, two mechanisms are proposed
I) A + B → AB* → C + D, k1' = 1 × 10 −5 M −1s −1
II) A → A* → E, k1 = 1 × 10 −4 s−1 ,
E + B → C + D, k2 = 1 × 1010 M −1s −1
(species with * are short- lived)
51. Rate of reaction for mechanism I when concentration of each is 0.1M, is [ ]
a) 1 × 10–7 Ms–1 b) 1 × 10–6 Ms–1 c) 1 × 10–5 Ms–1 d) 1 × 10–4 Ms–1
52. Rate of reaction for mechanism II when concentration of each 1 M is [ ]
a) 1 × 10–4Ms–1 b) 1 × 1010Ms–1 c) 1 × 10–5Ms–1 d) 1 × 10 Ms–10 –1

53. At what concentration of B, rates of two mechanism are equal ? [ ]

a) 1M b) 5M c) 7M d) 10M
Passage - II
The graph drawn between rate of reaction Vs concentration of reactant, gives a straight line pass-
ing through origin. The slope is 2.4 × 10–4 min–1
54. Order of the reaction is [ ]
a) zero b) one c) two d) three
55. Rate constant of the reaction is [ ]
a) 2.4 × 10–4 b) 4.8 × 10–4 c) 1.2 × 10–4 d) 2.4 × 10–3
56. Half life of reaction is [ ]
a) 288.75 min b) 28875 min c) 1443.75 min d) 2887.5 min
SECTION - IV
(Matrix matching type questions(+3, –1))
Column - I Column - II
57 a b c d
57. Molecularity of a reaction a) 0,1 possible
58 a b c d
58. Order of a reaction b) 1,2 possible
59 a b c d
59. the dissociation of H2 O2 (aq) c) first order
60 a b c d
60. H2(g) + Cl 2(g) ⎯⎯
→ 2 HCl
hv
d) zero order

Z
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