elAsSMAte
Date.
OC: Page
FREE RA01CAK feouton methanam that involve8
homolysib of covolnt bords with the
olDdution intemcdiates haui0g unpaired eletion&8
called rodals (oR) fiee rohats.
A B A B
i
HomeysHetaolysia 2dif cleavages ofaatent bond
)CHa 7e P bngoRGt plonarLio)j
CH h stoble lno otet)
H a)e aueptor (kewig Acd
3 paiamaantic
Iis elatntaly
4) neutial
neutrat and hahly
unStoble-fedly paits up As it is poor0gnetk.
No reaimngement tARRB plOte.
Ihis teotion tokes plot in ples enct ofF HELPR
Hheotl >50DA) STABIITY
eteutricity /Eleutoyis Stobilty e donor
Suntight lhu) oups
peronde H0a) R-o-0-R e (elea5 6nq
Haups
R Radicals (Cis)
LStability Df e
TR M) withdrawing Q0ups
lAsSMAte
Date
Page
NOTE Bridge-bdadpostion cOLbon_fiec adicate
highly unsaba Mulbiplbondd CaubonQie
Uinue Ca/bon)
having free sadicat s ehoiws ingtabilitu
CH Lunstable). CHEC un sLaN
unstable
Cuntable
un etDHe)
Lattut-ta
inu-Lunatobles
Vinyt
atly
Homoluicfavoled in ow potouity nas201 phose
ALBEnU D 00n polar 8oluenbs_4,LS
Stability o Colbonfiiadcats
Benzy altyt 3 2 1CH
foP C=C- -c
SCARBOLATIDN8 feation_mtchanis m bhot jnvot
CARBANIONS heterolytiziesion of
UA-
otm intaimediates 05 alint bn00s
obocatipn& COibanon
Veytow hotf tft of teacten-
ntemediats
A-B A 8 clasSMAte
Date.
Cabcabion Carbebon Page.
LARROCATIONS Sp hybridise. CH6
l20Trigonat plaar diamagntte
Rearrangemtnt feactions bakt plbe
Stability o Corbocations electiondonocgaps
Emply
(I,+R,+M
h C I,-R-M
brgi&
withdawing
giaup S
Stabitty+
posibion uhLLE ColboL0bion has_Dhe oL DIe lone
pgireleutions Ie ntieAse3 atobihhy due Eto
dalocgdisoton
C C- -d CHa--t
Cla
CH3B I TDonor qioup
dectea Bes eteutopositiuEy /de;uiency
Directly Lonneubed d po8iEion
CH-0 -O
p non boming: donoe
opo8iton
PleBent ., lone poir 8tabiliss tve) charge
CH e r lertoy_Amine but _catboch tion
-N p Stobilisz LH
Stability D Casbontions KaS N,
Page.
ibocation tunstah
head positon
of
NOTE Brigdge
Uoskable
choge h g h a
olom8 having t e)
Multple bondtd stability d
L:TEN
rotr uy lotyplan
>(H =CH > CH C
04a-CH
SPa 4 Sp
ENStobitity
ALD:CH, CH CC A stobM
CH ECD|Sobliu
Olde
Cuclopoput methu Zahcation 8_»oIe atnble_than
bnze
NTE
Exeption
Ctability 1 with 1 oftuckopopygups
Stabilit4
Alo
(Stobilty
CARBANIDN3 SPa damaqoetic, Py/0midat
-C-C)
lone pai)
Stabitlty o calbanion8 e witbdawing haup-
(IMR) T M
dooL Qioups
clasSMAte
Date
AnEul
AYISHa C> CH =CHO rs
CH Ci-C CHa Ch-CHC
a)
(3 CHa
Negabive Lhageon MulEipt bonded caibon_ is_ moe sLhe
due to 5-thorotten..
Stobiliby C 5
CHE CO CHh CHO >H-CH
SP
CHD CHs
Eap0aition of (OIhanion has funttiona ioup_whiuh
Lootoinpoultjple bonda (CEC, C =6, CEN.
inienses 2tablty 0 f O included)
Calbanion_due to 22o0anL2
CH3--CHD 2CH-C=
pl28ent on1 EN atom 1 stoble.
(Stobility)
Date .
Page
- I order N
NR R-methu NH
NH D
NDa CD0
SO R
CN
CLCHa
CH(CH
SOaH CHa-H
CHO- CT
CHs
CoOH
CoC
CONH |+I decieases|
F
C
Br
I
0 -R
D-1H C24
NH2 Hs
CH CHa
H
Idecrenses|
M : NO S0 H> N> CHO> - >
> t o
anhupida)- O-C-R> C-A
>toNH
tR/+M:0 >NHa NH R > NA >6 >öR N
0-i-R > F >tl>B >I >NO >cN.
Ecepb on OH OR. N I but R
