1
SCHOOLS, CHENNAI& RANIPET
D.A.V GROUP OF
EXAMINATION - 2022- 2023
COMMON QUARTERLY
CHEMISTRY
Time: 3 hours
Class: XI Max.Marks:70
Date: 23.09.22
General Instructions
compulsory.
question paper. Allquestions are
There are 33 questions in this Q. No. 1and 2 are
objective type questions. 16 carry 1 mark
Section A: Q. No. 1to 16 are 4 marks each while Q. No. 3 to
passage-based questions carrying
each.
each. questions and carry 2 marks
B: Q. No. 17 to 25 are short answer marks each.
Section carry 3
No. 26 to 30 are short answer questions and each.
Section C: Q.
long answerquestions carrying 5 markS
Section D: Q. No. 31 to 33are internal choices have been
provided.
choice. However,
There is nooverall
tables is not permitted.
Use of calculators and log
SECTION A
questions that follow:
(4)
and answer the
1.Read the given passage probability of finding
spaces where there is a maximum and
Orbitals are regions or
orbitals can be distinguished by their size, shape,
electron
electrons. Qualitatively, these of finding the
means there is more chance
orientation. An orbitalof small size direction in which the probability of
nucleus. Shape and orientation mean the
near the distinguished by quantum
finding the electron is maximum. Atomic orbitals can be and m1 (magnetic
by three quantum numbers n, I,
numbers. Each orbital is designated orientation but these are not
shape, and
quantum number) which define energy, atoms. Spin quantum number (ms)
sufficient toexplain spectra of multi-electrons two
angular momentum of the electron has
determines the spin of electrons. Spin quantum
are distinguished by spin
orientations relative to the chosen axis which
+h and-%.
numbers ms which can take values
in fourth energy level of an atom is
(i) The total number of atomic orbitals
a. 4
b.8
C. 16
d. 32
following
electrons that can be associated with the
(iü)A What is the maximum number of
I= 1and m =1
set of quantum numbers? n=3,
a. 10
b. 6
C. 4
d. 2
OR
energy of the listed orbitals in the atom of
(iü)BWhich is the correct order of increasing
titanium?
a. 3s 3p 3d 4s
b. 3s 3p 4s 3d
C. 3s 4s 3p 3d
d. 4s 3s 3p 3d
2
(ii) The quantum numbers + ½
and-% for the electron spin represent
a. rotation of the electron in
b. rotation of the electron
clockWise and anticlockwise direction respectively
anticlockwise and clockwise direction respectively
C. magnetic moment of the electron pointing up and
d. two quantum mechanical spin states which have no down respectively
classified analogue
(iv) The electrons identified by quantum
numbers n and I:
1. n=4, | =1 3. n =3,I=2
2. n =4, |=0 4. n =3, |=1
can be placed in order of increasing
energy as:
a. (1)< (3) < (2) < (4)
b. (3) < (4) < (2) < (1)
c. (4) < (2) < (3) < (1)
d. (2) < (4) <(1) <(3)
2.Read the following passage and
answer the questions that follow: (4)
Modern periodic table arranges the
It has 18 groups and 7 elements in the increasing order of atomic
increases in the group inperiods. Atomic numbers are
apattern. consecutive
number
in a period and
block, d-block, and f-block Elements are divided into four blocks,
based on their electronic
metals, about 20 elements S-bloc.p
metalloids. are configuration. 78%o of
non-motals, and few elements like B, Si, Ge.elemerts ar
from loft to Metallic charactor incronsos
right. The phyalcal and down the yroup but decr;aes 3ong he RAs a12
atomiC unboa Petlodic chemical proportigs
olection gain uouda ae obherved in alomicvty/0,peridically wt ie?
anthalpios, olectronegativity, and valence. Oxidesionizaion
8Ome aro amphotoria. nthalpe,
elements are soft, highlyNon-metals form acldic oxldes, some of metals are basic,
reactive, do not show variable form neutral oxides. sblock
elements are metals, non-metals as well as oxidation states. p-block
exist as solids, liquids, and metalloids, show
gases. d-block elements are metals, varíable oxidation states
show variable oxidation states,
have high melting and boiling form colourediors
actinoids are f-block elements, form
a.
coloured ions. Allactinoidspoints.
are Lanthanoids
anc
radioactve
Assertion and Reason both are correct
explanation for assertion. statements and reason is the correct
b. Assertion and Reason both are correct
correct explanation for assertion. staterments but reason is not the
c. Assertion is Correct statement but
reason is wrong statement
d. Assertion is wrong statoment but roason is correct
statement.
i)kssortilon: Gocond poriod consists of 8elements
A t Numther oflonento in oach period is four times the number of atmc ortas
9/ailnbls in he oioigy level that is being filled
(8) hasrtion ti/h petod is the longost period in the periodic table.
fano izh oiod involvos tho filling of all the orbitals of the sixth energy level
(w, bssortlon solononl willh (Xe}"4 4r'5d' 6s' is a d- block element
anson La6l eloctonontos in d- orbital in d- block elements
i
Tee g e f age #
(1)
6A
S2 alse e t enrgy d be ened ecns?
2
e14N
AAung be tutong he e cet compod
theC
4
what ie
OH are 502 KJ mol and 427 KJ mol:1, Then
H20 and
7B. The bond enthalpy of
the average bond enthalpy?
a. 502 KJ mol
b. 464.5 KJ mol1
c. 427 KJ mol:1 (1)
d. 75 KJ mol:1
boiling point
formed in many compounds e.g. H20, HF, NH3. The
8A.Hydrogen bonds are strength of hydrogen bond and
compounds depends to a large extent on the
of such order of the boiling points of
number of hydrogen bonds: The correct decreasing
the
above compounds is
a. HF > H20> NH3
b. Hz0 > HF > NH3
C. NH3> HF > H2O
d. NH3> H20> HF
OR
correct from the view point of molecular
8B. Which of the following statements is not
orbital theory?
a. Bez is not astable molecule.
exist.
b. Hez is not stable but He+2 is expected to molecules
C. Bond strength of N2 is maximum amongst the homonuclear diatomic
belonging to the second period.
orbitals in N2 molecule is o2s < o*2s < o2pz
d. The order of energies of molecular (1)
< (T2px = T2py) < (r* 2px= * 2py) < o*2pz
valence shellelectronic configuration of 5s5p
9. In the longform of the periodic table, the
corresponds to the element present in:
a.Group 16 and period 6
b. Group 17 and period 6
C. Group 16 and period 5
(1)
d. Group 17 and period 5
IUPAC name?
10. Which of the following the correct
CH,
CH,- CH,-CH,-- CH - CH,- CH,
a. 3-Ethyl-4,4-dimethylheptane
b. 4,4-Dimethyl-3-ethylheptane
c. 5-Ethyl-4,4-dimethylheptane (1)
d.4,4-Bis(methyl)-3-ethylheptane
following options?
11.Which one is strongest acid among
a. CH2FCOOH
b. CHzCICOOH
c. CHCI2COOH (1)
d. CHF2COOH
In the following quostions (Q. No. 12.16) a statomont of assortion followod by a
statemont of roason ls givon.Chooso tho corroct anawor out of tho following cholcos.
a. Assertion and reason both aro corroct statements and roason is correct oxplanation lor
assertion.
b. Assertion and reason both are corroct statomonts but roason ls not correct oxplanation
for assetion.
c. Assertion is correct statement but roason is wrong statoment.
d. Assertion is wrong statomont but reason Is corroct statomont.
easily than primary
12.Assertion: Tertiary carbocations are generally formed more
carbocations.
due to additional alkyl groups
Reason: Hyperconjugation as well as inductive effect (1)
stabilise tertiary carbocations.
shape.
13. Assertion: Alkyl carbanions like ammonia have pyramid octet of electrons. (1)
carrying negative charge has an
Reason: The carbon atom
the highest value of first ionisation enthalpy.
14A. Assertion:Of all the elements. helium has enthalpy of all the elements
Reason: Helium has the most positive electron gain
OR
more energy than ionisation of
14B. Assertion: The ionisationof s-electron requires
p-electrons of the same shell.
p-electrons and hence are more
Reason: S-electrons are closer to the nucleus than (1)
strongly attracted by the nucleus.
15. Assertion: Boling points of cls - isomera aro highor than trans - isomer
Reason: Dipole moments of Cis 0somors aro bighor than trano loomor. (1)
16. Assertion: Energy of resonance hybrid is equal to the average of energies of al
canonical forms.
Reason: Resonance hybrid cannot be explained by a single structure. (1)
SECTION -B
17A. Asample of drinking water was found to be severely contaminated with chloroform,
CHCI3, supposed to be carcinogenic in nature. The level of contamination was
15ppm (by mass).
() Express this in per cent by mass.
(ii) Determine the molality of chloroform in the water sample.
OR
17B. (i) State Avogadro's law
(i) Calculate the number of molecules present in 22g of CO2 (2)
18.Calculate the molarity of NaOH in solution prepared by dissolving 4g in enough water
to form 25oml of solution.(Atomic mass Na = 23;O= 16; H= 1) (2)
19A. Yellow light emitted from Sodium lamp has a wavelength (^) of 580nm. Calculate the
frequency and wave number of yellow light.
OR
19B. List any two short comings of Bohr's model (2)
6
20A.
(ín kJ mol)
(4H,) 1onization enthalpies elements
The frst (4H)and the second enthalpy (in kJ mol-) of a few are
and the (A H) electron gain
given below:
Elements aH, AH,
520 7300 -60
419 3051 -48
1681 3374 -328
IV 1008 1846 -295
2372 5251 +48
VI 738 1451 -40
Which of the abOve elements is likely to be:
the least reactive element
b. the most reactive metal
C. the most reactive non-metal
d. the least reactive non-metal
OR
20B (i) State Modern periodic law. (2)
(i) Write the general electronic configuration of d - block elements.
21. (0) Write the favourable factors for the formation of ionic bond.
() Represent the resonance structure of CO32
(2)
22. Arrange the following in order of increasing radi:
(0) 02, N3,$2, F (2)
following compound?
23. What is the type of hybridisation of marked carbon in the
() "CH3CH=*CHCN
(ii) Define octet rule (2)
compound gave 0.12g
24. In Carious method of estimation of halogen, 0.15g of an organic
(atomic mass Ag =108,
of AgBr. Find out the percerntage of bromine in the compound.
Br = 80)
(2)
example for each. (2)
25. What are electrophiles and nucleophiles? Give an
SECTION -C
26A () Write the electronic configuration of Cu (Z=29)
have n+|= 3?
(ü) How many electrons in sulphur (Z=16) can
(ii) what are degenerate orbitals
OR
26B. (i) State Hund's rule
following quantum numbers?
(ii) Howmany electrons in an atom may have the (3)
(a) n=4, ms = - (b) n =3, |=0
7
27A.3gof H2 react with 29g of O2 to form H20(Molecular mass of H2=2.016)
o Which is the limiting reagent?
(i) Calculate the maximum amount ofH20 that can be formed.
(ii) Calculate the amount of reactant unused.
OR
27B. Acompound containing carbon, hydrogen and oxygen gave the following analytical
data: C=40% and H=6.67%. Calculate the molecular formula if its molecular mass is
180. (3)
28.(i) Define ionisation enthalpy ?
() Among the second period elements, the actual ionisation energies are in the order
Li> B> Be > C>O> N>F>Ne
Explain why (a) Be has higher AiH than B (b) O has lower AiH than N? (3)
29. (i) Define dipole moment.
(W) Dipole moment of NH3 (4.90 x 10-30 Cm) is greater than NF3 (0.8 x 1030 Cm)
Explain. (3)
30. () Give the condensed and bond line formula for the following
a. 2-methylbuta-1,3-diene b. Hexa-1,3,5-triene
(0) ldentify the functional groups in the following compounds
OH OH
C
HN cI
(3)
SECTION -D
31A.() Classify the following types of reactions
CH,CH,Br + HS ’ CH,CH,SH + Br
(CH,), C=CH, +HC] - (CH,), CIC -CH,
(ii) In which of the following compounds the carbon marked with asterisk is expected
to have greatest positive charge?
CH, - CH,-CI b CH,-CH, -CH,
(ii) Write the IUPAC name of
on
CH,-C-CH, -CH,-C-OH
b.
OR
31B. (i) What are functional isomers? give an example.
(i) Suggest a method of separation to purify
a. Amixtue of liquid A (b.pt 365K) and a liquidB (b pt 356K)
b. A liquid which decomposes at its boiling point.
(ii) Explain the principle of paper chromatography. (5)
32A.(i) State Heisenberg uncertainty principle.
() Agolf ball has amass of 40g, and a speed of 45 m/s. If the speed can
easured within accuracyof 2%, calculate the uncertainty in the position.
(üi) What will be the wavelength of an object of mass 0.1 kg moving with a velocity of
10 ms-1?
OR
32B. () What is Bohr's radius?
(i) Calculate the energy and radius of Bohr's fifth orbit for hydrogen atom.
(i) Calculate the wavenumber for the longest wavelength transition in the Balmer
series of atomic hydrogen. (5)
33A.(i) BFs has zero dipole moment although the B-F bonds are polar -give reason
(ii)Represent the structure of CIF3 and SFa
(i) Describe the hybridisation and shape of methane
OR
33B. (i) Define Bond order
(i) Using MOT Compare the relative stability of the following species Oz, O2*
(ii) What are the two types of hydrogen bonding and give example for each (5)
