Single Correct Question
Q-1: What is the value of rate constant and the time (minutes) required for the solution to become
optically inactive from the following data.
t/min 0.0 7.2 36.8 46.0 68.0 ∞
Rotation of polarized
light/degree 24.1 21.4 12.4 10.0 5.5 -10.7
Options
(a) k= 0.01119 min-1 and t= 105.4 min
(b) k= 3.2659 min-1 and t= 25.3 min
(c) k= 2.0659 min-1 and t= 10.2 min
(d) k= 1.01119 min-1 and t= 205.4 min
Single Correct Question
Q-2: The gaseous reaction
v1A(g) → v2B(g)
is first order with respect to A. It is studied at a constant pressure with a0 as the initial amount of A.
Which of the following expressions is correct about the volume of the system and the concentration
of A at time t . Where V0 is the volume of the system at t = 0.
Options
(a)
(b)
(c)
(d) None of these
Single Correct Question
Q-3: A compound A dissociated by two parallel first order paths at certain temperature
The reaction is started with 1 mole of pure ‘A’ in 1 litre closed container with initial pressure 2 atm.
What is the pressure (in atm) developed in container after 50 minutes from start of experiment?
Options
(a) 1.25
(b) 0.75
(c) 1.50
(d) 2.50
Single Correct Question
Q-4: A reaction can take place by two paths. k1 and k2 are rate constants for the two paths & E1 and
E2 are their respective activation energies.
At temperature Ta: k1 > k2, E1 < E2
If temperature is raised to Tb, the rate constants change to k1’ & k2’. Which relation is correct between
k1, k2, k1’ & k2’ (considering activation energy does not change with temperature)
Options
(a)
(b)
(c)
(d)
Single Correct Question
Q-5: A(aq) → B(aq) + C(aq) is a first order reaction.
Time t ∞
Moles of reagent n1 n2
Reaction progress is measured with the help of titration of reagent ‘R’. If all
A, B and C react with reagent and have ‘n’ factors
[n factor ; ] in the ratio of 1 : 2 : 3 with the reagent, then k in term of t, n1
and n2 is:
Options
(a)
(b)
(c)
(d)
Single Correct Question
Q-6: Some graph are sketched for the reaction A → B (assuming different orders). Where ‘α’
represent the degree of dissociation.
The order of reaction are respectively.
Options
(a) 0, 1, 2
(b) 1, 0, 2
(c) 2, 0, 1
(d) 1, 2, 0
Single Correct Question
Q-7: Which of the following plots is (are) correct for the given reaction?
([P]0 is the initial concentration of P)
P Q
Options
(a)
(b)
(c)
(d)
Single Correct Question
Q-8: For the following parallel chain reaction what will be that value of overall half-life of A in
minutes?
Options
(a) 3.3
(b) 6.3
(c) 3.6
(d) None of these
Single Correct Question
Q-9: For a 1st order reaction (gaseous) (constant V, T):
a A → (b - 1) B + 1 C (with b > a) the pressure of the system rose by % in time of 10
min. The half life of the reaction is therefore.
Options:
(a) 10 min
(b) 20 min
(c) 30 min
(d) 40 min
Multiple Correct Question
Q-10: Which is correct graph:
Options:
(a)
(b)
(c)
(d)
Multiple Correct Question
Q-11: In the following gaseous phase first order reaction
A(g) → 2B(g) + C(g)
Initial pressure was found to be 400 mm of Hg and it changed to 1000 mm of Hg after 20 min. Then
Options:
(a) Half life for A is 10 min
(b) Rate constant is 0.0693 min-1
(c) Partial pressure of C at 30 min is 350 mm of Hg
(d) Total pressure after 30 min is 1150 mm of Hg
Multiple Correct Question
Q-12: For the reaction 2A + B → C with the rate law and started
with A and B in stoichiometric proportion. Which is/are true?
Options:
(a) Unit of k is Ms-1
(b) [A], [B] and [C] all will be linear functions of time
(c) [C] = 2kt
(d) [C] = kt
Multiple Correct Question
Q-13: For the following reaction the rate of reaction is
Two moles of X are mixed with one mole of Y to make 1.0 L of solution. At 50 s, 0.5 mole of Y is
left in the reaction mixture. The correct statement(s) about the reaction is(are) (Use: ln 2 = 0.693)
Options:
(a) The rate constant, k, of the reaction is 13.86 × 10-4 s-1
(b) Half-life of X is 50s
(c)
(d)
Multiple Correct Question
Q-14: For a first order reaction A(g) → 2B(g) + C(g) at constant volume and 300 K, the total
pressure at the beginning (t = 0) and at time t are P0 and Pt , respectively. Initially, only A is present
with concentration [A]0, and t1/3 is the time required for the partial pressure of A to reach 1/3rd of its
initial value. The correct
option(s) is (are) (Assume that all these gases behave as ideal gases)
Options:
(a)
(b)
(c)
(d)
Integer type question
Q-15: For any acid catalysed reaction,
Half-life period is independent of concentration of A at given pH. At same concentration of A
half-life time is 10 min at pH = 2 and half-life time is 100 min at pH = 3. If the rate law expression
of reaction is r = k[A]x[H+]y then calculate the value of (x + y).
Integer type question
Q-16:
The rate of the reaction for [A] = 0.15 mol dm-3, [B] = 0.25 mol dm-3 and [C] = 0.15 mol dm-3 is
found to be Y × 10-5 mol dm-3 s-1. The value of Y is…….
Integer type question
Q-17: In the decomposition of H2O2 at 300 K, the energy of activation was found to be 18 kcal/mol
while it decreases to 6 kcal/mol when the decomposition was carried out in the presence of a catalyst
at 300 K. How many times is the catalysed reaction faster than uncatalysed one?
(Given your answer by multiplying 107)
Integer type question
Q-18: Consider the following reversible reaction,
A(g)+ B(g) ⇌ AB(g)
The activation energy of the backward reaction exceeds that of the forward reaction by 2RT (in J
mol-1). If the pre-exponential factor of the forward reaction is 4 times that of the reverse reaction, the
absolute value of ΔGƟ (in J mol-1) for the reaction at 300 K is ____.
(Given; ln(2) = 0.7, RT = 2500 J mol-1 at 300 K and G is the Gibbs energy)
Integer type question
Q-19: A reaction take place at 300K. When catalyst is added rate of reaction increases. Calculate
the change in temp (in °C) which would have same effect effect on rate of reaction as that of
catalyst. (Assume catalyst change the activation energy by 20%).
