MATERIAL SAFETY DATA SHEET
PIX 8100 Print Date: 4/16/2015
INK Page 1 of 6
1. IDENTIFICATION OF PREPARATION AND OF THE COMPANY
Radhe Enterprise
108,New Ravikiran
Complex,Shapar (veraval). Gujarat. INDIA
Emergency phone: 102 in India
or phone to the nearest Medical Facility.
Use of the preparation: Printing ink for industrial use
Release: 007 Issue Date: 12/08/2014
2. COMPOSITION/INFORMATION ON INGREDIENTS
Blend of pigmetns, additives and synthetic resin in organic solvents.
Components contributing to hazard:
N.INDEX CAS EINECS Conc
2-Butanone 606-002-00-3 78-93-3 201-159-0 60-80% F ; R11
Xi ; R36-66-67
Ethanol 603-002-00-5 64-17-5 200-578-6 5-20% F ; R11
1-butanol 603-004-00-6 71-36-3 200-751-6 1-5% F ; R10
Xn ; R22-37/38-41-67
Isopropyl alcohol 603-117-00-0 67-63-0 200-661-7 1-10% F ; R11
Xi ; R36-67
1-methoxy-2-propanol 603-064-003 107-98-2 203-539-1 1-10% F ; R10
3. HAZARDS IDENTIFICATION
Highly flammable. Irritating to eyes. Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness. Harmful to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
4. FIRST-AID MEASURES
Never give fluids or nor induce vomiting if patient is inconscious or is having convulsions.
Inhalation
Remove to fresh air if effects occur. Consult a physician.
Skin Contact
Remove contaminated clothing. Wash off in flowing water or shower. Remove residues with soap
and water.
MATERIAL SAFETY DATA SHEET
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Eye Contact
Irrigate with flowing water immediately and continuously for 15 minutes. Consult medical
personnel.
Ingestion
Consult medical personnel.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Carbon dioxide, alcohol resistant foam, dry chemicals.
Extinguishing media which must not be used for safety reasons
Water fog. Use it only in case of big fire.
Hazardous Combustion Products
Incomplete combustion may lead to the build-up of toxic pyrolysis products. Complete
combustion will result in carbon oxides, nitrogen oxides and water.
Protection of Firefighters
Wear positive-pressure self contained breathing apparatus and protective fire fighting clothing
(includes fire fighting helmet, coat, trousers, boots and gloves).
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
Wear adequate personal protective equipment, see Section 8, Exposure Controls/Personal
Protection. Spills may cause slippery surfaces.
Environmental Precautions
Dike to prevent contamination of ground and surface water, then transfer into closed containers.
Recover if possible, or dispose of according to applicable regulations.
Methods of Cleaning Up
Spills should be contained by, and covered with large quantities of sand, earth or any other readily
available absorbent material which is then brushed in vigorously to assist absorption. The mixture
can then be collected into drums and removed for disposal. Wash area from residues with soap
and water and rinse down. Contaminated water should be retained likewise, not being allowed to
flow into ground or surface water.
7. HANDLING AND STORAGE
Handling
Highly flammable: keep away from possible ignition sources. Use non-sparking equipment and
tools. No smoking allowed in handling and storage area. Practice care and caution to avoid skin
and eye contact. Avoid breathing vapours. This product is combustible and may constitute a fire
hazard if improperly used or installed.
Storage
Keep container tightly closed. Containers of product should be stored and opened in well
ventilated areas away from ignition source.
MATERIAL SAFETY DATA SHEET
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Storage Temperature and Shelf-Life
The recommended storage temperature is 15-25 deg.C. Storage stability for sealed containers is 15
months.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure limit values of containing substances:
ACGIH TLV-TWA TLV-STEL
2-butanone 200 ppm (590 mg/mc) 300 ppm (885 mg/mc)
Ethanol 1000 ppm (1880 mg/mc)
1-butanol 50 ppm (150 mg/mc)
Isopropyl alcohol 400 ppm (983 mg/mc) 500 ppm (1230 mg/mc)
1-methoxy-2-propanol 100 ppm (369 mg/mc) 150 ppm (553 mg/mc)
Engineering Controls
Provide general and/or local exhaust ventilation to control airborne levels below the exposure
guidelines.
Personal Protective Equipment
• Respiratory Protection
For most conditions, no respiratory protection is needed; however, if handling at elevated
temperature without sufficient ventilation or in presence of aerosol, use an approvated air-
purifying respirator.
• Skin Protection
Use impervious gloves. Wear clean, long-sleeved, body-covering clothing. After work and before
eating, drinking or smoking wash and clean yourself carefully with soap and water.
• Eye/Face Protection
Use chemical goggles.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Black
Odour: Ketonic
pH: 5-7
Boiling point/range (deg.C): not determined
Melting point/range (deg.C): <0
Vapour pressure (mbar at 20 deg.C): not determined
Vapour relative density (air=1): >1
Relative density (water=1, 25/4 deg.C): 0.84-0.88
Viscosity (cps Brookfield LVTD 25°C): 2-4
Water solubility (%): partly miscible
LogP (n-octanol/water): not determined
Volatile substance (%): not determined
Flash point/range (deg.C): abt. - 4
Auto-ignition temp. (deg.C): not determined
MATERIAL SAFETY DATA SHEET
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Flammability-LFL (%vol): 1.8
Flammability-UFL (%vol): 11.5
10. STABILITY AND REACTIVITY
Chemical Stability
Stable under normal storage conditions.
Conditions to Avoid
Keep away from ignition sources.
Materials to Avoid
Acids. Oxidising agents..
Hazardous Decomposition Products
None under normal conditions of storage and use.
11. TOXICOLOGICAL INFORMATION
In order to evaluate the toxic effects of this product, the level of concentration of each and every
substance must be considered.
Reported below there is all relevant toxic information concerning the main substances that form
the product:
2-BUTANONE LD50 oral rat: >2000 mg/Kg
LD50 skin: >2000 mg/Kg
LD50 inalation: >5 mg/l
ETHANOL None notice about toxic effects
1-BUTANOL LD50 oral rat: 0.8-4 g/Kg
LD50 skin: 4.2-7.6 g/Kg
ISOPROPIL ALCOHOL LD50 oral rat: >2000 mg/Kg
LD50 skin: >2000 mg/Kg
LD50 inalation: >5 mg/l
1-METHOXY-2-PROPANOL LD50 oral rat: >2000 mg/Kg
LC50 inalation: >5 mg/l
LD50 skin: >2000 mg/Kg
12. ECOLOGICAL INFORMATION
Use the product according to the instructions given in the Sheet; avoid realise to the environment.
Assessment largely or completely based on data for similar material(s).
MATERIAL SAFETY DATA SHEET
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Mobility
Solvents are partially soluble into water and their dispersion for evaporation or dissolution is very
fast.
Degradation
Material is expected to degrade slowly in the environment.
Aquatic Toxicity
Acute toxicity to aquatic organisms has not been determined.
13. DISPOSAL CONSIDERATIONS
Disposal
The generation of waste should be avoided or minimized wherever possible. Disposal of the
product must comply with current national laws or local rules.
14. TRANSPORT INFORMATION
Road and Rail
Proper shipping name: PRINTING INK flammable
Truck - ADR Loaded: 3 F1 Empty: II Label: 3
Rail - RID/RMP Loaded: 3 F1 Empty: II
UN Number: 1210
Sea
Proper shipping name: PRINTING INK flammable
Sea - IMO/IMDG Class: 3 UN Number: 1210 Label: 3
Packing Group: II EMS: F-E, S-D
Air
Proper shipping name: PRINTING INK flammable
Air - ICAO/IATA Class: 3 UN Number: 1210 Label: 3
Packing Group: II
Packing Instructions Passenger: 305
Packing Instructions Cargo: 307
15. REGULATORY INFORMATION
EEC Classification and User Label Information:
Classification according to the criteria of the EEC Directive1999/45
Hazard Symbol: F - Highly Flammable
Xi - Irritant
Risk Phrases: R11 Highly flammable.
R36 Irritating to eyes
R52/53 Harmful to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
R66 Reapeted exposure may cause skin dryness or cracking
R67 vapours may cause drowsiness and dizziness
MATERIAL SAFETY DATA SHEET
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Safety Phrases: S7/9 Keep container tightly closed and in a well-ventilated place.
S16 Keep away from sources of ignition - NO SMOKING
S25 Avoid contact with eyes.
S33 Take precautionary measures against static discharges.
S60 This material and its container must be disposed of as
hazardous waste
16. OTHER INFORMATION
List of relevant R phrases of section 2:
R10 Flammable
R22 Harmful if swallowed
R32 Contact with acids liberates very toxic gas
R36/37/38 Irritating to eyes, respiratory system and skin
R37/38 Irritating to respiratory system and skin
R41 Risk of serious damage to eyes
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment
Replaces SDS issued:
Release 06 issue date: 03/09/2010
Changed parts:
Sea transport classification based on IMDG code, edition 2004
Regulatory information:
2001/58/CE defines and lay down the detailed arrangements for the system of specific
information relating to dangerous preparations
67/548/CEE regulations and administrative provisions relating to the classification, packaging
and labelling of dangerous substances
1999/45/CE regulations and administrative provisions relating to the classification, packaging and
labelling of dangerous preparations
The information herein is given in good faith and to the best of our knowledge but no warranty,
expressed or implied, is made.
