A Chemistry Project on
“Study of Constituents of Alloy
Session: 2023-24”
Submitted To: Farheen sultana
Submitted By: <YOUR NAME>
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CERTIFICATE
This is to certify that <YOUR NAME> has satisfactorily finished
his investigatory project work under the guidance of their
chemistry teacher Farheen sultana in the chemistry
Laboratory of the school in the academic year 2023-24.
INTER EXAMINER INTERNAL EXAMINER
PRINCIPAL SIGNATURE
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ACKNOWLEDGEMENT
I hereby like to Gratitude to my school
authorities For suggesting and encouraging me
to undertake the project entitled “Study the
constituents of an alloy”. I would also express
my special thanks to the members of the school
chemistry dept. for supporting me.
Name: <Your name>
Class: XII(sci)
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AIM
GENERAL OBJECTIVE:
This project was carried out to gain knowledge regarding
alloys, their constituents and uses. The projects mainly
stressed on analyzing the alloys for their constituents and
appreciate the chemistry behind it.
SPECIFIC OBJECTIVE:
In this project the alloys, bronze and brass have been
qualitatively analyzed in order to find out their
constituents.
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Contents
1. Certificate
2. Aim
3. Introduction
4. Apparatus
5. Theory
6. Procedure
7. Observations
8. Declaration
9. Bibliography
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Introduction
Pure metals possess few important physical and
metallic properties such as melting point, boiling
point, density, specific gravity, high malleability,
ductility, and heat and electrical conductivity. For
many human needs
the extents of these
properties possessed
by these pure metals
don’t become much
beneficial.
Therefore to change
(or improve) the
properties, often
these metals are
combined with other metals or non-metals. This
process of mixing a metal with other metals or a non-
metal is called alloying and the resultant solid
solution obtained in the process is termed as an
Alloy. The constituent elements are combined in
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such a way that they cannot be separated merely by
physical means. More than 90% of the metals used
are in the form of alloys.
A List of Alloys, their constituents and uses.
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Alloys are generally made to:
Enhance the hardness of a metal: An alloy is
generally harder than its constituents. The pure
metals are generally soft.
Lower the melting point: Pure metals have a
high melting point. The melting point lowers
when pure metals are alloyed with other metals
or nonmetals. This makes the metals easily
fusible.
Enhance tensile strength: Alloy formation
increases the tensile strength of the parent metal.
Enhance corrosion and/or heat resistance: Alloys
are more resistant to corrosion than pure metals.
Metals in pure form are chemically reactive and
can be easily corroded by the surrounding
atmospheric gases and moisture. Alloying a
metal increases the inertness of the metal, which,
in turn, increases corrosion resistance.
Modify color: The color of pure metal can be
modified by alloying it with other metals or
nonmetals containing suitable color pigments.
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Obtain superconductivity: Some metals can be
alloyed in such a way that their alloy behaves as
a superconductor which is of high importance
in technological advancement.
Provide better castability: One of the most
essential requirements of getting good castings
is the expansion of the metal on solidification.
Pure molten metals undergo contraction on
solidification. Metals need to be alloyed to
obtain good castings because alloys expand...
Few examples of alloys are stainless steel, brass,
bronze, nichrome, constantan, crown gold, solder,
amalgam etc…which are used in soldering, super
conduction making utensils, mechanical materials
like screws and blots etc…
In this project, the chemical
compositions of two alloys
namely, brass and bronze
have been quantitatively
analyzed.
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A few other materials made of alloys
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Apparatus
1. Brass and Bronze pieces
2. China dishes
3. Filtration apparatus
4. Nitric acid
5. Hydrogen sulphide gas
6. Ammonium chloride
7. Ammonium sulphide
8. Dil. hydrochloric acid
9. Mercuric chloride
10. Potassium Ferro cyanide
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Theory
Brass:
Brass is an alloy constituting Cu and Zn. Both the
ions dissolve in 50% of nitric acid due
to the formation of nitrates which are soluble.
4Zn + 10HNO3 −−→ 4Zn(NO3)2 + N2O + 5H2S
3Cu + 8HNO3 −→3Cu(NO3)2 + 4H2O + 2NO
A small piece of brass is dissolved in 50% nitric
acid. After the removal of excess of nitric acid, the
solution is tested for Cu2+ and Zn2+ ions.
Bronze:
Bronze contains Cu and Sn. Their nitrates are
obtained by dissolving the sample in conc.
nitricacid. The nitrates are precipitated as a sulphide
by passing H2S through their solution in dil. HCl.
CuS is insoluble in yellow ammonium sulphide,
while SnS is soluble. The ppt. is separated by
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filtration. The ppt. is dissolved in conc. HNO3
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and then Ammonium hydroxide solution is passed
through it. Blue coloration confirms the presence of
Cu.
The filtrate is treated with conc. HCl followed by
Zinc dust to obtain SnCl2.
Then HgCl2solution is added. Formation of slate-
coloured ppt. indicates the presence of Sn.
Procedure
For Brass:
1. A small piece of brass was taken in a china dish
and was heated with a small quantity of 50% HNO3
so as to dissolve the piece completely.
2. The solution was heated till a solid residue was
obtained.
3. The solid residue was dissolved in [Link] and
filtered. Distilled water was later added to the
filtrate.
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4. H2S gas was passed through the filtrate. A black
precipitate of CuSO4 was obtained. The black ppt.
was separated and the filtrate was kept for testing the
presence of Zn2+ ions. The black ppt. was dissolved
by heating it with 50% HNO3. To this solution,
ammonium hydroxide solution was added. A deep
blue color appeared in the solution which showed
the presence of copper ions in the solution.
5. To test for the presence of Zn2+ ions: The filtrate
was boiled to remove H2S gas. Then NH4Cl was
dissolved in this filtrate by heating. To make the
solution ammonical excess NH4OH was added. Then
H2S gas was passed through this ammonical
solution. A dirty white or grey ppt. was formed. The
ppt. was then dissolved in minimum amount of dil.
HCl. The solution was boiled to expel any H2S gas
and Potassium ferrocyanide solution was added.
Bluish white ppt. was formed which confirmed the
presence of Zn2+ ions in the solution.
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For Bronze:
1. The sample was dissolved in 50% HNO3 and then
heated to obtain nitrates
2. The nitrates were dissolved in dil. HCl and then
precipitated as sulphides by passing H2S gas.
3. The precipitates were treatedwith yellow
ammonium sulphide when a part of it dissolves. The
soln. was filtered.
4. The ppt. was tested for Cu as in the case of brass.
5. The filtrate was treated with conc. HCl followed by
Fe dust.
6. Then HgCl2 soln. was added. Formation of a slate-
colored ppt. confirmed the presence of Sn.
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Observations
The following were found to be the
constituents of the alloys which were
experimentally analyzed.
Alloy Constituents
Brass Zinc, Copper
Bronze Tin, Copper Toy of an
Alloy,
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Bibliography
List of alloys. - [Link]
[Link]/wiki/List_of_alloys
Alloys and their purposes. - [Link]
[Link]/reference/46877/2
03279/purpose-of-making-alloys
NCERT Chemistry - Class 12.
Comprehensive Class 12 Chemistry Practical’s.
Alloys And their properties – [Link]
[Link]/[Link]
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