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ORIGINAL PAPER
Received: 22 August 2010 / Accepted: 10 May 2011 / Published online: 25 May 2011
Springer Science+Business Media B.V. 2011
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760 Geotech Geol Eng (2011) 29:759–769
flocculation agglomeration reactions take place rap- 2005; Sezer et al. 2006; Prabakar et al. 2004; Basha
idly bringing immediate changes in soil properties, et al. 2003; Muntohar and Hantoro 2000; Kalkan
whereas pozzolanic reactions are time dependent. 2009; Basha et al. 2005; Rahman 1986) observed that
These pozzolanic reactions involve interactions soils treated with cementing additives show an
between soil silica and/or alumina and lime to form increase in optimum moisture content and a decrease
various types of cementation products thus enhancing in maximum dry density. Furthermore, the studies
the strength. (Sezer et al. 2006; Kolias et al. 2005; Senol et al.
The studies reported in the literature show that the 2006; Basha et al. 2005) indicate that the strength of
addition of lime increased the optimum moisture soils can be improved by addition of such cementing
content and strength, and reduce the plasticity index additives.
and maximum dry density of the soil (Guney et al. On the other hand, cementing additives react with the
2007). lime more effectively than alone. The efficiency of lime
Several investigators (Al-Rawas et al. 2005; stabilization may be greatly increased. Some investiga-
Goswami and Singh 2005; Rahman 1986; Muntohar tors (Goswami and Singh 2005; Muntohar and Hantoro
and Hantoro 2000; Attoh-Okine 1995; Nalbantoglu 2000; Bagherpour and Choobbasti 2003) found that
2006; Lasledj and Al-Mukhtar 2008; Osula 1996; Ola workability and strength behaviour of soft soils were
1977; Bagherpour and Choobbasti 2003; Kavak and greatly improved after a combined treatment.
Akyarli 2007; Manasseh and Olufemi 2008; Bell Hossain et al. (2007) utilized volcanic ash (VA)
1996; Okagbue and Yakubu 2000; Ansary et al. 2006) from natural resources of Papua New Guinea. Several
found that in most cases the effect of lime on the tests of compaction and unconfined compressive
plasticity of clay soils is more or less instantaneous. strength have been conducted for studying the
The works reported by several researchers (Ola influence of volcanic ash, finely ground natural lime,
1977; Rahman 1986; George et al. 1992; Bell 1996; cement and a combination of ash, cement and lime. In
Gay and Schad 2000; Hossain et al. 2007) indicate that term of compaction, the results showed that maxi-
soils treated with lime experienced notable increases in mum dry density decreased and optimum moisture
optimum moisture content while undergoing a content increased as VA content increased for both
decrease in maximum dry density. In addition, some soils tested. The combination of VA, lime and cement
investigators (Lin et al. 2007; Chen and Lin 2009) exhibited the same behaviour. On the other hand, the
postulated that failure behaviours similar to brittle compressive strength increased with the increase in
materials were observed in shear failure mode for soil curing time and VA content for both soils tested. For
specimens stabilized with lime. Moreover, some example, with a 20% volcanic ash content they
researchers (Ola 1977; Rahman 1986; Attoh-Okine observed an increase of 31 and 19 times compared
1995; Hossain et al. 2007; Manasseh and Olufemi with both tested untreated soils respectively after
2008) found that the strength behaviour of soils was 91 days of curing. In mixed mode of stabilization,
greatly improved after lime treatment. stabilizer combinations (VA, lime and cement) with
In recent years, industrial by-products have been higher dosages produced higher compressive
added and mixed with soft soils to improve their strength. For example, with the combination of
engineering properties. The improved characteristics 10%VA ? 4%L that both tested soils represented
of soft soils, resulting from the utilization of an increase of 10–21 times respectively compared
cementing additives like fly ash, rice husk ash and with untreated soils. But, apart from the study of
silica fume, bring about environmental and economic Hossain et al. (2007), the effect of the combination of
benefits. The effectiveness of these by-products for natural pozzolana (volcanic rock) and lime on soil
stabilization of soils has been investigated. The stabilization is not well documented in the literature.
addition of such materials reduced the plasticity Natural pozzolana is found abundantly in exten-
index (Parsons and Kneebone 2005; Goswami and sive areas of Beni-Saf quarry in the West of Algeria
Singh 2005; Kolias et al. 2005; Nalbantoglu 2004; (Ghrici et al. 2007). The use of natural pozzolana in
Basha et al. 2003; Basha et al. 2005; Rahman 1986; association with lime for the stabilization of cohesive
Muntohar and Hantoro 2000). In term of compaction, soils needs to be investigated. As the soil is a good
several researchers (Senol et al. 2006; Kolias et al. source of alumina, the effects of lime treatment can
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Geotech Geol Eng (2011) 29:759–769 761
be enhanced to a great extent if the apparent shortage West of Algeria. The NP was ground in a laboratory
of silica can be adequately supplemented by the mill to a specific surface area of 420 m2/kg. The
addition of natural pozzolana, which is high in chemical composition of NP is presented in Table 2.
reactive silica content. However, the literature indi-
cates only very few investigations on soils stabiliza- 2.1.3 Lime
tion in Algeria.
This paper presents the results of the effect of The lime (L) used was a commercially available lime
lime, natural pozzolana and their combination on typically used for construction purposes. The chem-
Atterberg limits, compaction characteristics, ical and physical properties of lime are presented in
undrained triaxial shear behaviour and unconfined Table 3.
compressive strength of two Algerian cohesive soils
classified as CH and CL according to the unified soil 2.2 Laboratory Tests
classification system (USCS).
A series of laboratory tests consisting of Atterberg
limits, compaction, shear strength and unconfined
2 Experimental Investigation compressive strength were conducted on the two
selected clayey soils. Extensive combinations of
2.1 Materials Used natural pozzolana and lime were used for stabiliza-
tion of the two soils. The percentages of NP were 0,
2.1.1 Soils 10, and 20%, while the percentages of the lime were
0, 4, and 8%. A total of 18 combinations based on soil
The soils used in this study were obtained from a site 1 and soil 2 with single and mixed modes of
situated near Chlef town West of Algeria. These clays stabilizers were studied (Table 4).
were encountered at a depth of about 4–5 m.
Laboratory tests were carried out to classify each 2.2.1 Atterberg Limits Tests
type of soil. The engineering properties of clayey
soils are presented in Table 1. Plastic (PL), liquid (LL) limit and plasticity index
(PI) were obtained following the method given in the
2.1.2 Natural Pozzolana ASTM D4318 (2000). Variations in the plasticity
index of untreated clayey soils before and after
The natural pozzolana (NP) used in this investigation admixtures added were then studied. The air dried
was collected from a quarry at Beni-Saf region in the soils (passing the N 40 sieve) were initially mixed
Table 1 Physical characteristics of the soils Table 2 Chemical composition of natural pozzolana
Basic characteristics Soil 1 Soil 2 Chemical composition Natural pozzolana (%)
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762 Geotech Geol Eng (2011) 29:759–769
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Geotech Geol Eng (2011) 29:759–769 763
P0L0 52.02 24.56 28.3 13.8 15.3 16.9 0.06 0.06 0.06 0.09 0.22 0.22 0.22 0.28
P0L4 21.47 22.63 30.4 13.2 17.8 16.4 0.27 0.57 1.03 1.95 0.33 0.48 0.69 2.11
P0L8 19.92 19.68 31.1 12.9 17.4 16.2 0.28 0.52 1.05 3.04 0.40 0.46 0.72 1.80
P10L0 52.99 17.41 27.6 14.0 14.3 17.1 0.05 0.07 0.08 0.13 0.25 0.25 0.27 0.37
P10L4 19.76 17.76 26.8 13.3 16.6 16.5 0.43 1.00 1.88 3.18 0.66 1.16 2.05 3.90
P10L8 19.25 20.64 29.8 13.3 17.7 16.1 0.35 0.88 1.74 4.69 0.66 1.10 2.00 4.75
P20L0 46.03 17.39 25.8 14.3 13.8 17.1 0.07 0.10 0.10 0.19 0.25 0.26 0.28 0.48
P20L4 20.15 18.03 29.0 13.6 18.7 16.4 0.41 1.11 1.66 2.45 0.87 1.63 2.89 4.70
P20L8 20.23 20.31 28.2 13.6 18.2 16.0 0.46 1.42 2.62 5.38 0.83 1.68 2.78 5.97
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764 Geotech Geol Eng (2011) 29:759–769
index compared to the use of the lime alone for the of either lime alone or lime combined with natural
grey soil. For red soil, the combination of 4%L ? NP pozolana. The addition of natural pozzolana alone
shows a similar decrease in plasticity index as that of results in a soil classified within the range falling
natural pozzolana alone. However, with high lime between a CL class and an ML class.
contents in the combination, the plasticity index The modification of the plasticity characteristics of
increases compared to natural pozzolana alone. the grey and red soils caused by the addition of
The consistency limits test results were plotted on natural pozzolana and lime is likely to render these
the Casagrande plasticity chart in order to determine soils satisfactory for most construction operations
the soil classification according to the unified soil even under severe environmental conditions such as
classification system (USCS) (Fig. 2). It is clearly rain.
seen from Fig. 2 that for the grey soil classified as CH
class clay, falls in the class of MH soil after addition 3.2 Compaction Characteristics
of a proportion of lime/or lime and natural pozzolana
except for the natural pozzolana alone. The compaction test was used to determine the effect
Similar trend was observed for the red soil of stabilizers on maximum dry density (MDD) and
classified as CL class, as it passes from CL class optimum moisture content (OMC). Fig. 3 shows the
clay to MH class soil after stabilization with addition effect of the addition of natural pozzolana (NP), lime
60
Grey soil
Lime U-line
50 NP
Soil+NP+4%Lime CH
Plasticity Index, PI(%)
Soil+NP+8%Lime
40 Soil+NP+10%Lime
A-line
30
20
CL
10
CL-ML ML or OL MH or OH
0
0 20 40 60 80 100
Liquid Limit, LL(%)
(a)
60
Red soil
Lime U-line
50 NP A-line
Plasticity Index, PI (%)
Soil+NP+4%Lime
Soil+NP+8%Lime CH
40 Soil+NP+10%Lime
30
20 MH or OH
CL
10
CL-ML ML or OL
0
0 20 40 60 80 100
Liquid Limit, LL (%)
(b)
Fig. 2 Location of untreated and treated cohesive soils in a Fig. 3 Variation of compaction characteristics of stabilized
plasticity chart. a Grey soil. b Red soil soils: Full line grey soil and dashed line red soil
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Geotech Geol Eng (2011) 29:759–769 765
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766 Geotech Geol Eng (2011) 29:759–769
Fig. 5 Stress-Strain relationships of UUU tests for the Fig. 6 Influence of stabilizers on unconfined compressive
untreated soil specimens with different proportions of stabiliz- strength. a Grey soil. b Red soil
ers when effective confining pressure was designed at 50 kPa.
a Grey soil. b Red soil
It can be seen from Fig. 6 that the addition of lime
Similar stress–strain relationships at the confining increases the compressive strength of stabilized soil
pressure of 50 kPa are illustrated in Fig. 5. The specimens. The compressive strength increases with
maximum shear stress is given by both samples of the increase in lime content from 0 to 8% for both
soils stabilized with lime alone and combined with grey and red soils. This increase is in agreement
natural pozzolana. Moreover, red soil specimens with earlier findings (Ola 1977; Rahman 1986;
exhibited a significant increase in shear stress com- Attoh-Okine 1995; Hossain et al. 2007; Lin et al.
pared to grey soil specimens. Maximum shear 2007; Manasseh and Olufemi 2008). This is attrib-
strengths are observed for clayey soils stabilized uted to soil lime reaction, which results in the
with a combination of natural pozzolana-lime com- formation of cementitious compounds that binds soil
pared to those stabilized with lime or natural particles together. In general, compressive strength
pozzolana alone. increases with increasing curing age. The grey soil
gave higher compressive strength than red soil. For
3.4 Unconfined Compressive Strength example, with 8% lime content, grey soil developed
an unconfined compressive strength of 3 MPa after
The trend of changes in unconfined compressive 90 days of curing which represented an increase of 33
strength (UCS) with various percentages of stabiliz- times compared to untreated soil. For red soil and for
ers for grey and red soils is presented in Fig. 6. the same lime content and curing, the soil developed
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Geotech Geol Eng (2011) 29:759–769 767
an unconfined compressive strength of 1.8 MPa lime and natural pozzolana will result in lower
which represented an increase of 6.3 times compared construction cost. For example, if stabilisation with
to untreated soil. 4% of cement for a high moisture content soil is
In contrast, the addition of natural pozzolana replaced with a mixture of lime (4%) and natural
slightly increases the strength for both grey and red pozzolana (20%), and assuming an average price for
soils. For example, with a 20% NP content both grey one ton of Portland cement, lime and natural
and red soils show a marginal increase of 2 times pozzolana of 80 €, 50 € and 5€ respectively, the cost
compared with the untreated soil after 90 days of reduction on materials could be about 20%.
curing. However, Hossain et al. (2007) observed,
after 91 days of curing of two untreated soils (S1 and
S2), an increase of 31 and 19 times, respectively
4 Conclusions
when 20% volcanic ash was used.
Stabilizer combinations with higher contents pro-
This study presents the effect of natural pozzolana,
duced higher compressive strength. It can be seen that
lime and their combinations on Atterberg limits,
at 90 days and with a combination of 10%NP ? 4%L
compaction, shear strength and unconfined compres-
for grey and red soils represented an increase of 34 and
sive strength of cohesive soils. On the basis of the test
14 times respectively compared with both untreated
results, the following conclusions can be drawn:
soils. Hossain et al. (2007) observed that the combi-
nation of 10%VA ? 4%L for both S1 and S2 soils • The plasticity index decreased with increasing
represented an increase of 21 and 10 times respectively lime contents. Moreover, when both natural
compared with both untreated soils. Also, it can be pozzolana and lime were added to the cohesive
noted that at 90 days, the combination NP ? 8%L soils, an appreciable change of the plasticity
produced higher compressive strength for both grey behaviour was observed. However, the addition of
and red soils. For example, with the combination of natural pozzolana has a minor effect on the
20%NP ? 8%L, grey soil developed an unconfined plasticity index of the grey soil. Both grey and red
compressive strength of 5.4 MPa after 90 days of soils tend to change according to the unified soil
curing which represented an increase of 1.8 times classification system. The use of lime alone and
compared with 8% lime alone and 58 times compared the combination of natural pozzolana-lime, trans-
with untreated soil. For red soil and the same combi- formed grey soil (CH) and red soil (CL) into MH
nation and curing age, the soil developed an unconfined class soils.
compressive strength of 6 MPa which represented an • The maximum dry density of lime stabilized soils
increase of 3.3 times compared with 8% lime alone and decrease with increasing lime content, in contrast
21 times compared with untreated soil. with natural pozzolana stabilized soils. The
Finally, for both soils, compressive strength combination lime-natural pozzolana increases
increases with increasing curing time and stabilizers the maximum dry density for grey soil and
content. The natural pozzolana- lime combinations decreases that of red soil. On the other hand, the
produced higher strength than stabilization with lime optimum moisture content of lime stabilized soils
alone or natural pozzolana alone. Therefore, natural increased with the increase in lime content, in
pozzolana cannot be used solely for soil stabilization. contrast with natural pozzolana stabilized soils.
However, lime stabilized soils can be intensified by The combination lime-natural pozzolana
adding between 10 and 20% of natural pozzolana. decreased the optimum moisture content for the
The better performance of natural pozzolana-lime grey soil and increased that of the red soil.
combination stabilized soil can be attributed to the • The failure modes were similar to that of brittle
pozzolanic properties of the mixture and to the materials for both soils stabilized with lime or
utilization of readily available silica and alumina with a combination of natural pozzolana-lime.
from natural pozzolana by the calcium from the lime Furthermore, maximum shear strengths were
to form cementitious compounds which binds the soil observed for samples stabilized with a combina-
particles together. Since lime is more costly than tion of natural pozzolana-lime compared to those
natural pozzolana, the use of a combination of both stabilized with lime or natural pozzolana alone.
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768 Geotech Geol Eng (2011) 29:759–769
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