Nationa Insil 47echrolog, Raipu

Chemust ra chic
noduthm
2o20-20-1

Name-H: Anshud
Banth- Meelhan cal ginuu
KoLlNa- 20 l19032
(Sec-T
uoed ly
.TMahanana Mam
 NTRoDUCTIoN To CHEMTCAL ANALY STS

Chemic Analis

Qualitative uanh tate Anal yis

Analy
vou melM Cqgamimenc Cuomatoqopic Spetto
)
(seperahim)
L
Aui dl Bae Qd ox
Pccipttie Comple xonehn -fta duay)
C c athm)

Pmaraans mua comthic Lodom ttn Cei e&n

(umnDr) CTode (Cous f¢an
 Exp.eumenl No-
AA 9 Cchpen t om

O8JECT Pucentage Conpohtin a

ivtn mintuu oMa c ane aelt, 2 gm 4 ohch
clusolved pen uK tht Solvend
APfARATUS Burtile, Piutle beakns y Conu'eal 3lask.

THEORY foy he hahon oNhw HCL, miX tUL Solutim

aCl f Na o , 04he Sol neeele4 U N H Soluh 'n
h bse lompontnt uoill Jua ctEwih Ae atcl_sof
toom a
in twe so| and aud Sol" oil! be Hbalsel and n
hu way we Can det umina t ndrm au'G Nady ancd htn t
Sheng l Can be dekamineof B Subfoa ting thi Strg
Sting
Naby m te totad Stbungt sol Canind
ROCE pURE: )Rinse Hhe wsked b u c t with i v n Ha
Take HC sol inte buretle t nou iw h'af
aqiy-
3fipc oul2omd iven mintu 8ol in h
Clean Cen'cad blask.
Adel adaop 4phenolph|halein to cbsv
Sol u i m
S)Ass eon ag the £oluh'm chang esom pink
Colou less,st+op tuthe a dedut'n t HCI &oD
and nolu mad uadung t rly sal
BSERvATI ON TAB LE

Vo/um Concrdans
S N ' v n mintue heading
Triti ml
20 5 3 VS 2
2) 20 S2
20 S2
CALCU LA TIoN
Normoli L t the HeI sol " Ni = N =

Vo mwtule takin hor Hbahon 20md ()

AS pe the a Lquvalm e
NV N22
Aud
NV = NX 20
S 2
Na = 0 0026
2000 2000

SthCngth of Naoy Mormalt ty Eg, hlr

=
Naoy
0 0016x t0 = Olo + 3n/L
Amoun Naou 0 1ot gmL =

Amoun Na
(2-o 10t) gmll 89C gnfL
New p tenlat Naou= O 10T ¢|Uo - 5:21.
2
Per unt age acl= :894x I = 987.
2
 pen ment Na-2

AIkalin'
O0JECT To dilz mine Uh ulkalin y 6ain
Sample a l i by uw'ng o ydochlmcaud
Soluh'm an d mithy1 ovang e and phenolph thl un
asindicatdys
REAUE NTT haln Sanpu, uydothlmc cuu'd coin 1o

Phenol phthalitn noli cceter, muty ang e

OBSERv AT I on\ TABLE:

ittm btt" givtn walin sampu ond MD
H Ssh

Buretle nau
Volunn Cnced ant
L volu m e ( m
S
d Ca mple
t a kcu
L) enolpth-
uthyl M
al e'n'

S4
6 IS 2
f2
2 9S
3
9:S S2
Koll No-209o32 Sub hemut
Dhunatphthal e'n Anol pr- 9. U)
No en
spt= IS: 2 m(
Let v3 V -y = S*m
VaV
Akaliniy is clu to bo f ouu
20 m waln Sampu eq 35 m N u
i phtnol sLthal ei'n indi a t
T

r t Hx1o r SDxtUDo ppM Ca ls e =22+S prm

C3 e4
AyD, 2 0 m wau sampu Conta'h IS2ml o
d ndu' cattr
2 0 x NM =1S*2*_L

3
f PM Cole e

n P>M 8ott ou4 s2 puent

Alauiuly u +o ou 2f-M
2 234 S - 3 D
S rM

AIKiiby due e ( 2N-)

= 2 3-237S
2oS prm a 3e q.
 Expeaimunt No i )

fe dox 7it«tiom(Pamang a nomety)

O8TECT seng ous ammou'um Sulphali Sol"
s h u s o Z4 owt te etngth a i'vcn
unknousn fcnous Sulphall solutim n ac'ds' modium
mby
4ibatt aq any- potfajium pmangaf 8o lut ay a
ite &ds'al
REAGNIS Fenous Suphal Sol" dulul Sphusc
Stndad FAS, A Krineq ", luHluol uwalen
OBS ERV ATTON TARLE
itatim beuden kNnoq- anmd FA S SolD
Buxu
Volume ok
Ret d'ng ny Volu me 4
FeSay-(NS4 6¥0Tnti n
Takon n )
0 19-
2 2o
2

Velum ob Burmue
ngty
Volum
eao
No Fsep3 o Takn nitial Fina! mno ud

2 o O0S
3 20 610'
CALCULATTON
Accer dug to laLo o e urvals n es
NV N2 V2
Vslumu FAS ssluhim Vo} um kMne4 use o,N Nomal
FAS N 2 Nomad 19 =

bMn*4 So |uhm
Lxo = N2 x1°.4

L2o N

Fos Fes Oq 4420 " Nmaiy ( )

ACCo el t eguvaln u

N2V2 NaV3
(KMno+) =

N3= N2V = O 0! x2 o

to s

Na 0 0 21
Shan Feus s Sulphall e Nlomal itj t esopM2d X
2qwivalunl- we'j he
O 021 278
S8 3 8/L
 Frpem
m u No 30
OBTECT Stngt uow ammovium &phalI So u N/o
To det um'ne h Stnu in unknousn
frous
Sulphali Sol" u au'cuc me olum ujind
an mt unoll al Sol" and N rhinyl anthran'lic aud a
ineucatr

Appotw Buretle,piptle, tonital Ak

Reag eny Diluli phune au'd, No frow amnanum
sulphat Se, pottasium clt'chromali, fee w

3ulpbes ol and N-pu nyl anthanili'c aud

O BSERVAT ToN ABIE (ition Leth Knoa and (Nhesoq}

S Volum k Byet aou'*g/o/um

ML)
fCma ug
No Cons uneu
S talTruhal
C)
99
O
19.8
19.&

Titah'n Leth Fim0q and unk noug o 4 tatun y

Buttu adiy /lu
S Volume
No saln ih Ama Lon ume o

164
6 2
6 2
CALCULATToN
NV N
Oh e
N Hmalily b korus amm Sulphalit
Voume
enwamm &ulplle So |1
N Noy m
adiy t k22 a
Volumu r qulnl 19 8
NV = N2V2

SI9 ] 0 011

N2V2 Na V3
N3 N2V2 O 0101 x 20

16 2
-00125
Sheng E o 420 =
Na x 2K
001 2X 2H
3 43S 8m] lihe .

Res Tu sheny t 1 un un
ferrous Sulpkau SolD Z»4a5 9m]
 Ex PE RT MENT No 4
FARDNES DETERMI NATION ( ComPLE Xo METEy)
O83ECL: Molam EPTA Sol u 01M To delumu'ne
fefa,Hcmpora and pumantn- haue nuy wcltnE
Samplt y co mplecxonctacEDTA tthatim M ths d usina
EioChome Bla ch-1 as inclitatr.
REAENNTS hlaliu Sampll, Ethyltnn Diamw Ttha Auhic Acu e
Solutim Buke Solutim ok f 8 -1, Eviohrome
Blak T
(EBT) indicater
TREORY: H Ydnu ú te Char
a cteistic li oih
preven latheing rom Soap
2 Tha e Sal U O hen c a cls o1 Soap Ce e
ohii
prupitatim in ad zomng eathu
CaMc) + 2(Uzrtoonta-
So dium 8era) 2Ng lo 2
Calcuum slera
Ml2t2(4UgloNg ( CaUrtw)Ma t
2Na

461 heraly h u ne ttos g

CrRogra
pe
i um
taid nuw
sbralt
Oalin
Tempory ttaudney ond peumament tudnu
Tempray hauclns u Cayedby tt putnt b-Calb-
Ohali sal, whith CoLn be su moved nplyy boiling
Ca ( ) , - A > C ( t u,3 + CozM

enmanu nl- hau d nu ay es mainy alue fo Chler'sle

On Sudp hau S l oich Cannot be emord
boli On lanly
 M O
e
CU U2

M-Ee (ompl

-M=NN-

R - E BT
Bue
M M- E D1A

(Colous )
BSE RVATTON 1AGLE
i t atm bet" hard uooiN sampu t Mheo p1A Solutn
&Na BueRli
ntid ino
Contrd ant
Reacu
26

2D

ibalim betwun bos oali Same E P T A Sdluti

vol
vol d ha Ru adi Con crd a nd-
SMo gal tthen niti od had Radtn
20

2
 ROCEpUFF Dekminatim 1ta ludresy
y 6lass Lo aLe eLL oahed on inNed hoogtuy o r h
an
ou'sHlLt e
2 0 ml_ had uwalin Samplu 9aSpipelt e outo
Con ce lsk
3 The above sol" uoas titalid gu'nl-FbIA Sa" 1itl calou
Chang ej fo blu
Detamnatim 4 Peamantnt Hau olnes
1 2.om4hud oalin Sampu oy P1ptR ou to
Conu' Ca Zlask
2 he above Sal" oas tifalio ag auns-EDIA Sa1n till
Colou Ch anger to lue.

CALCULA TTorN ttal kadny

pen t h e Las equvaunu
MV MV
MX26 00Iy 9.s
M 00I X 2 00 t M
2
fetu haLdnus ounknoen walin Samplu
MX Ca Mal L lod
M l o o x looo PfM z 00+*S xpo
( o6

PTm4 nen harolnuy

ASpe aw c egwva no
Mi MaV2
ME 001 x o - O 0f M
20
Pemannt
hoou
MX Ca Ce Mol' ot x Io6
oO x jo0 xIVno feM= 460 P fM

e n o r a y Ha c nuy Tod Haudn -Pumanint had uu:

reM
 peimont No -6
lardnus deerminati'n (bomploxomy)

ng th 4 EDTA IO To clutmin1 t h ea ond

M haeinuyd e gitn \uu Sam by E0A Titedtim

Metho using £nochone. Black T noPaton and Reud eá
as n oll Catr

REag eng 8
24 n Diamu Tetbu hcuht a dd (EDTAJ Fol ut n

n)Bu4fer 8oln dr PHi-10, ao coma Rl«tk T

ndtcatPatton an d Reel ens 1nducatr
ObseNation tale

But
8 NoVo_hand olun
aui tken (n) ThFino
20 &.9
2 20 O

vol um e volu
Taken (m) Truh'al Pha A d(d
2 6
20 2
3 h
 Cal cul ath' om
M= Mol emyK uooLl
VI= Volumi w a Sangu taktm
M2 Molam ij q- EDTA Soluhen
2 Volume dEorA u d in Soluhiom

(AFortotd hady
AS pet h law Eqwmltn ce
MV M2V2
lalin) EOTA)
HX20 = D1xV,

M, ro = 0:01 xlF2
M, O01 xlt c0 00 93S M
20
Tota tHavdnsy wali Sample- MI X Ca C9 Moux loo o

93 SPeM
f Ccaum laelnuj
M2
o01x 12S Ma X2
Mg Oo1x12 =°0o6yM

Cal aumftarhay= M3 X GCa Mal o-x /ood

2 o 0061xI0ox loo 0 2 62rPe M

nagnet un tlardy ="|etltndn ('al uumtlard nuy

(93S-6 frm =31o Pem
es u OTd tadney= 935fem
C o l ti un tardny = 6 Yrem

(7 Mag ny tum ttard ney = 3lo (rM