Chemistry - 2014 a4. Coordination number of a particle in body controd ible packing|s (a) 4 (0) 6 (©) 8 (a) 12 ans. (€)8 Q2. The value of order ofa reaction can bo (3) avo (b) -vo (c)_ fractional . (d)Allof these Q3. Forachomical reaction A+B itis found thatthe rato of reaction does not change when the concentration of A Is doubled. The order of action with respect to Ale (4) allof these. @ 4 () 2 (@)_zero (@ 3 Ans. (c) Zero {Q4. Which of the following is a lyophobic colloid? {a) Gelatin (b) Sulphur (c) Starch (4) Arabic gum. ‘Ans. (0) Sulphur ‘ 5. Which of the following ores is concentrated by froth floatation process? ‘ (a) Hematite (ce) Gopper pyrite ‘Ans. (6) Copper Pyrite G5. White of the followings the least stable hydride? + (b) Magnetite {d) Bauxite. (a) NH, (o) PH (c) AsH, (d) SbH,. ‘Ans, (6) SdH, Q7. Oxidation number of Crin Cro? is (a) 4 (<6 e) 6 (@ 7. Ans. () 8 a Q8, Which of the following is an ambidentate ligand? (a) H,0 (&) NH, (eNO; (Br Ans. (¢) NO; (Very Short Answer Type Questions) - 8. Write down the structural formula of a primary alky! halide. 2 1 Ans. R-C—X or 1 H .[Link] alcohol on oxidation gives which compound? ‘Ans, Ketone Q.t1,Write down the [Link].C. name of PhCH,CH,COOH ‘Ans, 3-Phenyl Propanoic acid [Link] I the hybridization of Nin RN. ‘Ans. SP” [Link] down the namo of hydrolysis of lactoso. ‘Ans, B-D-Galactose and B:D-Glucose or, Galactose and Glucose [Link] of Nylon-66. ‘Ans. Hexamothylone diamine and Adipic acid [Link] a hypnotic drug. fans, Veronal or amyl or luminal or seconal or valium. (Short Answer! Type Questions) . @.[Link] does molar conductivity change with concentration in the case of the product obtained on )) strong electrolyte? ~() weak electrolyte ‘Ans, (i), In the case of strong electrolyte, molar conductivity 4 increases slowly with dilution. (Inthe case of weak electrolyte, molar conductivity increases rapidly with dilution. 0.17. Whatis the difference between roasting and calcination? Calcination Calination is a process in which ore is converted into metallic oxide by neatng below its m.p. either in absence of air or in limited supply ofait. Ans. Roasting Roasting is a process in which ore ie converted into metalic oxide by heating strongly below its m.p. in the presence of excess of air. [Link] balanced equation of the following: |, 4NaCIO, > |, +Na,S,0, > ‘Ans. |,+NaClO, > 2NalO, +Cl, |, +Na,S,0, -> 2Nal+ 2Na,S,0, 0.19. What happens when aqueous ammonia reacts with (Mercury (!) chloride (i) Mercury (Il) chloride? ‘Ans. ()) “When aqueous ammonia reacts with mercury (1) chloride gives black finely divided mercury alongwith mercury amino chloride. Hg, Cl, +2NH, -» Hg(NH,)Cl+Hg +NH,Cl (i) When aqueous ammonia reacts with mercury (II) chloride give white precipitate of mercury amino chloride, HgCl, 1 2NH, > HgiNH,)Cl+NH,CI Q.20.())_ What are transition elements? (il) Why do transition elements show variation in oxidation number? d-biock elements with incompletely filed d- inground tate ern ine common ongation state are called transition elements. In general electronic configuration of these elements is (n—)d"ns"?, For Ans. ()oxamplo = So, Ti, Cu ete. (i) Transition elements, show variation in oxidation Humber duo to incomplete filling of d-orbitals, Incomplete filing of d orbitals taken place in much a Way that oxidation sato differ from oach ollie by unity For examplo, Fe”, Fe otc [Link] the following: (Linkage tsomerism (i) Hydrate Isomeriam. Ans. (i) Complex compounds which havo same molecula formula but differ in properties due to differance in the nature of atom through which an ambidentent ligand is attached to the central metal are called linkage isomers and the phenomenon Is called linkage isomerism. For exampla, [COWNH,),(ONO)]C, and [COWNH,),(NO,)]Cl, (i) Complex compounds which have same molecular formula but differ In properties duo to difference in number of water molecules inside and outside the co-ordination sphere are called hydrate isomers and the phenomenon is known as hydrate isomerism. For example, [COWH,0},]CI, and [CO(H,0),cI]cl, [Link] are synthetic polymers? Name to synthetic polymers. ‘Synthetic Polymers: Man made polymers are calléd synthetic polymers, Example are Nylon-6, Nylon-66, Buna- Sete. Ans. oR What Is natural rubber? Write down the name and structural formula of its monomer. . Natural rubber: Natural rubber is a natural polymer foiind inthe bark of rubber tree. Natural rubber s a linear polymer of isoprene which is 2-Methyl buta-1, 3-diene, OH, = cH = CH CH, [Link] a disinfectant? Name any two disinfectants. ‘Ans, Disinfectant: Chemical which either kill or prevent the grovth of micro organism and which are applied to inanimate objects such as floors, drainage system, instruments etc. are called disinfectants, For example, The solution of phenol and Cl, ete Q.24, Define the following: (Conductor (i) Insulator (ii) Semiconductor. Ans. (i) Conductor: Substance which allow the passage of electric current to a large extent through th: are called conductor. (ll) Insulator: The solid which almo~i do not allow the electric current to flow them Le. thuir conductivity is negligible or very small (= 10 "ohm: ‘cm'') are termed insulator. ‘Semi conductor: The solid material whose electrical conductivity lies between those of typical metallic conductor and insulators are termed as ‘miconductor © .[Link] Io corrosion? What aro the factors which affect corronlon?: ‘Ana. Corranton: The process of formation of compounds such ‘8 oxidos, sulphides, carbonates, sulphages etc on the ‘du to attack of atmospheric gases is called contorion. ‘usting of iton [Link] example of corrosion. The following factors promotes corrosion. (i) Reactivity ofthe motal (ii) Presence of impurities nce of air and moisture nce of electrolyte. OR [Link] of A°m of NH,CI,NaOH and NaCl atinfinite dilution aro 129.8 8 cm? mol ', 248.1 scm? mol", 126.48 ‘em? mol ' respectively. Find out the value of A¢m In NHOH ‘Ans. According to Kohirausch’s law OMNH,Cl = yg +2 r°mNAOH = 2g. +e romNaCl =). th, Therefore, °mNH,OH = x°mNH,Cl+x°NaOH ~x°mNaCl =129.8 s cm’mol +248 s om? mol" ~126.4 s cm*mol = 251.5 s cm'mol"* Q.26, Whatis half-life of a reaction? Find out the value of half- life of a zero order reaction. Ans. The half life of a reaction is the time in which the concentration of the reactant is reduced to one half of the itial concentration. Itis represented as ty. For a zero order reaction, rate constant is given by the ‘equation pulling these value in equation (i) ee \ eK Is clear that f,, for a zero order reaction is directly proportional to initial concentration of the reactant andinversely proportional to the rate constant. oR a Forthe reaction 28+8+ A,B, rate=K(A][B]° with K=2x10* mol7L's, Calculate the initial rate of the reaction when [A]=0.1molL” and [B]=0.2 mol L- Calculate the ratio of reaction after [A] is reduced to 0.06 mol L”. ans. Initial rate =k(A][BP = (210% mo! LFS") «([Link])x(0.2 mol = 8x10" moll" S* y when [A] is reduced from 0.1molL:* to 0.06 moll’, 0.04 mot Lt of [4] hos reacted. Rate = (2.010 mol *L°S*) (0.06 mol") »(02 molt") = 4.810" molL'S" [Link] the differonce botwoen physisorption and ‘chemisorption. Ans. Following difference exit between physisorption chemisorption. ~ SI Physi ‘Chemise: () [tt involves weak vander| It involves stron} waal's forces. it is|chemeal forces the co- exathermicprocess. | valent bonding Its a exothermic process (Witisreversible innature. |Iusireversdemnatce (w)} it forms multenolecular ayer layer 28. Complete the following: ()CH,-CH, - CH, - Cl- Nal— Wawe, (i) CH,-CH, -CH, -Br + NaHS HO.E anal =CH, -Br+KeN-“* Ans. (i) cee ch Cl+ Naif w CH, - CH, -OH+NaBr 10 Eranal (0) Cry = CH, Bt = KCL (iy [t occurs at ordinary} occurs at nigh temperature temperature Gi) It has low heat off tt has high neat qu adsorption SOIPLON w)]It requires insignificant] It requires sigpican| activation energy actwaton energy It forms unimolecular CH, ~CH, -CN+CH, -CH, -NC Mac? eet 2.28, How will you bring about the following conversions? () Propene + Propan-2-ol (i) Benzyl chloride + Benzyl alcohol (li) Ethyl magnesium bromide > 2-methy! propen-2-ot Ans. ()CH,-C=cH, ge, cH, cH = cH, OH (i) CH,.CH, - C3223 C,H,.CH, -OH i (ii), CHMG-Br saeeere CH, + CH, —C— OMG! 3 ° OMg! | —c— omg! cH,—C—CH, ‘OMg! oa on OMg! om, —d—cn, -2— c—d-on, eH ! 23 Complete tne folowing V0) CNM, «CHCl, KOH» WCRI c40H- (ui) Cpt, -NH, + HNO, -» me) G0 “KON cH, oH, CHC, -NeG + SKC + 3H,O (0) CALN,C1+ CPLOH + CyH, +N, + CH, CHO + HCI (wo) CPS NH, “HNO, + COHN, 0 231. Differentiate between globular and fibrous proteins Ana. Globular ang fibrous proteins show that following eterences [ST GetvarP w|ehen chans of poly pice co! around 0 ve a sohercal shape, fscatedgotuarprcten Fibrous Proteins ‘vihen polypeptide chain| run paralel and are held| togetner by nydrogen. ‘and cisulphice bonds, a file Lke structure is formed. tts cated fteous protein These are gene (These are usually! iy soluble in water. insolusie in water |For examzie, insuine,|For exampie. Keratin, Aurinets Myzos set(Long Answer Type Questions) following: Osmosis i) S2MOte pressure ‘emlpermeable mombrano. Ans, memes: 18 Sefined ac the spontaneous flow of solvent molecules through sony Pure sokent Z¥9" semipermeable membrane from a Solution, °° Solution or from a dilute to.a concentrated Osmoti a Teaied preven he ==CRT *= osmotic pressure C= Concentration R= Gas Constant T= Temperature. where !tis the membrane which allow only solute to pass through i. tis membrane which S mecessary for osmosis to take place. For example, animal bladder, cellophane paper etc. OR Bolling point of water at 750 mm Hg is 96.63°C. How Much Sucrose (C,,H.,0,,) is tobe added t6 500 g of water ‘Such that it boils at 400°C? ‘Molal elevation constant for water is 0.52 K kg mol". Ans. Elevation of [Link]. required, aT =T,-T, =100-96.63 =3.37°C we know, AT, cm xx1000 342x500 47, =K,m 1000 342x500 108.211g [Link] the following: _ ()_NaCl+H,S0,(concenirated) > (i) Na,SO, +HCI-> (ii) Cl, +H,O> ‘i host {iv) Cl, +NaOH (concentrated) "> (v)_Na,S,0,+H,0+Cl, 4 ve NaCl+H,SO, — NaHSO, +HC! (in col +HCI (On Heating) 3.37 =0.52« Ans. ()) NaHSO, +NaCl—> Na,SO, 0 (i) -Na,SO, +HCI-+ 2NaCl+ SO, +H ii) Cl,+H,O-9HCI+HOC! o . (conc) eet Nadi, + SNaCl+ 340 WV) 90, + 6N2OH “ Na,8,0,+H,0+Ch > Na,SO, + 2HC1+8 a,8,0, + Hi OR Q _Drawstructure of the followi SO, (i)_-H,8,0, 210, HCIO, (i), HEIO, ow () HCI, ° Loew Ans.) H—O— 3 — ° ° ° ll I t) HO B= 0—F— 0-H ° ° f (i) O=G—O—H | ° @ o=a—-o—H i] 0 ® ci—-o-H