ASHWAMEGH VIDHYALAYA

AEGH
Chapters :All Std 11:Chemistry Date: 18/03/23
Total Marks: 80 FINAL EXAM Time: 03 Hour
SCDHALIADA
Section A
Write the answer 0f the following questions. (Each carries 1Mark] RDI. DISt [24]
1.
Express the given in the scientific notation : 0.0048 Ko
2. How many significant figures are present in given : 208
3. Calculate : 8.56 >X 105 and 10.64 x 10 addition
4. State the species in which electron, proton and neutron are 10, 8, 8
respectively ?
(B) 'O (D) 'o.
What is same in isotone ?
(A) Electron (B) Proton (C).Neutron (D) Nucleon
6. The size of isoelectronic species - F, Ne and Nat is affected by
(A) nuclear charge (Z)
(B)valence principal quantum number (n)
(C) electron-electron interaction in the outer orbitals
(D) none of the factors because their size is the same.
7. Considering the elements B, Al, Mg, and K, the correct order of their metallic character is :
(A) B > Al > Mg > K (B) Al > Mg > B> K (C) Mg > Al > K > B
(D) K> Mg > Al > B
8 Which statement is not correct?
(A) o-bond is weak than T-bond (B) G-bond is strong than -bond
(C) C-C is shorter than C= C (D) double bond is stronger them single bond.
9.
0*,Oz and 0,2- arrange in bond order.
10. 1bar means Pa ?
11. Explain Gay Lussac Law.
12. is not a state function.
(A) Work (B) Enthalpy (C) Internal energy (D) Entropy
13. Which equation from the following is right ?
(A) AU= q- w (B) W = AU + q (C) AU= W+q (D) none of above
14. According to which theory, NH, is not a base ?
(A) Lewis (B) Arrhenius (C) Bronsted-Lowry (D) lonization
15. What is oxidation number of 'C' in C,0, ?
16. Which reaction is correct of oxidation half reaction in basic mnedium P ’ H,P0,-?
(A) P, + 80H ’ 4H,PO, + 40H (B) P, + 8H* ’ 4H,P0,+ 12H*
(C) P, + 40H ’ 4H,PO, (D) P, + 80H- ’ 4e + 4H,PO,
17. What is shape of H,O molecule ?
(A) Linear (B) Angular (C) Triangular (D) planar
18. Give two uses of caustic soda.
19. What is the molecular formula of borax ?
(A) Na,B40, 4H,0 (B) Na,B,O,0·10H,0 (C) Na B,0,· 10H,0 (D) Na,B40,· 10H,0
20. Shape of Cso fullerene is
 (A) Tenisball (C) Football (D) Wallyball
(B) Bukyball
carbocation and free radicals.
21. Write in ascending order of stability of 1°, 2° and 3°
22. 1UPAC name of CH=C- CH = CH - CH = CH, is
(A) Hexa-5-yne-1, 3-dine (B) Hexa-1, 3-dine-5-yne
(C) Hexa dine-yne-1, 3, 5 (D) Hexa-1-ene-l-yne-3-en
23. Explain product of reaction
CH,CH = CH, + HCI Peroxide
24. Which of the following is right from given table
Compound General formula
(p) Alkane () CH2n
(q) Alkene (ii) CHzn - 2
() Alkyne (iii) CH2n +2
(s) Cycloalkane (iv) C,Hzn +4
(A) (p - i), (q - ii), (r - ii), (s - iv) (B) (p - iü), (q - i), (r - ii), (s -)
(C) (p - ii), (q i), (r i), (s - iv) (D) (p - iv), (q - iii), (r - i), (s - i)
Section B
Write the answer of the following questions. [Each carries 2 Marks] [22]
25 Explain Law of Multiple Proportions.
26 The threshold frequency v, for a metal is 7.0x 104 s-l. Calculate the kinetic energy of an electron
emitted when radiation of frequency v = l.0 × 1015 s- hits the metal.
27. State limitations of octet rule.
28. A balloon is filled with hydrogen at room temperature. It will burst if pressure exceeds 0.2 bar. If at
1 bar pressure the gas occupies 2.27 L volume, upto what volume can the balloon be expanded ?
29. Explain the enthalpy of dilution.
OR

29. Prove the relationship between C, and C, for an ideal gas.

30. Write the Bronsted - Lowry principle for acids and bases.
31. Justify that the reaction :2Cu,O) +Cu,Ss) ’ 6Cug +SOzg) is a redox reaction. Identify the species
oxidised/reduced, which acts as an oxidant and which acts as a reductant.
32. Give anomalous properties of lithium.
33. Explain physical and chemical properties of borax.
34.1. Derive the structure of Pent-4-en-2-ol
34.2. Derive the structure of 6-Hydroxyheptanal
35 Write IUPACname of the product obtained by the ozonolysis of the following compound:
3,4-Dimethylhept-3-ene
OR
Ethanol
35 Complete the following reaction : 1-Cloropopane KOH
’ (B) r2 (C)
CCla
 SCuee

(Section C|
[24]
Write the answer of the following qucstions.[Each carries 3 Marks]
36.
37,
Explain when we go top to bottom in same group what change is observed in ionisation enthalpy?
Give Charle's law in brief.
38,
Tne conmbustion of one mole of benzene takes place at 298 Kand 1 atm. After combustion, CO2(g)
of
id H20 are produced and 3267.0 kJ of heat is liberated. Calculate the standard enthalpy
formation, A,He of benzene, Standard enthalpies of formation of CO2(g) and Hz0) are -393.3 K
mol-l and -285.83 kJ mol-l respectively.
OR
38
Explain the Born-Haber Cycle.
39.
aA +bB cC+ dD here A, B, C, Dare in gaseous phase. Derive the relation between k, and e
40. remanganate(VI) jon, Mn0, in basic solution oxidises iodide ion, I to produce molecular iodine
2 and manganese (IV) oxide (MnO,). Write a balanced ionic equation to represent this redox
reaction.
41.
Write chemical properties of hydrogen peroxide.
42.
Discuss preparation and properties of silicones.
OR
42.
Give physical and chemical properties of Orthoboric acid (H,BO,).
43.
Explain hyperconjugation or no bond resonance with example.
Section D
Write the answer of the following questions. [Each carries 5 Marks] [10]
44. Write down Bohr's model of hydrogen atom.
45, Anti Markonikov's rule or peroxide effect (Kharash effect) or free radical addition reaction with
example?
OR
45.
Addition of sulphuricacid in alkene and additionof sulphuriç acid in alkene with addition reaction.
Czonolyar a pend-2 -in