Target Test Contact Number: 9667591930 / 8527521718

7. Which of the following has the maximum number of

Chemistry - Section A unpaired electons-
1. Number of unpaired electrons in 1s2 2s2 2p3 is - 1. Mg2+
1. 2 2. Ti3+
2. 0 3. V3+
3. 3
4. Fe2+
4. 1
8. Which one of the following is not characteristic of
2. If uncertainty in the position of an electron is zero the
Planck's quantum theory of radiation –
uncertainty in its momentum will be:
1. The energy is not absorbed or emitted in whole
1. <h/4π
numbers or multiples of quantum.
2. >h/4π
2. Radiation is associated with energy.
3. zero
3. Radiation energy is not emitted or absorbed
4. infinite
continuously but in the form of small packets called
quanta.
3. The rest mass of a proton is 1.673 x 10-27 kg and that
4. Magnitude of energy associated with a quantum is
of the electron is 9.109 x 10-31 kg. What must be the proportional to the frequency.
speed of the proton which has the same de Broglie
wavelength as an electron moving with a speed of 9 x 9. The number of d- electrons retained in Fe2+ :
106 m/s? 1. 5
1. 3600 m/s 2. 6
2. 4900 m/s 3. 3
3. 4300 m/s 4. 4
4. 5600 m/s
10. When H2SO3 is converted into H2SO4 the change in
4. Which one of the following statement is not true about
the quantum numbers n, l, m and s the oxidation state of sulfur is from:
1. m gives the information on the energy of the electron 1. 0 to +2
in a given orbital. 2. +2 to +4
2. l gives an idea of the shape of the orbital. 3. +4 to +2
3. n gives information on the size of the orbit. 4. +4 to +6
4. s gives the direction of spin of the electron in the
orbital. 11. Fluorine is a strong oxidising agent because:
1. it has several isotopes
5. The brackett series of spectral lines arise when an 2. it is very small and has 7 electrons in valency shell
electron in an excited hydrogen atom jumps from an 3. its valency is one
energy level 4. it is the first member of the halogen series
1. n=5 to n=1
2. n=5 to n=3 12. The oxidation state of Ni in Ni(CO)4 is:
3. n=5 to n=4 1. zero
4. n=5 to n=2 2. +4
3. +8
6. The electronic transition in the hydrogen atom that 4. +2
emits maximum energy is:
1. 2 → 1 13. The reaction involving the transfer of five electrons
2. 1 → 4 is -
3. 4 → 3 1. MnO → Mn2+ −

4
4. 3 → 2
2. CrO →Cr3+2−

3. MnO → MnO2 −

4. Cr2O 2−

7
→ 2Cr3+

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 Target Test Contact Number: 9667591930 / 8527521718

14. In the reaction; 21. In the following unbalanced reaction

2Ag + 2H2SO4 →Ag2SO4 + 2H2O + SO2, H2SO4 acts A2+ + B3+ →A4+ + B
as: The total number of e- transferred during reaction is
1. Oxidizing agent 1. 2
2. Reducing agent 2. 3
3. Dehydrating agent 3. 6
4. None of the above 4. 8

15. During a redox change, the oxidant K2Cr2O7 is

always reduced to:
1. Cr5+ 22. What will be the value of x and y by balancing the
2. Cr4+ reaction
C2H5OH + X I2 + Y OH- →CHI3 + HCO2- + 5I- +
3. Cr3+
5H2O
4. Cr2+
1. 4,6
16. Which of the following sets of quantum numbers is 2. 2,6
not possible? 3. 2,4
1. n = 1, l=0, m=0, s=1/2 4. 4,4
2. n = 2, l=0, m=0, s= -1/2
3. n = 3, l= 3, m = -3, s = 1/2 23. Which is the correct set that can only act as an
4. n = 3, l= 1, m = 0, s = -1/2 oxidant?
1. NO3-, SO3, Na 2. Fe+3, NO3-, SO3
17. Which of the following has greater number of
electrons than neutrons? 3. I-, Na 4. I-, NO3-
1. Al3+
2. O2-
24. In the given reaction,
3. F-
4. C xBrO3- + yCr+3 + zH2O →Br2 + CrO42- + H+
The coefficients x, y, and z are respectively-
18. The transition in the He ion in the balmer series that 1. 6, 10, 11
+
would have the same wave number as the first Lyman 2. 6, 10, 20
line in the hydrogen spectrum is- 3. 6, 8, 22
4. 6, 10, 22
1. 2 → 1 2. 5 → 3
3. 4 → 2 4. 6 → 4 25. Identify the substance acting as an oxidant in the
following reaction:
BaCl2 + Na2SO4→BaSO4 + 2NaCl
19. When Cl is converted into Cl- & ClO then n-
−

2 3 1. BaCl2
factor of Cl2 will be: 2. Na2SO4
1. 3/5 3. NaCl
2. 5/3 4. None of the these
3. 7/2
4. 2 26. In the conversion, H SO → H S O which process
2 4 2 2 8
occurs?
20. Bohr's model is not valid for:-
1. Oxidation
1. H-atom
2. Reduction
2. D-atom
3. Oxidation as well as reduction
3. T-atom
4. Neither oxidation nor reduction
4. He-atom

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27. Which of the following pairs of d-orbitals will have 33. The strongest oxidising agent among the following
electron density along the axes? is -
1. dz2,dxz 1. BrO /Br , E = +1 .50
−

3
2+ o

2. dxz,dyz 2. F e /F e , E = +0 .76
3+ 2+ o

3. dz2,dx2-y2 3. M nO /M n , E = +1 .52
−

4
2+ o

4. dxy,dx2-y2 4. Cr O /Cr , E = +1 .33

2
2−

7
3+ o

28. From the given equation, certain conclusions are 34. In an alkaline medium ClO2 oxidize H2O2 in O2 and
drawn. reduces itself in Cl– . How many moles of H2O2 will be
2
−18 z
E = −2.178 × 10 (J)
n
2 oxidized by one mole of ClO2?
Choose the incorrect statement: 1. 1.0 2. 1.5
The negative sign in the equation implies that the 3. 2.5 4. 3.5
energy of an electron bound to the nucleus is lower
1.
than it would be if the electron were at an infinite
distance from the nucleus.
35. In a balanced equation
2. The larger the value of n, the greater the orbit radius. H SO + x H I → H S + y I + z H O, the values of
2 4 2 2 2

The equation can be utilized to calculate the change x, y, z are -

3. in energy when the electron transitions between (1) x = 3, y = 5, z = 2
orbits. (2) x = 4, y = 8, z = 5
For n=1, the electron has a more negative energy than (3) x = 8, y = 4, z = 4
4. it does for n=6. This means that the electron is more (4) x = 5, y = 3, z = 4
loosely bound in the smallest allowed orbit.

Chemistry - Section B
29. The oxidation states of P in H4P2O5, H4P2O6, 36. A pair of d-orbitals having electron density along the
H4P2O7, are respectively - axes is:
1. d , d 2

1. +3, +5, +4 2. +5, +3, +4 z xz

2. d , d xz zy
3. +5, +4, +3 4. +3, +4, +5 3. d , d 2 2 2
z x −y

4. d , d xy x −y
2 2

30. Given: The mass of electron is 9.11 x 10-31 kg

37. If the electronic structure of oxygen atom is written
Planck constant is 6.626 x 10-34 Js
the uncertainty involved in the measurement of velocity as 1s , 2s 2
it would violate
2

within a distance of 0.1 A is:

°

1. Hund's rule
(a) 5.79 x 106 ms-1 (b) 5.79 x 107 ms-1 2. Paulis exclusion principle
8
(c) 5.79 x 10 ms -1 5
(d) 5.79 x 10 ms -1 3. Both Hund's and Pauli's principles
4. None of the above
31. The oxidation number of P in Mg2P2O7 is -
38. ψ (r, θ, ϕ) represents: (for Schrodinger wave
2

1. +3 2. +2
mechanical model)
3. +5 4. –3 1. Amplitude of electron wave
2. Probability density of electron
3. Total probability of finding electron around nucleus
32. What is the oxidation number of sulphur in 4. Orbit
Na S O -
2 4 6

(1) 2

(2) 3

(3) 3

(4) 5

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 Target Test Contact Number: 9667591930 / 8527521718

39. Slope of V vs v curve is (where0 V0 =stopping 46. The energy of an electron in the first Bohr's orbit of
potential, v=subjected frequency) an H-atom is -13.6 eV. The possible energy value (s) of
1. e the excited state(s) for electrons in Bohr's orbits of
2. h

e
hydrogen is (are):
3. ϕ 1. -3.4 eV
4. h 2. -4.2 eV
3. -6.8 eV
40. P4 + NaOH → PH3 + NaH2PO2 4. +6.8 eV
The correct statement among the following is -
47. In Bohr series of lines of hydrogen spectrum, the
1. P is oxidized only.
third line from the red end corresponds to which one of
2. P is reduced only.
the following inter orbit jumps of the electron for Bohr's
3. P is oxidized as well as reduced.
orbits in an atom of hydrogen?
4. Na is reduced.
(1) 3 → 2
(2) 5 → 2
41. Nitrogen show different oxidation states in the range
(3) 4 → 1
:
(4) 2 → 5
1. 0 to +5
2. -3 to +5
48. The de Broglie wavelength of a tennis ball of mass
3. -5 to +3
60 g moving with a velocity of 10 metres per second is
4. -3 to +3
approximate-
(Planck's constant, h = 6. 63 × 10 J s)
−34

42. How many moles of K Cr O can be reduced 1

2 2 7
1. 10 metres−33

mole of Sn ?\ 2+

1. 1/3 2. 10 metres−31

2. 1/6 3. 10 metres−16

3. 2/3 4. 10 metres−25

4. 1
49. The wavelength of the radiation emitted when in a H
43. When potassium permangante is titrated against atom, the electron falls from infinity to stationary state
ferrous ammonium sulphate in acidic medium, the (n=1), is:
equivalent weight of potassium permanganate is : 1. 15 nm
molecular weight 2. 192 nm
1. 3 3. 406 nm
molecular weight
2. 5
4. 91 nm
molecular weight
3.
molecular
2
weight
50. The oxidation number of phosphorous in ATP
4. 10
(adenosine triphosphate) is -
1. 2 2. 3
44. Which of the following cannot act as an oxidising 3. 4 4. 5
agent?
1. S 2−

2. Br 2

3. H SO −

4. SO 2−

45. Which of the following can act as oxidant and

reductant :-
1. H O 2 2

2. KMnO 4

3. H SO 2 4

4. H S 2

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