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NASA-GLENN CHEMICAL EQUILIBRIUM PROGRAM CEA2, MAY 21, 2004

BY BONNIE MCBRIDE AND SANFORD GORDON
REFS: NASA RP-1311, PART I, 1994 AND NASA RP-1311, PART II, 1996

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problem o/f=3.4,3.3,
rocket equilibrium frozen nfz=2 tcest,k=3800
p,bar=70,
pi/p=70,
sup,ae/at=10,12,14,15,18,20,22,25,
react
fuel=CH4(L) wt=100 t,k=112
oxid=O2(L) wt=100 t,k=90
end

OPTIONS: TP=F HP=F SP=F TV=F UV=F SV=F DETN=F SHOCK=F REFL=F INCD=F
RKT=T FROZ=T EQL=T IONS=F SIUNIT=T DEBUGF=F SHKDBG=F DETDBG=F TRNSPT=F

TRACE= 0.00E+00 S/R= 0.000000E+00 H/R= 0.000000E+00 U/R= 0.000000E+00

Pc,BAR = 70.000000

Pc/P = 70.0000

SUBSONIC AREA RATIOS =

SUPERSONIC AREA RATIOS = 10.0000 12.0000 14.0000 15.0000 18.0000

20.0000 22.0000 25.0000

NFZ= 2 Mdot/Ac= 0.000000E+00 Ac/At= 0.000000E+00

REACTANT WT.FRAC (ENERGY/R),K TEMP,K DENSITY

EXPLODED FORMULA
F: CH4(L) 1.000000 -0.107322E+05 112.00 0.0000
C 1.00000 H 4.00000
O: O2(L) 1.000000 -0.156101E+04 90.00 0.0000
O 2.00000

SPECIES BEING CONSIDERED IN THIS SYSTEM

(CONDENSED PHASE MAY HAVE NAME LISTED SEVERAL TIMES)
LAST thermo.inp UPDATE: 9/09/04

g 7/97 *C tpis79 *CH g 4/02 CH2

g 4/02 CH3 g11/00 CH2OH g 7/00 CH3O
g 8/99 CH4 g 7/00 CH3OH srd 01 CH3OOH
tpis79 *CO g 9/99 *CO2 tpis91 COOH
tpis91 *C2 g 6/01 C2H g 1/91 C2H2,acetylene
g 5/01 C2H2,vinylidene g 4/02 CH2CO,ketene g 3/02 O(CH)2O
srd 01 HO(CO)2OH g 7/01 C2H3,vinyl g 6/96 CH3CO,acetyl
g 1/00 C2H4 g 8/88 C2H4O,ethylen-o g 8/88 CH3CHO,ethanal
g 6/00 CH3COOH srd 01 OHCH2COOH g 7/00 C2H5

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g 7/00 C2H6 g 8/88 C2H5OH g 7/00 CH3OCH3

srd 01 CH3O2CH3 g 8/00 C2O tpis79 *C3
n 4/98 C3H3,1-propynl n 4/98 C3H3,2-propynl g 2/00 C3H4,allene
g 1/00 C3H4,propyne g 5/90 C3H4,cyclo- g 3/01 C3H5,allyl
g 2/00 C3H6,propylene g 1/00 C3H6,cyclo- g 6/01 C3H6O,propylox
g 6/97 C3H6O,acetone g 1/02 C3H6O,propanal g 7/01 C3H7,n-propyl
g 9/85 C3H7,i-propyl g 2/00 C3H8 g 2/00 C3H8O,1propanol
g 2/00 C3H8O,2propanol g 7/88 C3O2 g tpis *C4
g 7/01 C4H2,butadiyne g 8/00 C4H4,1,3-cyclo- n10/92 C4H6,butadiene
n10/93 C4H6,1butyne n10/93 C4H6,2butyne g 8/00 C4H6,cyclo-
n 4/88 C4H8,1-butene n 4/88 C4H8,cis2-buten n 4/88 C4H8,tr2-butene
n 4/88 C4H8,isobutene g 8/00 C4H8,cyclo- g10/00 (CH3COOH)2
n10/84 C4H9,n-butyl n10/84 C4H9,i-butyl g 1/93 C4H9,s-butyl
g 1/93 C4H9,t-butyl g12/00 C4H10,n-butane g 8/00 C4H10,isobutane
g 8/00 *C5 g 5/90 C5H6,1,3cyclo- g 1/93 C5H8,cyclo-
n 4/87 C5H10,1-pentene g 2/01 C5H10,cyclo- n10/84 C5H11,pentyl
g 1/93 C5H11,t-pentyl n10/85 C5H12,n-pentane n10/85 C5H12,i-pentane
n10/85 CH3C(CH3)2CH3 g 2/93 C6H2 g11/00 C6H5,phenyl
g 8/00 C6H5O,phenoxy g 8/00 C6H6 g 8/00 C6H5OH,phenol
g 1/93 C6H10,cyclo- n 4/87 C6H12,1-hexene g 6/90 C6H12,cyclo-
n10/83 C6H13,n-hexyl g 6/01 C6H14,n-hexane g 7/01 C7H7,benzyl
g 1/93 C7H8 g12/00 C7H8O,cresol-mx n 4/87 C7H14,1-heptene
n10/83 C7H15,n-heptyl n10/85 C7H16,n-heptane n10/85 C7H16,2-methylh
n 4/89 C8H8,styrene n10/86 C8H10,ethylbenz n 4/87 C8H16,1-octene
n10/83 C8H17,n-octyl n 4/85 C8H18,n-octane n 4/85 C8H18,isooctane
n10/83 C9H19,n-nonyl g 3/01 C10H8,naphthale n10/83 C10H21,n-decyl
g 8/00 C12H9,o-bipheny g 8/00 C12H10,biphenyl g 6/97 *H
g 1/01 HCO g 6/01 HCCO g 4/02 HO2
tpis78 *H2 g 5/01 HCHO,formaldehy g 6/01 HCOOH
g 8/89 H2O g 6/99 H2O2 g 6/01 (HCOOH)2
g 5/97 *O g 4/02 *OH tpis89 *O2
g 8/01 O3 n 4/83 C(gr) n 4/83 C(gr)
n 4/83 C(gr) g11/99 H2O(cr) g 8/01 H2O(L)
g 8/01 H2O(L)

O/F = 3.400000

EFFECTIVE FUEL EFFECTIVE OXIDANT MIXTURE

ENTHALPY h(2)/R h(1)/R h0/R
(KG-MOL)(K)/KG -0.66898729E+03 -0.48783267E+02 -0.18973873E+03

KG-FORM.WT./KG bi(2) bi(1) b0i

*C 0.62334580E-01 0.00000000E+00 0.14166950E-01
*H 0.24933832E+00 0.00000000E+00 0.56667800E-01
*O 0.00000000E+00 0.62502344E-01 0.48297266E-01

POINT ITN T C H O
1 22 3551.198 -15.778 -9.856 -15.237
Pinf/Pt = 1.729280
2 3 3379.316 -16.111 -10.061 -15.487
Pinf/Pt = 1.727117
2 2 3379.696 -16.110 -10.061 -15.487
3 6 2351.626 -17.560 -11.352 -18.393
4 3 2320.609 -17.545 -11.379 -18.546
4 3 2369.610 -17.567 -11.337 -18.307
4 1 2369.638 -17.567 -11.337 -18.307
5 3 2298.557 -17.531 -11.397 -18.658

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5 1 2298.593 -17.531 -11.396 -18.657

6 3 2237.432 -17.479 -11.444 -18.982
7 3 2147.664 -17.373 -11.507 -19.499
7 3 2209.777 -17.450 -11.464 -19.136
7 1 2209.801 -17.450 -11.464 -19.136
8 3 2136.372 -17.357 -11.515 -19.568

THEORETICAL ROCKET PERFORMANCE ASSUMING EQUILIBRIUM

COMPOSITION DURING EXPANSION FROM INFINITE AREA COMBUSTOR

Pin = 1015.3 PSIA

CASE =

REACTANT WT FRACTION ENERGY TEMP

(SEE NOTE) KJ/KG-MOL K
FUEL CH4(L) 1.0000000 -89233.000 112.000
OXIDANT O2(L) 1.0000000 -12979.000 90.000

O/F= 3.40000 %FUEL= 22.727273 R,EQ.RATIO= 1.173313 PHI,EQ.RATIO= 1.173313

CHAMBER THROAT EXIT EXIT EXIT EXIT EXIT EXIT

Pinf/P 1.0000 1.7271 70.000 65.910 83.399 101.73 111.20 140.63
P, BAR 70.000 40.530 1.0000 1.0621 0.83934 0.68807 0.62952 0.49777
T, K 3551.20 3379.70 2351.63 2369.64 2298.59 2237.43 2209.80 2136.37
RHO, KG/CU M 5.1374 0 3.1665 0 1.1972-1 1.2613-1 1.0292-1 8.6770-2 8.0411-2 6.5823-2
H, KJ/KG -1577.58 -2299.27 -6176.96 -6126.46 -6321.53 -6481.35 -6551.42 -6732.12
U, KJ/KG -2940.14 -3579.24 -7012.26 -6968.53 -7137.05 -7274.33 -7334.30 -7488.35
G, KJ/KG -44819.2 -43452.6 -34811.9 -34980.7 -34310.7 -33725.8 -33459.4 -32746.0
S, KJ/(KG)(K) 12.1766 12.1766 12.1766 12.1766 12.1766 12.1766 12.1766 12.1766

M, (1/n) 21.670 21.954 23.408 23.398 23.435 23.460 23.469 23.489

(dLV/dLP)t -1.03846 -1.03385 -1.00292 -1.00319 -1.00222 -1.00160 -1.00138 -1.00090
(dLV/dLT)p 1.6864 1.6367 1.0794 1.0862 1.0617 1.0455 1.0394 1.0266
Cp, KJ/(KG)(K) 7.0770 6.8984 3.0041 3.0675 2.8359 2.6749 2.6129 2.4761
GAMMAs 1.1309 1.1277 1.1558 1.1540 1.1612 1.1672 1.1697 1.1761
SON VEL,M/SEC 1241.3 1201.4 982.6 985.8 973.1 962.0 957.0 943.1
MACH NUMBER 0.000 1.000 3.087 3.060 3.165 3.255 3.296 3.405

PERFORMANCE PARAMETERS

Ae/At 1.0000 10.477 10.000 12.000 14.000 15.000 18.000

CSTAR, M/SEC 1840.0 1840.0 1840.0 1840.0 1840.0 1840.0 1840.0
CF 0.6529 1.6483 1.6392 1.6740 1.7020 1.7141 1.7449
Ivac, M/SEC 2266.8 3308.4 3295.4 3345.0 3384.9 3402.2 3446.3
Isp, M/SEC 1201.4 3032.9 3016.2 3080.2 3131.7 3154.0 3210.8

MOLE FRACTIONS

*CO 0.17932 0.17297 0.13118 0.13166 0.12982 0.12829 0.12761 0.12579

*CO2 0.12765 0.13803 0.20044 0.19981 0.20219 0.20406 0.20487 0.20698
COOH 0.00001 0.00001 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000

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*H 0.02267 0.01959 0.00327 0.00346 0.00274 0.00220 0.00198 0.00147

HCO 0.00001 0.00001 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000
HO2 0.00012 0.00008 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000
*H2 0.08183 0.07817 0.06722 0.06700 0.06798 0.06903 0.06957 0.07114
H2O 0.48660 0.50485 0.59164 0.59123 0.59252 0.59302 0.59308 0.59278
H2O2 0.00002 0.00001 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000
*O 0.01021 0.00798 0.00016 0.00019 0.00011 0.00006 0.00005 0.00002
*OH 0.06826 0.05835 0.00550 0.00597 0.00427 0.00311 0.00267 0.00174
*O2 0.02329 0.01995 0.00059 0.00068 0.00038 0.00022 0.00017 0.00008

* THERMODYNAMIC PROPERTIES FITTED TO 20000.K

PRODUCTS WHICH WERE CONSIDERED BUT WHOSE MOLE FRACTIONS

WERE LESS THAN 5.000000E-06 FOR ALL ASSIGNED CONDITIONS

*C *CH CH2 CH3 CH2OH

CH3O CH4 CH3OH CH3OOH *C2
C2H C2H2,acetylene C2H2,vinylidene CH2CO,ketene O(CH)2O
HO(CO)2OH C2H3,vinyl CH3CO,acetyl C2H4 C2H4O,ethylen-o
CH3CHO,ethanal CH3COOH OHCH2COOH C2H5 C2H6
C2H5OH CH3OCH3 CH3O2CH3 C2O *C3
C3H3,1-propynl C3H3,2-propynl C3H4,allene C3H4,propyne C3H4,cyclo-
C3H5,allyl C3H6,propylene C3H6,cyclo- C3H6O,propylox C3H6O,acetone
C3H6O,propanal C3H7,n-propyl C3H7,i-propyl C3H8 C3H8O,1propanol
C3H8O,2propanol C3O2 *C4 C4H2,butadiyne C4H4,1,3-cyclo-
C4H6,butadiene C4H6,1butyne C4H6,2butyne C4H6,cyclo- C4H8,1-butene
C4H8,cis2-buten C4H8,tr2-butene C4H8,isobutene C4H8,cyclo- (CH3COOH)2
C4H9,n-butyl C4H9,i-butyl C4H9,s-butyl C4H9,t-butyl C4H10,n-butane
C4H10,isobutane *C5 C5H6,1,3cyclo- C5H8,cyclo- C5H10,1-pentene
C5H10,cyclo- C5H11,pentyl C5H11,t-pentyl C5H12,n-pentane C5H12,i-pentane
CH3C(CH3)2CH3 C6H2 C6H5,phenyl C6H5O,phenoxy C6H6
C6H5OH,phenol C6H10,cyclo- C6H12,1-hexene C6H12,cyclo- C6H13,n-hexyl
C6H14,n-hexane C7H7,benzyl C7H8 C7H8O,cresol-mx C7H14,1-heptene
C7H15,n-heptyl C7H16,n-heptane C7H16,2-methylh C8H8,styrene C8H10,ethylbenz
C8H16,1-octene C8H17,n-octyl C8H18,n-octane C8H18,isooctane C9H19,n-nonyl
C10H8,naphthale C10H21,n-decyl C12H9,o-bipheny C12H10,biphenyl HCCO
HCHO,formaldehy HCOOH (HCOOH)2 O3 C(gr)
H2O(cr) H2O(L)

NOTE. WEIGHT FRACTION OF FUEL IN TOTAL FUELS AND OF OXIDANT IN TOTAL OXIDANTS

3 3 2020.405 -17.161 -11.590 -20.323

3 3 2093.819 -17.292 -11.543 -19.834
3 1 2093.869 -17.292 -11.543 -19.834
4 3 2055.531 -17.226 -11.568 -20.085
4 1 2055.493 -17.226 -11.568 -20.085
5 3 2004.232 -17.130 -11.600 -20.437
5 1 2004.295 -17.130 -11.600 -20.436

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THEORETICAL ROCKET PERFORMANCE ASSUMING EQUILIBRIUM

COMPOSITION DURING EXPANSION FROM INFINITE AREA COMBUSTOR

Pin = 1015.3 PSIA

CASE =

REACTANT WT FRACTION ENERGY TEMP

(SEE NOTE) KJ/KG-MOL K
FUEL CH4(L) 1.0000000 -89233.000 112.000
OXIDANT O2(L) 1.0000000 -12979.000 90.000

O/F= 3.40000 %FUEL= 22.727273 R,EQ.RATIO= 1.173313 PHI,EQ.RATIO= 1.173313

CHAMBER THROAT EXIT EXIT EXIT

Pinf/P 1.0000 1.7271 161.04 182.04 214.54
P, BAR 70.000 40.530 0.43467 0.38453 0.32629
T, K 3551.20 3379.70 2093.87 2055.49 2004.29
RHO, KG/CU M 5.1374 0 3.1665 0 5.8667-2 5.2883-2 4.6032-2
H, KJ/KG -1577.58 -2299.27 -6833.59 -6923.56 -7041.48
U, KJ/KG -2940.14 -3579.24 -7574.50 -7650.69 -7750.30
G, KJ/KG -44819.2 -43452.6 -32329.9 -31952.6 -31447.1
S, KJ/(KG)(K) 12.1766 12.1766 12.1766 12.1766 12.1766

M, (1/n) 21.670 21.954 23.497 23.504 23.510

(dLV/dLP)t -1.03846 -1.03385 -1.00070 -1.00056 -1.00040
(dLV/dLT)p 1.6864 1.6367 1.0209 1.0168 1.0124
Cp, KJ/(KG)(K) 7.0770 6.8984 2.4131 2.3647 2.3106
GAMMAs 1.1309 1.1277 1.1794 1.1822 1.1855
SON VEL,M/SEC 1241.3 1201.4 934.8 927.1 916.7
MACH NUMBER 0.000 1.000 3.468 3.527 3.606

PERFORMANCE PARAMETERS

Ae/At 1.0000 20.000 22.000 25.000

CSTAR, M/SEC 1840.0 1840.0 1840.0 1840.0
CF 0.6529 1.7620 1.7770 1.7965
Ivac, M/SEC 2266.8 3470.7 3492.2 3520.1
Isp, M/SEC 1201.4 3242.2 3269.9 3305.7

MOLE FRACTIONS

*CO 0.17932 0.17297 0.12469 0.12368 0.12225

*CO2 0.12765 0.13803 0.20819 0.20930 0.21082
COOH 0.00001 0.00001 0.00000 0.00000 0.00000
*H 0.02267 0.01959 0.00122 0.00103 0.00080
HCO 0.00001 0.00001 0.00000 0.00000 0.00000
HO2 0.00012 0.00008 0.00000 0.00000 0.00000
*H2 0.08183 0.07817 0.07216 0.07314 0.07454
H2O 0.48660 0.50485 0.59234 0.59178 0.59084
H2O2 0.00002 0.00001 0.00000 0.00000 0.00000
*O 0.01021 0.00798 0.00001 0.00001 0.00000
*OH 0.06826 0.05835 0.00133 0.00103 0.00072
*O2 0.02329 0.01995 0.00005 0.00003 0.00002

* THERMODYNAMIC PROPERTIES FITTED TO 20000.K

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PRODUCTS WHICH WERE CONSIDERED BUT WHOSE MOLE FRACTIONS

WERE LESS THAN 5.000000E-06 FOR ALL ASSIGNED CONDITIONS

*C *CH CH2 CH3 CH2OH

CH3O CH4 CH3OH CH3OOH *C2
C2H C2H2,acetylene C2H2,vinylidene CH2CO,ketene O(CH)2O
HO(CO)2OH C2H3,vinyl CH3CO,acetyl C2H4 C2H4O,ethylen-o
CH3CHO,ethanal CH3COOH OHCH2COOH C2H5 C2H6
C2H5OH CH3OCH3 CH3O2CH3 C2O *C3
C3H3,1-propynl C3H3,2-propynl C3H4,allene C3H4,propyne C3H4,cyclo-
C3H5,allyl C3H6,propylene C3H6,cyclo- C3H6O,propylox C3H6O,acetone
C3H6O,propanal C3H7,n-propyl C3H7,i-propyl C3H8 C3H8O,1propanol
C3H8O,2propanol C3O2 *C4 C4H2,butadiyne C4H4,1,3-cyclo-
C4H6,butadiene C4H6,1butyne C4H6,2butyne C4H6,cyclo- C4H8,1-butene
C4H8,cis2-buten C4H8,tr2-butene C4H8,isobutene C4H8,cyclo- (CH3COOH)2
C4H9,n-butyl C4H9,i-butyl C4H9,s-butyl C4H9,t-butyl C4H10,n-butane
C4H10,isobutane *C5 C5H6,1,3cyclo- C5H8,cyclo- C5H10,1-pentene
C5H10,cyclo- C5H11,pentyl C5H11,t-pentyl C5H12,n-pentane C5H12,i-pentane
CH3C(CH3)2CH3 C6H2 C6H5,phenyl C6H5O,phenoxy C6H6
C6H5OH,phenol C6H10,cyclo- C6H12,1-hexene C6H12,cyclo- C6H13,n-hexyl
C6H14,n-hexane C7H7,benzyl C7H8 C7H8O,cresol-mx C7H14,1-heptene
C7H15,n-heptyl C7H16,n-heptane C7H16,2-methylh C8H8,styrene C8H10,ethylbenz
C8H16,1-octene C8H17,n-octyl C8H18,n-octane C8H18,isooctane C9H19,n-nonyl
C10H8,naphthale C10H21,n-decyl C12H9,o-bipheny C12H10,biphenyl HCCO
HCHO,formaldehy HCOOH (HCOOH)2 O3 C(gr)
H2O(cr) H2O(L)

NOTE. WEIGHT FRACTION OF FUEL IN TOTAL FUELS AND OF OXIDANT IN TOTAL OXIDANTS

THEORETICAL ROCKET PERFORMANCE ASSUMING FROZEN COMPOSITION

AFTER POINT 2

Pin = 1015.3 PSIA

CASE =

REACTANT WT FRACTION ENERGY TEMP

(SEE NOTE) KJ/KG-MOL K
FUEL CH4(L) 1.0000000 -89233.000 112.000
OXIDANT O2(L) 1.0000000 -12979.000 90.000

O/F= 3.40000 %FUEL= 22.727273 R,EQ.RATIO= 1.173313 PHI,EQ.RATIO= 1.173313

CHAMBER THROAT EXIT EXIT EXIT EXIT EXIT EXIT

Pinf/P 1.0000 1.7271 70.000 82.499 105.43 129.62 142.13 181.23
P, BAR 70.000 40.530 1.0000 0.84850 0.66392 0.54006 0.49250 0.38625
T, K 3551.20 3379.70 1792.13 1739.15 1662.30 1599.65 1572.27 1501.79
RHO, KG/CU M 5.1374 0 3.1665 0 1.4734-1 1.2882-1 1.0546-1 8.9145-2 8.2711-2 6.7912-2
H, KJ/KG -1577.58 -2299.27 -5827.79 -5937.64 -6095.62 -6223.15 -6278.51 -6419.95
U, KJ/KG -2940.14 -3579.24 -6506.51 -6596.29 -6725.17 -6828.97 -6873.97 -6988.71
G, KJ/KG -44819.2 -43452.6 -27650.0 -27114.7 -26336.9 -25701.5 -25423.5 -24706.7
S, KJ/(KG)(K) 12.1766 12.1766 12.1766 12.1766 12.1766 12.1766 12.1766 12.1766

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M, (1/n) 21.670 21.954 21.954 21.954 21.954 21.954 21.954 21.954

Cp, KJ/(KG)(K) 7.0770 6.8984 2.0804 2.0663 2.0448 2.0263 2.0179 1.9954
GAMMAs 1.1309 1.1277 1.2226 1.2244 1.2273 1.2299 1.2310 1.2343
SON VEL,M/SEC 1241.3 1201.4 910.9 898.0 879.0 863.2 856.2 837.9
MACH NUMBER 0.000 1.000 3.201 3.288 3.420 3.531 3.581 3.714

PERFORMANCE PARAMETERS

Ae/At 1.0000 8.8560 10.000 12.000 14.000 15.000 18.000

CSTAR, M/SEC 1840.0 1840.0 1840.0 1840.0 1840.0 1840.0 1840.0
CF 0.6529 1.5845 1.6048 1.6337 1.6566 1.6664 1.6913
Ivac, M/SEC 2266.8 3148.3 3176.0 3215.4 3246.9 3260.4 3294.8
Isp, M/SEC 1201.4 2915.5 2953.0 3006.0 3048.1 3066.2 3112.0

MOLE FRACTIONS

*CO 0.17297 *CO2 0.13803 COOH 0.00001

*H 0.01959 HCO 0.00001 HO2 0.00008
*H2 0.07817 H2O 0.50485 H2O2 0.00001
*O 0.00798 *OH 0.05835 *O2 0.01995

* THERMODYNAMIC PROPERTIES FITTED TO 20000.K

PRODUCTS WHICH WERE CONSIDERED BUT WHOSE MOLE FRACTIONS

WERE LESS THAN 5.000000E-06 FOR ALL ASSIGNED CONDITIONS

*C *CH CH2 CH3 CH2OH

CH3O CH4 CH3OH CH3OOH *C2
C2H C2H2,acetylene C2H2,vinylidene CH2CO,ketene O(CH)2O
HO(CO)2OH C2H3,vinyl CH3CO,acetyl C2H4 C2H4O,ethylen-o
CH3CHO,ethanal CH3COOH OHCH2COOH C2H5 C2H6
C2H5OH CH3OCH3 CH3O2CH3 C2O *C3
C3H3,1-propynl C3H3,2-propynl C3H4,allene C3H4,propyne C3H4,cyclo-
C3H5,allyl C3H6,propylene C3H6,cyclo- C3H6O,propylox C3H6O,acetone
C3H6O,propanal C3H7,n-propyl C3H7,i-propyl C3H8 C3H8O,1propanol
C3H8O,2propanol C3O2 *C4 C4H2,butadiyne C4H4,1,3-cyclo-
C4H6,butadiene C4H6,1butyne C4H6,2butyne C4H6,cyclo- C4H8,1-butene
C4H8,cis2-buten C4H8,tr2-butene C4H8,isobutene C4H8,cyclo- (CH3COOH)2
C4H9,n-butyl C4H9,i-butyl C4H9,s-butyl C4H9,t-butyl C4H10,n-butane
C4H10,isobutane *C5 C5H6,1,3cyclo- C5H8,cyclo- C5H10,1-pentene
C5H10,cyclo- C5H11,pentyl C5H11,t-pentyl C5H12,n-pentane C5H12,i-pentane
CH3C(CH3)2CH3 C6H2 C6H5,phenyl C6H5O,phenoxy C6H6
C6H5OH,phenol C6H10,cyclo- C6H12,1-hexene C6H12,cyclo- C6H13,n-hexyl
C6H14,n-hexane C7H7,benzyl C7H8 C7H8O,cresol-mx C7H14,1-heptene
C7H15,n-heptyl C7H16,n-heptane C7H16,2-methylh C8H8,styrene C8H10,ethylbenz
C8H16,1-octene C8H17,n-octyl C8H18,n-octane C8H18,isooctane C9H19,n-nonyl
C10H8,naphthale C10H21,n-decyl C12H9,o-bipheny C12H10,biphenyl HCCO
HCHO,formaldehy HCOOH (HCOOH)2 O3 C(gr)
H2O(cr) H2O(L)

NOTE. WEIGHT FRACTION OF FUEL IN TOTAL FUELS AND OF OXIDANT IN TOTAL OXIDANTS

THEORETICAL ROCKET PERFORMANCE ASSUMING FROZEN COMPOSITION

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AFTER POINT 2

Pin = 1015.3 PSIA

CASE =

REACTANT WT FRACTION ENERGY TEMP

(SEE NOTE) KJ/KG-MOL K
FUEL CH4(L) 1.0000000 -89233.000 112.000
OXIDANT O2(L) 1.0000000 -12979.000 90.000

O/F= 3.40000 %FUEL= 22.727273 R,EQ.RATIO= 1.173313 PHI,EQ.RATIO= 1.173313

CHAMBER THROAT EXIT EXIT EXIT

Pinf/P 1.0000 1.7271 208.48 236.60 280.31
P, BAR 70.000 40.530 0.33576 0.29585 0.24973
T, K 3551.20 3379.70 1462.26 1427.23 1381.29
RHO, KG/CU M 5.1374 0 3.1665 0 6.0631-2 5.4735-2 4.7738-2
H, KJ/KG -1577.58 -2299.27 -6498.57 -6567.81 -6657.94
U, KJ/KG -2940.14 -3579.24 -7052.36 -7108.33 -7181.07
G, KJ/KG -44819.2 -43452.6 -24304.0 -23946.6 -23477.4
S, KJ/(KG)(K) 12.1766 12.1766 12.1766 12.1766 12.1766

M, (1/n) 21.670 21.954 21.954 21.954 21.954

Cp, KJ/(KG)(K) 7.0770 6.8984 1.9823 1.9703 1.9541
GAMMAs 1.1309 1.1277 1.2362 1.2380 1.2404
SON VEL,M/SEC 1241.3 1201.4 827.4 818.0 805.5
MACH NUMBER 0.000 1.000 3.792 3.862 3.957

PERFORMANCE PARAMETERS

Ae/At 1.0000 20.000 22.000 25.000

CSTAR, M/SEC 1840.0 1840.0 1840.0 1840.0
CF 0.6529 1.7050 1.7169 1.7323
Ivac, M/SEC 2266.8 3313.7 3330.3 3351.7
Isp, M/SEC 1201.4 3137.2 3159.2 3187.6

MOLE FRACTIONS

*CO 0.17297 *CO2 0.13803 COOH 0.00001

*H 0.01959 HCO 0.00001 HO2 0.00008
*H2 0.07817 H2O 0.50485 H2O2 0.00001
*O 0.00798 *OH 0.05835 *O2 0.01995

* THERMODYNAMIC PROPERTIES FITTED TO 20000.K

PRODUCTS WHICH WERE CONSIDERED BUT WHOSE MOLE FRACTIONS

WERE LESS THAN 5.000000E-06 FOR ALL ASSIGNED CONDITIONS

*C *CH CH2 CH3 CH2OH

CH3O CH4 CH3OH CH3OOH *C2
C2H C2H2,acetylene C2H2,vinylidene CH2CO,ketene O(CH)2O
HO(CO)2OH C2H3,vinyl CH3CO,acetyl C2H4 C2H4O,ethylen-o
CH3CHO,ethanal CH3COOH OHCH2COOH C2H5 C2H6
C2H5OH CH3OCH3 CH3O2CH3 C2O *C3
C3H3,1-propynl C3H3,2-propynl C3H4,allene C3H4,propyne C3H4,cyclo-
C3H5,allyl C3H6,propylene C3H6,cyclo- C3H6O,propylox C3H6O,acetone
C3H6O,propanal C3H7,n-propyl C3H7,i-propyl C3H8 C3H8O,1propanol

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C3H8O,2propanol C3O2 *C4 C4H2,butadiyne C4H4,1,3-cyclo-

C4H6,butadiene C4H6,1butyne C4H6,2butyne C4H6,cyclo- C4H8,1-butene
C4H8,cis2-buten C4H8,tr2-butene C4H8,isobutene C4H8,cyclo- (CH3COOH)2
C4H9,n-butyl C4H9,i-butyl C4H9,s-butyl C4H9,t-butyl C4H10,n-butane
C4H10,isobutane *C5 C5H6,1,3cyclo- C5H8,cyclo- C5H10,1-pentene
C5H10,cyclo- C5H11,pentyl C5H11,t-pentyl C5H12,n-pentane C5H12,i-pentane
CH3C(CH3)2CH3 C6H2 C6H5,phenyl C6H5O,phenoxy C6H6
C6H5OH,phenol C6H10,cyclo- C6H12,1-hexene C6H12,cyclo- C6H13,n-hexyl
C6H14,n-hexane C7H7,benzyl C7H8 C7H8O,cresol-mx C7H14,1-heptene
C7H15,n-heptyl C7H16,n-heptane C7H16,2-methylh C8H8,styrene C8H10,ethylbenz
C8H16,1-octene C8H17,n-octyl C8H18,n-octane C8H18,isooctane C9H19,n-nonyl
C10H8,naphthale C10H21,n-decyl C12H9,o-bipheny C12H10,biphenyl HCCO
HCHO,formaldehy HCOOH (HCOOH)2 O3 C(gr)
H2O(cr) H2O(L)

NOTE. WEIGHT FRACTION OF FUEL IN TOTAL FUELS AND OF OXIDANT IN TOTAL OXIDANTS

O/F = 3.300000

EFFECTIVE FUEL EFFECTIVE OXIDANT MIXTURE

ENTHALPY h(2)/R h(1)/R h0/R
(KG-MOL)(K)/KG -0.66898729E+03 -0.48783267E+02 -0.19301676E+03

KG-FORM.WT./KG bi(2) bi(1) b0i

*C 0.62334580E-01 0.00000000E+00 0.14496414E-01
*H 0.24933832E+00 0.00000000E+00 0.57985655E-01
*O 0.00000000E+00 0.62502344E-01 0.47966915E-01

POINT ITN T C H O
1 3 3539.207 -15.606 -9.799 -15.359
Pinf/Pt = 1.730180
2 3 3364.239 -15.917 -9.999 -15.627
Pinf/Pt = 1.728341
2 2 3364.569 -15.917 -9.999 -15.627
3 5 2272.722 -16.902 -11.189 -19.013
4 3 2238.973 -16.865 -11.212 -19.195
4 3 2284.161 -16.913 -11.181 -18.952
4 1 2284.198 -16.913 -11.181 -18.952
5 3 2207.325 -16.827 -11.233 -19.372
5 1 2207.395 -16.827 -11.233 -19.371
6 3 2142.445 -16.737 -11.275 -19.753
7 3 2048.887 -16.578 -11.334 -20.350
7 3 2113.402 -16.691 -11.294 -19.932
7 1 2113.473 -16.691 -11.294 -19.931
8 3 2037.463 -16.557 -11.341 -20.427
8 1 2037.490 -16.557 -11.341 -20.427

THEORETICAL ROCKET PERFORMANCE ASSUMING EQUILIBRIUM

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COMPOSITION DURING EXPANSION FROM INFINITE AREA COMBUSTOR

Pin = 1015.3 PSIA

CASE =

REACTANT WT FRACTION ENERGY TEMP

(SEE NOTE) KJ/KG-MOL K
FUEL CH4(L) 1.0000000 -89233.000 112.000
OXIDANT O2(L) 1.0000000 -12979.000 90.000

O/F= 3.30000 %FUEL= 23.255814 R,EQ.RATIO= 1.208868 PHI,EQ.RATIO= 1.208868

CHAMBER THROAT EXIT EXIT EXIT EXIT EXIT EXIT

Pinf/P 1.0000 1.7283 70.000 67.545 85.712 104.78 114.63 145.26
P, BAR 70.000 40.501 1.0000 1.0363 0.81669 0.66804 0.61068 0.48190
T, K 3539.21 3364.57 2272.72 2284.20 2207.40 2142.44 2113.47 2037.49
RHO, KG/CU M 5.0883 0 3.1365 0 1.2134-1 1.2509-1 1.0211-1 8.6106-2 7.9809-2 6.5356-2
H, KJ/KG -1604.84 -2334.16 -6219.46 -6189.96 -6383.88 -6542.16 -6611.34 -6789.26
U, KJ/KG -2980.54 -3625.43 -7043.62 -7018.42 -7183.72 -7318.00 -7376.52 -7526.60
G, KJ/KG -45057.8 -43643.0 -34123.1 -34234.4 -33485.4 -32846.3 -32559.7 -31804.8
S, KJ/(KG)(K) 12.2776 12.2776 12.2776 12.2776 12.2776 12.2776 12.2776 12.2776

M, (1/n) 21.390 21.664 22.928 22.924 22.946 22.960 22.965 22.975

(dLV/dLP)t -1.03576 -1.03076 -1.00153 -1.00163 -1.00109 -1.00077 -1.00065 -1.00042
(dLV/dLT)p 1.6399 1.5808 1.0424 1.0448 1.0309 1.0221 1.0190 1.0125
Cp, KJ/(KG)(K) 6.8485 6.5912 2.6709 2.6948 2.5507 2.4551 2.4190 2.3406
GAMMAs 1.1323 1.1296 1.1710 1.1700 1.1763 1.1811 1.1831 1.1878
SON VEL,M/SEC 1248.1 1207.7 982.4 984.5 970.0 957.3 951.5 935.8
MACH NUMBER 0.000 1.000 3.092 3.076 3.187 3.283 3.326 3.441

PERFORMANCE PARAMETERS

Ae/At 1.0000 10.277 10.000 12.000 14.000 15.000 18.000

CSTAR, M/SEC 1847.9 1847.9 1847.9 1847.9 1847.9 1847.9 1847.9
CF 0.6536 1.6440 1.6388 1.6731 1.7005 1.7124 1.7426
Ivac, M/SEC 2276.9 3309.3 3301.8 3350.3 3389.3 3406.1 3449.1
Isp, M/SEC 1207.7 3038.0 3028.2 3091.6 3142.4 3164.3 3220.1

MOLE FRACTIONS

*CO 0.18846 0.18277 0.14704 0.14732 0.14541 0.14372 0.14294 0.14075

*CO2 0.12159 0.13127 0.18534 0.18501 0.18723 0.18912 0.18998 0.19231
COOH 0.00001 0.00001 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000
*H 0.02321 0.01993 0.00242 0.00253 0.00189 0.00145 0.00128 0.00090
HCO 0.00001 0.00001 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000
HO2 0.00010 0.00006 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000
*H2 0.09047 0.08707 0.08327 0.08303 0.08474 0.08638 0.08716 0.08937
H2O 0.48659 0.50462 0.57881 0.57881 0.57857 0.57789 0.57745 0.57595
H2O2 0.00002 0.00001 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000
*O 0.00871 0.00661 0.00005 0.00006 0.00003 0.00001 0.00001 0.00000
*OH 0.06283 0.05282 0.00291 0.00309 0.00204 0.00139 0.00116 0.00070
*O2 0.01798 0.01483 0.00015 0.00017 0.00008 0.00004 0.00003 0.00001

* THERMODYNAMIC PROPERTIES FITTED TO 20000.K

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PRODUCTS WHICH WERE CONSIDERED BUT WHOSE MOLE FRACTIONS

WERE LESS THAN 5.000000E-06 FOR ALL ASSIGNED CONDITIONS

*C *CH CH2 CH3 CH2OH

CH3O CH4 CH3OH CH3OOH *C2
C2H C2H2,acetylene C2H2,vinylidene CH2CO,ketene O(CH)2O
HO(CO)2OH C2H3,vinyl CH3CO,acetyl C2H4 C2H4O,ethylen-o
CH3CHO,ethanal CH3COOH OHCH2COOH C2H5 C2H6
C2H5OH CH3OCH3 CH3O2CH3 C2O *C3
C3H3,1-propynl C3H3,2-propynl C3H4,allene C3H4,propyne C3H4,cyclo-
C3H5,allyl C3H6,propylene C3H6,cyclo- C3H6O,propylox C3H6O,acetone
C3H6O,propanal C3H7,n-propyl C3H7,i-propyl C3H8 C3H8O,1propanol
C3H8O,2propanol C3O2 *C4 C4H2,butadiyne C4H4,1,3-cyclo-
C4H6,butadiene C4H6,1butyne C4H6,2butyne C4H6,cyclo- C4H8,1-butene
C4H8,cis2-buten C4H8,tr2-butene C4H8,isobutene C4H8,cyclo- (CH3COOH)2
C4H9,n-butyl C4H9,i-butyl C4H9,s-butyl C4H9,t-butyl C4H10,n-butane
C4H10,isobutane *C5 C5H6,1,3cyclo- C5H8,cyclo- C5H10,1-pentene
C5H10,cyclo- C5H11,pentyl C5H11,t-pentyl C5H12,n-pentane C5H12,i-pentane
CH3C(CH3)2CH3 C6H2 C6H5,phenyl C6H5O,phenoxy C6H6
C6H5OH,phenol C6H10,cyclo- C6H12,1-hexene C6H12,cyclo- C6H13,n-hexyl
C6H14,n-hexane C7H7,benzyl C7H8 C7H8O,cresol-mx C7H14,1-heptene
C7H15,n-heptyl C7H16,n-heptane C7H16,2-methylh C8H8,styrene C8H10,ethylbenz
C8H16,1-octene C8H17,n-octyl C8H18,n-octane C8H18,isooctane C9H19,n-nonyl
C10H8,naphthale C10H21,n-decyl C12H9,o-bipheny C12H10,biphenyl HCCO
HCHO,formaldehy HCOOH (HCOOH)2 O3 C(gr)
H2O(cr) H2O(L)

NOTE. WEIGHT FRACTION OF FUEL IN TOTAL FUELS AND OF OXIDANT IN TOTAL OXIDANTS

3 3 1994.105 -16.470 -11.367 -20.728

4 3 1912.690 -16.286 -11.416 -21.334
4 3 1955.260 -16.386 -11.391 -21.010
4 1 1955.294 -16.386 -11.391 -21.010
5 3 1903.936 -16.265 -11.421 -21.402

THEORETICAL ROCKET PERFORMANCE ASSUMING EQUILIBRIUM

COMPOSITION DURING EXPANSION FROM INFINITE AREA COMBUSTOR

Pin = 1015.3 PSIA

CASE =

REACTANT WT FRACTION ENERGY TEMP

(SEE NOTE) KJ/KG-MOL K
FUEL CH4(L) 1.0000000 -89233.000 112.000
OXIDANT O2(L) 1.0000000 -12979.000 90.000

O/F= 3.30000 %FUEL= 23.255814 R,EQ.RATIO= 1.208868 PHI,EQ.RATIO= 1.208868

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CHAMBER THROAT EXIT EXIT EXIT

Pinf/P 1.0000 1.7283 166.52 188.38 222.23
P, BAR 70.000 40.501 0.42037 0.37158 0.31498
T, K 3539.21 3364.57 1994.11 1955.29 1903.94
RHO, KG/CU M 5.0883 0 3.1365 0 5.8262-2 5.2530-2 4.5737-2
H, KJ/KG -1604.84 -2334.16 -6888.90 -6977.03 -7092.37
U, KJ/KG -2980.54 -3625.43 -7610.41 -7684.39 -7781.06
G, KJ/KG -45057.8 -43643.0 -31371.7 -30983.4 -30468.2
S, KJ/(KG)(K) 12.2776 12.2776 12.2776 12.2776 12.2776

M, (1/n) 21.390 21.664 22.980 22.983 22.986

(dLV/dLP)t -1.03576 -1.03076 -1.00032 -1.00025 -1.00018
(dLV/dLT)p 1.6399 1.5808 1.0097 1.0077 1.0056
Cp, KJ/(KG)(K) 6.8485 6.5912 2.3046 2.2768 2.2456
GAMMAs 1.1323 1.1296 1.1901 1.1920 1.1943
SON VEL,M/SEC 1248.1 1207.7 926.6 918.3 906.9
MACH NUMBER 0.000 1.000 3.508 3.570 3.653

PERFORMANCE PARAMETERS

Ae/At 1.0000 20.000 22.000 25.000

CSTAR, M/SEC 1847.9 1847.9 1847.9 1847.9
CF 0.6536 1.7592 1.7738 1.7928
Ivac, M/SEC 2276.9 3472.8 3493.7 3520.7
Isp, M/SEC 1207.7 3250.9 3277.9 3312.9

MOLE FRACTIONS

*CO 0.18846 0.18277 0.13940 0.13813 0.13634

*CO2 0.12159 0.13127 0.19372 0.19504 0.19687
COOH 0.00001 0.00001 0.00000 0.00000 0.00000
*H 0.02321 0.01993 0.00073 0.00059 0.00045
HCO 0.00001 0.00001 0.00000 0.00000 0.00000
HO2 0.00010 0.00006 0.00000 0.00000 0.00000
*H2 0.09047 0.08707 0.09074 0.09203 0.09386
H2O 0.48659 0.50462 0.57489 0.57381 0.57222
H2O2 0.00002 0.00001 0.00000 0.00000 0.00000
*O 0.00871 0.00661 0.00000 0.00000 0.00000
*OH 0.06283 0.05282 0.00051 0.00038 0.00026
*O2 0.01798 0.01483 0.00001 0.00000 0.00000

* THERMODYNAMIC PROPERTIES FITTED TO 20000.K

PRODUCTS WHICH WERE CONSIDERED BUT WHOSE MOLE FRACTIONS

WERE LESS THAN 5.000000E-06 FOR ALL ASSIGNED CONDITIONS

*C *CH CH2 CH3 CH2OH

CH3O CH4 CH3OH CH3OOH *C2
C2H C2H2,acetylene C2H2,vinylidene CH2CO,ketene O(CH)2O
HO(CO)2OH C2H3,vinyl CH3CO,acetyl C2H4 C2H4O,ethylen-o
CH3CHO,ethanal CH3COOH OHCH2COOH C2H5 C2H6
C2H5OH CH3OCH3 CH3O2CH3 C2O *C3
C3H3,1-propynl C3H3,2-propynl C3H4,allene C3H4,propyne C3H4,cyclo-
C3H5,allyl C3H6,propylene C3H6,cyclo- C3H6O,propylox C3H6O,acetone
C3H6O,propanal C3H7,n-propyl C3H7,i-propyl C3H8 C3H8O,1propanol
C3H8O,2propanol C3O2 *C4 C4H2,butadiyne C4H4,1,3-cyclo-

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C4H6,butadiene C4H6,1butyne C4H6,2butyne C4H6,cyclo- C4H8,1-butene

C4H8,cis2-buten C4H8,tr2-butene C4H8,isobutene C4H8,cyclo- (CH3COOH)2
C4H9,n-butyl C4H9,i-butyl C4H9,s-butyl C4H9,t-butyl C4H10,n-butane
C4H10,isobutane *C5 C5H6,1,3cyclo- C5H8,cyclo- C5H10,1-pentene
C5H10,cyclo- C5H11,pentyl C5H11,t-pentyl C5H12,n-pentane C5H12,i-pentane
CH3C(CH3)2CH3 C6H2 C6H5,phenyl C6H5O,phenoxy C6H6
C6H5OH,phenol C6H10,cyclo- C6H12,1-hexene C6H12,cyclo- C6H13,n-hexyl
C6H14,n-hexane C7H7,benzyl C7H8 C7H8O,cresol-mx C7H14,1-heptene
C7H15,n-heptyl C7H16,n-heptane C7H16,2-methylh C8H8,styrene C8H10,ethylbenz
C8H16,1-octene C8H17,n-octyl C8H18,n-octane C8H18,isooctane C9H19,n-nonyl
C10H8,naphthale C10H21,n-decyl C12H9,o-bipheny C12H10,biphenyl HCCO
HCHO,formaldehy HCOOH (HCOOH)2 O3 C(gr)
H2O(cr) H2O(L)

NOTE. WEIGHT FRACTION OF FUEL IN TOTAL FUELS AND OF OXIDANT IN TOTAL OXIDANTS

THEORETICAL ROCKET PERFORMANCE ASSUMING FROZEN COMPOSITION

AFTER POINT 2

Pin = 1015.3 PSIA

CASE =

REACTANT WT FRACTION ENERGY TEMP

(SEE NOTE) KJ/KG-MOL K
FUEL CH4(L) 1.0000000 -89233.000 112.000
OXIDANT O2(L) 1.0000000 -12979.000 90.000

O/F= 3.30000 %FUEL= 23.255814 R,EQ.RATIO= 1.208868 PHI,EQ.RATIO= 1.208868

CHAMBER THROAT EXIT EXIT EXIT EXIT EXIT EXIT

Pinf/P 1.0000 1.7283 70.000 82.760 105.80 130.09 142.67 181.96
P, BAR 70.000 40.501 1.0000 0.84582 0.66165 0.53809 0.49065 0.38469
T, K 3539.21 3364.57 1779.19 1725.31 1648.57 1586.02 1558.69 1488.33
RHO, KG/CU M 5.0883 0 3.1365 0 1.4645-1 1.2774-1 1.0458-1 8.8400-2 8.2021-2 6.7348-2
H, KJ/KG -1604.84 -2334.16 -5889.12 -6001.72 -6160.69 -6288.98 -6344.67 -6486.91
U, KJ/KG -2980.54 -3625.43 -6571.95 -6663.87 -6793.39 -6897.68 -6942.87 -7058.11
G, KJ/KG -45057.8 -43643.0 -27733.4 -27184.5 -26401.2 -25761.5 -25481.6 -24760.0
S, KJ/(KG)(K) 12.2776 12.2776 12.2776 12.2776 12.2776 12.2776 12.2776 12.2776

M, (1/n) 21.390 21.664 21.664 21.664 21.664 21.664 21.664 21.664

Cp, KJ/(KG)(K) 6.8485 6.5912 2.0971 2.0824 2.0604 2.0415 2.0329 2.0100
GAMMAs 1.1323 1.1296 1.2240 1.2259 1.2289 1.2315 1.2327 1.2360
SON VEL,M/SEC 1248.1 1207.7 914.2 901.0 881.8 865.8 858.7 840.2
MACH NUMBER 0.000 1.000 3.202 3.291 3.423 3.535 3.585 3.719

PERFORMANCE PARAMETERS

Ae/At 1.0000 8.8365 10.000 12.000 14.000 15.000 18.000

CSTAR, M/SEC 1847.9 1847.9 1847.9 1847.9 1847.9 1847.9 1847.9
CF 0.6536 1.5841 1.6048 1.6335 1.6564 1.6662 1.6910
Ivac, M/SEC 2276.9 3160.5 3188.7 3228.2 3259.6 3273.2 3307.6
Isp, M/SEC 1207.7 2927.2 2965.4 3018.6 3060.8 3078.9 3124.8

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MOLE FRACTIONS

*CO 0.18277 *CO2 0.13127 COOH 0.00001

*H 0.01993 HCO 0.00001 HO2 0.00006
*H2 0.08707 H2O 0.50462 H2O2 0.00001
*O 0.00661 *OH 0.05282 *O2 0.01483

* THERMODYNAMIC PROPERTIES FITTED TO 20000.K

PRODUCTS WHICH WERE CONSIDERED BUT WHOSE MOLE FRACTIONS

WERE LESS THAN 5.000000E-06 FOR ALL ASSIGNED CONDITIONS

*C *CH CH2 CH3 CH2OH

CH3O CH4 CH3OH CH3OOH *C2
C2H C2H2,acetylene C2H2,vinylidene CH2CO,ketene O(CH)2O
HO(CO)2OH C2H3,vinyl CH3CO,acetyl C2H4 C2H4O,ethylen-o
CH3CHO,ethanal CH3COOH OHCH2COOH C2H5 C2H6
C2H5OH CH3OCH3 CH3O2CH3 C2O *C3
C3H3,1-propynl C3H3,2-propynl C3H4,allene C3H4,propyne C3H4,cyclo-
C3H5,allyl C3H6,propylene C3H6,cyclo- C3H6O,propylox C3H6O,acetone
C3H6O,propanal C3H7,n-propyl C3H7,i-propyl C3H8 C3H8O,1propanol
C3H8O,2propanol C3O2 *C4 C4H2,butadiyne C4H4,1,3-cyclo-
C4H6,butadiene C4H6,1butyne C4H6,2butyne C4H6,cyclo- C4H8,1-butene
C4H8,cis2-buten C4H8,tr2-butene C4H8,isobutene C4H8,cyclo- (CH3COOH)2
C4H9,n-butyl C4H9,i-butyl C4H9,s-butyl C4H9,t-butyl C4H10,n-butane
C4H10,isobutane *C5 C5H6,1,3cyclo- C5H8,cyclo- C5H10,1-pentene
C5H10,cyclo- C5H11,pentyl C5H11,t-pentyl C5H12,n-pentane C5H12,i-pentane
CH3C(CH3)2CH3 C6H2 C6H5,phenyl C6H5O,phenoxy C6H6
C6H5OH,phenol C6H10,cyclo- C6H12,1-hexene C6H12,cyclo- C6H13,n-hexyl
C6H14,n-hexane C7H7,benzyl C7H8 C7H8O,cresol-mx C7H14,1-heptene
C7H15,n-heptyl C7H16,n-heptane C7H16,2-methylh C8H8,styrene C8H10,ethylbenz
C8H16,1-octene C8H17,n-octyl C8H18,n-octane C8H18,isooctane C9H19,n-nonyl
C10H8,naphthale C10H21,n-decyl C12H9,o-bipheny C12H10,biphenyl HCCO
HCHO,formaldehy HCOOH (HCOOH)2 O3 C(gr)
H2O(cr) H2O(L)

NOTE. WEIGHT FRACTION OF FUEL IN TOTAL FUELS AND OF OXIDANT IN TOTAL OXIDANTS

THEORETICAL ROCKET PERFORMANCE ASSUMING FROZEN COMPOSITION

AFTER POINT 2

Pin = 1015.3 PSIA

CASE =

REACTANT WT FRACTION ENERGY TEMP

(SEE NOTE) KJ/KG-MOL K
FUEL CH4(L) 1.0000000 -89233.000 112.000
OXIDANT O2(L) 1.0000000 -12979.000 90.000

O/F= 3.30000 %FUEL= 23.255814 R,EQ.RATIO= 1.208868 PHI,EQ.RATIO= 1.208868

CHAMBER THROAT EXIT EXIT EXIT

Pinf/P 1.0000 1.7283 209.36 237.64 281.60

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P, BAR 70.000 40.501 0.33435 0.29456 0.24858

T, K 3539.21 3364.57 1448.87 1413.90 1368.06
RHO, KG/CU M 5.0883 0 3.1365 0 6.0129-2 5.4283-2 4.7345-2
H, KJ/KG -1604.84 -2334.16 -6565.96 -6635.56 -6726.15
U, KJ/KG -2980.54 -3625.43 -7122.01 -7178.19 -7251.19
G, KJ/KG -45057.8 -43643.0 -24354.6 -23994.9 -23522.6
S, KJ/(KG)(K) 12.2776 12.2776 12.2776 12.2776 12.2776

M, (1/n) 21.390 21.664 21.664 21.664 21.664

Cp, KJ/(KG)(K) 6.8485 6.5912 1.9966 1.9844 1.9678
GAMMAs 1.1323 1.1296 1.2380 1.2398 1.2423
SON VEL,M/SEC 1248.1 1207.7 829.7 820.2 807.6
MACH NUMBER 0.000 1.000 3.797 3.867 3.963

PERFORMANCE PARAMETERS

Ae/At 1.0000 20.000 22.000 25.000

CSTAR, M/SEC 1847.9 1847.9 1847.9 1847.9
CF 0.6536 1.7046 1.7165 1.7319
Ivac, M/SEC 2276.9 3326.5 3343.0 3364.5
Isp, M/SEC 1207.7 3150.0 3172.0 3200.4

MOLE FRACTIONS

*CO 0.18277 *CO2 0.13127 COOH 0.00001

*H 0.01993 HCO 0.00001 HO2 0.00006
*H2 0.08707 H2O 0.50462 H2O2 0.00001
*O 0.00661 *OH 0.05282 *O2 0.01483

* THERMODYNAMIC PROPERTIES FITTED TO 20000.K

PRODUCTS WHICH WERE CONSIDERED BUT WHOSE MOLE FRACTIONS

WERE LESS THAN 5.000000E-06 FOR ALL ASSIGNED CONDITIONS

*C *CH CH2 CH3 CH2OH

CH3O CH4 CH3OH CH3OOH *C2
C2H C2H2,acetylene C2H2,vinylidene CH2CO,ketene O(CH)2O
HO(CO)2OH C2H3,vinyl CH3CO,acetyl C2H4 C2H4O,ethylen-o
CH3CHO,ethanal CH3COOH OHCH2COOH C2H5 C2H6
C2H5OH CH3OCH3 CH3O2CH3 C2O *C3
C3H3,1-propynl C3H3,2-propynl C3H4,allene C3H4,propyne C3H4,cyclo-
C3H5,allyl C3H6,propylene C3H6,cyclo- C3H6O,propylox C3H6O,acetone
C3H6O,propanal C3H7,n-propyl C3H7,i-propyl C3H8 C3H8O,1propanol
C3H8O,2propanol C3O2 *C4 C4H2,butadiyne C4H4,1,3-cyclo-
C4H6,butadiene C4H6,1butyne C4H6,2butyne C4H6,cyclo- C4H8,1-butene
C4H8,cis2-buten C4H8,tr2-butene C4H8,isobutene C4H8,cyclo- (CH3COOH)2
C4H9,n-butyl C4H9,i-butyl C4H9,s-butyl C4H9,t-butyl C4H10,n-butane
C4H10,isobutane *C5 C5H6,1,3cyclo- C5H8,cyclo- C5H10,1-pentene
C5H10,cyclo- C5H11,pentyl C5H11,t-pentyl C5H12,n-pentane C5H12,i-pentane
CH3C(CH3)2CH3 C6H2 C6H5,phenyl C6H5O,phenoxy C6H6
C6H5OH,phenol C6H10,cyclo- C6H12,1-hexene C6H12,cyclo- C6H13,n-hexyl
C6H14,n-hexane C7H7,benzyl C7H8 C7H8O,cresol-mx C7H14,1-heptene
C7H15,n-heptyl C7H16,n-heptane C7H16,2-methylh C8H8,styrene C8H10,ethylbenz
C8H16,1-octene C8H17,n-octyl C8H18,n-octane C8H18,isooctane C9H19,n-nonyl
C10H8,naphthale C10H21,n-decyl C12H9,o-bipheny C12H10,biphenyl HCCO
HCHO,formaldehy HCOOH (HCOOH)2 O3 C(gr)
H2O(cr) H2O(L)

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NOTE. WEIGHT FRACTION OF FUEL IN TOTAL FUELS AND OF OXIDANT IN TOTAL OXIDANTS

16