Structure of Atom JEE Main 2023 (April) Chapter-wise Qs Bank

Questions with Solutions MathonGo

1. The wavelength of an electron of kinetic energy 4. 50 × 10 −29

J is ________ × 10– 5 m. (Nearest integer) Given: mass of electron is
9 × 10– 31 kg, h = 6. 6 × 10– 34 Js

[2023 (06 Apr Shift 1)]

2. If the radius of the first orbit of hydrogen atom is a , then de Broglie’s wavelength of electron in 3 orbit is
0
rd

[2023 (06 Apr Shift 2)]

(1)
πa0

(2)
πa0

(3) 6πa0

(4) 3πa0

3. The number of following statement/s which is/are incorrect is ______

A) Line emission spectra are used to study the electronic structure
B) The emission spectra of atoms in the gas phase show a continuous spread of wavelength from red to violet.
C) An absorption spectrum is like the photographic negative of an emission spectrum
D) The element helium was discovered in the sun by spectroscopic method
[2023 (08 Apr Shift 1)]
4. Henry Moseley studied characteristic X-ray spectra of elements. The graph which represents his observation correctly is
Given v = Frequency of X-ray emitted
Z = Atomic number
[2023 (08 Apr Shift 2)]
(1)

(2)

(3)

(4)

5. The number of atomic orbitals from the following having 5 radial nodes is
7s, 7p, 6s, 8p, 8d

[2023 (08 Apr Shift 2)]

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Structure of Atom JEE Main 2023 (April) Chapter-wise Qs Bank
Questions with Solutions MathonGo

6.

The electron in the n th

orbit of Li 2+
is excited to (n + 1) orbit using the radiation of energy 1. 47 × 10 −17
J (as shown in the diagram). The value of n is
___________
Given : R H
= 2. 18 × 10
−18
J

[2023 (10 Apr Shift 2)]

7. For a metal ion, the calculated magnetic moment is 4. 90 BM . This metal ion has _______ number of unpaired electrons
[2023 (10 Apr Shift 2)]
8. Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R :
Assertion A: In the photoelectric effect, the electrons are ejected from the metal surface as soon as the beam of light of frequency greater than threshold
frequency strikes the surface.
Reason R : When the photon of any energy strikes an electron in the atom, transfer of energy from the photon to the electron takes place.
In the light of the above statements, choose the most appropriate answer from the options given below :
[2023 (11 Apr Shift 1)]
(1) Both A and R are correct and R is the correct explanation of A
(2) A is correct but R is not correct
(3) Both A and R are correct but R is NOT the correct explanation of A
(4) A is not correct but R is correct
9. The number of correct statements from the following is ...........
A. For 1s orbital, the probability density is maximum at the nucleus
B. For 2s orbital, the probability density first increases to maximum and then decreases sharply to zero.
C. Boundary surface diagrams of the orbitals encloses a region of 100% probability of finding the electron.
D. p and d-orbitals have 1 and 2 angular nodes respectively
E. probability density of p-orbital is zero at the nucleus

[2023 (11 Apr Shift 2)]

10. Given below are two statement : one is labelled as Assertion A and the other is labelled as Reason R
Assertion A : 5f electron can participate in bonding to a far greater extent than 4f electrons
Reason R : 5f orbitals are not as buried as 4f orbitals
In the light of the above statements, choose the correct answer from the options given below
[2023 (12 Apr Shift 1)]
(1) A is false but R is true
(2) Both A and R are true and R is the correct explanation of A
(3) A is true but R is false
(4) Both A and R are true but R is NOT the correct explanation of A
11. Values of work function (W 0
) for a few metals are given below
Metal Li Na K Mg Cu Ag

W0
2. 42 2. 3 2. 25 3. 7 4. 8 4. 3
eV

The number of metals which will show photoelectric effect when light of wavelength 400 nm falls on it is _____
Given: h = 6. 6 × 10 –34
J s

8 –1
c = 3 × 10 ms

–19
e = 1. 6 × 10 C

[2023 (12 Apr Shift 1)]

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Structure of Atom JEE Main 2023 (April) Chapter-wise Qs Bank
Questions with Solutions MathonGo

12. The energy of an electron in the first Bohr orbit of hydrogen atom is −2. 18 × 10 −18
J Its energy in the third Bohr orbit is_______.
[2023 (13 Apr Shift 1)]
(1) 1

9
th of the value
(2) 1

27
of this value
(3) Three times of this value
(4) One third of this value
13. The orbital angular momentum of an electron in 3 s orbital is xh

2π
. The value of x is (nearest integer)
[2023 (13 Apr Shift 2)]
14. Given below are two statements
Statement I : According to Bohr’s model of hydrogen atom, the angular momentum of an electron in a given stationary state is quantised.
Statement II : The concept of electron in Bohr’s orbit, violates the Heisenberg uncertainty principle. In the light of the above statements, choose the most
appropriate answer from the options given below
[2023 (15 Apr Shift 1)]
(1) Statement I is incorrect but Statement II is correct
(2) Both Statement I and Statement II are correct
(3) Both Statement I and Statement II are incorrect
(4) Statement I is correct but Statement II is incorrect
15. The total number of isoelectronic species from the given set is ________.
2− – 2+ + + 3+
O , F , Al, Mg , Na , O , Mg, Al , F

[2023 (15 Apr Shift 1)]

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Structure of Atom JEE Main 2023 (January) Chapter-wise Qs Bank
Questions with Solutions MathonGo

Q1 - 24 January - Shift 1

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Q2 - 24 January - Shift 1

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Q3 - 24 January - Shift 2

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Q4 - 25 January - Shift 1

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Structure of Atom JEE Main 2023 (January) Chapter-wise Qs Bank
Questions with Solutions MathonGo

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Q5 - 25 January - Shift 1

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Q6 - 29 January - Shift 1

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Q7 - 29 January - Shift 2

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Structure of Atom JEE Main 2023 (January) Chapter-wise Qs Bank
Questions with Solutions MathonGo

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Q8 - 30 January - Shift 1

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Q9 - 30 January - Shift 2

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Q10 - 30 January - Shift 2

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Structure of Atom JEE Main 2023 (January) Chapter-wise Qs Bank
Questions with Solutions MathonGo

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Q11 - 31 January - Shift 1

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Q12 - 31 January - Shift 2

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Q13 - 01 February - Shift 1

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Structure of Atom JEE Main 2023 (January) Chapter-wise Qs Bank
Questions with Solutions MathonGo

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Q14 - 01 February - Shift 2

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Structure of Atom JEE Main 2023 (January) Chapter-wise Qs Bank
Questions with Solutions MathonGo

Answer Key
(As per Official NTA Key released on 2 Feb)

Q1 (3) Q2 (492) Q3 (4) Q4 (3)

Q5 (2) Q6 (2) Q7 (270) Q8 (798)

Q9 (2) Q10 (4) Q11 (1) Q12 (2)

Q13 (2) Q14 (4)

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Structure of Atom JEE Main 2022 (July) Chapter-wise Qs Bank
Questions MathonGo

Q1 - 25 July - Shift 1

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Q2 - 25 July - Shift 2

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Q3 - 26 July - Shift 1

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Q4 - 26 July - Shift 2

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Structure of Atom JEE Main 2022 (July) Chapter-wise Qs Bank
Questions MathonGo

Q5 - 27 July - Shift 1

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Q6 - 27 July - Shift 2

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Q7 - 28 July - Shift 1

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Structure of Atom JEE Main 2022 (July) Chapter-wise Qs Bank
Questions MathonGo

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Q8 - 28 July - Shift 2

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Q9 - 29 July - Shift 1

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Q10 - 29 July - Shift 2

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Structure of Atom JEE Main 2022 (July) Chapter-wise Qs Bank
Questions MathonGo

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Structure of Atom JEE Main 2022 (July) Chapter-wise Qs Bank
Questions MathonGo

Answer Key

Q1 (C) Q2 (4) Q3 (1758) Q4 (4)

Q5 (A) Q6 (A) Q7 (D) Q8 (2)

Q9 (548) Q10 (B)

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Structure of Atom JEE Main 2022 (June) Chapter-wise Qs Bank
Questions MathonGo

Q1 - 24 June - Shift 1

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Q2 - 24 June - Shift 2

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Q3 - 25 June - Shift 1

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Structure of Atom JEE Main 2022 (June) Chapter-wise Qs Bank
Questions MathonGo

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Q4 - 25 June - Shift 1

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Q5 - 25 June - Shift 2

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Q6 - 26 June - Shift 1

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Structure of Atom JEE Main 2022 (June) Chapter-wise Qs Bank
Questions MathonGo

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Q7 - 26 June - Shift 2

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Q8 - 27 June - Shift 1

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Q9 - 27 June - Shift 2

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Structure of Atom JEE Main 2022 (June) Chapter-wise Qs Bank
Questions MathonGo

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Q10 - 28 June - Shift 1

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Q11 - 28 June - Shift 2

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Structure of Atom JEE Main 2022 (June) Chapter-wise Qs Bank
Questions MathonGo

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Q12 - 29 June - Shift 1

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Structure of Atom JEE Main 2022 (June) Chapter-wise Qs Bank
Questions MathonGo

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Q13 - 29 June - Shift 1

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Q14 - 29 June - Shift 2

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Structure of Atom JEE Main 2022 (June) Chapter-wise Qs Bank
Questions MathonGo

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Structure of Atom JEE Main 2022 (June) Chapter-wise Qs Bank
Questions MathonGo

Answer Key

Q1 (B) Q2 (C) Q3 (D) Q4 (4)

Q5 (C) Q6 (B) Q7 (A) Q8 (22)

Q9 (2) Q10 (300) Q11 (C) Q12 (D)

Q13 (A) Q14 (B)

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Structure of Atom JEE Main 2021 (August) Chapter-wise Questions
Questions with Answer Keys MathonGo

Q1 2021 (01 Sep Shift 2)

A 50 watt bulb emits monochromatic red light of wavelength of 795 nm. The number of photons emitted per

second by the bulb is x × 10 . The value of x is ____.

20

[ Given : h = 6.63 × 10 −34

Js and c = 3.0 × 10
8
ms
−1
]

Q2 2021 (31 Aug Shift 2)

The value of magnetic quantum number of the outermost electron of Zn ion is ____. +

Q3 2021 (31 Aug Shift 1)

Ge(Z = 32) in its ground state electronic configuration has x completely filled orbitals with m l
= 0 . The
value of x is ____.

Q4 2021 (27 Aug Shift 2)

The number of photons emitted by a monochromatic (single frequency) infrared range finder of power 1 mW
and wavelength of 1000 nm, in 0.1 second is x × 10 . The value of x is ____. (Nearest integer)
13

−34 8 −1
(h = 6.63 × 10 Js, c = 3.00 × 10 ms )

Q5 2021 (27 Aug Shift 1)

2

The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is equal to h

2
. The value of
xma
0

10x is ____. (a is radius of Bohr's orbit)

0

(Nearest integer) [Given : π = 3.14 ]

Q6 2021 (26 Aug Shift 2)

A metal surface is exposed to 500 nm radiation. The threshold frequency of the metal for photoelectric current
is 4.3 × 10 14
Hz. The velocity of ejected electron is ____×10 5
ms
−1
(Nearest integer)

[ Use : h = 6.63 × 10
−34
Js, me = 9.0 × 10
−31
kg]

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Structure of Atom JEE Main 2021 (August) Chapter-wise Questions
Questions with Answer Keys MathonGo

Q7 2021 (26 Aug Shift 1)

Given below are two statements.

Statement I : According to Bohr's model of an atom, qualitatively the magnitude of velocity of electron
increases with decrease in positive charges on the nucleus as there is no strong hold on the electron by the

nucleus.
Statement II : According to Bohr's model of an atom, qualitatively the magnitude of velocity of electron
increases with decrease in principal quantum number.

In the light of the above statements, choose the most appropriate answer from the options given below:

(1) Both Statement I and Statement II are false

(2) Both Statement I and Statement II are true

(3) Statement I is false but Statement II is true

(4) Statement I is true but Statement II is false

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Structure of Atom JEE Main 2021 (August) Chapter-wise Questions
Questions with Answer Keys MathonGo

Answer Key

Q1 (2) Q2 (0) Q3 (7) Q4 (50)

Q5 (3155) Q6 (5) Q7 (3)

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Structure of Atom JEE Main 2021 (July) Chapter-wise Questions
Questions with Answer Keys MathonGo

Q1 (20 July 2021 Shift 1)

The Azimuthal quantum number for the valence electrons of Ga ion is ___ +

(Atomic number of Ga = 31 )

Q2 (20 July 2021 Shift 2)

Outermost electronic configuration of a group 13 element, E, is 4 s 2

, 4p
1
. The electronic configuration of an
element of p-block period-five placed diagonally to element, E is :

(1) [Kr]3 d 10 2
4 s 4p
2

(2) [Ar]3 d 10 2
4 s 4p
2

(3) [Xe]5 d 10 2
6 s 6p
2

(4) [Kr]4 d 10 2
5 s 5p
2

Q3 (20 July 2021 Shift 2)

Which one of the following species doesn't have a magnetic moment of 1.73BM, (spin only value) ?

(1) O
+

(2) CuI

(3) [Cu(NH 3)
4
] Cl2

(4) O
−

Q4 (20 July 2021 Shift 2)

The wavelength of electrons accelerated from rest through a potential difference of 40kV is x × 10 −12
m. The
value of x is ___ (Nearest integer)
Given : Mass of electron = 9.1 × 10 −31
kg

Charge on an electron = 1.6 × 10 −19

C

Planck's constant = 6.63 × 10 −34

JS

Q5 (22 July 2021 Shift 1)

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Structure of Atom JEE Main 2021 (July) Chapter-wise Questions
Questions with Answer Keys MathonGo

Number of electrons that Vanadium (Z = 23) has in p-orbitals is equal to _____.

Q6 (25 July 2021 Shift 1)

A source of monochromatic radiation of

wavelength 400 nm provides 1000 J of energy in 10 seconds. When this radiation falls on the surface of
sodium, x × 10 20
electrons are ejected per second. Assume that wavelength 400 nm is sufficient for ejection
of electron from the surface of sodium metal. The value of x is

(Nearest integer) (h = 6.626 × 10 −34

Js)

Q7 (25 July 2021 Shift 2)

The spin only magnetic moments (in BM) for free Ti 3+

,V
2+
and Sc 3+
ions respectively are (At.No.
Sc : 21, Ti : 22, V : 23)

(1) 3.87, 1.73, 0

(2) 1.73, 3.87, 0

(3) 1.73, 0, 3.87

(4) 0, 3.87, 1.73

Q8 (25 July 2021 Shift 2)

An accelerated electron has a speed of 5 × 10 6

ms
−1
with an uncertainty of 0.02%. The uncertainty in finding

its location while in motion is x × 10 −9

m . The value of x is . (Nearest integer) [Use mass of electron

= 9.1 × 10
−31
kg ,
−34
h = 6.63 × 10 Js, π = 3.14]

Q9 (27 July 2021 Shift 1)

Given below are two statements:

Statement I : Rutherford's gold foil experiment cannot explain the line spectrum of hydrogen atom. Statement

II : Bohr's model of hydrogen atom contradicts Heisenberg's uncertainty principle. In the light of the above

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Structure of Atom JEE Main 2021 (July) Chapter-wise Questions
Questions with Answer Keys MathonGo

statements, choose the

most appropriate answer from the options given

below:

(1) Statement I is false but statement II is true.

(2) Statement I is true but statement II is false.

(3) Both statement I and statement II are false.

(4) Both statement I and statement II are true.

Q10 (27 July 2021 Shift 2)

If the Thompson model of the atom was correct, then the result of Rutherford's gold foil experiment

would have been:

(1) All of the α -particles pass through the gold foil without decrease in speed.
(2) α -Particles are deflected over a wide range of angles.

(3) All α -particles get bounced back by 180 ∘

(4) α -Particles pass through the gold foil deflected by small angles and with reduced speed.

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Structure of Atom JEE Main 2021 (July) Chapter-wise Questions
Questions with Answer Keys MathonGo

Answer Key

Q1 (0) Q2 (4) Q3 (2) Q4 (6)

Q5 (12) Q6 (2) Q7 (2) Q8 (58)

Q9 (4) Q10 (4)

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Structure of Atom JEE Main 2021 (March)
Questions with Answer Keys MathonGo

Q1: 16 March (Shift 1) - Numerical

When light of wavelength 248nm falls on a

metal of threshold energy 3.0eV, the de-Broglie wavelength of emitted electrons is____\AA.
(Round off to the Nearest Integer).
[Use: √3 = 1.73, h = 6.63 × 10
−34
JS

−31 8 −1
me = 9.1 × 10 kg; c = 3.0 × 10 ms

−19
leV = 1.6 × 10 J]

Q2: 16 March (Shift 2) - Single Correct

Arrange the following metal complex/ compounds in the increasing order of spin only magnetic moment.
Presume all the three, high spin system. (Atomic numbers Ce = 58, Gd = 64 and Eu = 63. )

(a) (NH 4)
2
[Ce(NO3 ) ]
6

(b) Gd(NO 3)
3
and
(c) Eu(NO 3)
3

Answer is:

(1) (b) < (a) < (c)

(2) (c) < (a) < (b)
(3) (a) < (b) < (c)

(4) (a) < (c) < (b)

Q3: 16 March (Shift 2) - Numerical

The number of orbitals with n = 5, m1 = +2 is ___

(Round off to the Nearest Integer).

Q4: 17 March (Shift 1) - Single Correct

What is the spin-only magnetic moment value (BM) of a divalent metal ion with atomic number 25, in it's

aqueous solution?

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Structure of Atom JEE Main 2021 (March)
Questions with Answer Keys MathonGo

(1) 5.92

(2) 5
(3) zero
(4) 5.26

Q5: 17 March (Shift 1) - Numerical

A certain orbital has n = 4 and m L = −3 . The number of radial nodes in this orbital is ____ (Round off to the

Nearest Integer).

Q6: 17 March (Shift 2) - Numerical

In the ground state of atomic Fe(Z = 26 ), the spin-only magnetic moment is ____ ×10 −1
BM . (Round off to
the Nearest Integer).

[ Given : √3 = 1.73, √2 = 1.41]

Q7: 18 March (Shift 1) - Single Correct

A certain orbital has no angular nodes and two radial nodes. The orbital is:

(1) 2 s

(2) 3 s
(3) 3p

(4) 2p

Q8: 18 March (Shift 2) - Single Correct

Given below are two statements:

Statement I : Bohr's theory accounts for the

stability and line spectrum of Li ion.

+

Statement II : Bohr's theory was unable to

explain the splitting of spectral

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Structure of Atom JEE Main 2021 (March)
Questions with Answer Keys MathonGo

lines in the presence of a

magnetic field. In the light of the above statements, choose the

most appropriate answer from the options given below:

(1) Both statement I and statement II are true.

(2) Statement I is false but statement II is true.

(3) Both statement I and statement II are false.

(4) Statement I is true but statement II is false.

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Structure of Atom JEE Main 2021 (March)
Questions with Answer Keys MathonGo

Answer Key

Q1 (9) Q2 (4) Q3 (3) Q4 (1)

Q5 (0) Q6 (49) Q7 (2) Q8 (2)

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Atomic Structure JEE Main 2021 (February)
Questions with Answer Keys MathonGo

Q1: 24 Feb (Shift 1) - Single Correct

Given below are two statements :

Statement-I: Two photons having equal linear momenta have equal wavelengths.
Statement-II: If the wavelength of photon is decreased, then the momentum and energy of a photon will also
decrease.
In the light of the above statements, choose the correct answer from the options given below.

(1) Statement-I is false but Statement-II is true

(2) Both Statement-I and Statement-II are true

(3) Both Statement-I and Statement-II are false

(4) Statement-I is true but Statement-II is false

Q2: 24 Feb (Shift 1) - Numerical

A proton and a Li 3+
nucleus are accelerated by the same potential. If λ and λ denote the de Broglie
Li p

wavelengths of Li and proton respectively, then the value of is x × 10 The value of x is ____.
3+ λLi −1
.
λp

[Rounded off to the nearest integer] [Mass of Li 3+

= 8.3 mass of proton]

Q3: 24 Feb (Shift 2) - Single Correct

According to Bohr's atomic theory :

2

(A) Kinetic energy of electron is ∝

Z

2
n

(B) The product of velocity (v) of electron and principal quantum number (n). 'vn' ∝ Z . 2

(C) Frequency of revolution of electron in an orbit is ∝ .

Z

3
n

(D) Coulombic force of attraction on the electron is ∝ . Choose the most appropriate answer from the
Z

4
n

options given below:

(1) (C) only

(2) (A) and (D) only

(3) (A) only
(4) (A), (C) and (D) only

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Atomic Structure JEE Main 2021 (February)
Questions with Answer Keys MathonGo

Q4: 25 Feb (Shift 1) - Single Correct

The plots of radial distribution functions for various orbitals of hydrogen atom against 'r' are given below:

(A)

(B)

(C)

(D)

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Atomic Structure JEE Main 2021 (February)
Questions with Answer Keys MathonGo

The correct plot for 3 s orbital is:

(1) D

(2) B

(3) A
(4) C

Q5: 25 Feb (Shift 2) - Numerical

Electromagnetic radiation of wavelength 663nm is just sufficient to ionize the atom of metal A. The ionization
energy of metal A in kJmol −1
is ____. (Rounded off to the nearest integer)
−34 8 −1 23 −1
[h = 6.63 × 10 Js, c = 3.00 × 10 ms , NA = 6.02 × 10 mol ]

Q6: 26 Feb (Shift 1) - Single Correct

The orbital having two radial as well as two angular nodes is

(1) 5 d

(2) 4f
(3) 3p
(4) 4 d

Q7: 26 Feb (Shift 2) - Numerical

A ball weighing 10 g is moving with a velocity of 90 ms . If the uncertainty in its velocity is 5%, then the
−1

uncertainty in its position is ____ ×10 −33

m. (Rounded off to the nearest integer) [Given :
h = 6.63 × 10
−34
Js ]

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Atomic Structure JEE Main 2021 (February)
Questions with Answer Keys MathonGo

Answer Key

Q1 (4) Q2 (2) Q3 (2) Q4 (1)

Q5 (180) Q6 (1) Q7 (1)

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