GARUD SHIKSHA KENDRA

Ch = Hydrocarbon Std 11 : Chemistry Date : 27/01/24

Total Marks : 100 Marks DPP Time : 01 Hour
Section A
//X
• Write the answer of the following questions. [Each carries 1 Mark] [100]

1. Which of the following possess tertiary carbon ?

(A) Propane (B) n-butane
(C) 2-methyl propane (D) 2,2-dimethylpropane
2. Which of the following is sodalime ?
(A) KOH, CaO (B) Ca(OH)2, NaOH (C) H2O, NaOH (D) NaOH, CaO

3. Which of the following has common formula CnH2n ?

(A) Alkane (B) Alkene (C) Alkyne (D) Cycloalkene
4. Which of the following is Lindlar’s catalyst ?
(A) Ni + Pt (B) CaO · NaOH (C) Pd + C (D) Pt + H2

5. Which of the following is saturated hydrocarbon ?

(A) Ethene (B) Propane (C) Ethyne (D) Butyne
6. Which of the following type of hydrogen is not possible ?
(A) 3° (B) 2° (C) 4° (D) 1°
7. 4° hydrogen is not possible, give reasons…..
(A) Carbon has four covalent bond.
(B) Centre carbon is attach with other four carbon and so there is no valence for attachment of
hydrogen.
(C) 1°, 2° and 3° carbon are stable but 4° carbon is unstable.
(D) Free radical is formed with 4° carbon.
8. Which of the following is right from given table ?
Compound General formula
(p) Alkane (i) CnH2n
(q) Alkene (ii) CnH2n – 2
(r) Alkyne (iii) CnH2n + 2
(s) Cycloalkane (iv) CnH2n + 4

(A) (p – i), (q – ii), (r – iii), (s – iv) (B) (p – iii), (q – i), (r – ii), (s – i)

(C) (p – iii), (q – ii), (r – ii), (s – iv) (D) (p – iv), (q – iii), (r – ii), (s – i)
9. Which of the following is true for structure given in Group-A with Group-B find correct option.
Group-A Group-B
(i) (CH3)2 CHCH3 (p) 2,2-dimethylpropane
(ii) (CH3)4 C (q) 2,2-dimethylbutane
(iii) (CH3)3 CCH2CH3 (r) 2,3-dimethylbutane
(iv) [(CH3)2 CH]2 (s) 2-methylpropane

(A) (i – s), (ii – p), (iii – r), (iv – q) (B) (i – p), (ii – q), (iii – r), (iv – s)
(C) (i – s), (ii – p), (iii – q), (iv – r) (D) (i – p), (ii – s), (iii – q), (iv – r)

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10. Find correct option for compound given in Group-A, their bond angle in Group-B and bond length
between carbon-carbon in Group-C.
Bond angle Bond length
Group-A
Group-B Group-C
(i) C – C alkane (p) 90° (a) 139 pm
(ii) C = C alkene (q) 109.5° (b) 154 pm
(iii) C º C alkyne (r) 120° (c) 134 pm
(iv) C = C benzene (s) 180° (d) 120 pm

(A) (i - p, (d)), (ii - r, (c)), (iii - s, (a)), (iv - q, (b))

(B) (i - q, (b)), (ii - r, (c)), (iii - s, (d)), (iv - r, (a))
(C) (i - p, (a)), (ii - q, (b)), (iii - r, (c)), (iv - s, (d))
(D) (i - r, (c)), (ii - r, (b)), (iii - s, (a)), (iv - p, (d))

11. C – C s-bond enthalpy of ethane is 397 kJ mol–1 and C – C p-bond enthalpy in ethene is 284 kJ
mol–1 . So what is the bond enthalpy of double bond in kJ mol–1 in ethene ?
(A) 384 (B) 823 (C) 681 (D) 284
12. What is the single bond, double bond and triple bond enthalpy in ethane, ethene and ethyne
respectively in kJ mol–1 ?
(A) 681, 384, 823 (B) 384, 681, 823 (C) 823, 681, 384 (D) None of the above
13. Find correct chemical reactivity order for the (a) ethane (b) ethene and (c) ethyne
(A) (a) > (b) > (c) (B) (c) > (b) > (a) (C) (a) > (c) > (b) (D) (c) > (a) > (b)
14. What is the correct order for boiling point having same carbon in alkane, alkene and alkyne ?
(A) Alkane < Alkene < Alkyne (B) Alkyne < Alkene < Alkane
(C) Alkene < Alkane < Alkyne (D) Alkane < Alkyne < Alkene
15. Which of the following compound possess geometrical isomerism ?
(A) Alkane (B) Alkene (C) Alkyne (D) None of these
16. Which of the following is not benzenoid ?

(A) (B) (C) (D) OCH3

O
17. Which of the following product can be obtained on reaction of benzene with chlorine in presenece
of anhydrous AlCl3 ?
(A) Chlorobenzene (B) Hexachlorocyclohexane
(C) Benzene hexachloride (D) None of these
18. Which of the following reactant can react with benzene ?
(A) I2 and sunlight (Normal temperature) (B) With cold KMnO4
(C) With bromine water (D) With bromine + FeBr3

19. Which scientist has obtained benzene first ?

(A) Kekule (B) Friedel - Craft (C) Michael Faraday (D) August Hoffman
20. Which of the following has highest boiling point ?
(A) Neo-pentane (B) n-pentane (C) Iso-pentane (D) n-hexane
(C6H5CO)2 OO
21. Propene + X¾¾¾¾¾¾¾ ® 1-halopropene, then what is ‘X’ ?
(A) HI (B) HCl (C) HBr (D) All of the given
22. X + water ® ethyne, so what is compound X ?
(A) Sodium carbide (B) Sodium ethenide (C) Calcium carbide (D) Calcium oxide
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 X + water ® ethyne, so what is compound X ?
(A) Sodium carbide (B) Sodium ethenide (C) Calcium carbide (D) Calcium oxide
Na
NH3
23. On following reaction which product is formed HC º CH + NaNH2 ¾¾¾® ?

(A) HC º CNa (B) NaC º CNa (C) H2 (D) All of the given

24. o-xylene, m-xylene and p-xylene are isomers of each other. What type of isomerism they possess ?
(A) Functional group isomerism (B) Chain isomerism
(C) Position isomerism (D) Geometrical isomerism
25. In nitration of benzene …..… is electrophile.
(A) Nitrate ions (B) Nitrite ions (C) Nitronium ions (D) Nitro
26. If on electrophilic substitution reaction of C6H5Y gives m-NO2C6H4Y then what is not Y form the
following ?
(A) –NH2 (B) –NO2 (C) –COOH (D) –SO3H

27. Which of the following does not possess zero magnetic momentum ?
(A) Transvinyl chloride (B) p-xylene (C) cis-but-2-ene (D) Methane
28. Benzene burns with sooty flame in burner, because…
(A) it is aliphatic compound. (B) it is aromatic.
(C) it is cyclic compound. (D) due to resonance effect.
29. Which main product is obtained when 3-methyl-pent-2-ene react with HBr in presence of peroxides ?
(A) 3-bromo-3-methylpentane (B) 4-bromo-3-methylpentane
(C) 2-bromo-3-methylpentane (D) All of these
30. The decreasing order of boiling points is
(A) n-pentane > iso-pentane > neo-pentane (B) iso-pentane > n-pentane > neo-pentane
(C) neo-pentane > iso-pentane > n-pentane (D) n-pentane > neo-pentane > iso-pentane
31. In the preparation of Grignard reagent from haloalkane, the metal used is
(A) Mg (B) Zn (C) Li (D) K
32. Sodium acetate can be converted to ethane by
(A) Heating with LiAlH4 (B) Electrolysing its aqueous solution
(C) Heating with sodalime (D) Heating with calcium acetate
33. In the reaction CH3 – Br + 2Na + Br – CH3 ® , the reaction is called
(A) Wurtz reaction (B) Aldol condensation (C) Perkin’s reaction (D) Levit reaction
34. In Wurtz reaction, the reagent used is
(A) Na (B) Na/liquid NH3 (C) Na/dry ether (D) Na/dry alcohol

35. Which of the following has highest octane number

(A) n-hexane (B) n-heptane
(C) n-pentane (D) 2, 2, 4-trimethyl pentane
36. n-hexadecane has cetane number
(A) 90 (B) 100 (C) 110 (D) Zero
37. Petroleum refining is
(A) distillation of petroleum to get different fractions.
(B) obtaining aromatic compounds from aliphatic compounds present in petroleum.
(C) cracking of petroleum to get gaseous hydro-carbons.
(D) purification of petroleum.

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38. The chemical added to leaded petrol to prevent the deposition of lead in the combustion chamber
is
(A) Iso-octane (B) Ethylene dibromide
(C) Tetraethyl lead (D) Mercaptan
39. Which of the following is not formed by the reaction of Cl2 on CH4 in sunlight
(A) CHCl3 (B) CH3Cl (C) CH3 CH3 (D) CH3CH2 CH3
40. Alkenes usually show which type of reaction
(A) Addition (B) Substitution (C) Elimination (D) Superposition
41. Towards electrophilic reagents
(A) ethene is more reactive than ethyne. (B) ethene is less reactive than ethyne.
(C) both have equal reactivity. (D) the reactivity of both cannot be predicted.
42. The final product formed when ethyl bromide is treated with excess of alcoholic KOH is
(A) Ethylene (B) Ethane (C) Ethyne (D) Vinyl bromide
43. The intermediate during the addition of HCl to propene in the presence of peroxide is
· + · +
(A) CH 3 CHCH 2Cl (B) CH 3 CHCH 3 (C) CH 3CH2 CH 2 (D) CH 3CH 2 CH 2
KMnO
44. CH2 = CH2 ¾¾¾¾¾ 4 ® X.
Product ‘X’ in above reaction is
KOH/H O 2
(A) Ethylene glycol (B) Glucose (C) Ethanol (D) All of these
45. The test for unsaturation is confirmed by the decolourisation of which of the following.
(A) Iodine water (B) CuSO4 solution (C) Bromine water (D) All of these

46. Which of the following compound is produced when CH2 = CH – (CH2)2COOH reacts with HBr in
presence of peroxides
(A) CH3CH(CH2)5COOH (B) BrCH2 CH2(CH2)2COOH
(C) CH3 CH2CH2(CH2)5COOH (D) CH3 CH2 BrCH 2CH2COOH

47. 1, 3-butadiene reacts with ethylene to form

(A) Benzene (B) Cyclohexane
(C) Cyclohexene (D) 2,3-dimethyl butane
48. In paraffins, with the increasing molecular weight, it is found that
(A) Freezing point decreases (B) Boiling point decreases
(C) Boiling point increases (D) Vapour pressure decreases
49. A gas formed by the action of alcoholic KOH on ethyl iodide, decolourises alkaline KMnO4 solution.
The gas is
(A) CH4 (B) C2 H6 (C) C2 H4 (D) C2 H2

50. Which of the following gases is used for welding.

(A) Methane (B) Ethane (C) Acetylene (D) Ethene
51. 1-butyne reacts with cold alkaline KMnO4 to produce
(A) CH3 CH2COOH (B) CH3 CH2CH2COOH
(C) CH3 CH2COOH + CO 2 (D) CH3 CH2COOH + HCOOH
52. Acetylenic hydrogens are acidic because.
(A) Sigma electron density of C – H bond in acetylene is nearer to carbon, which has 50% s-
character.
(B) Acetylene has only one hydrogen on each carbon.
(C) Acetylene contains least number of hydrogens among the possible hydrocarbons having two
carbons.
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(D) Acetylene belongs to the class of You - All
alkynes withThemolecular
Best formula Cn H2n – 2
 (B) Acetylene has only one hydrogen on each carbon.
(C) Acetylene contains least number of hydrogens among the possible hydrocarbons having two
carbons.
(D) Acetylene belongs to the class of alkynes with molecular formula Cn H2n – 2

53. Poisonous gas ‘Lewisite’ is obtained by the reaction of

(A) CH º CH and AsCl3 (B) CH2 = CH2 and AsCl3
(C) CH º CH and S2Cl2 (D) CH2 = CH2 and NOCl
54. Hydrocarbon containing following bond is most reactive
(A) C º C (B) C = C (C) C – C (D) All of these
55. Acetylene gives
(A) White precipitate with AgNO3 and red precipitate with Cu2Cl2 .
(B) White precipitate with Cu2Cl2 and red precipitate with AgNO 3 .
(C) White precipitate with both the reagents.
(D) Red precipitate with both the reagents.
56. When propyne reacts with aqueous H2SO4 in the presence of HgSO4, the major product is
(A) Propanal (B) Propyl hydrogen sulphate
(C) Acetone (D) Propanol
57. Which of the following is used to distinguish ehtylene and acetylene
(A) Alkaline KMnO 4 (B) Bromine water
(C) Ammonical cuprous chloride (D) Conc. H2SO 4

58. The reaction of propene with HOCl proceeds via the addition of
(A) H+ in the first step (B) Cl+ in the first step
(C) OH– in the first step (D) Cl+ and OH– in a single step
59. Acetylene reacts with ammonical AgNO3 forming
(A) Silver acetylene (B) Silver acetate (C) Metal silver (D) Silver mirror
60. The function of anhydrous AlCl3 in the Friedel-Craft’s reaction is to
(A) Absorb water (B) Absorb HCl
(C) To produce electrophile (D) To produce nucleophile
61. Meta-directing and deactivating group in aromatic electrophilic substitiution is
(A) –CH3 (B) –OH (C) –NO2 (D) –Cl(E)–OCH3

62. The ratio of s and p-bonds in benzene is

(A) 2 (B) 4 (C) 6 (D) 8
63. Carbon atoms in benzene molecule is inclined at an angle of
(A) 120o (B) 180o (C) 109o28' (D) 60o
Anhydrous
64. C6H6 + CH3Cl ® C6H5CH3 + HCl is an example of
AlCl 3
(A) Friedel-Craft’s reaction (B) Kolbe’s synthesis
(C) Wurtz reaction (D) Grignard reaction
65. Naphthalene is a/an
(A) Ionic solid (B) Covalent solid (C) Metallic solid (D) Molecular solid
66. CH º CH + HBr ® X, product X is
(A) Ethylene bromide (B) Vinyl bromide
(C) Bromo ethane (D) Ethyledine bromide
67. The addition of HBr is easiest with
(A) Cl2C = CHCl (B) ClCH = CHCl (C) CH3 – CH = CH2 (D) (CH3 )2C = CH2

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68. In ethylene, carbon monoxide and water is heated at high temperature, which of the following if
formed
(A) C4 H8 O 2 (B) C2 H5 COOH
(C) CH3COOH (D) CH2 = CH – COOH

69. The treatment of CH3MgX with CH3C º C – H produces

(A) CH4 (B) CH3 – CH = CH2
H H
| |
(C) CH3C º C – CH3 (D) CH 3 – C = C – CH 3

70. Liquid hydrocarbons can be converted to a mixture of gaseous hydrocarbons by :

(A) oxidation (B) cracking
(C) distillation under reduced pressure (D) hydrolysis
71. The IUPAC name of the compound having the formula CH º C – CH = CH2 is :
(A) 1-butyn-3-ene (B) but-1-yne-3-ene (C) 1-butene-3-yne (D) 3-butene-1-yne
72. The hydrocarbon which can react with sodium in liquid ammonia is
(A) CH3 CH2C º CCH2 CH3 (B) CH3CH2 CH2C º CCH2CH2 CH3
(C) CH3 CH2C º CH (D) CH3CH = CHCH3

73. The reaction of toluene with Cl2 in presence of FeCl3 gives predominantly
(A) m-chlorobenzene (B) benzoyl chloride
(C) benzyl chloride (D) o– and p-chlorotoluene
74. Which mixture is used as Lindlar’s catalyst ?
(A) Pd + Charcoal (B) Ni + P (C) Pt + Halogen (D) Pd + Pt
75. Which of the following is strong reducing agent ?
(A) Al2O3 (B) BF3 (C) LiAlH4 (D) AlCl3

76. Which is the correct structure of TNT from the following ?

COOH CH3 CH3 OH
O2 N NO2 NO2 O2 N NO2 O2 N NO2
(A) (B) (C) (D)
NO2 NO2 NO2 NO2

77. What will be the total no. of isomers of an acylic saturated hydrocarbon having molecular mass 72
g/mol. ?
(A) 3 (B) 4 (C) 5 (D) 2
78. Which substance has fruity sweet smell ?
(A) Pent-l-ene (B) Propene (C) But-l-ene (D) Ethene
79. Which of the reagent is used in Kharash effect ?
(A) HI (B) HCl (C) HBr (D) HF
80. The number of s and p bonds in phenol respectively are ...........
(A) 12, 3 (B) 13, 4 (C) 13, 2 (D) 13, 3
81. Which compound with react with Zn to form 2-butene ?
(A) 2,3-dibromobutane (B) 1,2-dibromobutane (C) 2-butyne (D) None of these
82. The molecular formula of Napthalene is .........
(A) C18H10 (B) C18H12 (C) C14H28 (D) C18H14

83. The catalyst used for obtaining carbonyl compound from alkyne during hydration is....
(A) HCN (B) HgSO4 (C) HgCl2 (D) Pt
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 The catalyst used for obtaining carbonyl compound from alkyne during hydration is....
(A) HCN (B) HgSO4 (C) HgCl2 (D) Pt
O
84. Give IUPAC name..
OH
(A) 5-ethyl-3-ene-2-one hexan-1-ol (B) 2-ethyl-3-ene-hexanoic acid
(C) 5-ethyl-3-ene-hexanoic acid (D) 3-ethyl-2-one-tiept-1-ol
85. The hybrid state of Carbon in Acetylene is same as that of ...........
(A) Graphite (B) BeH2 (C) Benzene (D) Diamond

86. Which of the following hydrocarbon cannot have cyclic type ?

(A) Alkane (B) Alkene (C) Alkyne (D) Arene
87. Which of the following substitution reaction of alkane is reversible ?
(A) Fluorination (B) Chlorination (C) Bromination (D) Iodination
88. What will be the number of s and p bonds in Biphenyl respectively ?
(A) 12 s and 6 p (B) 22 s and 6 p (C) 23 s and 6 p (D) 13 s and 6 p
COOH
KMnO 4 / KOH Ca(OH)
89. X ¾¾¾¾¾ ¾¾® ¾¾¾¾¾ 2®
D + 2H O Y
D 2

then X and Y respectively are....

(A) Benzaldehyde, Benzal dichloride (B) Toluene, Benzo trichloride
(C) Toluene, Benzal dichloride (D) Benzaldehyde, Benzyl chloride
90. What will be the main product obtained during hydrobromination of Pent-1-ene in presence of
Benzoyl peroxide ?
(A) 1-bromo pentane (B) 2-bromo pentane
(C) 3-bromo pentane (D) 2-methyl, 1-bromo butane
91. Which mixture is used as Lindlar’s catalyst ?
(A) Pt + Charcoal (B) Pd + Halogen (C) Pt + Halogen (D) Pd + Charcoal
92. Friedel-Craft’s reaction of Toluene with Ethanoic anhydride produces
(A) Acetophenone (B) Methyl benzene
(C) Ethyl benzene (D) p-methyl acetophenone
93. Give IUPAC name of (CH3)3 C · C º C · C (CH3)3.
(A) Di(tri methyl)but-2-yne (B) 3, 3, 4, 4-tetramethylhex-3-yne
(C) 2, 2, 5, 5-tetramethylhex-3-yne (D) 2, 2, 5, 5-tetramethylhex-4-yne
94. Which of the following is used as catalyst in preparation of PVC ?
(A) Hg2Cl2 (B) HgCl2 (C) Hg (D) HgSO4

95. Which of the following compounds possesses 3° carbon atom ?

(A) 1-Chloro butane (B) n-Butane (C) Cyclo butane (D) Iso butane
96. How many carbon atoms are sp3 hybridized in but-2-ene ?
(A) 4 (B) 2 (C) 3 (D) 1
97. With which reactant ethyne will react to form vinyl cyanide ?
(A) HCN (B) KCN (C) HgCl2 (D) NaCN

98. Write IUPAC name of Parachloro toluene.

(A) 1-chloro-2-methyl benzene (B) 2-chloro-4-methyl benzene
(C) 4-chloro-2-methyl benzene (D) 1-chloro-4-methyl benzene
99. Which of the following functional groups passes on electron towards the phenyl ring ?
(A) –SO3H (B) – CHO (C) – Cl (D) – NO2
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 Which of the following functional groups passes on electron towards the phenyl ring ?
(A) –SO3H (B) – CHO (C) – Cl (D) – NO2

100. Possible number of cyclic isomers for the compound having molecular formula C6H4Cl2 is ...... .
(A) 6 (B) 4 (C) 5 (D) 3

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