SAFETY DATA SHEET according to Regulation (EC) No.

1907/2006

KARARE 2.5% (FINISHED GOODS)

Version 7 - This version replaces all previous versions.
Revision Date 22.07.2014 Print Date 22.07.2014

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1 Product identifier

Product name : KARARE 2.5% (FINISHED GOODS)

Design code : A12678A

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use : Insecticide

1.3 Details of the supplier of the safety data sheet

Company : Syngenta Crop Protection AG

Postfach
CH-4002 Basel
Switzerland
Telephone : +41 61 323 11 11
Telefax : +41 61 323 12 12
E-mail address : [Link]@[Link]

1.4 Emergency telephone number

Emergency tele- : +44 1484 538444

phone number

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Classification according to Regulation (EU) 1272/2008

Flammable liquids Category 3 H226
Acute toxicity (Oral) Category 4 H302
Aspiration hazard Category 1 H304
Skin irritation Category 2 H315
Serious eye damage Category 1 H318
Acute toxicity (Inhalation) Category 3 H331
Specific target organ toxicity - single exposure Category 3 H335
Specific target organ toxicity - single exposure Category 3 H336
Acute aquatic toxicity Category 1 H400
Chronic aquatic toxicity Category 1 H410

For the full text of the H-Statements mentioned in this Section, see Section 16.

Classification according to EU Directives 67/548/EEC or 1999/45/EC

T, Toxic
N, Dangerous for the environment
R10: Flammable.
R22: Harmful if swallowed.
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R23: Toxic by inhalation.

R37/38: Irritating to respiratory system and skin.
R41: Risk of serious damage to eyes.
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic en-
vironment.
R65: Harmful: may cause lung damage if swallowed.

2.2 Label elements

Labelling: Regulation (EC) No. 1272/2008

Hazard pictograms

Signal word : Danger

Hazard statements : H226 Flammable liquid and vapour.

H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements : P102 Keep out of reach of children.

P210 Keep away from heat, hot surfaces, sparks, open
flames and other ignition sources. No smoking.
P280 Wear protective gloves/ protective clothing/ eye pro-
tection/ face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER or doctor/ physician.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for sev-
eral minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/ phy-
sician.
P331 Do NOT induce vomiting.
P501 Dispose of contents/ container to an approved waste
disposal plant.

Supplemental information : EUH401 To avoid risks to human health and the environment,
comply with the instructions for use.

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Hazardous components which must be listed on the label:

 lambda-cyhalothrin
 Octylphenol ethoxylate
 calcium dodecylbenzenesulphonate
 solvent naphtha (petroleum), light arom.

Labelling: EU Directives 67/548/EEC or 1999/45/EC

Symbol(s)

Dangerous
for the envi-
Toxic ronment

R-phrase(s) : R10 Flammable.

R22 Harmful if swallowed.
R23 Toxic by inhalation.
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
R50/53 Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.

S-phrase(s) : S 1/2 Keep locked up and out of the reach of children.

S13 Keep away from food, drink and animal feedingstuffs.
S20/21 When using do not eat, drink or smoke.
S26 In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice.
S35 This material and its container must be disposed of in
a safe way.
S36/37/39 Wear suitable protective clothing, gloves and eye/face
protection.
S45 In case of accident or if you feel unwell, seek medical
advice immediately (show the label where possible).
S57 Use appropriate container to avoid environmental
contamination.

Additional Labelling : To avoid risks to man and the environment, comply with the instructions
for use.

Hazardous components which must be listed on the label:

 lambda-cyhalothrin
 Octylphenol ethoxylate
 calcium dodecylbenzenesulphonate
 solvent naphtha (petroleum), light arom.

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2.3 Other hazards

May cause temporary itching, tingling, burning or numbness of exposed skin,

called paresthesia.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures

Hazardous components
Chemical Name CAS-No. Classification Classification Concentration
EC-No. (67/548/EEC) (REGULATION (EC) No
Registration num- 1272/2008)
ber
solvent naphtha 64742-95-6 Xn, N Flam. Liq.3; H226 60 - 90 % W/W
(petroleum), 265-199-0 R10 STOT SE3; H335
light arom. R37 STOT SE3; H336
R51/53 Asp. Tox.1; H304
R65 Aquatic Chronic2; H411
R66
R67

Octylphenol 9036-19-5 Xn, N Acute Tox.4; H302 5- 15 % W/W

ethoxylate R22 Eye Dam.1; H318
R41 Aquatic Chronic2; H411
R51/53

lamb- 91465-08-6 T+, N Acute Tox.3; H301 2.8 % W/W

da-cyhalothrin 415-130-7 R21 Acute Tox.3; H311
R25 Acute Tox.2; H330
R26 Aquatic Acute1; H400
R50/53 Aquatic Chronic1; H410

calcium do- 26264-06-2 Xi Skin Irrit.2; H315 1- 5 % W/W

decylbenzene- 90194-26-6 R38 Eye Dam.1; H318
sulphonate 247-557-8 R41

2-methylpropan- 78-83-1 Xi Flam. Liq.3; H226 1- 5 % W/W

1-ol 201-148-0 R10 STOT SE3; H335
01-2119484609-23-0 R37/38 Skin Irrit.2; H315
012
R41 Eye Dam.1; H318
R67 STOT SE3; H336

Substances for which there are Community workplace exposure limits.

For the full text of the R-phrases mentioned in this Section, see Section 16.
For the full text of the H-Statements mentioned in this Section, see Section 16.

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SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures

General advice : Have the product container, label or Material Safety Data Sheet with you
when calling the Syngenta emergency number, a poison control center or
physician, or going for treatment.

Inhalation : Move the victim to fresh air.

If breathing is irregular or stopped, administer artificial respiration.
Keep patient warm and at rest.
Call a physician or poison control centre immediately.

Skin contact : Take off all contaminated clothing immediately.

Wash off immediately with plenty of water.
If skin irritation persists, call a physician.
Wash contaminated clothing before re-use.

Eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least
15 minutes.
Remove contact lenses.
Immediate medical attention is required.

Ingestion : If swallowed, seek medical advice immediately and show this container or
label.
Do NOT induce vomiting.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms : Aspiration may cause pulmonary oedema and pneumonitis.

Skin contact paresthesia effects (itching, tingling, burning or numbness)
are transient, lasting up to 24 hours.

4.3 Indication of any immediate medical attention and special treatment needed

Medical advice : Do not induce vomiting: contains petroleum distillates and/or aromatic
solvents.
Treat symptomatically.

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media

Extinguishing media - small fires
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Extinguishing media - large fires
Alcohol-resistant foam

Do not use a solid water stream as it may scatter and spread fire.

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5.2 Special hazards arising from the substance or mixture

As the product contains combustible organic components, fire will pro-

duce dense black smoke containing hazardous products of combustion
(see section 10).
Exposure to decomposition products may be a hazard to health.
Flash back possible over considerable distance.

5.3 Advice for firefighters

Wear full protective clothing and self-contained breathing apparatus.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Refer to protective measures listed in sections 7 and 8.

Keep people away from and upwind of spill/leak.
Beware of vapours accumulating to form explosive concentrations. Va-
pours can accumulate in low areas.
Remove all sources of ignition.
Pay attention to flashback.

6.2 Environmental precautions

Prevent further leakage or spillage if safe to do so.
Do not flush into surface water or sanitary sewer system.

6.3 Methods and materials for containment and cleaning up

Contain spillage, and then collect with non-combustible absorbent mate-

rial, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in
container for disposal according to local / national regulations (see section
13).

If the product contaminates rivers and lakes or drains inform respective

authorities.

6.4 Reference to other sections

Refer to protective measures listed in sections 7 and 8.
Refer to disposal considerations listed in section 13.

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SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling

Avoid contact with skin and eyes.
When using do not eat, drink or smoke.
Use only in an area containing flame proof equipment.
Take precautionary measures against static discharges.
For personal protection see section 8.

7.2 Conditions for safe storage, including any incompatibilities

Keep containers tightly closed in a dry, cool and well-ventilated place.

Keep out of the reach of children.
Keep away from combustible material.
Keep in an area equipped with sprinklers.
Keep away from food, drink and animal feedingstuffs.
No smoking.

7.3 Specific end use(s)

Registered Crop Protection products:For proper and safe use of this
product, please refer to the approval conditions laid down on the product
label.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Components Exposure limit(s) Type of expo- Source
sure limit
lambda-cyhalothrin 0.04 mg/m3 (Skin) 8 h TWA SYNGENTA

solvent naphtha (pe- 19 ppm, 100 mg/m3 8 h TWA SUPPLIER

troleum), light arom.
2-methylpropan-1-ol 1,600 ppm NIOSH
50 ppm 8 h TWA SUVA
100 ppm 15 min STEL SUVA
50 ppm 8 h TWA ACGIH
100 ppm 8 h TWA DFG
50 ppm, 231 mg/m3 8 h TWA UK HSE

The following recommendations for exposure controls/personal protection are intended for the manu-
facture, formulation and packaging of the product.

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8.2 Exposure controls

Engineering measures : Containment and/or segregation is the most reliable technical protection
measure if exposure cannot be eliminated.
The extent of these protection measures depends on the actual risks in
use.
If airborne mists or vapors are generated, use local exhaust ventilation
controls.
Assess exposure and use any additional measures to keep airborne
levels below any relevant exposure limit.
Where necessary, seek additional occupational hygiene advice.

Protective measures : The use of technical measures should always have priority over the use of
personal protective equipment.
When selecting personal protective equipment, seek appropriate profes-
sional advice.
Personal protective equipment should be certified to appropriate stand-
ards.

Respiratory protection : A combination gas, vapor and particulate respirator may be necessary
until effective technical measures are installed.
Protection provided by air-purifying respirators is limited.
Use a self-contained breathing apparatus in cases of emergency spills,
when exposure levels are unknown, or under any circumstances where
air-purifying respirators may not provide adequate protection.

Hand protection : Suitable material:Nitrile rubber

Break through time: > 480 min
Glove thickness: 0.5 mm
Chemical resistant gloves should be used.
Gloves should be certified to an appropriate standard.
Gloves should have a minimum breakthrough time that is appropriate to
the duration of exposure.
The breakthrough time of gloves varies according to the thickness, mate-
rial and manufacturer.
Gloves should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.

Eye protection : If eye contact is possible, use tight-fitting chemical safety goggles and a
face shield.

Skin and body protection : Assess the exposure and select chemical resistant clothing based on the
potential for contact and the permeation / penetration characteristics of
the clothing material.
Wash with soap and water after removing protective clothing.
Decontaminate clothing before re-use, or use disposable equipment
(suits, aprons, sleeves, boots, etc.)
Wear as appropriate:
impervious protective suit

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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Physical state : liquid

Form : clear to slightly turbid liquid
Colour : yellow
Odour : No data available
Odour Threshold : No data available
pH : No data available
Melting point/range : No data available
Boiling point/boiling range : No data available
Flash point : 43 °C
Evaporation rate : No data available
Flammability (solid, gas) : No data available
Lower explosion limit : No data available
Upper explosion limit : No data available
Vapour pressure : No data available
Relative vapour density : No data available
Density : 0.9 g/cm3
Solubility in other solvents : Miscible
in Water
Partition coefficient: : No data available
n-octanol/water
Auto-ignition temperature No data available
Thermal decomposition : No data available
Viscosity, dynamic : No data available
Viscosity, kinematic : No data available
Explosive properties : Not explosive
Oxidizing properties : not oxidizing

9.2 Other information

: No data available

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity
No information available.

10.2 Chemical stability

No information available.

10.3 Possibility of hazardous reactions

None known.
Hazardous polymerisation does not occur.

10.4 Conditions to avoid

No information available.

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10.5 Incompatible materials

No information available.

10.6 Hazardous decomposition products

Combustion or thermal decomposition will evolve toxic and irritant vapors.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Acute oral toxicity : LD50 male rat, 923 mg/kg

: LD50 female rat, 923 - 1,930 mg/kg

Acute inhalation toxicity : LC50 male rat, 1.384 mg/l , 4 h

The toxicological data has been taken from products of similar composi-
tion.

: LC50 female rat, 1 mg/l , 4 h

The toxicological data has been taken from products of similar composi-
tion.

Acute dermal toxicity : LD50 male and female rat, > 1,780 mg/kg

Skin corrosion/irritation : rat: Severely Irritating

The toxicological data has been taken from products of similar composi-
tion.

Serious eye damage/eye : rabbit: Moderately irritating

irritation

Respiratory or skin sensi- : Maximisation Test (GPMT) guinea pig: A mild skin sensitizer in animal
tisation tests

Germ cell mutagenicity

lambda-cyhalothrin : Did not show mutagenic effects in animal experiments.
2-methylpropan-1-ol : Did not show mutagenic effects in animal experiments.

Carcinogenicity
lambda-cyhalothrin : Did not show carcinogenic effects in animal experiments.
2-methylpropan-1-ol : Did not show carcinogenic effects in animal experiments.

Reproductive toxicity
lambda-cyhalothrin : Did not show reproductive toxicity effects in animal experiments.
2-methylpropan-1-ol : Did not show reproductive toxicity effects in animal experiments.

STOT - single exposure : May cause respiratory irritation.

Derived from components.

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: May cause drowsiness or dizziness.

Derived from components.

STOT - repeated exposure

lambda-cyhalothrin : No adverse effect has been observed in chronic toxicity tests.
2-methylpropan-1-ol : No adverse effect has been observed in chronic toxicity tests.

SECTION 12: ECOLOGICAL INFORMATION

12.1 Toxicity

Toxicity to fish : LC50 Fish, ca. 0.007 mg/l , 96 h

Derived from components.

Toxicity to aquatic inver- : EC50 Daphnia magna (Water flea), ca. 0.012 mg/l , 48 h
tebrates Derived from components.

Toxicity to aquatic plants : EC50 Algae, ca. 1 mg/l , 72 h

Derived from components.

12.2 Persistence and degradability

Biodegradability
lambda-cyhalothrin : Not biodegradable.

Stability in water
lambda-cyhalothrin : Degradation half life: 7 d
Not persistent in water.

Stability in soil
lambda-cyhalothrin : Degradation half life: 56 d
Not persistent in soil.

12.3 Bioaccumulative potential

lambda-cyhalothrin : Lambda-cyhalothrin bioaccumulates.

12.4 Mobility in soil

lambda-cyhalothrin : Lambda-cyhalothrin is immobile in soil.

12.5 Results of PBT and vPvB assessment

lambda-cyhalothrin : This substance is not considered to be persistent, bioaccumulating nor

toxic (PBT).
This substance is not considered to be very persistent nor very bioac-
cumulating (vPvB).

12.6 Other adverse effects

Other information : Classification of the product is based on the summation of the concentra-
tions of classified components.

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SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods

Product : Do not contaminate ponds, waterways or ditches with chemical or used

container.
Do not dispose of waste into sewer.
Where possible recycling is preferred to disposal or incineration.
If recycling is not practicable, dispose of in compliance with local regula-
tions.

Contaminated packaging : Empty remaining contents.

Triple rinse containers.
Empty containers should be taken to an approved waste handling site for
recycling or disposal.
Do not re-use empty containers.

SECTION 14: TRANSPORT INFORMATION

Land transport (ADR/RID)

14.1 UN number: UN 1993

14.2 UN proper shipping name: FLAMMABLE LIQUID, N.O.S. (SUBSTITUTED BENZENOID
HYDROCARBONS AND LAMBDA-CYHALOTHRIN)
14.3 Transport hazard class(es): 3
14.4 Packing group: III
Labels: 3
14.5 Environmental hazards : Environmentally hazardous
Tunnel restriction code: D/E

Sea transport(IMDG)

14.1 UN number: UN 1993

14.2 UN proper shipping name: FLAMMABLE LIQUID, N.O.S. (SUBSTITUTED BENZENOID
HYDROCARBONS AND LAMBDA-CYHALOTHRIN)
14.3 Transport hazard class(es): 3
14.4 Packing group: III
Labels: 3
14.5 Environmental hazards : Marine pollutant

Air transport (IATA-DGR)

14.1 UN number: UN 1993

14.2 UN proper shipping name: FLAMMABLE LIQUID, N.O.S. (SUBSTITUTED BENZENOID
HYDROCARBONS AND LAMBDA-CYHALOTHRIN)
14.3 Transport hazard class(es): 3
14.4 Packing group: III
Labels: 3

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14.6 Special precautions for user

none

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

not applicable

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mix-
ture

GHS-Labelling

Hazard pictograms

Signal word : Danger

Hazard statements : H226 Flammable liquid and vapour.

H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements : P102 Keep out of reach of children.

P210 Keep away from heat, hot surfaces, sparks, open
flames and other ignition sources. No smoking.
P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER or doctor/ physician.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/
physician.
P331 Do NOT induce vomiting.
P501 Dispose of contents/ container to an approved
waste disposal plant.

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Remarks : Classified using all GHS hazard classes and categories.

Where the GHS contains options, the most conservative option has
been chosen.
Regional or national implementations of GHS may not implement all
hazard classes and categories.

Hazardous components which must be listed on the label:

 lambda-cyhalothrin
 Octylphenol ethoxylate
 calcium dodecylbenzenesulphonate
 solvent naphtha (petroleum), light arom.

15.2 Chemical Safety Assessment

A Chemical Safety Assessment is not required for this substance.

SECTION 16: OTHER INFORMATION

Further information
Full text of R-phrases referred to under sections 2 and 3:

R10 Flammable.
R21 Harmful in contact with skin.
R22 Harmful if swallowed.
R25 Toxic if swallowed.
R26 Very toxic by inhalation.
R37 Irritating to respiratory system.
R37/38 Irritating to respiratory system and skin.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.

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Full text of H-Statements referred to under sections 2 and 3.

H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H311 Toxic in contact with skin.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H330 Fatal if inhaled.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.

Full text of other abbreviations

ADR: European Agreement Concerning the International RID: Regulations concerning the International Car-
Carriage of Dangerous Goods by Road riage of Dangerous Goods by Rail
IMDG: International Maritime Code for Dangerous Goods IATA-DGR: International Air Transport Association Danger-
ous Goods Regulations
LC50: Lethal concentration, 50% LD50: Lethal dose, 50%
EC50: Effective dose, 50% GHS: Globally Harmonized System of Classification
and Labelling of Chemicals (GHS)

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and
belief at the date of its publication. The information given is designed only as a guidance for safe handling,
use, processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not be valid
for such material used in combination with any other materials or in any process, unless specified in the
text.
Changes since the last version are highlighted in the margin. This version replaces all previous versions.
Product names are a trademark or registered trademark of a Syngenta Group Company.

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