CALORIMETRY JEEJEE

MAIN-JR-PHY-VOL-IV
MAINS - VOL - VI

CALORIMETRY
 If specific heat varies with temperature then heat
SYNOPSIS energy given to substance is
2
INTRODUCTION
 Heat is a form of energy in transit, that flows from Q  m  Sd
1
a body at high temperature to a body at low
temperature.  Water has largest specific heat among solids and
liquids. So it is used as coolant in automobile
 The S.I. Unit of heat is Joule (J)
radiators.
 The C.G..S. Unit of heat is calorie (Cal)  Among solids, liquids, and gases specific heat is
1 Cal = 4.186 J  4.2J maximum for Hydrogen. (3.5 Cal/g- º C ) and
 The quantity of heat required to warm a given minimum for radon, actinium. (  0.022 Cal/g- º C )
substance depends on its mass ( m), the change  Specific heat slightly increases with increase of
in temperature    and nature of the substance. temperature.
 Among liquids specific heat is minimum for
i.e  Q  mS  
mercury.
Where Q  quantity of heat gained  The value of specific heat may lie between 0 and
m = mass of substance .
 = rise in temperature  In isothermal process, the value of specific heat is
S= specific heat (depends on nature of the infinity but in adiabatic process its value is zero.
material)  Specific heat of all substances is zero at 0K.
Specific Heat  Substances with highest specific heat are bad
 The amount of heat required to raise the conductors of heat and with low specific heat are
temperature of unit mass of a substance good thermal and electrical conductors.
through 10C is called specific heat of the material  The substance with large specific heat warms up
of the body. slowly and cools down slowly.
1 Q [Link]. Substance Specific heat
S CGS Value S.I Value
m 
a) Water 1cal g-1 0C-1 4186 JKg-1 K-1
 The S.I unit of S is J/kg- K
b) Ice 0.5 cal g C-1 0 -1
2100 Jkg-1 K-1
 The C.G.S unit of S is Cal./g- 0C
c) Steam 0.47 cal g-1 0C-1 1970 Jkg-1 K-1
 Dimensional formula of S is L2T 2 1
 Molar specific heat capacity Thermal capacity or Heat capacity
1 Q
C (n = number of moles)  It is the amount of heat required to raise the
n 
temperature of the body by 10C
 The SI unit of C is J/mole - K
 The C.G.S. unit of C is Cal / mole - º C Q
H
 Dimensional formula of C is ML2T 2 1mole 1 
 Gases will have two specific heats  The [Link] of H is JK-1
(i) Specific heat at constant volume (Cv)  The C.G.S unit of H is Cal oC-1
(ii) Specific heat at constant pressure (Cp).  Dimensional formula of H is ML2T 2 1
 Specific heat depends only on the nature of  Thermal capacity depends on mass and nature of
material and temperature. Usually temperature the substance.
dependence of specific heat is neglected.
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Water equivalent W.E. 4: Two spheres of radii in the ratio 1:2, have
specific heats in the ratio 2:3. The densities
 Mass of water which has same thermal capacity are in the ratio 3:4. Find the ratio of their
as that of the substance is called water equivalent thermal capacities.
 It is numerically equal to heat capacity (ms) in CGS Sol: Thermal capacity of a body = mS.
units The ratio of thermal capacities
 The S.I unit of water equivalent is kg 4 3
 The C.G.S unit of water equivalent is g. m1 S1 V1 1 S1
 r1 1 S1  r  3     S 
  3   1   1  1 
 Dimensional formula of water equivalent is ML0T 0 m 2 S 2 V2  2 S 2 4  r 3  S
2 2 2
 r2    2   S 2  .
3
 If mW , ms are masses of water and substance and
r1 1 S1 2 1 3
SW , S S are their specific heats respectively then, Here, r  2 ; S  3 ;   4
2 2 2
mW  SW    mS S S   The ratio of thermal capacities
3
 mW  1  mS S S ,  mW  mS S S  1   3  2 
= 2     
1
W.E-1:A lead piece of mass 25g gives out 1200    4   3  16
calories of heat when it is cooled from 900 C CALORIMETRY
 Calorimetry means measurement of heat.
to 100 C . What is its (i) specific heat (ii) ther-  A device in which heat measurement can be made
mal capacity (iii) water equivalent. is called “ calorimeter” .
Sol: Mass of lead piece (m) = 25 g = 0.025 kg Law of method of mixtures (or)
Heat energy given out  dQ   1200  4.2 J Principle of calorimetry
 If two liquids at different temperatures are mixed
1 dQ together, the heat lost by hot body is equal to the
(i) specific heat S  heat gained by the cold body. This is called law
m d
of method of mixtures.
1 1200  4.2  When three substances of different masses m1,
   2520JKg 1 K 1
0.025 80 m2 and m3 ,specific heats S1,S2,S3 and at different
(ii) Thermal capacity = mS = 0.025  2520 temperatures 1 , 2 , and 3 respectively are
= 63 J/K
mixed, then the resultant temperature is
63 m S m S  m S 
(iii) Water equivalent Kg  0.015 Kg   1 1 1 2 2 2 3 3 3 (when state of
4200 m1S1  m2 S2  m3S3
W.E-2 : The specific heat of a substance varies
contents does not change)
as  3 2    103 cal /g º C. What is the  Two liquids of masses m 1 and m 2 and specific
amount of heat required to raise the heats S1 and S 2 respectively are mixed. Then
temperature of 1kg of substance from the specific heat of the mixture is
10ºC to 20ºC?
Sol.:For small change in temperature d  , heat m S  m2 S 2
 S mix  1 1
required, dQ  mSd .  m1  m2 
2 W.E 5: 10 litres of hot water at 70º C is mixed
 Q   mSd with an equal volume of cold water at 20º C .
1 Find the resultant temperature of the water.
20 (Specific heat of water = 4200 J/kg -K)
20
2
 2

Q   1000 3   10 d   3 3

2
m1S11  m2S22
Sol. Resultant temperature,   m S  m S
10 10
1 1 2 2

 20   3 10 
2 2 Here, m1  m2  10kg ,
  203    10    8200 1050  7150cal (since mass of 1 litre of water is 1 kg).
 2   2 
W.E-3: Find the water equivalent of copper block 1  70º C;2  20º C
of mass 200g. The specific heat of copper is and S1  S 2  4200 J / kg  K
0.09 cal / g 0C . 10  4200  70  10  4200  20
  45º C
Sol: Water equivalent w= mS  200  0.09  18g 10  4200  10  4200
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W.E 6. A sphere of aluminium of 0.047 kg is CHANGE OF STATE
placed for sufficient time in a vessel  Matter exists in three states or phases such as
containing boiling water, so that the sphere solid, liquid and gas.
is at 1000 C . It is then immediately  A transition from one of these states to
transferred to 0.14 kg copper calorimeter another is called change of state.
containing 0.25 kg of water at 200 C . The Melting of ice or vaporisation of water is an
example for change of state. During change of
temperature of water rises and attains a
state, temperature remains constant.
steady state at 230 C . Calculate the specific Melting:
heat capacity of aluminium.  The change of state from solid to liquid is called
( Scu  386 J / Kg  K , S w  4180 J / Kg  K ) melting (and the reverse process is called fusion).
Sol: Heat lost by aluminium sphere =  Every solid melts at a definite temperature called
(heat gained by water) + (heat gained by melting point.
calorimeter)  The melting point remains constant until the entire
amount of solid substance melts.
0.047  S Al  1000  230   0.25  4180  230  200   During melting, solid and liquid states are in
0.14  386  23  20
0 0
 equilibrium.
 Melting point of a solid depends on its nature,
 S Al  911J / Kg  K pressure and presence of impurities.
Vaporisation (Boiling) :
W.E 7: The temperature of equal masses of three  The change of state from liquid to vapour at a
different liquids A, B and C are 12ºC, particular temperature is called vaporisation.(and
19ºC and 28ºC respectively. The common the reverse process is called condensation)
temperature when A and B are mixed is  Every liquid vaporises at a definite temperature
16ºC and when B and C are mixed is 23ºC. called boiling point.
What should be the common temperature  The boiling point remains constant until the entire
when A and C are mixed? amount of liquid vaporises.
Sol. Given  A  12º C ,  B  19º C and C  28º C .  During vaporisation liquid and gaseous states are
in equilibrium.
Let S A , S B and S C are the specific heats of  Boiling point of a liquid depends on nature of the
respective liquids. liquid, applied pressure and presence of impurities.
When liquid A and B are mixed Evaporation:
Heat gain = Heat lost  The escape of molecules from the free surface of
a liquid is called evaporation
mS A 16  12   mS B 19  16 
 Refrigerators, air coolers etc., work on the
4 principle of cooling produced by evaporation.
or S B  S A ........(i )  Body temperature is also controlled by
3
When liquid B and C are mixed evaporation of sweat.
Heat gain = Heat lost  Evaporation is a slow process where as boiling
is a quick process.
mS B  23  19   mSC  28  23  or  Evaporation takes place at all temperatures
5 whereas boiling takes place at a particular
SB  S C .....(ii ) temperature.
4  Evaporation takes place only at the surface of a
15 liquid where as boiling occurs through out the
From (i) and (ii), we get S A  SC
liquid.
16
When A and C are mixed, let equilibrium tempera-  The rate of evaporation depends on the nature of
ture of mixture is  , then the liquid.
Heat gain = Heat lost  The rate of evaporation is more when the difference
in temperatures of the liquid and the surrounding
mSA  12  mSC  28     20.26º C air is high.

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Effect of pressure on melting point and Regelation of ice:

 The melting of ice when pressure is applied and
boiling point resolidification on removal of pressure is called
 Effect of pressure on M.P and B.P can be regelation. Snow-ball preparation is due to
explained with Clausius-Clapeyron relation which regelation.
can be derived on the basis of thermodynamics  Skating is possible on snow due to the formation
of water below the skates.
dP L
i.e. dT  T V  V  Triple point :
f i  The temperature and pressure at which solid, liquid
L = Latent heat of fusion and vapour states co-exist is called triple point.
Vi = Initial volume, Vf = Final volume  The triple point of water is
273.16K (0.010C) and pressure 0.006 atm.
 In case of boiling as volume of vapour V f is always
(0.459 cm of Hg)
dP  Negative slope of ice line showing that the melting
greater than volume of liquid Vi hence is point decreases with increasing of the pressure
dT
positive. i.e boiling point of every liquid rises with  Sublimation is the change from a solid to the vapour
increase in pressure state without the intermediate liquid state and the
 In case of melting for substances like wax and reverse process of direct condensation of vapour
sulphur which expands on melting to solid is called hoar frost.
V f  Vi and hence melting point rises with increase Phase diagram of water
in pressure.
 In case of substances like ice and rubber which
contracts on melting V f  Vi and hence V f  Vi
pressure c ice line steamline A
negative i.e. melting point is lowered with increase
in pressure.
 On mountains, it is difficult to cook food because 0
with increase in height, pressure decreases and 0.006 atm
hence the boiling point of water decreases.
W.E-8: The melting point of ice is 0ºC at 1 atm. hoar frost line
At what pressure will it be -1ºC? B
 1  3 3
(Given, V2  V1  1    10 m )
 0.9 
 Under normal conditions of pressure, solids like
Sol. Here T   1  0   1, T  273  0  273K
camphor, iodine, arsenic, etc., do not melt when
 1  3 3
heated, but they under go “sublimation”.
and V2  V1  1    10 m (given) Latent Heat :
 0.9 
 It is the amount of heat required to change unit
L  80cal / g
mass of a substance from one state to another
P L state without any change of temperature.
we have, T  T V  V 
Q
 J / Kg or Cal / g 
2 1
L
m
P 80  4.2  103
  Q  mL ; L  Latent Heat
 1 
273 1 
1  3
  10  Latent heat of fusion of ice is 80Cal/g or
 0.9 
0.335  106 J/kg.
P  110.8 105 N / m 2  110.8 atm  Latent heat of vapoursiation of water is 540 Cal/
P2  P1  110.8 atm  P2 110.8  P1 111.8 atm g or 2.26  106 J/kg

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 The amount of heat required to convert m grams W.E-9 : A piece of ice of mass 100 g and at
of ice at –100C to m grams of steam at 1000C is temperature 00 C is put in 200 g of water at
0
250 C . How much ice will melt as the
-10 C m gm
temperature of the water reaches 00 C ? (
Q1  msice  specific heat capacity of water
 4200J kg 1 K 1 and latent heat of fusion
0
0C m gm
Q2  mLice of ice  3.4 105 J Kg 1 )
0C
0 m gm Sol: The heat released as the water cools down from
Q3  msw  250 C to 00 C is
0
100 C
m gm
Q  mS    0.2  4200  25   21000 J
Q4  mLsteam The amount of ice melted by this heat is
0
100 C m gm Q 21000
m   62 g
L 3.4  10 5
Y W.E-10 : The following graph represents change
of state of 1 gram of ice at 200 C . Find the
Boiling
net heat required to convert ice into steam at
Point
1000 C
Melting Sice  0.53cal / g  0 C
Point
0
T( C)
X

Total heat required Q  Q1  Q2  Q3  Q4 d

100 e
 During melting or boiling the heat absorbed by
the substance is used in increasing the molecular 0
b c
distances
a Q(cal)
Temperature -20 Q1 Q2 Q3 Q4
F
Sol: In the figure :
0
100 C a to b: Temperature of ice increases until it reaches
D its melting point 00 C .
0CB
0
C
Q1  mSice  0   20    1 0.53 20   10.6cal
ice
b to c: Temperature remains constant until all the
A Heat ice has melted
Length of BC  Latent Heat of fusion of ice
Length of DE  Latent Heat of Vapourisation Q2  mL f  1 80   80cal
Length of DE > Length of BC ( i.e. always Lv  L f ) c to d : Temperature of water again rises until it
reaches its boiling point 1000 C
1
Slope of AB  mS Q3  mSwater 100  0  11.0 100   100cal
solid
d to e : Temperature is again constant until all the
1 water is transformed into the vapour phase
slope of CD  mS
Liquid Q4  mLv  1 539   539cal
Note:
Thus, the net heat required to convert 1g of ice at
(i) Latent heat of a substance becomes zero at
critical temperature. 200 C into steam at 1000 C is
(ii) Latent heat depends on the nature of a substance Q  Q1  Q2  Q3  Q4  729.6cal
and pressure.
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W.E-11 : A calorimeter of water equivalent 83.72 W.E-14: 20g of steam at 100ºC is passed into 100g
Kg contains 0.48 Kg of water at 35ºC. How of ice at 0ºC. Find the resultant temperature
much mass of ice at 0ºC should be added to
decrease the temperature of the calorimeter if latent heat of steam is 540 cal/g, latent heat
to 20ºC. (S W = 4186J / Kg-K and of ice is 80 cal/ g and specific heat of water is
Lice  335000 J / Kg ) 1 cal/gºC.
Sol. Heat capacity of the calorimeter = 83.72J K-1 Sol. For steam
From law of method of mixtures, Heat lost by the steam in condensation
H e a t lo s t b y c a lo r im e te r 

   H e a t g a in e d b y th e ic e Q1  ms Ls  20  540  10800cal .........(1)
H e a t lo s t b y w a te r 

For ice
83.7215 0.48418615  m 335000 83720 Heat gained by the ice in melting and to rise its
 m  0.07498 Kg temperature from 0o C to 1000 C is
W.E-12: A steam at 100ºC is passed into 1 kg of
water contained in a calorimeter of water Q2  mice Lice  mice S w t
equivalent 0.2 kg at 9ºC till the temperature
of the calorimeter and water in it is increased  100  80  100 1100  18000cal ......(2)
to 90ºC. Find the mass of steam condensed From eq. (1) and (2) ; Q2  Q1
in kg ( SW=1 cal/g ºC, & Lsteam = 540 cal/
g)(EAM-14E) Let  = resultant temperature of the mixture
[Link], m be the mass of the steam condensed.
mass of the steam passed into calorimeter, According to law of method of mixtures
m2 = 1kg = 1000 g. Heat lost by steam = Heat gained by ice
Water equivalent of calorimeter,
m1Sl = 0.2 kg = 200g mL s water 100 miceLice miceSwater  0
s s mS

1 = temperature of the steam = 100ºC

 20540 201100  10080 1001 
2 = temperature of the water = 9ºC
3 = resultant temperature = 90ºC    40º C
From law of method of mixtures, Note: The temperature of mixture can never be lesser
Heat lost = heat gained (calorimeter + water) than lower temperature and can never be greater
m  Lsteam  SW 1  3     m1S1  m2 SW  3  2  than higher temperature
m 540  1100  90     200  1000 1  90  9   L  mix   H
 m  176 g  0.176kg  0.18kg If ‘m’ g of steam at 1000 C is mixed with ‘m’ g of
W.E.13: 1g steam at 100ºC is passed in an insulat-
ing vessel having 1g ice at 0ºC. Find the equi- ice at 00 C then
librium composition of the mixture. (Neglect- a) Resultant temperature of mixture is 1000 C
ing heat
capacity of the vessel). m
Sol. Available heat from steam b) Mass of steam condensed  g
3
mL  1 540  540 cal
Heat required for melting of ice and to rise its tem- 2m
perature to 100º C  mice Lice  mwater S water  c) Mass of steam left uncondensed  g
3
 1 80  11 100  0   180cal
4m
Let m be the mass of steam condensed, then d) The final mixture contains g of water and
3
180 1
m 540  180  m  540  3 g 2m
g of steam both at 1000 C
1 4 3
Final contents : Water = 1   g ,
3 3
1 2
steam = 1  g
3 3
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W.E-15 : 6 gm of steam at 1000 C is mixed with 6 [Link] a small ice crystal is placed into
super cooled water, it begins to freeze
gm of ice at 00 C . Find the mass of steam left instantaneously. What amount of ice is
uncondensed formed from 1kg of water super cooled to
8º C .
( L f  80cal / g , Lv  540cal / g ,
Sol. mL  m1S ; m 80  1000 1 8 ; m = 100g
SWater  1cal / g  0 C ) Saturated and Unsaturated Vapours :
(a)When the pressure exerted by a vapour is
Sol: For steam maximum it is called saturated vapour, when
Heat lost by the steam in condensation pressure exerted is not maximum, it is called
unsaturated vapour.
Q1  ms Ls  6  540  3240cal .........(1) (b)Saturated vapours do not obey the gas laws and
For ice saturated vapour pressure of liquid is independent
Heat gained by the ice in melting and to rise its of volume occupied. But unsaturated vapour obey
temperature from 0o C to 1000 C is the gas laws.
(c)At boiling point of a liquid saturated vapour
Q2  mice Lice  mice S w t pressure is equal to atmospheric pressure at that
 6  80  6 1100  1080cal ......(2) place.
NOTE:
From eq (1) and (2) Q1  Q2
i.e , the total steam should not condensed in to Uni ts
Physical
water. CG S
Q uantity SI
( Practical )
Let ‘m’ gm of steam is condensed into water by Heat Joul e Calo ries
giving 1080cal. of heat . Specific Heat Joul e/Kg-K Cal/ g-0 C
1080 Molar s pecific Joul e/m ol -
mLs  1080 ; m   2 gm Heat K
Cal/ mol -0 C
540
Thermal
 mass of the steam left uncondensed  6  2  4g Joul e/Kg Cal/ 0C
capacity
W.E-16:A piece of ice(heat capacity =2100J/Kg 0C Water
Kg g
and latent heat  3.36 105 J / Kg ) of mass m Equi valent

grams is at 5º C at atmospheric pressure. It

is given 420 J of heat so that the ice starts C.U.Q
melting. Finally when the ice-water mixture
is in equilibrium, it is found that 1gm of ice 1. Heat capacity of a substance is infinite. It
has melted. Assuming there is no other heat means
exchange in the process. Find the value of 1) heat is given out 2) heat is taken in
m. (JEE-2010) 3) no change in temperature whether heat is taken
Sol. Here, heat given is used to increase the in (or) given out
temperature of the ice to 0º C and to melt 1gm 4) all of the above
of ice. 2. The heat capacity of material depends upon
Given m is mass of ice in gm. 1) the structure of a matter
2) temperature of matter
 
 420  m  2100  5  1 3.36 105  10 3 3) density of matter 4) specific heat of
 m  8 gm . matter
3. Heat required to raise the temperature of one
Super cooling : gram of water through 10C is
 Most liquids, if cooled in a pure state in a perfectly 1) 0.001 Kcal 2) 0.01 Kcal
clean vessel, with least disturbance, can be 3) 0.1 Kcal 4) 1.0 Kcal
lowered to a temperature much below the normal 4. In defining the specific heat, temperature is
freezing point, without solidifying. This is known represented in 0F instead of 0C. Then the
as super cooling or super fusion. value of specific heat will
 In super cooling, water can be cooled upto 1) decreases 2) increases
10ºC without becoming solid. 3) remain constant
4) be converted to heat capacity
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5. Which of the following states of matter have 14. In a pressure cooker cooking is done quickly
two specific heats ? because
1) solid 2) gas 3) liquid 4) vapour 1) the cooker does not absorb any heat
6. The specific heat of a gas in an isothermal 2) it has a safety valve
process is 3) boiling point of water rises due to increased
1) infinity 2) zero pressure
3) negative 4) remains constant 4) it is a prestige to cook in a cooker
7. Why the specific heat at a constant pressure 15. A large block of ice is placed on a table when
is more than that at constant volume the surroundings are at 00C
1) there is greater inter molecular attraction at 1) ice melts at the sides 2) ice melts at the top
constant pressure 3) ice melts at the bottom
2) at constant pressure molecular oscillation are 4) ice does not melt at all
more violent 16. Which of the following at 1000C produces
3) external work need to be done for allowing most severe burns ?
expansion of gas at constant pressure 1) hot air 2) water 3) steam 4) oil
4) due to more reasons other than those 17. The latent heat of vaporisation of water is
mentioned in the above more than latent heat of fusion of ice, why
8. The ratio [Cp / Cv] of the specific heats at a 1) on vaporisation much larger increase in volume
constant pressure and at a constant volume of takes place
any perfect gas 2) increase in kinetic energy is much larger on
1) can’t be greater than 5/4 boiling
2) can’t be greater than 3/2 3) kinetic energy decreases on boiling
3) can’t be greater than 5/3 4) volume decreases when the ice melts
4) can have any value 18. The latent heat of vaporisation of a substance
9. During melting process, the heat given to a is always
solid is used in (generally) 1) greater than its latent of fusion
1) Increasing the temperature 2) greater than its latent heat of sublimation
2) Increasing the density of material 3) equal to its latent heat of sublimation
3) Increasing the average distance between the 4) less than its latent heat of fusion
molecules 19. A piece of ice at 00C is dropped into water at
4) Increasing the average K.E. of the molecules 00C. Then ice will
10. When two blocks of ice are pressed against 1) melt 2) be converted to water
each other then they stick together (coalesce) 3) not melt 4) partially melt
because C.U.Q-KEY
01) 3 02) 4 03) 1 04) 1 05) 2 06) 1
1) cooling is produced 2) heat is produced
07) 3 08) 3 09) 3 10) 4 11) 1 12) 1
3) increase in pressure, increase in melting point
13) 1 14) 3 15) 3 16) 3 17) 1 18) 1
4) increase in pressure, decrease in melting point
11. Ice is found to be slippery when a man walks 19) 3
on it This is so because
1) increase in pressure causes ice to melt faster LEVEL - I (C.W)
2) increase in pressure causes ice to melt slower
3) its surface is smooth and cold HEAT CAPACITY (OR)
4) ice is colder THERMAL CAPACITY
12. Cooking is difficult on mountains because 1. The ratio of densities of two substances is
1) water boils at low temperature 2:3 and that of specific heats is 1 : 2. The
2) water boils at high temperature ratio of thermal capacities per unit volume is
3) water does not boil 4) it is cool there 1) 1 : 2 2) 2 : 1 3) 1 : 3 4) 3 : 1
13. Paraffin wax expands on melting. The melting 2. Two spheres of copper of diameters 10cm and
point of wax with increasing pressure is 20 cm will have thermal capacities in the ratio
1) increases 2) decreases 1 1 1 1
3) remains same 4)we can’t say 1) 2) 3) 4)
8 2 4 6
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3. Two liquids A and B of equal volumes have in the ratio 3 : 4. The resultant temperature
their specific heats in the ratio 2 : 3. If they of the mixture, when the above liquids, are
have same thermal capacity, then the ratio mixed (Neglect the water equivalent of
of their densities is container ) is
1) 1 : 1 2) 2 : 3 3) 3 : 2 4) 5 1) 1250C 2) 1000C 3) 500C 4) 1500C
:6 13. 1g of ice at 00 C is mixed 1g of steam at
4. Specific heat of aluminium is 0.25 cal/g-0c.
The water equivalent of an aluminium vessel 1000 C . The mass of water formed is
of mass one kilogram is 1) 1.33g 2) 13.3 g 3) 0.133 g 4) 13.3g
1) 40 cal/0C 2) 250 g 14. A piece of metal of mass 112g is heated to
3) 250 cal/0C 4) 40 g 1000 C and dropped into a copper calorimeter
LAW OF MIXTURES (OR) of mass 40g containing 200g of water at
CALORIMETRY AND CHANGE OF 160 C . Neglecting heat loss, the specific heat
of the metal is nearly, if the equilibrium
STATE PRINCIPLE temperature reached is 240 C
5. The quantity of heat which can rise the
temperature of x gm of a substance through ( Scu  0.1 cal / g  º C )
t1°C can rise the temperature of y gm of 1) 0.292cal / gm 0 C 2) 0.392cal / gm 0 C
water through t2°C is same. The ratio of 3) 0.192cal / gm 0 C 4) 0.492cal / gm 0 C
specific heats of the substances is
1) yt1/xt2 2) xt2/yt1 15. Three liquids with masses m1 , m2 , m3 are
3) yt2/xt1 4) xt1/yt2 thoroughly mixed. If their specific heats are
6. Two liquids A and B are at 300C and 200C
respectively. When they are mixed in equal S1 , S 2 , S3 and their temperatures 1 ,  2 ,3
masses the temperature of the mixture is respectively, the temperature of the mixture is
found to be 260C. The ratio of specific heats S11  S22  S33
is 1) m S  m S  m S
1) 4 : 3 2) 3 : 4 3) 2 : 3 4) 3 1 1 2 2 3 3
:2 m1S11  m2 S22  m3 S33
7. M g of ice at 00C is mixed with M g of water 2) m1S1  m2 S2  m3 S3
at 100c. The final temperature is
1) 80C 2) 60C 3) 40C 4) 00C m1S11  m2 S22  m3 S33
8. A beaker contains 200g of water. The heat 3) m11  m22  m33
capacity of the beaker is equal to that of 20g
water. The initial temperature of water in the m11  m2 2  m3 3
beaker is 200C. If 440g of hot water at 920C 4) S   S   S 
1 1 2 2 3 3
is poured in it, the final temperature LEVEL - I (C.W)-KEY
(neglecting radiation loss) will be nearly
1) 580C 2) 680C 3) 730C 4) 780C 01) 3 02) 1 03) 3 04) 2 05) 3 06) 4
9. If 10g of the ice at 0 C is mixed with 10g of
0
07) 4 08) 2 09) 2 10) 3 11) 1 12) 1
water at 1000C, then the final temperature of
the mixture will be 13) 1 14) 3 15) 2
1) 50C 2) 100C 3) 100 K 4) 00C
LEVEL - I (C.W)-HINTS
10. 10 grams of steam at 1000 C is mixed with 50
H1  1  S1 
gm of ice at 00 C then final temperature is 1. H  mS  VS  H     S 
2  2  2 
1) 200 C 2) 500 C 3) 400 C 4) 1000 C
3
11. The heat energy required to vapourise 5kg 4 H r 
of water at 373 K is 2. H  mS    r 3 S  1   1 
3 H 2  r2 
1) 2700 [Link] 2) 1000 [Link]
3) 27 [Link] 4) 270 [Link] 1 S2
12. Two liquids A and B are at temperatures of 3. m1S1 = m2S2  v11S1 = v2 2 S2 ;  = S
2 1
750C and 1500C respectively. Their masses
are in the ratio of 2 : 3 and specific heats are 4. water equivalent = mS gram.

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5. Q1  Q2  m1S11  m2 S2 2 liquid ‘B’ is 0.6 g/c.c . Heat capacity of 8 litres

6. Heat lost by A = Heat gain by B of ‘A’ is equal to that of 10 litres of ‘B’ . Then
their specific heats ratio is
S A    B 1) 4:5 2) 1:1 3) 2:3 4) 3:2
mS A    A  mSB    B  
SB    A 4. A copper block of mass 500 gm and specific
heat 0.1 cal/gm0C heated from 300 C to
7.  M  80    M 10   Final Temp. is 00 c
8. From principle of calorimetry 2900 C , the thermal capacity of the block is
1) 50cal / 0 C 2) 50gm 3) 5cal / 0 C 4) 5gm
mwater  Sw    20   mS     20
LAW OF MIXTURES (OR)
 mhot water  Sw  92   CALORIMETRY & CHANGE OF
9. From principle of calorimetry
STATE PRINCIPLE
 m  L   m  S  1   m  S 2 5. 75 gm of copper is heated to increase its
10. Heat lost = Heat gained temperature by 100 C . If the same quantity
mice Lice  mice Sw    of heat is given to ‘m’ gm of water, to have
same rise in temperature is ( specific heat of
msteam Lsteam  msteam S w 100   
copper = 420 J / Kg 0 C )
11. Q = m x Lsteam
12. mASA (  -75) = mBSB (150 -  ) 1) 7.5gm 2) 5gm 3) 10gm 4) 2.5gm
13. Here the resultant temperature is 1000 C 6. Two liquids are at 40 C and 300 C . When they
0

m| is mass of the steam condensed are mixed in equal masses, the temperature
of the mixture is 360 C . Ratio of their specific
m| Lv  mice L f  mice S water  
heats is
 water formed = 1g + m| 1) 3:2 2) 2:3 3) 4:3 4) 3:4
14. Heat lost by metal = heat gained by calorimeter 7. If 10g of the ice at 00C is mixed with 10g of
and water
water at 100C, then the final temperature of
mmetal Smetal 100  24   the mixture will be
 mcu Scu  mwater Sw   24 16 1) 50C 2) 00C 3) 1000 C 4) 400C
8. 5 gm of steam at 1000 C is passed into
15. Let 1   2   3 and  = resultant temperature.
calorimeter containing liquid. Temperature of
From principle of colorimetry
liquid rises from 320 C to 400 C . Then water
m3 S3 3     m1S1   1   m2 S2   2 
equivalent of calorimeter and contents is
1) 40 g 2) 375 g 3) 300 g 4) 160 g
LEVEL - I (H.W)
9. M grams of ice at 00 C is mixed with 3 M
gram of water at 800 C then the final
HEAT CAPACITY (OR) THERMAL temperature is
CAPACITY 1) 300 C 2) 400 C 3) 500 C 4) 600 C
1. The densities of two substances are in the
10. 50 g of steam at 1000 C is passed into 250 g
ratio 5:6 and the specific heats are in the ratio
3:5 respectively. The ratio of their thermal of ice at 00 C . Find the resultant temperature(
capacities per unit volume is if latent heat of steam is 540 cal/g , latent
1) 2:1 2) 1:2 3) 4:1 4) 1:4 heat of ice is 80 cal/g and specific heat of
2. Two spheres with radii in the ratio 1:2 have water is 1 cal/g-0C)
specific heats in the ratio x:y and densities in 1) 400 C 2) 300 C 3) 200 C 4) 100 C
the ratio z:x. The ratio of their thermal 11. Quantity of heat lost in condensation of 10
capacities is gm of steam at 1000 C is
1) z:2y 2) zy:8 3) z:8y 4) xy:2z
3. Density of a liquid ‘A’ is 0.5 g/c.c and that of 1) 2.26 105 J 2) 2.26 10 4 J
3) 22.6 J 4) 44.52  104 J
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12. Two liquids at temperatures 600 C and 200 C 10. Heat lost by steam = Heat gained by ice.
respectively have masses in the ratio 3:4 msteam Lv  ms  Sw 1000   0 
their specific heats in the ratio 4:5 . If the
two liquids are mixed, the resultant = mw L f  mw Sw  0  0 
temperature is (2000 E) 11. Q = mLsteam
1) 700 C 2) 500 C 3) 400 C 4) 350 C 12. Heat lost = Heat gained
13. Steam at 1000 C is passed into 22 grams of m S   m2 S2 2
water at 200 C . When resultant temperature
 1 11
m1S1  m2 S2
is 900 C , then weight of the water present is
13. msteam Lv  msteam S w 1000  900 
1) 27.33 g 2) 24.8 g 3) 2.8 g 4) 30 g
14. A calorimeter of water equivalent 100 grams  mw S w  900  200 
contains 200 grams of water at 100 C . A solid
msteam  mass of steam converted into water
of mass 500 grams at 450 C is added to the
calorimeter. If equilibrium temperature is  mass of water = 22 g + msteam
250 C then, the specific heat of the solid is 14. Heat lost by solid = Heat gained by calorimeter
and water
( in c a l / g  0 C )
1) 0.45 2) 0.1 3) 4.5 4) 0.01 ms S s  450  250    mc Sc  mw Sw   250  100 
15. Two liquids of masses m and 5 m at 15. From principle of calorimetry
temperatures 3 , 4 are mixed. If their m S   m2 S22
specific heats are 2S,3S respectively, the  1 11
m1S1  m2 S2
resultant temperature of mixture is
66 55 44 33 LEVEL - II (C.W)
1)  2)  3)  4) 
17 17 17 17
LEVEL - I ( H.W )-KEY SPECIFIC HEAT
01) 2 02) 3 03) 4 04) 1 05) 1 06) 1
07) 2 08) 2 09) 2 10) 1 11)2 12) 4 1. A metal block absorbs 4500 cal of heat when
13) 2 14) 1 15) 1 heated from 300 C to 800 C . Its thermal
capacity is
LEVEL - I ( H.W )-HINTS 1) 90 gm 2) 90 cal / 0 C 3) 9 gm 4) 9 cal / 0 C
H1  1  S1  2. Two beakers A and B contain liquids of
1. H  mS  VS  H     S  masses 300 g and 420 g respectively and
2  2  2 
3 specific heats 0.8 cal / g  0 C and
4 H  S r 
2. H  mS   r3S  1  1  1   1  0.6 cal / g  0 C . The amount of heat on them
3 H 2  2 S 2  r2 
is equal. If they are joined by a metal rod
3. mASA = mBSB   AVA S A   BVB S B 1) heat flows from the beaker B to A
4. Thermal capacity , H = mS 2) heat flows from A to B
5. Q1  Q2  m1S11  m2 S2  2 3) no heat flows
4) heat flows neither from A to B nor B to A
6. Heat lost by 1st liquid = Heat gained by 2nd liquid.
LAW OF MIXTURES (OR)
mS1  400  360   mS 2  360  300  CALORIMETRY AND CHANGE OF
STATE PRINCIPLE
7.  m  Lice   mSw 10  final temp is 0º C 3. Three liquids A,B and C of masses 400gm,
8. Heat lost by steam = Heat gained by the 600 gm and 800 gm are at 300c, 400c and 500c
calorimeter and contents. respectively. When A and B are mixed
msteam  Lv  ms 11000  400   mS  400  320  resultant temperature is 360C when B and C
are mixed resultant temperature is 440C Then
9. 80M  M 1  0  0   3M 1  800   0  ratio of their specific heats are
1) [Link] 2) [Link] 3) [Link] 4) [Link]
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4. 1gm of ice at 00C is converted to steam at 4. Q = mLice+mSw(100-0)+mLs
1000C the amount of heat required will be 5. Q1  Q2  mSc 1  mSw 2
( LSteam  536 cal / g ) 6. From principle of calorimetry
1) 756 cal 2)12000 cal 3)716 cal 4)450 cal
5. 50g of copper is heated to increase its m S   m2 S2 2
 1 11
temperature by 100C. If the same quantity m1S1  m2 S2
of heat is given to 10 g of water, the rise in its
temperature is  G iv e n , m 2 S 2
 1 .5  m 1 S 1 
( Scu = 420J/kg/0C and S w = 4200J/kg/0C ) 7. Heat lost by hot water = Heat gained by cold
water.
1) 50C 2) 60C 3) 70C 4) 80C
6. A liquid of mass ‘m’ and specific heat ‘S’ is at  m1 1 
a temperature ‘2t’. If another liquid of thermal m1S1  1  m2 S 2 2  Given,  
 m 3
capacity 1.5 times, at a temperature of t/3 is 2

added to it, the resultant temperature will be 8. Here a part of ice is melted because heat given by
4 t 2 water when it comes to 0ºC is less than the heat
1) t 2) t 3) 4) t required for ice to melt completely.
3 2 3 Let m| is the mass of the ice melted.
7. Boiling water at 1000C and cold water at t0C
are mixed in the ratio 1:3 and the resultant mSice 10   mLice  mwater Sw  60 
maximum temperature was 370C. Assuming
no heat losses, the value of ‘t’ is mL f
9. P
1) 40C 2) 90C 3) 120C 4) 160C t
8. The fraction of ice that melts by mixing equal 10. Heat lost by steam = Heat gained by ice
masses of ice at -10°C and water at 60°C is
msteam  Lv  msteamSw 1000  0   mice Lf  miceSw 0 0
6 11 5 11
1) 2) 3) 4)
11 16 16 15
9. Power of a man who can chew 0.3 kg ice in LEVEL - II (H.W)
one minute is ( in cal/s)
1) 400 2) 4 3) 24 4) 240 SPECIFIC HEAT
10. The final temperature, when 10 g of steam at
1. A calorimeter takes 200 cal of heat to rise its
1000 C is passed into an ice block of mass 100g temperature through 100 C . Its water
L steam  540 cal / g , Lice  80 cal / g ; S water  1 cal / g 0C  equivalent in gm is
is 1) 2 2) 10 3) 20 4) 40
1) 21.80C 2)15.70C 3) 16.90C 4) 20.40C 2. Three different substances have the specific
LEVEL - II (C.W) - KEY heats in the ratio [Link] and the temperature
increases in the ratio [Link] when the same
01) 2 02) 2 03) 3 04) 3 05) 1 06) 2
heat is supplied to the three substances. The
07) 4 08) 2 09) 1 10) 1 ratio of their masses is
LEVEL - II (C.W) - HINTS 1) [Link] 2) [Link] 3) [Link] 4) [Link]
H 
Q LAW OF MIXTURES (OR)
1.
 CALORIMETRY & CHANGE OF
2. Quantity of heat on A = Quantity of heat on B
m A  S A   1  m B  S B   2  1   2 STATE PRINCIPLE
3. When A, B are mixed 3. Equal masses of 3 liquids A, B and C have
temperatures 10º C , 25º C and 40º C
mA S A    A  mB S B    B ...... (i) respectively. If A and B are mixed, the mixture
When B, C are mixed has a temperature of 15º C . If B and C are
m B S B     B  mC S C    C ...... (ii) mixed ,the mixture has a temperature of
From (i) and (ii) we get relation between SA and SC. 30º C . If A & C are mixed the temperaturee
When A and C are mixed of the mixture is (EAM-2012M)
m AS A  A  m C SC  C 1) 16º C 2) 35º C 3) 20º C 4) 25º C

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4. 1 gram of ice at 100 C is converted to steam 3. When A & B are mixed, mS A  5  mS B 10 
at 1000 C the amount of heat required is  S A  2S B
 Sice  0.5 cal / g º C  When B & C are mixed, mS B  5  mSC 10 
( Lv  536 cal / g & L f  80 cal / g , )  S B  2 SC So, S A  4 SC
1) 861 cal 2)12005 cal 3)721 cal 4)455 cal When A & C are mixed
5. 30 gram of copper is heated to increase its
mS A   10   mSC  40   
temperature by 200 C if the same quantity of
heat is given to 20 gram of water the rise in 4. Q = m Sice 10  mLice+mSw(100-0)+mLs
its temperature. 5. Q1  Q2  mcu Scu 1  mwSw 2
( S w  4200 J / kg  K & Scu  420 J / kg  K ) 6. From principle of calorimetry
1) 50 C 2) 60 C 3) 30 C 4) 80 C m1 S11  m2 S 2 2

6. A liquid of mass m and specific heat c is m1 S1  m 2 S 2
heated to a temperature 2T. Another liquid 7. From principle of calorimetry
of mass m/2 and specific heat 2c is heated to m1 S1 1  m 2 S 2 2
a temperature T. If these two liquids are  
mixed, the resulting temperature of the m1 S1  m 2 S 2 ( Given, m1+m2=20)
mixture is 8. Q  m  Lice  ice V  Lice
1) (2/3)T 2) (8/5)T 3) (3/5)T 4) (3/2)T
7. A tap supplies water at 100 C and another tap Q
9. P , Q  m Sw  30  m  Lice
at 1000 C . How much hot water must be taken t
10. Heat lost by steam = Heat gained by water
so that we get 20kg of water at 350 C
1) 40/9 kg 2) 50/9 kg 3) 20/9 kg 4) 130/9 kg msteam  Lv  msteamSw 1000  400   mwater Sw  400 100 
8. Find the amount of heat supplied to decrease
the volume of an ice water mixture by 1 cm3 LEVEL - III
without any change in temperature.
  0.9  water , Lice  80cal / gm 
ice LAW OF MIXTURES (OR)
1) 360 cal. 2) 500 cal. CALORIMETRY & CHANGE OF
3) 72 cal. 4) 720 cal
9. The power of a system which can convert 10 STATE PRINCIPLE
kg of water at 300 C into ice at 00 C in one 1. 30g of ice 00C and 20 g of steam at 1000C are
mixed. The composition of the resultant
minute ( L ice = 336000 J/Kg; and
mixture is
S water  4200 J / kg / K ) will be 1) 40g of water and 10g steam at 1000C
1) 77 kW 2) 55 kW 2) 10g of ice and 40g of water at 00C
3) 38.5 kW 4) 40 kW 3) 50g of water at 1000C
10. The amount of steam at 1000 C that should 4) 35g of water and 15g of steam at 1000C
be passed into 600 g of water at 100 C to make 2. 30 gms of water at 30ºC is in a beaker. Which
of the following, when added to water, will
the final temperature as 400 C will be have greatest cooling effect? (Specific heat
1) 40 g 2) 30 g 3) 20 g 4) 45 g of copper = 0.1 cal/gmºC)
LEVEL-II ( H.W ) - KEY 1) 100gm of water at10ºC
01) 3 02) 4 03) 1 04) 3 05) 3 06) 4 2) 15gm of water at 0ºC
07) 2 08) 3 09) 1 10) 2 3) 3gm of ice at 0ºC 4) 18gm of copper at 0ºC
3. ‘n’ number of liquids of masses m,2m,3m,4m,
LEVEL-II ( H.W ) - HINTS ....... having specific heats S, 2S,3S, 4S, ....
Q are at temperatures t, 2t, 3t, 4t . . . . are mixed.
1. H The resultant temperature of mixture is

m1 S2  2 3n 2n  n  1 3n  n  1 3n  n  1
Q  mS     const    1) t 2) t 3) t 4) t
2. m2 S1 1 2n  1 3  2 n  1 2  2 n  1  2n  1
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4. Steam is passed into a calorimeter with all melted, the temperature of whole become
water having total thermal capacity 110 10ºC. Neglecting heat lost to surroundings
cal/gm and initial temperature 30ºC. If the latent heat of fusion of ice is
the resultant temperature is 90ºC, the 1) 80 cal/gm 2) 90 cal/gm
increase in the mass of the water is 3) 70 cal/gm 4) 540 cal/gm
1) 12 gm 2) 1.2 gm 3) 5 gm4) 12.4 gm LEVEL - III-KEY
5. 2 kg of ice at 20ºC is mixed with 5 kg of 01) 1 02) 1 03) 3 04) 1 05) 2
water at 20ºC in an insulating vessel having 06) 1 07) 3 08) 2 09) 2 10) 2
a negligible heat capacity. The final mass of LEVEL - III- HINTS
water in the vessel. ( The specific heat of 1. msLs = (mice Lice  mice s )
water and ice are 1k cal/kg0C and 0.5 k cal/ Where ms=mass of steam condensed to rise
kg/0C respectively and the latent heat of temperature of ice to 1000c water.
fusion of ice is 80 k cal/kg) is 2. From principle of calorimetry
1) 7 kg 2) 6 kg 3) 4 kg 4) 2 kg
(i) mS w  30  1   m1Sw 1  10 
6. A thermally insulated vessel contains some
water at 00 C . The vessel is connected to a (ii) mS w  30   2   m2 Sw  2  0 
vacuum pump to pump out water vapour. This
results in some water getting frozen. The (iii) mS w  30  3   m3 Lice  m3 Sw 3  0 
maximum percentage amount of water that (iv) mS w  30  4   m4 Scu  4  0 
will be solidified in this manner will be
here m1  100 g , m2  15 g , m3  3 g , m4  18 g
( Lsteam  21105 J / kg and Lice  3.36105 J / kg ).
1) 86.2% 2) 33.6% 3) 21% 4) 24.36% above calculations will be show that 1 is least.
7. The specific heat of a substance varies with 3. From principle of calorimetry
temperature as s=0.20+0.14  +0.023  2 (cal/ m S   m2 S22  ......
gmºC) .Heat required to raise the temperature  1 11
m1S1  m2 S2  .....
of 2 gm of the substance from 50 C to 150 C is
(  is in º C )

1  2 3 3
 33  ........  n3 t
1) 24 cal 2) 56 cal 3) 82 cal 4) 100 cal
8. In an industrial process 10 kg of water per
1  2 2 2
 3  .........  n
2 2

hour is to be heated from 200 C to 800 C . To 4. From principle of calorimetry
do this steam at 1500 C is passed from a boiler  mS water 1  m  Lsteam  S 2 
into a copper coil immersed in water. The (mS)water= 110, Sw = 1, Lice = 540 ,
steam condenses in the coil and is returned 1  60 &  2  10
to the boiler as water at 900 C . How many 5. Let m be mass of ice melted into water
kilograms of steam is required per hour mice  Sice  20  m Lice  mwater  Sw  20
(specific heat of steam = 1 cal / gm , latent final mass of water in vessel = m + 5kg.
heat of vapourisation = 540 cal/gm)? 6. Let m1 mass is vaporised and m2 mass gets
1) 1gm 2) 1 kg 3) 10 gm 4) 10 kg solidified
9. A heater melts 0ºC ice in a bucket completely Then heat taken in vaporisation = heat given
into water in 6 minutes and then evaporates during
all that water into steam in 47 minutes 30 sec.
If latent heat of fusion of ice is 80 cal/gram, or m1  21 105    m2   3.36  105 
latent heat of steam will be (specific heat of
m2
water is 1 cal /gam-ºC) m2  6.25m1 ; %  m  m  100
1) 536 Cal/gram 2) 533.3 Cal/gram 1 2
3) 540 Cal/gram 4) 2.268  106 J/Kg 2
10. Ice at 0ºC is added to 200gm of water initially
7. Q   m  S  d
at 70ºC in a vacuum flask. When 50gm of ice 1
has been added and has all melted, the 15
temperature of flask and contents is 40ºC.
When a further 80gm of ice is added and has 
Q  2  0.2  0.14  0.023 2 d 
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8. Let mkg of steam is required for this process 2. Three liquids A,B and C having same specific
heats have masses m,2m and [Link]
temperatures  , 2 and 3 respectively. The
0
steam, 150 C 0
water, 90 C
temperature of mixture.
Column-I Column-II

5
a) when A and B are mixed p)   
2
water

5
b) When A and C are mixed q)   
3
m w  S w  8 0  2 0 
 mSsteam 150100  mLsteam  mSw 100  7
c) When B and C are mixed r)   
9. Let m be the mass of ice in bucket 3
Heat given out by heater in 6min is 80m
Heat given out in 47.5min is 100m+mLv  13 
m  80 --  6 minutes d) When A,B and C all are mixed s)   
5
(m  1  100 )+ (m  Lv)  47.5 minutes
 80  47.5 = 6(100+Lv) 3. Match the following.
10. According to principle of calorimetry Column-I Column-II
ML f  MS    mS   water   mS   flask a) Specific heat p) watt
5Lf  400 3w....(i), here w   mS  flask b) Heat capacity q) j/kg-oC
Now the system contains (200+50)gm of c) Heat current r) j/sec
water at 40ºC, so when further 80gm of ice d) Latent heat s) none
is added 4. In a container of negligible mass m grams of
8 L f  670  3w .....( ii )
steam at 1000 C is added to 100gm of water
from (i) & (ii) we get L f .
that has temperature 200 C . If no heat is lost
LEVEL - IV to the surroundings at equilibrium, match the
following.
Matching Type Questions Column-I Column-II
1. One gram of ice at 0 C is heated to change
0
a)If m=20gm, mass of steam p)114.8
to steam at 1000 C having volume 1673cc at in the mixture (in mg)
normal pressure b)If m=20gm, mass of water q)76.4
Column-I Column-II
(event) Heat required in the mixture (in mg)
a) Change in total potential p) 40cal / g c)If m=20gm, final temperature r)5.2
energy of the mixture (in 0 C )
b) External work done in q) 497cal / g
d)If m=10gm, final temperature s)100
expanding the gas
c) Change in kinetic energy r)100cal / g of the mixture (in 0 C )
d)Change in potential energy s) 577cal / g
and boiling process
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 JEEJEE
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Assertion & Reason Type Questions Statement-2: Latent heat is the heat required to
melt a unit mass of solid.
Read the following Questions and Choose if
12. Statement-1:At room temperature ice does not
1) both, Assertion and Reason are true and the sublimate from ice to steam.
Reason is correct explanation of the Assertion. Statement-2: The critical point of water is much
2) both, Assertion and Reason are true, but Reason above the room temperature.
is not correct explanation of the Assertion. 13. Statement-1 : When two liquid samples with
3) Assertion is true, but the Reason is false. temperature T1 and T2 but same specific heat
4) Both, Assertion and Reason are false. capacities are mixed the equilibrium temperature
5. Assertion: The specific heat capacity of a body T1  T2
depends on the material of the body. of the mixture is
2
Reason: The specific heat capacity of a body
Statement-2:The amount of heat lost by the hotter
depends on heat given
liquid is equal to the amount of heat absorbed by
6. Assertion: Latent heat of fusion of ice is 336000
the cooler liquid.
J kg 1 LEVEL - IV- KEY
Reason: Latent heat refers to change of state Matching Type Questions
without any change in temperature.
7. Assertion: Change of state is an example of 1) a-s, b-p, c-r,d-q
isothermal process. 2) a-q, b-p, c-s, d-r
Reason: Change of state from solid to liquid 3) a-q, b-s, c-p,r, d-s
occurs only at melting point of solid: and change 4) a-r, b-p, c-s,d-p
of state from liquid to gas occurs only at boiling Assertion & Reason Type Questions
point of liquid. Thus, there is no change of
5) 3 6) 2 7) 1 8) 2
temperature during change of state.
8. Assertion: Specific heat of a substance during Statement Type Questions
change of state is infinite. 9) 1 10) 1 11) 3 12) 1 13) 3
Reason: During change of state Q  mL ,
LEVEL - IV - HINTS
specific heat does not come in. 1. Specific heat depends on nature of the material but
Statement Type Questions not depends on heat given.
Options : 2. From definition we know that temperature remains
1. Statement 1 is true and statement 2 is true constant during change of state. From experiments
2. Statement 1 is true and statement 2 is false we get the value of Lice.
3. Statement 1 is false and statement 2 is true 3. The process in which temperature remain constant
4. Statement 1 is false and statement 2 is false is called isothermal process.
9. Statement-1: Specific heat capacity is the cause During the change of state temperature remain
of formation of land and sea breeze. constant until total amount of substance can
Statement-2: The specific heat of water is more undergoes change of state.
than land. 4. During the change of state   0
10. Statement-1:When solid melts or a liquid boils, 1 Q
the temperature does not increase when heat is S  
m 
supplied.
Statement-2:The heat supplied is used to increase Q
From definition L 
internal kinetic energy. m
11. Statement-1:Melting of solid causes no change
in internal energy.

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