®

TEST TYPE : CLASS TEST-1

TARGET : JEE (MAIN+ADVANCED)
COURSE NAME : JRS01
SUBJECT : CHEMISTRY
FACULTY NAME : BRJ SIR
TEST DATE : 22-12-2024 Time : 1 Hr. Max. Marks : 128
PHYSICAL PAPER

SECTION A (Maximum Marks: 80)

 This section contains Twenty five (25) questions for each subject.
 Each question has four options (1), (2), (3) and (4). ONLY ONE of these four options is the most
appropriate or best answer, which will be considered the correct answer.
 The answer to each question will be evaluated according to the following Marking Scheme:
 Full Marks : +4 If ONLY the correct option is chosen.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –1 In all other cases
1. Liquids A and B form an ideal solution. At a certain temperature the total vapour pressure of a mixture
of A and B is 400 mm. The mole fraction of A in the liquid mixture in equilibrium with the vapour phase
is 0.5. If the vapour pressure ratio (PA0/PB0) for the pure liquids at this temperature is 3/5, what is the
partial pressure of A in the vapour phase ?
nzo A rFkk B ,d vkn'kZ foy;u cukrs gSA ,d fuf'pr rki ij] feJ.k A rFkk B dk dqy ok"i nkc 400 mm. gSA
lkE;koLFkk ij ok"i voLFkk ds lkFk nzo feJ.k esa A dk eksy izHkkt 0.5 gSA ;fn blh rki ij 'kq) nzo ds fy, ok"i
nkc dk vuqikr (PA0/PB0) ; 3/5 gSA ok"i voLFkk esa A dk vkaf'kd nkc gksxkA
(1) 50mm (2*) 150mm (3) 75mm (4) 40mm

2. Two liquids X and Y are perfectly immiscible. If X and Y have molecular masses in ratio 1:2, the total
vapour pressure of a mixture of X and Y prepared in weight ratio 2:3 should be (P X0 = 400 torr, PY0 =
200 torr)
nks nzo X rFkk Y iw.kZr;k vfeJ.kh; gS ;fn X rFkk Y dk eksyj nzO;eku vuqikr 1 : 2 gS rc X rFkk Y ds feJ.k dk
dqy ok"i nkc fuEu gksuk pkfg,] ;fn ;g feJ.k X rFkk Y ds 2 : 3 Hkkj vuqikr ls cuk;k tkrk gSA (PX0 = 400
torr, PY0 = 200 torr)
(1) 300 torr (2) 466.7 torr (3*) 600 torr (4) 700 torr
Sol. For immiscible solution vfeJ.kh; foy;u ds fy, = PT = PA0 + PB0
= 400 + 200 = 600.

3. A solution of a pair of volatile liquids A and B will show negative deviation from Raoult's law if it fulfills
the following condition :
[XA, XB are the mole fraction of A and B in liquid mixture,
PA0, PB0 are vapour pressure of A and B repectively]

(1) PA > XAPºA and PB > XBPºB

(2) Vmixing is positive
(3) Hmixing is positive
(4*) Vmixing is negative
ok"i'khy nzoks A rFkk B ds ;qXe dk ,d foy;u] jkWÅYV fu;e ls _.kkRed foy;u n'kkZrk gSA ;fn ;g fuEu
ifjfLFkfr;ksa dk vuqlj.k djrk gS %
[XA, XB nzo feJ.k esa] A rFkk B ds eksy izHkkt,

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 PA0, PB0 Øe'k% A rFkk B ok"inkc gSA]

(1) PA > XAPºA rFkk PB > XBPºB

(2) VfeJ.k /kukRed gSA
(3) HfeJ.k /kukRed gSA
(4*) VfeJ.k _.kkRed gSA
Sol. Factual

4. Positive deviation from raoults law is shown by which of the following mixtures :
(1) Benzene and toluene (2) CHCl3 & acetone
(3*) ethanol & water (4) HCl & water
fuEu esa ls fdl feJ.k }kjk jkÅYV fu;e ls /kukRed fopyu dks n'kkZ;k tkrk gS :
(1) csUthu o VkWyqbu (2) CHCl3 o ,lhVksu
(3*) ,FksukWy o ty (4) HCl o ty
Sol. It is a fact. (;g ,d rF; gSA)

5. A gas 'X' is present with saturated water vapour over water liquid at total pressure of 1.5 atm. Vapour
pressure of H2O at same temperature is 0.5 atm. What is the solubility of gas 'X' in terms of moles in 10
mole H2O().

(1) 1 × 10–3 mole (2) 5 × 10–2 mole (3*) 2 × 10–3 mole (4) 1 × 10–2 mole

dqy nkc 1.5 atm dh ifjfLFkfr esa ty ok"i ls lar`Ir ty nzo ij] ,d xSl 'X' mifLFkr gSA leku rki ij H2O dk
ok"i nkc 0.5 atm gSA 10 eksy H2O() esa xSl 'X' dh foys;rk eksy ds inksa esa D;k gS \

(1) 1 × 10–3 mole (2) 5 × 10–2 mole (3*) 2 × 10–3 mole (4) 1 × 10–2 mole
Sol. PT = px + pH2O
px = 1.5 – 0.5 = 1 atm
slope of graph (vkjs[k dk <+ky) = kH = 5 × 103
nx
px = kH
nH O2

nx
1 = 5 × 103 ×
10
1
nx = = 2 × 10–3.
500

6. 1 mol CH3COOH is added in 250 g benzene. Acetic acid dimerises in benzene due to hydrogen bond.
Kb of benzene is 2 K kgmol–1. The boiling point has increased by 6.4K. % dimerisation of acetic acid is :
1 eksy CH3COOH dks 250 g csathu esa feykrs gSA gkbMªkstu ca/k ds dkj.k ,flfVd vEy csathu esa f}ydhd`r gks
tkrk gSA csathu ds Kb dk eku 2 K kgmol–1 gSA DoFkukad esa 6.4K dh o`f) gksrh gSA ,flfVd vEy dk %
f}ydhdj.k (dimerisation) gS %
(1) 50 (2*) 40 (3) 30 (4) 20

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Sol. Tb = i Kb .m
1 1000
Given molality (eksyyrk) = = 4m, 6.4 = i  2  4 or i = 0.8
250
For dimerisation (f}ydhdj.k ds fy,)

i=1–
2
–
 0.8 – 1 =
2
or  = 0.4  40%

7. A solution containing 500 g of a protein per litre is isotonic with a solution containing 3.42 g of sucrose
per litre. The molecular mass of protein is :
,d foy;u tks izksVhu ds 500 g izfryhVj ;qDr gS] ;g ,d vU; lqØksl ds 3.42 g izfryhVj ;qDr foy;u ds lkFk
leijkljh gSA vr% izksVhu dk v.kqHkkj gS :
(1) 5 (2) 146 (3) 34200 (4*) 50000

8. How many moles of KMnO4 are needed to oxidise a mixture of 1 mole of each FeSO4 & FeC2O4 in
acidic medium {(EQT-NOR(P)-M)}
vEyh; ek/;e esa FeSO4 rFkk FeC2O4 izR;sd ds 1 eksy ds feJ.k dks vkWDlhd`r djus ds fy, KMnO4 ds fdrus
eksy vko';d gaS \
4 5 3 5
(1*) (2) (3) (4)
5 4 4 3
Sol. Equivalents of KMnO4 = equivalent of FeSO4 + equivalent of FeC2O4
x×5=1×1+1×3
4
x = mole
5
Sol. KMnO4 ds rqY;kad = FeSO4 ds rqY;kad + FeC2O4 ds rqY;kad
x×5=1×1+1×3
4
x = eksy
5

9. When KMnO4 acts as an oxidising agent and ultimately forms Mn O24 , MnO2, Mn2O3 and Mn2+, then the
number of electrons transferred in each case is :
tc KMnO4 ,d vkWDlhdkjd dh rjg dk;Z djrk gS rFkk vkf[kj esa Mn O24 , MnO2, Mn2O3 rFkk Mn2+ cukrk gS]
rks izR;sd fLFkfr esa LFkkukUrfjr fd, x, bySDVªkWuksa dh la[;k fuEu gS %
(1) 4, 3, 1, 5 (2) 1, 5, 3, 7 (3*) 1, 3, 4, 5 (4) 3, 5, 7, 1
Sol.

10. The ratio of coefficients of MnO4– and I– after balancing the reaction -
vfHkfØ;k dks larqfyr djus ds i'pkr~ MnO4– o I– ds xq.kkadksa dk vuqikr fuEu gS&
MnO4– + I– + H+  Mn2+ + I2 + H2O, will be
(1*) 1 : 5 (2) 2 : 5 (3) 1 : 20 (4) None of these (buesa ls dksbZ ugha)
Sol. 5e–+ 8H+ + MnO4–  Mn2+ + 4H2O × (2)
2I–  I2 + 2e– × (5)
__________________________________________
16H+ + 2MnO4– + 10 I–  2Mn2+ + 8H2O + 5I2
__________________________________________
Ratio of coefficients of MnO4– and I– = 2/10 = 1/5
MnO4– o I– ds fy, xq.kkadks dk vuqikr

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11. A 0.200 gm sample containing copper () was analysed iodometrically, copper () is reduced to copper
() by iodine. 2Cu2+ + 4–  2 Cu + 2
If 20.0mL of 0.10 M Na2S2O3 is required for titration of the liberated iodine then the percentage of
copper in the sample will be (Cu = 63.5 g/mole)
dkWij () ;qDr 0.200 g uewusa dk vk;ksMksfefr :i ls v/;;u fd;k x;kA dkWij () vk;ksfMu }kjk dkWij () esa
vipf;r gksrh gS 2Cu2+ + 4–  2 Cu + 2
;fn 0.10 M Na2S2O3 ds 20 ml, eqDr vk;ksMhu ds vuqekiu ds fy, vko';d gSa rks uewusa esa dkWij dk izfr'kr
gksxkA (Cu = 63.5 g/mole)
(1) 31.75 % (2*) 63.5 % (3) 53 % (4) 37 %
Sol. 2 moles of Cu2+ = 1 mole of 2
= 2 moles of hypo.
so moles of hypo used = 20 × 10–3 × 0.1 = 2 m moles = moles of copper hence
2  10 3  63.5
% of copper = × 100% = 63.5%
0.2
Sol. Cu2+ ds 2 eksy = 2 dk 1 eksy
= gkbiks ds 2 eksy
blfy;s iz;qDr gkbiks ds eksy = 20 × 10–3 × 0.1 = 2 feyh- eksy = dkWij ds eksy
3
2  10  63.5
dkWij dk izfr'kr = × 100% = 63.5%
0.2

12. In a balanced redox reaction.

,d larqfyr mikip; vfHkfØ;k esa]
a Cl2 + b OH–  c Cl– + d ClO3– + e H2O
a b c d e a b c d e
(1) 3 6 1 5 3 (2) 3 12 2 5 3
(3) 1 6 1 5 3 (4*) none of these buesa ls dksbZ ugha

13. The correct sequence of the ionic radius of the following is :

fuEu esa ls fdlesa] Lih'kht dh vk;fud f=kT;kvksa dk vuqØe lgh gS %
 (1) Br– > Cl– > S2– > O2– > F–  (2*) Br– > S2– > Cl– > O2– > F–
 – 2– –
(3) Br > S > Cl > F > O – 2–  (4) S2– > Br– > Cl– > O2– > F–
Sol. The correct ionic radius is : Br > S > Cl > O2– > F–
– 2– –
–
Br has maximum number of shells. So, it is the largest.
Then, S2– > Cl– and O2– > F– , because for isoelectronic species, as Z increases, ionic radii decreases.
Sol. vk;fud f=kT;kvksa dk lgh Øe gS % Br– > S2– > Cl– > O2– > F–
Br–,dks'kksa dh vf/kdre la[;k j[krk gSA blfy,] ;g lcls cMk gksrk gSA
rc, S2– > Cl– o O2– > F– , D;ksafd lebySDVªkWfud Lih'kht ds fy,, tSls gh Z esa o`fð gksrh gS, oSls gh vk;fud f=kT;k
esa deh vkrh gSA

14. Which of the following statements is correct :

(1) E of elements generally decreases on moving left to right along the period.
(2) E of Boron is less than that of Aluminium.
(3) E of group 15 elements is less than that of group 16 elements belonging to the same period.
(4*) IE of Gallium is slightly greater than that of Aluminium.
fuEu esa ls dkSulk dFku lR; gS %
(1) vkorZ esa cka;h ls nka;h vksj c<+us ij lkekU;r% rRo dh E ?kVrh gSA
(2) cksjksu dh E, ,Y;qfefu;e ls de gksrh gSA
(3) leku vkorZ ls lEcfU/kr oxZ 15 ds rRoksa dh E,oxZ 16 ds rRoksa dh E ls de gksrh gSA
(4*) xSfy;e dh IE, ,Y;qfefu;e ls FkksMh (vkaf'kd) lh T;knk gksrh gSA
Sol. (1) Generally I.E. increases along the period.
(2) I.E. decreases on moving down the group.

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 (3) I.E. of group 16 elements < I.E. of group 15 elements (due to half filled configuration of group 15
elements)
e.g. O < N
(4) Due to poor shielding of nuclear charge by 3d e–.
gy. (1) lk/kkj.kr% vkorZ esa ck,¡ ls nk,¡ tkus ij I.E. c<+rh gSA
(2) oxZ esa uhps dh vksj tkus ij I.E. ?kVrh gSA
(3) oxZ 16 ds rRoksa dh I.E. < oxZ 15 ds rRoksa dh I.E. ( oxZ 15 ds rRoksa ds vðZHkjs foU;kl ds dkj.k)
mnkgj.k O < N
(4) 3d e }kjk ukfHkdh; vkos'k ds nqcZy ifjj{k.k ds dkj.k
–

15. Pick out the correct statement ?

(1) Electron affinity is affected by stable electronic configuration but ionisation potential is not affected
by stable configuration.
(2) Cs2O and K2O are basic oxides, their solution in water are acidic in nature.
(3) The formation of O2–(g) from O–(g) is an exothermic process.
(4*) The element like F, Cl, O etc. having high values of electron affinity they act as strong oxidising
agent.
fuEu esa ls dkSulk dFku lgh gS \
(1) bysDVªkWu ca/kqrk LFkk;h bysDVªkWfud vfHkfoU;kl ij fuHkZj djrh gS ysfdu vk;uu foHko LFkk;h bysDVªkWfud
vfHkfoU;kl ij fuHkZj ugha gksrk gSA
(2) Cs2O rFkk K2O ,d {kkjh; vkWDlkbM gS] buds tyh; foy;u vEyh; izd`fr ds gksrs gSA
(3) O–(g) ls O2–(g) dk fuekZ.k ,d Å"ek{ksih izØe gSA
(4*) F, Cl, O rRoksa dh bysDVªkWu cU/kqrk dk eku mPp gksus ds dkj.k ;g izcy vkWDLkhdkjd vfHkdeZd dh rjg dk;Z
djrs gSA

16. Calcualte the energy required to convert all the atoms of magnesium to magnesium ions present in 24
mg of magnesium vapours? First and second ionization enthalpies of Mg are 737.76 and 1450.73 kJ
mol–1 respectively.
(1*) 2.188 kJ (2) 21.88 kJ (3) 218.8 kJ (4) 281.8 kJ
24 mg eSaXuhf'k;e ok"i esa mifLFkr lHkh eSaXuhf'k;e ijek.kqvksa dks eSaXuhf'k;e vk;u esa ifjofrZr djus ds fy,
fdruh ÅtkZ dh vko';drk gksxh \ ;fn Mg dh izFke ,oe~ f}rh; vk;uu ,sUFkSYih ds eku Øe'k% 737.76 rFkk
1450.73 kJ mol–1 gSA
(1*) 2.188 kJ (2) 21.88 kJ (3) 218.8 kJ (4) 281.8 kJ
Sol. According to the definition of sucessive ionization energies.
Mg(g) + IE1  Mg+ (g) ; IE1 = 737.76 kJ mole–1
Mg+(g) + IE2  Mg2+ (g) + e– (g) ; IE2 = 1450.73 kJ mole–1
 Total amount of energy needed to convert Mg (g) at atom into Mg2+ (g) ion = IE1 + IE2
= 737.76 + 1450.73 kJ mol–1
= 2188.49 kJ mol–1
24
24 mg of Mg =
g
1000
24
= 1000  24
mole
= 10–3 mole
 Amount of energy needed to ionize 10–3 mole of Mg vapours = 2188.49 × 10–3
= 2.188 kJ
gy % Øekxr vk;uu ÅtkZ dh ifjHkk"kk ds vk/kkj ij
Mg(g) + IE1  Mg+ (g) ; IE1 = 737.76 kJ eksy–1
Mg+(g) + IE2  Mg2+ (g) + e– (g) ; IE2 = 1450.73 kJ eksy–1
 Mg (g) esa mifLFkr Mg ijek.kqvksa dks Mg2+ (g) vk;u esa ifjofrZr djus ds fy, vko';d ÅtkZ = IE1 +
IE2
= 737.76 + 1450.73 kJ eksy–1
= 2188.49 kJ eksy–1

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 24
24 mg Mg = 1000
g

24
mole eksy
= 1000  24
= 10–3 eksy
 10–3 eksy Mg ok"i dks vk;fur djus ds fy, vko';d ÅtkZ dh ek=kk = 2188.49 × 10–3
= 2.188 kJ

17. Magnitude Electron gain enthalpy of first element in the following pairs is higher ?
fuEu esa ls fdl ;qXe ds izFke rRo dh bysDVªkWu xSu ,sUFkSYih vf/kd gS \
(1) F, Cl (2*) Se, O (3) O, F (4) S, Cl
Sol. Negative electron gain enthalpy of F is less than Cl. This is due to the fact that when an electron is
added to F, the added electron goes to the smaller n = 2 energy level and experiences significant
repulsion from the other electrons present in this level. In Cl, the electron goes to the larger n = 3
energy level and consequently occupies a larger region of space leading to much less electron-electron
repulsion.
Sol. F dh _.kkRed bysDVªkWu xSu ,sUFkSYih dk eku Cl ls de gksrk gSaA bldk dkj.k ;g gSa fd tc bysDVªkWu F esa tqM+rk
gSa] rks tqM+us okyk bysDVªkWu vis{kkd`r NksVs n = 2 ÅtkZ Lrj esa izos'k djrk gSa rFkk bl ÅtkZ Lrj esa mifLFkr vU;
bysDVªkWuksa ls lkFkZd izfrd"kZ.k vuqHko djrk gSaA fdUrq Cl dh ifjfLFkfr esa] bysDVªkWu vis{kkd`r cM+s n = 3 ÅtkZ Lrj esa
izos'k djrk gSa ftlds ifj.kkeLo:i vf/kd cM+k vodk'k {ks=k gksus ds dkj.k bysDVªkWu&bysDVªkWu izfrd"kZ.k de yxrk
gSA

18. Molecular shapes of SO42–, CF4 and XeO4 are respectively :

(1*) the same with 0, 0 and 0 lone pair of electrons respectively.
(2) the same with 1, 1 and 1 lone pair of electrons respectively.
(3) different with 0, 1 and 2 lone pair of electrons respectively.
(4) different with 1, 0 and 2 lone pair of electrons respectively.
SO42– , CF4 rFkk XeO4 dh vkf.od vkÑfr Øe'k% gksxh %
(1*) 0, 0 rFkk 0 ,dkadh bysDVªkWu ;qXe ds lkFk leku (2) 1, 1 rFkk 1 ,dkadh bysDVªkWu ;qXe ds lkFk leku
(3) 0, 1 rFkk 2 ,dkadh bysDVªkWu ;qXe ds lkFk fHkUu (4) 1, 0 rFkk 2 ,dkadh bysDVªkWu ;qXe ds lkFk fHkUu

19. In which of the following species, d-orbital having xz and yz nodal planes involved in hybridisation of
central atom :
fuEUk esa ls fdl Lih'khT+k esa] dsfUnz; ijek.kq ds ladj.k esa] xz o yz uksMy ryksa okyk d-d{kd Hkkx ysrk gS %
(1) IO2F2– (2) ClF4– (3*) IF7 (4) XeF2
Sol. The d-orbitals having nodal plane in xz and yz planes is dxz and dyz orbitals.
Hybridisation of IF7 is sp3d3.
xz o yz ryksa esa uksMy ry okys d-d{kd Øe'k% dxz o dyz gSA
(IF7 dk ladj.k sp3d3 gSA)

20. The hybridisation and shape of BrF3 molecule are:

(1*) sp3d and T shaped (2) sp2d2 and tetragonal
3
(3) sp d and bent (4) none of these
BrF3 v.kq dk ladj.k rFkk vkd`fr gS :
(1*) sp3d rFkk T vkdkj (2) sp2d2 rFkk prq"Qydh;
(3) sp d rFkk csUV
3 (4) buesa ls dksbZ ugha

21. Select the correct order(s).

(1) PH3 < AsH3 < NH3 < SbH3 : bond angle (2) F2O > H2O > Cl2O : bond angle
(3*) O2 < O3 < O22– : O – O bond length (4) BF3 > BCl3 > BBr3 : bond angle
lgh Øe vFkok Øeksa dk p;u dhft;s %
(1) PH3 < AsH3 < NH3 < SbH3 : ca/k dks.k (2) F2O > H2O > Cl2O : ca/k dks.k
(3*) O2 < O3 < O22– : O – O ca/k yEckbZ (4) BF3 > BCl3 > BBr3 : ca/k dks.k

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Sol. (1) NH3 (106.6º) > PH3 (93.8º) > AsH3 (91.83º) > SbH3 (91.3º) – bond angle
(2) Cl2O (110.9º) > H2O (104.5°) > F2O (103.3º)

(3)

(4) All are trigonal planar (bond angle 120º).

gy (1) NH3 (106.6º) > PH3 (93.8º) > AsH3 (91.83º) > SbH3 (91.3º) – ca/k dks.k
(2) Cl2O (110.9º) > H2O (104.5°) > F2O (103.3º)

(3)

(4) lHkh lery f=kdks.kh; gS (ca/k dks.k 120º).

22. The bond length O–O in dioxygen (i.e. O2) molecule is 120 pm. What would be the expected O–O bond
length in O2[AsF4] ?
MkbZ vkWDlhtu v.kq (vFkkZr~ O2) esa O–O cU/k yEckbZ 120 pm gSA O2[AsF4] esa vuqekfur O–O cU/k yEckbZ D;k
gksxh\
(1) 120 pm (2*) 112 pm (3) 128 pm (4) 149 pm
Sol. O2[As(III)F4] exists as O2+[AsF4]–
10 – 5
O2+ bond order = = 2.5
2
10 – 6
O2 bond order = = 2.0
2
1
Bond length  bond order
As bond order in O2+ is 2.5 which is greater than bond order of O 2 (i.e. 2.0) and so the bond length (O–
O) will be shorter than 120 pm.
Sol. O2[As(III)F4], O2+[AsF4]– ds :i esa vfLrRo j[krk gSA
10 – 5
O2+ dk cU/kØe = = 2.5
2
10 – 6
O2 dk cU/kØe = = 2.0
2
1
cU/k yEckbZ 
cU/kØe
pwafd O2+ dk cU/k Øe 2.5 gS tks fd O2 ds cU/k Øe (vFkkZr 2.0) ls vf/kd gSA vr% bldh (O–O) cU/k yEckbZ 120
pm dh rqyuk esa de gksxhA

23. Which of the following species is most ionic.

fuEu esa ls dkSulh Lih'kht vf/kd vk;fud gS \
(1) SnCl4 (2) CCl4 (3*) SnCl2 (4) SnI2
Sol. SnCl2 is more ionic than others.
SnCl2 vU; ls vf/kd vk;fud gSA

24. Which of the following is correct increasing order of dipole moment?

fuEu f}/kzqo vk?kw.kZ ds vkjksgh Øeksa esa ls dkSulk Øe lgh gS \
(1) CO2 < SO2 < SO3 (2) PCl5 > PCl2F3 > PCl3F2
(3) CHCl3 < CH2Cl2 < CH3– Cl < CH4 (4*) CH3I < CH3Br < CH3F < CH3Cl

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Sol. CO2 = SO3 < SO2
XeF2 = XeF4 > XeF6
CH4 < CHCl3 < CH2Cl2 < CH3Cl
PCl3F2 = PCl5 < PCl2F3

25. Which among the following shows strongest H-bonding?

fuEu esa ls dkSu izcyre~ H-cU/ku j[krk gS\

(1*) (2)

(3) (4)
Sol. Electron negative O with positive charge becomes much more electro negative.
/kukos'k ds lkFk vf/kd _.krk okyk O vkSj vf/kd fo|qr_.kh gks tkrk gSA
SECTION B (Maximum Marks: 20)
 This Section contains Seven (07) questions.
 Candidates are advised to do the calculations with the constants given (if any) in the questions. The
answer should be rounded off to the nearest Integer.
 For each question, enter the correct integer value of the answer using the mouse and the on-screen
virtual numeric keypad in the place designated to enter the answer.
 The answer to each question will be evaluated according to the following Marking Scheme:
 Full Marks : +4 If ONLY the correct option is chosen.
 Zero Marks : 0 If none of the values are entered (i.e. the question is unanswered).
 Negative Marks : –1 In all other cases.

26.

In the arrangement shown above, initially, 10 moles of N2 and 5 moles of Helium were present above
water. Further 10 moles of N2 are added and total pressure above the mixture becomes 50 atm. If 8 ×
10–3 moles of N2 are dissolved at this pressure, and Henry's constant (in atm) of N 2 is 1 × 10y then y is.
[T]

mijksDr n'kkZ;h x;h O;oLFkk es]a ty ds Åij 10 eksy N2 o 5 eksy ghfy;e mifLFkr FkhA vkxs 10 eksy N2 feyk;s
tkrs gSa rFkk feJ.k ds Åij dqy nkc 50 atm gks tkrk gSA ;fn bl nkc ij 8 × 10–3 eksy N2 ?kksys tkrs gSa rFkk
N2 dk gsujh fu;rkad (atm esa) 1 × 10y gS] rks y gSA
Ans. 5
20 4
Sol. XN2 (gas) = =
25 5
4
PN2 = 50  = 40 atm
5
8  10 3
40 = K H 
20
40  20
KH = = 105 atm.
8  10 3
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27. Relative decrease in vapour pressure of an aqueous solution containing 2 moles [Cu(NH 3)3 Cl] Cl in 3
moles H2O is 0.50. On reaction with AgNO3, this solution will form how many mole of AgCl (assuming
no change in degree of ionisation of substance on adding AgNO3)
,d tyh; foy;u esa 3 eksy H2O esa 2 eksy [Cu(NH3)3 Cl] Cl fo|eku gSA bl foy;u ds ok"inkc esa vkisf{kd deh
0.50 gSA AgNO3 ds lkFk foy;u dh vfHkfØ;k djus ij ;g fuEu esa ls D;k cuk;sxh (AgNO3 feykus ij inkFkZ ds
vk;uhdj.k dh ek=kk esa ifjorZu ugha ekusaA) %
Ans. 1
P ni
Sol. =
P ni  N
2i
0.5 =
2i  3
i + 1.5 = 2 i
i = 1.5
i = 1 + (y – 1) 
1.5 = 1 + (2 – 1) 
 = 0.5
mole of Cl– (Cl– vk;u ds eksy) = 1.0 mol AgCl
mole of AgCl ppt. (AgCl vo{ksi ds eksy) = 1.0 mol AgCl

28. How many of following atoms have higher atomic radius than nitrogen :
fuEu esa ls fdrus ijek.kqvksa dh ijekf.od f=kT;k ukbVªkstu ls vf/kd gS %&
O, Rb, P, C, F, B, Na, K, Cs & o Ba
Ans. 8
Sol. Rb, P, C, B, Na, K, Cs & o Ba

29. In how many of the following :

Cases, H is positive ?
fuEu esa ls fdruh ifjfLFkfr;ksa esa H /kukRed gS \
(a) N(g) N+(g) + e– H1
(b) Ne(g) + e– Ne– (g) H2
(c) NaCl (s)  Na+ (g) + Cl– (g) H3
(d) O–(g) + e– O2–(g) H4
(e) O–(g) O(g) + e– H5
Ans. 5

30. BaO, ZnO, SnO2, CO, N2O4, Sb2O3, NO, Cr2O3, N2O – Total number of neutral oxides is
BaO, ZnO, SnO2, CO, N2O4, Sb2O3, NO, Cr2O3, N2O – mHk;/kehZ vkWDlkbMksa dh dqy la[;k = X
Ans. 3
Sol. Total number of neutral oxides = 3 (CO, NO, N2O).
mHk;/kehZ vkWDlkbMksa dh dqy la[;k = 3 (CO, NO, N2O).

31. Find the sum of total number of p-p bonds in one molecule each of CO2, H2SO4, P4O10 and SO3.
CO2, H2SO4, P4O10 rFkk SO3 izR;sd ds ,d v.kq esa p-p cU/kksa dh dqy la[;k dk ;ksx Kkr dhft;sA
Ans. 3
Sol. CO2 (two p-p bonds), H2SO4 (No p-p bonds), P4O10 (No p-p bonds) and SO3 (One p-p bond).
Sum = 2 + 1 = 3
CO2 (nks p-p cU/k), H2SO4 (dksbZ p-p cU/k ugha), P4O10 (dksbZ p-p cU/k ugha) o SO3 (,d p-p cU/k).
;ksx = 2 + 1 = 3

32. How many of the following are both isoelectronic and isostructural?
NO2 , SO3, PO3–, NH3, XeO3
fuEu es ls fdruh Lih'kht lebySDVªkWfud o lelajpukRed] nksuksa gSa \
NO2 , SO3, PO3–, NH3, XeO3
Ans. 2
Sol. SO3 and o PO3–
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