Ee LUCKNOW RANI LAXMI BAI MEMORIAL SCHOOL SARVODAYA NAGAR @Name = Shivansh Sonkar oCclass —XIll 8 oSubject = Chemistry oBoard Roll no.STERILIZATION OF WATER USING BLEACHING POWDER A CHEMISTRY INVESTIGATORY PROJECT THIS PROJECT LOOKS AT THE TECHNIQUE CALLED STERILIZATION OF WATER USING BLEACHING POWDER, WHICH IS USED TO PURIFY WATER AND MAKE IT FIT FOR DRINKING. Signature(Subject Teacher) Signature(Examiner)CERTIFICATE This is to certify that Shivansh a student of class XII has successfully completed the research project on the topic “Sterilization of Water by using Bleaching Powder” under the guidance of Mrs.Uma Sharma (Subject Teacher). This project is absolutely genuine and does not indulge in plagiarism of any kind. The references taken in making this project have been declared at the end of this report. Internal Examiner Signature- External Examiner Signature-ACKNOWLEDGEMENT I would like to express my special thanks of gratitude to my subject teacher Mrs. Uma Sharma ma’am to give her guidance to make this project successful. I extend my hearty thanks to our principal ma’am Mrs.Ranjana Singh Ma‘am for her encouragement and for all the facilities that she provided for this project work. Secondly I would like to thanks my parents and classmates who helped to complete this project with in the given timeTABLE OF CONTENT 1. Certificate 2. Acknowledgement 3. Introduction " Need of Water * Purification of Water = Need for a stable purification technique 4. Theory * History of Water purification = Bleaching powder and its preparation * Bleaching powder in Sterilization of water 5. Experiment =» Aim = Pre-Requisite Knowledge = Requirements = Procedure " Observation * Calculations 6. Result 7. Day to Day Usage 8. BibliographyINTRODUCTION Need of water Water is an important and essential ingredient in our quest for survival on this planet. It is very essential for carrying out various metabolic processes in our body and also to carry out Hemoglobin throughout the body. A daily average of 1 gallon per man is sufficient for drinking and cooking purposes. With the increasing world population, the demand for drinking water has also increased dramatically and therefore it is very essential to identify resources of water from which we can use water for drinking purposes. Since many available resources of water do not have it in drinkable form, inorder to fulfill the demand of water, it needs to be purified and supplied in an orderly and systematic way. Purification of Water There are many methods for the purification of water, such as: 1. Boiling 2. Filtration 3. Bleaching powder treatment 4. SODIS (Solar Water Disinfection) Need for a stable purification technique Therefore we need a purification technique which can be used anytime and anywhere, does not require the use of any third party content and which is also economically feasible on both normal scale and large scale. Hence we look at the method of purification of water using the technique of treatment by bleaching powder commonly known as “Chlorination”.THEORY In 1854 it was discovered that a cholera epidemic spread through water. The outbreak seemed less severe in areas where sand filters were installed. British scientist John Snow found that the direct cause of the outbreak was water pump contamination by sewage water. He applied chlorine to purify the water, and this paved the way for water disinfection. This discovery led to governments starting to install municipal water filters (sand filters and chlorination). So in the 1890s America started building large sand filters to protect public health. These turned out to be a success. Instead of slow sand filtration, rapid sand filtration was now applied. Subsequently, Dr. Fuller found that rapid sand filtration worked much better when it was preceded by coagulation and sedimentation techniques. But the victory obtained by the invention of chlorination did not last long. After some time the negative effects of this element were discovered. Chlorine vaporizes much faster than water, and it was linked to the aggravation and cause of respiratory disease. Water experts started looking for alternative water disinfectants. In 1902 calcium hypo chlorite and ferric chloride were mixed in a drinking water supply in Belgium, resulting in both coagulation and disinfection. To this day, bleaching powder remains the most commonly used drinking water disinfectant. Almost all systems use some type of chlorine-based process to disinfect water. Inaddition to controlling disease-causing organisms, chlorination offers a number of benefits including: * Reduces many disagreeable tastes and odors * Eliminates slime bacteria, molds and algae that commonly grow in water supply reservoir * Removes chemical compounds that have unpleasant tastes and hinder disinfection * Helps remove iron and manganese from raw water. For more than a century, the safety of drinking water supplies has been greatly improved by the addition of bleaching powder. However, bleaching powder also reacts with the organic matter, naturally present in water, such as decaying leaves thus forming a group of chemicals known as disinfection by-products. When used with modern water filtration methods, chlorine is effective against virtually all microorganisms. Bleaching powder is easy to apply and small amounts of the chemical remain in the water as it travels in the distribution system from the treatment plant to the consumer's tap, thus ensuring prevention of recontamination of water. But what is bleaching powder and how is it prepared? Bleaching powder or Calcium hypochlorite is a chemical compound with formula Ca(ClO)>. This chemical is considered to be relatively stable and has greater available chlorine thansodium hypochlorite (liquid bleach). It is prepared by either calcium process or sodium process. Calcium Process 2Ca(OH)2 + 2 Cl, SY Ca(ClO), + CaCl, + 2 HO Sodium Process 2Ca(OH)2 + 3Cl2 + 2NaOH Bae, Ca(ClO)2 + CaClz + 2H20 + 2NaCl What are the actual processes involved in disinfecting and purifying water? The combination of following processes is used for municipal drinking water treatment worldwide: 1. Pre-chlorination - for algae or any biological growth control 2. Aeration - removal of dissolved iron and manganese 3. Coagulation - for flocculation 4. Coagulant aids also known as polyelectrolyte’s - to improve coagulation and for thicker floc formation 5. Sedimentation - for solids separation i.e. removal of suspended solids trapped in the floc 6. Filtration - for removal of carried over floc 7. Disinfection - for killing bacteria Out of these processes, the role of Bleaching powder is only in the last step i.e. for Disinfection of water.EXPERIMENT Aim: To determine the dosage of bleaching powder required for sterilization or disinfection of different samples of water. Requirements: Burette, titration flask, 100ml graduated cylinder, 250ml measuring flask, weight box, glazed tile, glass wool. Bleaching Powder, Glass wool, 0.1 N Na2S203 solution, 10% KI solution, different samples of water, starch solution. Pre-Requisite Knowledge: 1. Bleaching powder when dissolved in contains dissolved chlorine, liberated by the action of bleaching powder with water. Ca(OCl)2+H20 — Ca(OH)+Cl, 2. The amount of Chlorine present is determined by treating a known volume with excess of 10% KI solution, when equivalent amount of Iz is liberated. The Iz, thus liberated is then estimated by titrating it against a standard solution of Sodium thiosulphate, using starch solution as Cl+2K1 ND? 2KCI+1, 2Na2$203l2+ Sess Na2S40s+2NalProcedure: ee °2°o 1. Preparation of bleaching Oe powder solution Weigh accurately 2.5g bleaching powder and transfer it to a 250ml conical flask. Add about 100ml of distilled water. Stopper the flask and shake it vigorously. The suspension thus obtained is filtered through glass wool and the filtrate is diluted with water to make the volume 250ml. The solution obtained is 1% bleaching powder solution. 2. Take 20ml of bleaching powder solution in a stoppered conical flask and add it to 20ml of 10% KI solution. Stopper the flask and shake it vigorously. Titrate this solution against 0.1N Na2S203 solution taken in the burette. When the solution in the conical flask becomes light yellow in color, add about 2m! starch solution. The solution now becomes blue in color. Continue titrating till the blue color just disappears. Repeat the titration to get a set of three concordant readings.Observation: + Volume of bleaching powder sol. taken 20ml « Volume of KI solution added 20ml « Volume of different samples of water 100ml Titration Table for Distilled Water Sr.No.|| Initial Final Final Vol. of 0.2N |) Mean Vol. (ml) Reading] Reading || NazSaO¢ sol. Used (ml) 2.0 |to.1 ig. 10.1 18.4 o: 8.2 18.4 26.6 Ee Titration Table for Tank Water Sr.No.|| Initial Final Final Vol. of 0.2N || Mean Vol. (ml) Reading] Reading | NazS4O¢ sol. used (ml) 15.1 25.2 10.1 2. jes.2 — [35.2 10.0 | 10. 3. 35.2 45.4 10.2 Titration Table for Pond WaterFinal Vol. of 0.2N || Mean Vol. (ml) NazS.O¢ sol. used (ml) Sr.No.|| Initial Final Reading] Reading 7.2 # 42-1 16.9 8 4.8 3. 16.9 21.9 he ye Calculations: TANK WATER (Sample 1) Amount of bleaching powder used to disinfect 100ml of tap water = (8.2 — 10.1) ml of 0.2 N of Na2S,0¢ solution = 1.9ml. Of 0.2 N of Na2S40¢ solution Since, 250ml bleaching powder solution contains 2.5g bleaching powder Thus, 1ml of bleaching powder solution contains bleaching powder =2.5/250 = 0.01g Also, 20ml of bleaching powder solution = 8.2ml of 0.2N of Na2S.03 So 1ml of Na2S203 solution = 20/8.2 ml of bleaching powder solution.Volume of bleaching powder solution used to disinfect 100ml of water = 1.9x20/8.2ml. 1.9 x 20/8.2 ml. of bleaching powder solution =1.9x20x0.01/8.2 (gm) Bleaching Powder Amount of bleaching powder used to disinfect 1 Itr. of water = 1.9x20x0.01x1000/8.2x100 = 0.4634gm POND WATER (Sample I!) Amount of bleaching powder used to disinfect 100m! of water. = (8.2 — 4.8) ml of 0.2 N Na2$203 solution =3.4ml Accordingly, Volume of Ca(OCl)2 solution required to disinfect 1It. of water = 3.4x20x0.01x1000/8.2x100 = 0.8293 gm.RESULT Amount of the given samples of bleaching powder required to disinfect one liter of water:- Samples | = 0.4634gm Samples II = 0.8293 gm Since amount of bleaching powder required for disinfecting POND WATER is more than that required for TANK WATER, thus it can be concluded that former contains more impurities.Day to Day Usage While household bleaching solutions are widely available but it is not recommended to use it for household water treatment. If bleach is used for household water treatment system, concentration should be regularly checked and proper dosage strategy should be developed recommended by authorized organizations. Bleaching Powder water treatment is useful in disinfecting water in places or conditions where boiling method cannot be practiced.