CLASS XI CHEMISTRY WORKSHEET

REDOX REACTIONS
1.Which of the following halogens do not exhibit a positive oxidation number in their
compounds?
(a) F (b) Br (c) I (d) Cl
2.Which of the following is most powerful oxidizing agent in the following.
(a) O3 (b) KMnO4 (c) H2O2 (d) K2Cr2O7
3.In the reaction
2Ag + 2H2SO4 ———-> Ag2 SO4 + 2H2O + SO2
sulphuric acid acts as
(a) an oxidizing agent (b) a reducing agent
(c) a catalyst (d) an acid as well as an oxidant
4.The oxidation number of the carboxylic carbon atom in CH3COOH is
(a) + 2 (b) +4 (c) +1 (d) +3
5.When methane is burnt in oxygen to produce CO2 and H2O the oxidation number of carbon
changes by
(a) -8 (b) zero (c)+8 (d)+ 4
6.The oxidation number of carbon is zero in
(a) HCHO (b) CH2Cl2 (c)C12H22O21 (d) C6H12 O
7.What is the oxidation state of Ni in Ni (CO)4?
8.What is salt bridge?
9.Why is standard hydrogen electrode called reversible electrode?
10.What is a disproportionation reaction ? Give one example.
11.What is meant by cell potential?
12. a) Given the standard electrode potentials,
K+/K = -2.93 V,Ag+/Ag = 0.80 V, Hg2+/Hg = 0.79 V, Mg2+/Mg = -2.37 V,Cr3+/Cr = -0.74V
Arrange these metals in increasing order of their reducing power.

13.Give two important functions of salt bridge.

14.Balance the following equation by oxidation number method:
Fe2+ + Cr2O72- + H+ ———> Fe3+ + Cr3+ +H2O
15.Identify the substance oxidised, reduced, oxidising agent and reducing agent for each of the
following reactions.

16.Calculate the oxidation number of

(i) C in CH3COOH (ii) S in S2O8-2 iii)Cr in [Cr (H2O)6]3+ ion.
17. How can CuSO4 solution not be stored in an iron vessel?

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18.Balance the following redox reactions :
(a) MnO4–(aq) +I–(aq) ———>MnO2(s) + I2 (s) (in basic medium)
(b) MnO4–(aq) + C2O42- (g) ——-> Mn2+(aq) +CO2(in acidic solution)
(c) H2O2(aq) + Fe2+(aq) ———-> Fe3+(aq) + H2O(l) (in acidic solution)
(d) Cr2O72- (aq) + SO2 (g)——> Cr3+ (aq) + SO42-(aq) (in acidic solution)
19.Depict the galvanic cell in which the reaction,
Zn(s) + 2Ag+(aq) ————> Zn2+(aq) + 2Ag(s)
takes place. Further show:
(i) which of the electrode is negatively charged.
(ii) the carriers of current in the cell and
(iii) individual reaction at each electrode.
20.Consider the elements: Cs, Ne, I, F
(a) Identify the element that exhibits -ve oxidation state.
(b) Identify the element that exhibits +ve oxidation state.
(c) Identify the element that exhibits both +ve and -ve oxidation states.
(d) Identify the element which neither exhibits -ve nor +ve oxidation state.
EQUILIBRIUM
1.Find the value of Kc for each of the following equilibria from the value of K

2.For the following equilibrium, K =6.3 x 1014 at 1000 K.

NO(g)+O3 —–>NO2(g) + O2(g) Both the forward and reverse reactions in the equilibrium are
elementary bimolecular reactions. What is Kc for the reverse reaction?
3.A sample of HI (g) is placed in a flask at a pressure of 0.2 atm. At equilibrium partial pressure
of HI (g) is 0.04 atm. What is Kp for the given equilibrium?

4.The equilibrium constant expression for a gas reaction is,

5.Does the number of moles of reaction products increase, decrease or remain same when each
of the following equilibria is subjected to a decrease in pressure bp increasing the volume?

6.Hydrogen gas is obtained from the natural gas by partial oxidation with steam as per the
following endothermic reaction:

Write the expression for Kp for the above reaction

7.How will the value of Kp and composition of equilibrium mixture be affected by:
(i) increasing the pressure, (ii) increasing the temperature, (iii) using a catalyst?
8.What is the effect of:
(i) addition of H2 (ii) addition of CH3OH (iii) removal of CO (iv) removal of CH3OH

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9.What is meant by conjugate acid-base pair? Find the conjugate acid/base for the following
species: HNO2, Cl–, HClO4 , OH–, CO32-, S2-
10.Which of the following are Lewis Acids?
H2O,BF3, H+ and NH4+
11.What will be the conjugate bases for the Bronsted acids?
HF, H2SO4 and H2CO3?
12.What is meant by ionic product of water (kw)?
13.What are acidic and basic buffers?Give two characteristics of a buffer solution.
14.For the equilibrium :2 NOCl(g)——-> 2NO(g) + Cl2(g) ,the value of the equilibrium constant
Kc is 3.75 x 10-6 at 1069 K. Calculate the Kp for the reaction at this temperature?
15.The value of Kc for the reaction 2A——>B + C is 2 x 10-3. At a given time, the composition
of reaction mixture is [A] = [B] = [C] = 3 x 10-4 M. In which direction the reaction will proceed?
16.PCl5, PCl3 and Cl2 are at equilibrium at 500 K and having concentration 1.59M PCl 5 1.59M
Cl2 and 1.41M PCl5. Calculate Kc for the reaction PCl5———>PC13+ Cl2
17.(i) State Le Chatelier’s principle.
(ii) Following reactions occur in a Blast furnace.
Fe2O3(s) + 3CO(g) ———–>2Fe(s) + 3CO2(g)
Use Le chatelier’s principle to predict the direction of reaction when equilibrium mixture is
disturbed by
(a) adding Fe2O3 (b) removing CO2 (c) removing CO.
18.Define solubility product. How does common ion affect the solubility of electrolyte?
19.Write the conjugate acids for the following Bronsted bases:
NH2_, NH3 and HCOO–
20.Classify the following species into Lewis acids and Lewis bases and show how these can act
as Lewis acid/Lewis base?
(a) OH– ions (b) F– (c) H+ (d) BCl3
21.The species H2O, HCO3–, HSO4– and NH3 can act both as Bronsted acid and base. For each
case, give the corresponding conjugate acid and base.
22.The concentration of hydrogen ions in a sample of soft drink is 3.8 x 10-3 M. What is the pH
value?
23.The pH of a sample of vinegar is 3.76. Calculate the concentration of hydrogen ion in it.
24.The ionization constant of HF, HCOOH and HCN at 298 K are is 6.8 x 10 -4 ,1.8 x 10-4 and
4.8 x 10-9 respectively, Calculate the ionization constant of the corresponding conjugate base.
25.i)Assuming complete dissociation, calculate the pH of the following solutions:
(a) 0.003 M HCl (b) 0.005 M NaOH (c) 0.002 M HBr (d) 0.002 M KOH
ii)Calculate the pH of the following solutions:
(a) 2g of TlOH dissolved in water to give 2 litre of the solution
(b) 0.3 g of Ca(OH)2 dissolved in water to give 500 mL of the solution
(c) 0.3 g of NaOH dissolved in water to give 200 mL of the solution
(d) l ml of 13.6 M HCl is diluted with water to give 1 litre of the solution.

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THERMODYNAMICS
1.An isochoric process takes place at constant
(a) temperature (b) pressure (c) volume (d) concentration
2. For a cyclic process, the change in internal energy of the system is
(a) always +ve (b) equal to zero (c) always -ve (d) none of the above
3. Which of the following properties is not a function of state?
(a) concentration (b) internal energy (c) enthalpy (d) entropy
4. Which of the following relation is true?
5. Which of the following always has a negative value?
(a) heat of reaction (b) heat of solution (c) heat of combustion (d) heat of formation
6. The bond energy depends upon
(a) size of the atom (b) electronegativity (c) bond length (d) all of the above
7. For an endothermic reaction.
(a) ∆H is -ve (b) ∆H is +ve (c) ∆H is zero (d) none of these
8. The process depicted by the equation.
H2O (s) ——> H2O (l) ∆H = +1.43 kcal represents
(a) fusion (b) melting (c) evaporation (d) boiling
9.Which one is the correct unit for entropy?
(a) KJ mol (b)JK mol (c)JK mol-1 (d) KJ mol-1
10. A reaction, A + B—>C + D + q is found to have a positive entropy change. The reaction will
be-
(i) possible at high temperature (ii) possible only at low temperature
(iii) not possible at any temperature (iv) possible at any
11.The enthalpies of all elements in their standard states are : ‘
(i) unity (ii) zero (iii) < 0 (iv) different for each element
12. temperatureFor the process to occur under adiabatic conditions, the correct condition is:
(i) ∆T= 0 (ii) ∆p = 0 (iii) q = 0 (iv) w = 0
13.In a process, 701J of heat is absorbed by a system and 394 J of work is done by the system.
What is the change in internal energy for the process?
14.Given : N2(g) + 3H2(g) ————> 2NH3(g); ∆r H– = -92.4 KJ mol-1 .What is the
standard enthalpy of formation of NH3 gas?
15.For an isolated system ,∆U = 0; what will be ∆S?
16.For the reaction; 2Cl(g) ———-> Cl2(g); what will be the signs of ∆H and ∆S?
17.For a reaction at 298 K
2A + B————->C
∆H = 400 KJ mol-1and ∆S = 0.2 KJ K-1mol-1.
At what temperature will the reaction become spontaneous considering ∆H and ∆S to be
constant over the temperature range?
18.When is bond energy equal to bond dissociation energy ?
19. What do you mean by entropy? Predict the sign of ∆S for the following reaction heat
CaCO3 (s) ———> CaO(s) + CO2(g)
How is entropy of a substance related to temperature?
20.a)State Hess’s law.
b)Define extensive and intensive properties.Give examples.
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21.Give reason for the following:
(a)Neither q nor w is a state function but q + w is a state function.
(b)A real crystal has more entropy than an ideal crystal.
22.Predict in which of the following, entropy increases/decreases.
(i) A liquid crystallizes into a solid
(ii) Temperature of a crystallize solid is raised from OK to 115 K
(iii) 2NaHCO3 (s) ———-> Na2 CO3 (s) + CO2 (g) + H2O (g)
(iv) H2(g)——>2H(g)
23.Why standard entropy of an elementary substance is not zero whereas standard enthalpy of
formation is taken as zero?
24.Under what conditions will the reaction occur, if
(i) both ∆H and ∆S are positive
(ii) both ∆H and ∆S are negative
25.a)Explain Born Haber’s cycle with an example.
b)What are the applications of Hess’s law?
c)State the I,II and III laws of thermodynamics.
d)When is ∆G=0?
CHEMICAL BONDING
1. A co-ordinate bond is formed by:
(a)sharing of electrons contributed by both the atoms
(b)complete transfer of electrons
(c)sharing of electrons contributed by one atom only
(d) none of these
2.The species CO, CN–and N2 are:
(a) isoelectronic (b) having coordinated bond
(c)having polar bond (d) having low bond energies
3.The axial overlap between the two orbitals leads to the formation of a:
(a) sigma bond (b) pi bond (c) multiple bond (d) none of these
4.In SO2 molecule, S atom is:
(a)sp3 hybridized (b) sp hybridized (c) sp2 hybridized (d) d sp2 hybridized
5.A molecule or ion is stable if:
(a) Nb = Na (b) Nb < Na (c) Na < Nb (d) Na – Nb = + ve
6.The molecule Ne2 does not exist because
(a) Nb > Na (b) Nb = Na + (c) Nb < Na (d) None of these
7.Which one is diamagnetic among NO , NO and NO ?
+

(a)NO+ (b) NO (c) NO– (d) None of these

8.In sp , sp and sp hybridized carbon atom, the p character is maximum in:
3 2

(a) sp3 (b) sp2 (c) sp (d) all of the above have same p-character
9. Out of the following, intramolecular hydrogen bonding exists in:
(a) water (b)H2S (c) 4-nitrophenol (d) 2-nitrophenol
10.Discuss the shape of the following molecules using the VSEPR model:
BeCl2, BCl3 , SiCl4, AsF5, H2S, PH3
11.How do you express the bond strength in terms of bond order?
12.Explain the important aspects of resonance with reference to the CO32- ion.
13.Write the significance/applications of dipole moment.
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14.Define electronegativity. How does it differ from electron gain enthalpy?
15.Explain why BeH2 molecule has a zero dipole moment although the Be—H bonds are polar.
16.Define dipole moment.Which out of NH3 and NF3 has higher dipole moment and why?
17.Which hybrid orbitals are used by carbon atoms in the following molecules?
(a) CH3-CH3 (b) CH3-CH = CH2 (c) CH3-CH2-OH (d) CH3-CHO (e) CH3COOH.
18.a)Write the important conditions required for the linear combination of atomic orbitals to
form molecular orbitals.
b) Why N2 is more stable than O2? Explain on the basis of molecular orbital theory.
19.Compare the relative stability of the following species and indicate their magnetic properties:
i)O2, O2+ , O2– (Superoxide),O22- (peroxide)
ii) N2, N2+ , N2–
20.a)State the types of hybrid orbitals associated with (i) P in PCl 5 and (ii) S in SF6
b)Describe the hybridisation in case of PCl5 and SF6. Why are the axial bonds longer as
compared to equatorial bonds?
21.a)Define hydrogen bonds. Is it weaker or stronger than the van der Waals forces?
b)Out of sigma and Π bonds, which one is stronger and why?
c) Out of bonding and antibonding molecular orbitals, which one has lower energy and which
one has higher stability?
22.a)Predict the shapes of the following molecules using VSEPR theory?
(i) BeCl2(ii) SiCl4
b) Arrange the following, according to increasing covalent nature.
NaCl, MgCl2, AlCl3
23.What is the total number of sigma and pi bonds in the following molecules?
(a) C2 H2 (b) C2 H4
24.Name the two conditions which must be satisfied for hydrogen bonding to take place in a
molecule.
25. Account for the following:
(i) Water is a liquid while H2S is a gas
(ii) NH3 has higher boiling point than PH3.
STRUCTURE OF ATOM
1.Cathode rays are deflected by
(a) electric field only (b) electric and magnetic field
(c) magnetic field only (d) none of these
2.In a sodium atom(atomic number =11 and mass number =23) and the number of neutrons is
(a) equal to the number of protons (b) less than the number of protons
(c) greater than the number of protons (d) none of these
3.The Balmer series in the spectrum of hydrogen atom falls in
(a) ultraviolet region (b) visible region (c) infrared region (d) none of these
4.The idea of stationary orbits was first given by
(a) Rutherford (b) J.J. Thomson (c) Niels Bohr (d) Max Planck
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5. de Broglie equation is

6. The orbital with n = 3 and l = 2 is ,

(a) 3s (b) 3p (c) 3d (d) 3j
7.The outermost electronic configuration of manganese (at. no. = 25) is
(a) 3d5 4s2 (b) 3d6 4s1 (c) 3d74s° (d) 3d6 4s2
8. The energy needed to remove a single electron (most loosely bound) from an isolated –
gaseous atom is called
(a) ionisation energy (b) electronegativity (c) kinetic energy (d) electron affinity
9. The maximum number of electrons in a sub-shell is given by the equation
(a) n2 (b) 2n2 (c) 2l – 1 (d) 2l + 1
10. If the value of azimuthal quantum number is 2, what will be the values for magnetic quantum
number?
11.a)Which of the following are iso-electronic species ?
Na+, K+, Mg2+, Ca2+, S2-, Ar.
b)What is the relation between K.E,frequency, intensity and number of photoelectrons?
12.(i) Write the electronic configuration of the following ions : (a) H - (b) Na+ (c) O2-(d) F–.
(ii) What are the atomic numbers of the elements whose outermost electronic configurations are
represented by :
(a) 3s1 (b) 1p3 and (c) 3d6 ?
(iii) Which atoms are indicated by the following configurations ?
(a) [He]2s1 (b) [Ne] 3s2 3p3 (c) [Ar] 4s2 3d1.
13.What is the lowest value of n which allows ‘g’ orbital to exist ?
14.An electron is in one of the 3d orbitals. Give the possible values of n, l and nil for the
electron.
15.An atom of an element contains 29 electrons and 35 neutrons. Deduce (i) the number of
protons and (ii) the electronic configuration of the element.
16.Give the number of electrons in the species : H2+, H2 and O2+.
17.(i) An atomic orbital has n = 3. What are the possible values of l and m l ?
(ii) List the quantum numbers m l and l of electron in 3rd orbital.
(iii) Which of the following orbitals are possible ?
1p, 2s, 2p and 3f.
18.Using s, p and d notations, describe the orbitals with follow ing quantum numbers :
(a) n = 1, l = 0 (b) n = 4, l = 3 (c) n = 3, l = 1 (d) n = 4, l = 2
19.From the following sets of quantum numbers, state which are possible. Explain why the
others are not possible.
(i) n = 0, l = 0, ml = 0, ms = +1/2
(ii) n = 1, l = 0, ml = 0, ms = – 1/2
(iii) n = 1, l = 1, ml = 0, ms= +1/2
(iv) n = 1, l = 0, ml = +1, ms= +1/2
(v) n = 3, l = 3, ml = -3, ms = +1/2
(vi) n = 3, l = 1, ml = 0, ms= +1/2

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20.How many electrons in an atom may have the following quantum numbers?
(a) n = 4 ; ms = -1/2
(b) n = 3, l = 0.
21.Calculate the number of atoms present in :
(i) 52 moles of He
(ii) 52 u of He
(iii) 52 g of He.
22.Among the following pairs of orbitals, which orbital will experience more effective nuclear
charge (i) 2s and 3s (ii) 4d and 4f (iii) 3d and 3p ?
23.a)Indicate the number of unpaired electrons in :
(a) P (b) Si (c) Cr (d) Fe and (e) Kr.
b)Write the electronic configuration and number of unpaired electrons in Fe2+ion. Which
one Fe3+, Fe2+is more paramagnetic and why?
24.a)How many sub-shells are associated with n = 4 ?
b) How many electrons will be present in the sub-shells having ms value of -1/2 for n = 4 ?
25.a)Give the relation between wavelength and momentum of moving microscopic particle.
What is the relation known as?
b)What type of metals are used in photoelectric cells? Give one example.
c)State and explain the following:
(i) Aufbau’s principle
(ii) Pauli’s exclusion principle.
(iii) Hund’s rule of maximum multiplicity.
CLASSIFICATION OF ELEMENTS
1.The highest ionization energy is exhibited by
(a) halogens (b) alkaline earth metals (c) transition metals (d) noble gases
2.Which of the following oxides is neutral?
(a) SnO2 (b) CO (c) Al2O3 (d) Na2O
3.Which of the following is arranged in order of increasing radius?
(a) K+ (aq) < Na+ (aq) < Li+ (aq) (b) K+ (aq) > Na+ (aq) > Zn2+ (aq)
(c) K+ (aq) > Li+ (aq) > Na+ (aq) (d) Li+ (aq) < Na+ (aq) < K+ (aq)
4. What is the electronic configuration of the elements of group 14?
(a) ns2 np4 (b) ns2 np6 (c) ns2 np2 (d) ns2
5. Among the following elements, which has the least electron affinity?
(a) Phosphorous (b) Oxygen (c) Sulphur (d) Nitrogen
6. In halogens, which of the following, increases from iodine to fluorine?
(a) Bond length (b) Electronegativity
(c) The ionization energy of the element (d) Oxidizing power
7. Diagonal relationships are shown by
(a) Be and A1 (b) Mg and A1 (c) Li and Mg (d) B and P
8. Which of the following species are not known?
(a) AgOH (b) PbI4 (c) PI5 (d) SH6 (e) All of the above
9. Which one of the following is isoelectronic with Ne?
(a) N3- (b) Mg2+ (c) Al3+ (d)all of the above

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10.Which element has smallest size?
(a) B (b) N (c) Al (d) P
11.In the modem periodic table, the period indicates the value of
(a)atomic number (b) mass number
(c) principal quantum number (d) azimuthal quantum number?
12.Which of the following statements related to the modem periodic table is incorrect?
(a) The p-block has six columns, because a maximum of 6 electrons can occupy all the orbitals
in a p-subshell.
(b) The d-block has 8 columns, because a maximum of 8 electrons can occupy all the orbitals in
a d-subshell.
(c) Each block contains a number of columns equal to the number of electrons that can occupy
that subshell.
(d) The block indicates value of azimuthal quantum number (l)for the last subshell that received
electrons in building up the electronic configuration.
13.Anything that influences the valence electrons will affect the chemistry of the element. Which
one of the following factors does not affect the valence shell?
(a) Valence principal quantum number (n) (b) Nuclear charge (Z)
(c) Nuclear mass (d) Number of core electrons.
14.The size of isoelectronic species-F–, Ne and Na+ is affected by
(a) nuclear charge (Z) (b) valence principal quantum number (n)
(c) electron-electron interaction in the outer orbitals
(d) none of the factors because their size is the same
15.Which of the following statements is incorrect in relation to ionization enthalpy?
(a)ionization enthalpy increases for each successive electron.
(b)The greatest increase in ionization enthalpy is experienced on removal of electrons from core
noble gas configuration.
(c)End of valence electrons is marked by a big jump in ionization enthalpy.
(d)Removal of electron from orbitals bearing lower n value is easier than from orbital having
higher n value.
16.Considering the elements B, Al, Mg and K, the correct order of their metallic character is:(a)
B> Al> Mg > K (b) Al> Mg > B> K (c) Mg > Al> K> B (d) K> Mg > Al> B
17.Considering the elements B, C, N, F and Si, the correct order of their non-metallic character
is: (a) B>C>Si>N>F (b) Si>C>B>N>F (c) F>N>C>B>Si (d) F>N>C>Si>B
18.Considering the elements F, Cl, O and N, the correct order of their chemical reactivity in
terms of oxidising property is:
(a) F > Cl> O > N (b) F > O > Cl> N (c) Cl> F > O > N (d) O > F > N > Cl
19.The first ionisation enthalpy of magnesium is higher than that of sodium. On the other hand,
the second ionisation enthalpy of sodium is very much higher than that of magnesium. Explain.
20.Give reasons:
(i) IE1 of sodium is lower than that of magnesium whereas IE2 of sodium is higher than that of
magnesium.
(ii) Noble gases have positive value of electron gain enthalpy.
21.On the basis of quantum numbers, justify that the sixth period of the periodic table should
have 32 elements.
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22.In terms of period and group where will you locate the element with z = 114?
23.Write the atomic number of the element present in the third period and seventeenth group of
the periodic table.
24.Why do elements in the same group have similar physical and chemical properties?
25.How do atomic radius vary in a period and in a group? How do you explain the variation?
26.What do you understand by isoelectronic species? Name a species that tvill be iso electronic
with each of the following atoms or ions.
(i) F– (ii) Ar (iii) Mg2+ (iv) Rb+
27.Consider the following species:
N3-, O2-, F–, Na+, Mg2+, Al3+
(a) What is common in them? (b) Arrange them in order of increasing ionic radii?
28.Explain why cation are smaller and anions larger in radii than their parent atoms?
29.Among the second period elements, the actual ionization enthalpies are in the order:
Li < B < Be < C < O < N < F < Ne.
Explain why
(i) Be has higher ∆iH1than B ? (ii) O has lower ∆iH1 than N and F?
30.How would you explain the fact that the first ionization enthalpy of sodium is lower than that
of magnesium but its second ionization enthalpy is higher than that of magnesium?
31.The first ionization enthalpy values (in kJ mol -1) of group 13 elements are:
B Al Ga In Tl
801 577 579 558 589
How would you explain this deviation from the general trend?
32.Which of the following pairs of elements would have a move negative electron gain
enthalpy? (i) O or F (ii) F or Cl.
33. Would you expect the second electron gain enthalpy of O as positive, more negative or less
negative than the first? Justify your answer.
34.Would you expect the first ionization enthalpies of two isotopes of the same element to be the
same or different? Justify your answer.
35.The increasing order of reactivity among group 1 elements is Li < Na < K < Rb < Cs whereas
that of group 17 is F > Cl > Br > I. Explain?
36.Write the general electronic configuration of s,p, d and f-block elements?
37.Assign the position of the element having outer electronic configuration,
(i) ns2 np4 for n = 3 (ii) (n – 1) d2 ns2 for n = 4 and (iii) (n – 2) f7 (n – 1) d1 ns2 for n = 6
in the periodic table?
38.Why are electron gain enthalpies of Be and Mg positive?
b) Write the symbol and IUPAC name of an element with atomic number 118.
39.a)What are representative elements?
b)Show by a chemical reaction with water that Na 2O is a basic oxide and Cl2O7 is an acidic
oxide.

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40.a) How does atomic radius vary in group in the periodic table?
(b) Explain
(i) Radius of cation is less than that of the atom.
(ii) Radius of anion is more than that of the atom.
(iii) In iso-electronic ion, the ionic radii decreases with increase in atomic number.
SOME BASIC CONCEPTS OF CHEMISTRY
1.In three moles of ethane (C2H6), calculate the following:
(i) Number of moles of carbon atoms (ii) Number of moles of hydrogen atoms
(iii) Number of molecules of ethane
2.How many significant figures are present in the following?
(i) 0.0025 (ii) 208 (iii) 5005 (iv) 126,000 (v) 500.0 (vi) 2.0034
3.In the reaction, A + B2——> AB2, identify the limiting reagent, if any, in the
following mixtures
(i) 300 atoms of A + 200 molecules of B
(ii) 2 mol A + 3 mol B
(iii) 100 atoms of A + 100 molecules of B
(iv) 5 mol A + 2.5 mol B
(v) 2.5 mol A + 5 mol B
4.a)How are 0.50 mol Na2CO3 and 0.50 M Na2CO3 different?
b)If ten volumes of dihydrogen gas reacts with five volumes of dioxygen gas, how many
volumes of water vapour could be produced?
6.Which one of the following will have largest number of atoms?
(i) 1 g Au (s) (ii) 1 g Na (s) (iii) 1 g Li (s) (iv) 1 g of Cl2(g) (Atomic masses: Au = 197, Na = 23,
Li = 7, Cl = 35.5 amu)
6.How is empirical formula of a compound related to its molecular formula?
7. Define molality. How does molality depend on temperature?
8.What will be the molality of the solution containing 18.25 g of HCl gas in 500 g of water?
(a) 0.1 m (b) 1 M (c) 0.5 m (d) 1 m
9.The empirical formula and molecular mass of a compound are CH 20 and 180g respectively.
What will be the molecular formula of the compound?
(a) C9H18O9, (b) CH2O (c) C6H12O6 (d) C2 H4O2
10.Which of the following solutions have the same concentration?
(a) 20 g of NaOH in 200 mL of solution
(b) 0.5 mol of KC1 in 200 mL of solution
(c) 40 g of NaOH in 100 mL of solution
(d) 20 g of KOH in 200 mL of solution
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