Ejector-Powered Absorption Refrigeration Cycle
Ejector-Powered Absorption Refrigeration Cycle
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Ahmed Bellagi
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Article history: The objective of the present work is to investigate the feasibility and the eventual improvement in perfor-
Received 9 August 2018 mance of an ejector powered water/lithium bromide double-effect absorption/recompression refrigeration
Revised 24 November 2018
cycle driven by high temperature heat sources.
Accepted 26 November 2018
The results show that the cycle performance parameters are significantly affected by the presence of
Available online 20 December 2018
the ejector and its characteristics. Further, the COP responses to variation of working conditions are differ-
Keywords: ent from those observed for the conventional double-effect absorption refrigeration cycles. The maximum
Double-effect absorption/recompression COP values of the ejector cycle occur at HP-generator temperatures lower by 20 °C to 25 °C than those of
cycle the conventional double-effect absorption cycle. The enhancement factor of the COP varies between 1.34
Water/lithium bromide and 1.70 at a driving steam temperature ranging from 240 °C to 340 °C. As regards the ejector design,
Ejector the ratio of HP-generator pressure and driving steam pressure should be kept as low as possible. The
High temperature heat sources
geometry of the design should allow for the maximum entrainment ratio feasible.
© 2018 Elsevier Ltd and IIR. All rights reserved.
Mots-clés: Cycle à absorption/recompression double effet; Bromure de lithium/eau; Éjecteur; Sources de chaleur à haute température
https://doi.org/10.1016/j.ijrefrig.2018.11.042
0140-7007/© 2018 Elsevier Ltd and IIR. All rights reserved.
454 D. Sioud, M. Bourouis and A. Bellagi / International Journal of Refrigeration 99 (2019) 453–468
Their results showed that the new design was simpler than that of
Nomenclature the two-stage heat transformer and double absorption heat trans-
former (where a pump and an absorber/evaporator are added to
Symbols a single-stage heat transformer). The delivered useful temperature
A Surface area, [m2 ] was higher than in the case of a single-stage heat transformer, and
COP Coefficient of performance, [–] the COP improved (Shi et al., 2001). Vereda et al. (2012) evaluated
F Circulation ratio, [–] the feasibility of an adjustable nozzle area in an ejector absorption
h Specific enthalpy, [kJ.kg-1 ] refrigerator using ammonia/lithium nitrate. They reported that the
m ˙ Mass flowrate, [g.s-1 , kg.s-1 ] activation temperature was reduced by about 9 °C on integrating
M Mach number, [–] the ejector, and the COP increased at moderate temperatures, par-
M∗ Modified Mach number, [–] ticularly when the temperature of the driving hot water inlet gen-
P Pressure, [kPa, bar] erator was lower than 81–92 °C. Garousi Farshi et al. (2014) com-
Q˙ Heat exchange rate, [kW] pared the results obtained by Vereda et al. (2012) with those of
R Gas constant, [J.kg-1 .K-1 ] the ammonia/NaSCN ejector absorption cycles. They concluded that
T Temperature, [°C, K] both COP and exergy efficiency were higher than in single-effect
W ˙ Pump power, [kW] absorption refrigeration cycles especially at low generator temper-
x, X Lithium bromide mass fraction in solution, [–] atures.
An advanced configuration, reported in the literature for ejec-
Greek symbols
tor absorption refrigeration cycles, consists of coupling the ejec-
α Mass ratio of regenerated refrigerant in MP and HP-
tor with the solution generator via an external loop. This in-
generators, [–]
volved a steam generator and a steam ejector which compressed
γ Specific heat ratio, (Cv/Cp), [–]
the vapour desorbed from the water/lithium bromide solution in
ε COP enhancement factor, [–]
order to re-heat the solution in the desorber. Thus, Eames and
η Efficiency (Appendix), [–]
Wu (20 0 0) described the configuration of an ejector powered wa-
ϱ Density, [kg.m-3 ]
ter/lithium bromide single-effect absorption/recompression refrig-
τ Temperature ratio, [–]
eration cycle and theoretically investigated its energy efficiency
ω Entrainment ratio, [–]
and performance characteristics. Their results showed that the COP
Indices of the cycle increased with the temperature of the driving heat.
ABS Absorber Eames and Wu (20 0 0) and Wu and Eames (1998) also investigated
CD Condenser experimentally a 5 kW re-compression refrigerator prototype. The
c Ejector constant area section coefficient of performance (COP) of this prototype was 1.03 at the
EVAP Evaporator design operating conditions, which was 14% lower than that of the
GEN Generator estimated theoretical value. However, it was higher than that of
HP High pressure the single-effect absorption chiller and close to the typical value of
in Input the conventional double-effect absorption cycle. The authors con-
HX Heat exchanger cluded that the ejector absorption refrigeration cycle was an effi-
MP Intermediate pressure cient configuration when a high temperature heat source is avail-
n Nozzle exit section able.
out Output The integration of ejectors into more elaborated configura-
P Pump tions of absorption cooling cycles was also considered. Hong et
sat Saturation state al. (2011) investigated a parallel-flow double-effect ejector absorp-
STM Steam tion cycle. Compared to the basic configuration of the single-effect
t Nozzle throat section absorption cycle, their results showed that the COP improved by
10%, 20% and 30% when the heat source temperature was set at
130 °C, 136 °C and 142 °C, respectively. Moreover, at heat source
Aphornratana and Eames (1998) carried out an experimental study temperatures higher than 122 °C and lower than 150 °C, the effi-
on a three-pressure ejector absorption refrigeration machine and ciency of the ejector double-effect absorption cycle was better than
showed that the COP of the ejector absorption machine was 30– that of the conventional double-effect absorption cycle. Farshi et al.
60% higher than that of the basic single-effect absorption cycle and (2012) investigated an ejector series-flow double-effect absorption
achieved the COP of small commercial double-effect absorption refrigeration cycle. The authors performed a thermodynamic anal-
refrigeration machines. In the literature on ammonia/water ejector ysis comparing their cycle with the single-effect and series-flow
absorption refrigeration systems, it is reported that higher values double-effect absorption cycles. They concluded that at a particu-
of the coefficient of performance can be achieved by adding a lar range of the heat source temperature between 92 °C and 137 °C,
flash tank between the ejector and the evaporator. Hence, Sirwan the proposed cycle operated more efficiently than the two other
et al. (2013) and Abed et al. (2015) carried out a theoretical study cycles.
to analyse the effect of the flash tank on the entertainment ratio For heat sources at temperatures over 170 °C, the triple-effect
and the cycle performances. Their results showed that this cycle configuration of the absorption cycle was investigated by several
configuration (ejector and flash tank) improved the coefficient researchers. Grossman and Wilk (1994, 1993) compared the the-
of performance. This was because the increase in the amount of oretical performances of parallel-flow and series-flow triple-effect
refrigerant delivered to the evaporator coming from the flash tank water/lithium bromide absorption chillers. In both cases, heat from
increased the cooling effect. external source was supplied solely to the HP-generator; each
Other researchers investigated the second configuration in intermediate-pressure generator was powered by heat rejected
which the ejector is located at the absorber entrance and replaced by the next high temperature condenser. In the configuration of
the solution expansion valve. Shi et al. (2001) explored this ar- series-connected generators, the aqueous salt solution exiting the
rangement for heat transformers using water/lithium bromide as absorber fed successively the low-pressure generator, then the
a working pair, and Sözen and Özalp (2003) using ammonia/water. intermediate-pressure generator and finally the HP-generator. In
D. Sioud, M. Bourouis and A. Bellagi / International Journal of Refrigeration 99 (2019) 453–468 455
the parallel-connected arrangement, the refrigerant-rich solution Lizarte and Marcos (2016) optimized the coefficient of performance
was split into three streams that fed simultaneously the three of a parallel flow water/lithium bromide triple-effect absorption
generators. The authors reported that the triple-effect parallel-flow cooling system both under design and off-design conditions (for
designs, similar to what they noticed in the case of double-effect a variable-temperature heat source). For off-design conditions and
cycles, always yielded a higher performance than the series-flow at high generator temperatures ranging from 142 °C to 227 °C the
configurations. The performances reached at the specific thermal optimal COP achieved was within the range of 1.05–2.13.
conditions (Tgen = 260 ◦ C; Tevap = 4.1 ◦ C; Tcond = 32 ◦ C) were In conclusion of this literature overview, it can be stated that:
COPPARALLEL =1.44 vs. COPSERIES =1.29. More elaborated triple-effect
configurations were also reported to reach even higher values of (i) The coefficient of performance of the conventional single
the COP (Grossman et al., 1993), COPPARALLEL =1.78; COPSERIES =1.40 and double-effect water/LiBr absorption chillers is rather
Erickson et al. (1996) studied a water/lithium bromide triple-effect low: 0.7–0.8 for the former and 1.0–1.2 for the latter.
absorption refrigerator. Their results showed that triple-effect (ii) The integration of ejectors into single and double-effect ar-
absorption systems can attain a COP 50% over double-effect cy- rangements of absorption cooling systems can enhance their
cles, almost equal to 1.8. Kim et al. (2002) theoretically analysed performance under specific working conditions.
four configurations of compressor-assisted water/lithium bromide (iii) The highest COPs are reached with triple-effect designs (up
series-flow triple-effect absorption cooling cycles. The aim of their to 2) but, besides the growing complexity of these designs,
study was to reduce the temperature of the driving heat by 40 °C temperatures over 180 °C are required for the heat source.
in order to avoid corrosion problems associated with generator At these working temperatures in the generator, the con-
temperatures over 180 °C. In the considered configurations the ventional working fluid water/LiBr suffers from serious prob-
compressor was placed alternatively posterior to the high-pressure, lems of corrosion and thermal decomposition.
the middle-pressure, the low-pressure generator or to the evap-
The objective of the present paper is to propose a novel
orator. The authors concluded that all four configurations were
ejector powered water/lithium bromide double-effect absorp-
suitable as the COP was found to have increased from 1.54 in the
tion/recompression refrigeration cycle driven by high temperature
case of the conventional triple-effect cycle to a COP of 1.70–1.74 for
heat sources. The ejector is placed, as proposed in reference Eames
the newly proposed schemes. The work required of the compressor
and Wu (20 0 0), in an external circuit to the absorption cycle,
was about a 3–5% of the cooling capacity of equivalent mechanical
and is itself driven by a steam generator. The investigations, per-
energies. Using the software ABSIM (Grossman and Wilk, 1994,
formed by numerical simulations, aim to assess the feasibility and
1993; Grossman et al., 1993), Kaita (2002) investigated three con-
the eventual improvement in performance of the proposed cycle
figurations of the triple-effect water/lithium bromide absorption
configuration at temperatures of the driving steam ranging from
cooling cycle, namely parallel-flow, series-flow and reverse-flow.
240 °C to 340 °C. The objective is to reach COP−values comparable
The author found that the parallel-flow configuration achieved the
to those of triple-effect cycles, maintaining the working tempera-
highest coefficient of performance (2.0); however the driving heat
ture lower than 170 °C in the high pressure generator to overcome
temperature exceeded 220 °C. Gebreslassie et al. (2010) estimated
the corrosive effect and thermal instability of water/LiBr at high
the coefficient of performance, the exergetic efficiency and the
temperatures.
exergy destruction rate for half- to triple-effect water/lithium
The operating principles of the absorption/recompression re-
bromide absorption cooling cycles. The authors concluded that the
frigeration cycle considered and the thermodynamic simulation
COP increased significantly from the double to the triple-effect
methodology are described. The effect of the driving heat source
cycles and decreased gradually at high temperature heat sources.
temperature, the generator temperature and the ejector design on
Similar trends were observed for the exergetic efficiency. Álvarez
the cycle performance is analysed.
et al. (2015) investigated a triple-effect absorption cooling cycle
driven by high temperature heat sources (up to 260 °C). The cycle
configuration consisted of a water/lithium bromide double-effect 2. Configuration of the water/lithium bromide double-effect
cycle coupled with a high pressure single-effect cycle in which an absorption/ recompression cycle
aqueous (lithium, potassium, sodium) nitrate solution was used
as a working pair. The authors reported that the coefficient of The ejector powered water/lithium bromide double-effect ab-
performance was 1.73 at a heat source temperature of 250 °C and a sorption/recompression cycle is shown schematically in Fig. 1. It
cooling water temperature of 30 °C. Azhar and Siddiqui (2013) car- comprises three fluid circuits: driving steam loop, refrigerant and
ried out a performance and economic analysis of water/lithium solution circuits.
triple-effect absorption cooling cycles. Depending on the config-
uration of the considered cycles, they found a COP in the range 2.1. Steam circuit
(0.70 − 0.86) for single-effect, (1.20 − 1.55) for double-effect and
up to 2.16 for the optimized triple-effect designs. The results also A high temperature heat source is used in a steam generator to
showed that the operating cost of the double-effect cycle was generate water vapour at high pressure (20). This is piped to the
about 68% of that of the single-effect cycle, the operating cost of ejector primary nozzle, where an expansion takes place producing
the triple-effect cycle was 60 to 75% of that of the double-effect a high velocity jet and generating a partial vacuum in the mixing
cycle and around 45% of that of the single-effect cycle. Shirazi et al. chamber of the ejector. A fraction (22) of the steam liberated in the
(2016) investigated five configurations of solar absorption cooling high-pressure generator (HP-generator) is sucked off in this cham-
and heating systems. The authors performed the analysis taking ber and entrained by the primary flow. The mixed stream then
into account energetic, economic, and environmental aspects at passes through a supersonic-subsonic diffuser that compresses it
different climate conditions. They reported that the COP of triple- to the pressure P23 . The exiting steam (23) condenses inside the
effect cycle driven by solar collectors was between 1.61 to 1.72, tubing coil immersed in the salt solution of the HP-generator, lib-
depending on the location, and that the required temperature in erating the heat needed for the desorption of water (17) from
the collector was about 210 °C. They concluded that the extra capi- the aqueous solution. Part (27) of the condensate water from the
tal cost compared to solar single-effect systems could be recovered heater coil (24) is pumped back into the steam generator via a wa-
in less than 10 years and that this configuration had the lowest ter pump (W – PMP) and the rest (25) flows into the high-pressure
carbon dioxide emissions of the systems taken into consideration. condenser (HP-condenser).
456 D. Sioud, M. Bourouis and A. Bellagi / International Journal of Refrigeration 99 (2019) 453–468
Fig. 1. Schematics of the ejector powered double-effect absorption/recompression refrigeration cycle investigated.
The rest of the cycle is a conventional double-effect lithium then preheated (3) in the solution heat exchanger (S–HX1). Partic-
bromide absorption cycle including the two remaining fluid cir- ular to this double effect cycle is the fact that the MP-generator
cuits, solution and refrigerant loops. is fed by two solution streams. As illustrated in the box to the
right of Fig. 1, the splitter (S – SPL) divides the refrigerant-rich
stream 3 into two parts: one part (3a), together with the partially
2.2. Refrigerant circuit
cooled concentrated salt solution (16), feeds this generator, while
the other part (11) flows further via the pump (S–MP2) and heat
The HP-condenser is alimented by two streams. The first one
exchanger (S–HX2) to the HP-generator. The two mounted heat ex-
(26) comes from the liquid water splitter (L–SPL) mounted at
changers (S–HX1 and S–HX2) are used to recuperate heat from the
the exit of the HP-generator, after decompression to the appropri-
salt-rich solutions (14 and 4) exiting the generators and to preheat
ate pressure in the liquid expansion valve (W – VLV) takes place.
the refrigerant-rich solution flowing counter-currently.
The second stream is the rest (21) of the water vapour (17) liber-
Two liquid expansion valves (S–VLV2 and S–VLV1) are mounted
ated in the HP-generator. The released condensation heat Q˙ HP−CD
on the salt-rich solution line in order to reduce the pressure of the
is used to drive the water desorption in the intermediate-pressure
solution 14 gradually to that of the MP-generator (16) and finally
generator (MP-generator). The formed condensate (18) passes
to that of the absorber (6). The splitting ratio in the splitter (S–SPL)
through the valve R – VLV2 where its pressure is reduced to that
is set by the condition that the heat duty of the HP-condenser is
of MP-condenser (19). The steam liberated in the MP-generator (7)
large enough to produce as much vapour from the MP-desorber as
also feeds this condenser. The exiting liquid water (8) undergoes a
is necessary to make the composition of the salt-rich solution (4)
last adiabatic pressure reduction (R – VLV1), which causes a large
equal to that of the solution leaving the HP-generator (14), i.e.
decrease in temperature as a result of partial evaporation. It then
flows (9) into the machine evaporator where it totally evaporates, x4 = x14
making available the cooling capacity Q˙ EVAP . Formed refrigerant
Fig. 2 presents the proposed cycle on the Dühring–diagram for
vapours (10) are dissolved in the absorber by the salt-rich solu-
a particular set of operating conditions. The solution circulation
tion (6) returning from the generators. The heat released by this
loop (1 − 11 − 13 − 14 − 4 − 6) is similar to that of a conventional
exothermic process Q˙ ABS , like the condensation heat Q˙ MP−CD from
double effect absorption cycle: Water is taken up at the absorber
the MP-condenser, is rejected to the cooling medium.
(6 − 1 ), released as vapor at the generators (17 and 7), and con-
densed at 18 and 8. In the considered cycle however, a fraction of
2.3. Solution circuit the formed vapor 17 is compressed in the ejector and contributes
to heat the solution 13 by condensation. Thus, heat otherwise re-
The salt-weak (refrigerant-rich) solution leaving the absorber jected to the environment is recovered in order to improve the ef-
(1) is pumped (S–MP1) into the MP-generator pressure (2) and ficiency of the system. The ejector process is shown in Fig. 3 on
D. Sioud, M. Bourouis and A. Bellagi / International Journal of Refrigeration 99 (2019) 453–468 457
(P − h )−chart. The external ejector loop processes are represented formulated for each machine component. Hypotheses and assump-
by the line (20 − Nozzle exit − 23 − 24 − 28). In the mixing cham- tions for the calculations are summarized in the following:
ber, after expansion in the nozzle, stream 20 mixes with stream 22,
and the resulting gas mixture is compressed to backpressure P23.
The line through points (18 − 19 − 8 − 9 − 10) represents a process • Simulations and analyses are performed under steady state con-
series in the condensers and evaporator. ditions.
• Heat losses to surroundings at generators, condensers, absorber
3. Cycle simulation model and evaporator are negligible.
• Pressure losses in ducts and machine components are negligi-
3.1. Mathematical modelling ble.
• Refrigerant exiting condensers is in saturated liquid state.
In order to develop a simulation model for the configuration • Refrigerant exiting evaporator is in saturated vapour state.
of the proposed absorption chiller, mass and energy balances are • Solution and refrigerant expansion valves are isenthalpic.
458 D. Sioud, M. Bourouis and A. Bellagi / International Journal of Refrigeration 99 (2019) 453–468
• Refrigerant vapour and liquid solution leaving generators are at Combining with the energy balance of the high-pressure
same temperature. generator leads finally to
• Liquid solutions leaving absorber and generators are saturated.
(h17 − h13 ) + F2 (h14 − h13 )
• Heat from HP-condenser covers intermediate generator heat ˙ 20 = m
m ˙ 17 (12)
needs with 5 °C temperature pinch.
(1 + ω )(h23 − h24 )
• Solution liquid compositions leaving generators are identical. where F2 =
˙ 14
m
=
x13
is the circulation factor in the new
˙ 17
m x14 −x13
• Absorption and condensation temperatures are equal, T8 = T1 .
cycle configuration.
• Evaporation temperature, T10 , is set to a fixed value. • Energy balance
• Effectiveness of heat exchangers is set to ηS−HX1 = ηS−HX2 =
50%. h20 + ωh22
h20 + ωh22 = (1 + ω )h23 ⇒ h23 = (13)
• Liquid pumping is isentropic, ηS−PMP1 = ηS−PMP2 = ηW−PMP = 1+ω
100%. c. Water pump
• Mass balance
Neglecting kinetic and potential energy changes, the balance
equations are as follows: ˙ 28 = m
m ˙ 27 = m
˙ 20 (14)
Total mass balance
• Energy balance
˙ in =
m ˙ out
m (1)
m ˙ w−PMP = m
˙ 20 h27 + W ˙ 20 h28 (15)
Species mass balances
with
(xi m˙ )in = (xi m˙ )out i = H2 O, LiBr (2) P28 − P27
˙ w−PMP = m
W ˙ 20 (16)
Energy balance ρ27
(m˙ h )in − (m˙ h )out + W
˙ + Q˙ = 0 (3) d. Steam generator
• Mass balance
Q˙ and W
˙ are heat and work transfer rates, respectively.
˙ 20 = m
m ˙ 28 (17)
The system coefficient of performance COP is per definition:
• Energy balance, with QSTMG the driving heat supplied to the
Q˙ EVAP Q˙ EVAP
COPED = ≈ (4) chiller at the steam generator
Q˙ STM + W ˙ P Q˙ STM
˙ 20 (h20 − h24 )
QSTMG = m (18)
As an illustration of the modelling procedure, the particular
case of the steam generator-loop is treated. e. Expansion valve
• Mass balance
solutions, (h13 , h14 ), the circulation ratio F2 and the specific con- The simulation program consists of two subprograms corre-
densation enthalpy (h23 − h24 ). sponding to the actual refrigerator configuration: a subprogram
The useful cold Q˙ EVAP is produced by the evaporation of the re- for the water-lithium bromide circuit and another for the driving
frigerant in the machine evaporator, steam circuit with the ejector as the main component.
Before running the simulations for the ejector powered double-
Q˙ EVAP = (m ˙ 7 )(h10 − h9 )
˙ 17 + m (22)
effect absorption/recompression cycle, the simulation program was
Neglecting the energy supplied to the three pumps, it fol- first tested and validated by comparing the calculated results with
lows that for the coefficient of performance of the proposed cycle, the literature data whenever available. For the validation, three
COPER : tests were performed. First, the ejector subprogram was validated.
Then, the simulation model was tested for an ejector driven single-
Q˙ EVAP (m˙ 17 + m˙ 7 )(h10 − h9 ) effect absorption cycle. Finally, the main program was validated for
COPER = = (23)
Q˙ STM m˙ 20 (h20 − h28 ) a conventional double-effect absorption chiller without ejector.
Fig. 4. Validation of the ejector model based on experimental data of reference (Chen and Sun, 1997).
Table 1
Comparison of results calculated with data from reference (Somers, 2009).
Ref. (Somers, 2009) Present work Ref. (Somers, 2009) Present work Ref. (Somers, 2009) Present work Ref. (Somers, 2009) Present work
values ( ∼ 0.7) usually achieved with conventional water/lithium imum deviation of 0.4%. Pressure deviations for low, medium
bromide single-effect absorption cycles. and high pressure are 0.3%, 0.1%, and 4%, respectively. The gap
in LiBr-concentration is approximately 0.6%. Finally the absolute
4.3. Validation using a double-effect absorption refrigeration cycle average deviation in flow rate is 0.9%, an acceptable value as the
without an ejector flow rate is calculated according to mass and energy balances,
so it accumulates all the previous deviations. In conclusion, this
The third test of our program was based on the simulation subprogram of our simulation tool can be considered validated
results reported by Somers (2009), obtained using an ASPEN as the calculated cycle data are well in agreement with those
PLUS model for a double-effect absorption chiller. The simulations reported in reference Somers, (2009).
were performed under following operating conditions: Evaporator
temperature, 5.1 °C; condenser temperature, 29.7 °C; absorber 5. Thermodynamic analysis of the ejector driven double-effect
temperature, 29.9 °C; heat exchanger effectiveness, 0.5 and flow cycle: simulation results and discussion
rate of refrigerant-rich solution leaving the absorber, 1 kg/s. Table 1
shows a detailed comparison of our simulation results with the The first step in our investigations of the proposed cycle was
data reported in reference Huang et al. (1999). As can be noticed, an extension of the last test. For similar operating conditions, a
the obtained results are well in agreement with the published steam driven ejector was integrated in the double-effect absorp-
data. Calculated temperatures are almost identical, with a max- tion/recompression cycle (Fig. 1) and the effect of the primary flow
D. Sioud, M. Bourouis and A. Bellagi / International Journal of Refrigeration 99 (2019) 453–468 461
Table 3
Operating conditions investigated.
Table 4
Nozzle area ratio and primary flow temperature for cases dealt with.
200 °C 4 5 4 4
240 °C 7 8 5 6
280 °C 9 11 7 8
Fig. 5. Model predicted COP vs. LiBr-concentration in the generator in comparison 320 °C 13 17 10 12
with experimental data from reference (Eames and Wu, 20 0 0).
Table 2
Base case study conditions.
• For ejector driving steam temperatures of 200 °C and larger, the
COP increases, reaches a maximum and decreases progressively
T20 [°C] T14 [°C] Nozzle area ratio ( An
)
At to join the COP-curve of the double-effect absorption cycle.
200 [103–127] 5 • The COP-maximum occurs at HP-generator temperatures in the
240 [103–145] 8 range of 120 °C–125 °C, thus it is lower by 20 °C to 25 °C than
280 [103–151] 12
that of the maximum COP for the conventional double-effect
320 [103–155] 18
340 [103–158] 20 absorption cycle.
• The maximum COP is higher as the driving steam tempera-
ture increases: 1.38 for T20 = 240 ◦ C, 1.40 for T20 = 280 ◦ C, 1.43
for T20 = 320 ◦ C and 1.44 for T20 = 340 ◦ C. The calculations
show that the enhancement factor ∈, and consequently the COP
increases with increasing T20 and HP-generator temperature:
from 1.0 (no enhancement) to 1.24 for T14 = 105 ◦ C and from
1.34 to 1.7 for T14 = 135 °C, i.e., ∈= 0.24 for the lower HP-
generator temperature and ∈= 0.36 for the higher tempera-
ture.
Fig. 7. COP vs. HP-generator temperature T14 for the cases #1 (a), #3 (b), #2 (c) and #4 (d) and various driving steam temperatures T20 .
5.1. Effect of evaporator and condenser/absorber temperatures sorber/condenser temperature, T1 = 30 ◦ C, and higher evaporator
temperature, T10 = 12 ◦ C. Following are some specific remarks.
The results of the simulations of the cases #1 to #4 are de-
picted graphically in Fig. 7. Table 5 summarizes the most impor-
tant results. • As observed earlier in the discussion of Fig. 6, the maximum
The COP of the conventional double-effect configuration ex- COP is higher as the driving steam temperature increases. In
pectedly increases with an increase in HP-generator tempera- fact, for the lowest steam temperature, T20 = 200 ◦ C, no or in-
ture T14 , it reaches a maximum and then decreases slowly. The significant effect is noticed in the case studies #1, #2 and #4,
maximum performance depends also on the evaporator and con- as the COP −curves for ejector driven and conventional cycles
denser/absorber temperature, T10 and T8 (or T1 ) respectively. The cover each other. This is also true for steam temperature T20 =
lowest COP is seen in the cycle with the lowest evaporator tem- 240 ◦ C in case #2.
perature (T10 = 4 ◦ C ) and highest condenser and absorber tem- • For cases #1 and #2, the enhancement effect of the ejector re-
perature (T1 = 40 ◦ C ): COP=1.17 at T14 = 200 ◦ C. Conversely, a compression on the maximum COP is insignificant; however,
COP=1.35 produced by an HP-generator temperature T14 = 155 ◦ C this maximum is now reached at lower HP-generator temper-
is obtained in a thermodynamically favourable case (lower ab- ature (by 25 °C less).
D. Sioud, M. Bourouis and A. Bellagi / International Journal of Refrigeration 99 (2019) 453–468 463
Table 5
Summary of simulation results.
Case # Conventional double-effect Ejector recompression double-effect T20 = 320 °C Temperature range for COP–Enhancement
• The maximum enhancement of the COP is observed in case #3 The ejector model presented in the Appendix will help inter-
(35 °C at the absorber/condenser and 12 °C at the evaporator). pret the numerical simulation results and apprehend the beneficial
Here a maximum COP of 1.57 is reached at T14 = 120 ◦ C. The effects –and limits–of the integration of ejectors into an absorption
performance improvement is lower in the case of a higher cool- chiller. According to this model, the entrainment ratio depends on
ing temperature (case #4). For the highest steam temperature, nozzle area ratio, primary flow and secondary flow stagnant prop-
a COP of 1.35 is reached at T14 = 145 ◦ C. erties, and backpressure, i.e.
• The effect of the ejector recompression is limited to a specific
An
HP-generator temperature range T14 depending on the driv- ω =f , P20 , T20 , P22 , T22 , P23 (28)
At
ing steam temperature. For higher T20 the range T14 is more
extended. The last column of Table 5 gives T14 for cases #1 to However, and as mentioned earlier, in an ejector driven chiller
#4 at the highest driving steam temperature T20 = 320 ◦ C. It is the secondary flow properties depend on the processes taking
noteworthy also that this range is dependent on the operation place in the HP-generator. These are determined by the evapo-
conditions and increases with increasing COP maximum. rator and absorber/condenser temperatures (salt concentration of
incoming solution) as well as by the temperature of the heat-
On concluding this part of the investigations, it is noted that ing coil, i.e., by the backpressure properties. For fixed driving flow
the ejector recompression technique affects the performance of the conditions and absorber/condenser temperature, the entrainment
double-effect absorption cycle in two aspects: improvement of the ratio thus depends solely on nozzle geometry (An /At ) and back
COP as in the cases #3 and #4 and the shift of maximum COP at pressure P23 , ω = f(An /At , P23 ). As an illustration of this depen-
lower HP-generator temperatures in all the cases considered. dency, Fig. 9(a) depicts the evolution of ω with nozzle area ra-
tio and backpressure for case #3 with a primary flow temperature
T20 = 240 ◦ C (P20 = 33.4 bar). It shows that for fixed values of P23
5.2. Effect of ejector operation the entrainment ratio first grows with increasing (An /At ), reaches a
maximum, then decreases and finally vanishes. Conversely, for a
We now focus attention on the ejector operation to inter- constant nozzle area ratio, ω increases with falling backpressure,
pret some of the simulation results previously presented. As an passes through a maximum and decreases to zero. Fig. 9(a) reveals
illustration, Fig. 8(a) and 8(b) depict the evolution of the entrain- also that the extent of the feasible variation range for both vari-
ment ratio for cases #1 and #2 with HP-generator temperature T14 ables reduces continuously for higher entrainment ratios, culmi-
for various primary flow temperatures T20 . One notices that ω de- nating in one single point. Further, larger values of ω are obtained
creases monotonously, quasi-linearly, with increasing T14 and van- for lower values of the variables (An /At ) and P23 . The intersection
ishes at a certain temperature. The same behaviour is observed of a horizontal plane with the 3D-surface in Fig. 9(a) (illustrated
when varying the T20 . However, when the primary flow temper- in light green for ω = 0.3) is a curve representing the set of vari-
ature is increased, the ω vs. T14 line is shifted up to higher values able couples generating the same entrainment ratio. The projec-
of the entrainment ratio, and the limit temperature T14 is pushed tion of such intersection lines on the basis horizontal plane consti-
farther away. For case #1 the maximum value of ω (0.5) is reached tutes a so-called contour plot sketch of the 3D–surface, depicted in
at the lowest possible temperature T14 = 120 ◦ C and the high- Fig. 9(b).
est considered T20 = 320 ◦ C. For the thermodynamically less favor- The 3D−surface ω = f(An /At , P23 ) as well as its contour plot
able case #2 (Fig. 8b), a maximum ω = 0.37 is obtained at T14 = representation are bounded. In Fig. 9(a) the feasible ω region is
140 ◦ C and the highest T20 . Further the range of T14 in Figs. 7 (and limited by two curves plotted in red corresponding to ω = 0. Be-
Table 5), where an enhancement of the COP is observed yond these limits the ejector is in off-design conditions and will
corresponds to the feasible, non-vanishing range of ω in Fig. 8(a) not work.
and 8(b). Consider first the limit of the feasibility domain for lower noz-
The behaviour of ω vs. backpressure depicted in Fig. 8(c) and zle area ratios (“Lower Limit” curve in Fig. 9(b)). This curve sets
(d) matches up with its evolution vs. T14 , since the flow 23 ex- a geometrical lower limit to the nozzle design. In fact, with de-
iting the ejector (Fig. 1) constitutes the heat source for the HP- creasing nozzle area ratio (Ai /At ), the nozzle exit pressure Pn ex-
generator. A rise (or drop) of backpressure P23 –and consequently pectedly rises and comes closer to the secondary flow pressure P22 .
of T23 – results in an increase (or decrease) of the HP-generator The suction of the secondary flow into the mixing chamber, driven
temperature T14 . In fact, the secondary flow pressure and salt so- by the pressure difference (P22 − Pn ), declines gradually and even-
lution in the HP-generator are monotonously increasing functions tually vanishes for Pn = P22 . Consequently, at this limit ω falls to
of the backpressure for fixed primary flow conditions and constant zero. For higher backpressure–and therefore higher secondary flow
absorber/condenser temperature. pressure –, the lower limit of (Ai /At ) is accordingly further reduced.
464 D. Sioud, M. Bourouis and A. Bellagi / International Journal of Refrigeration 99 (2019) 453–468
Fig. 8. Effect of HP-generator temperature T14 (a & b) and backpressure (c & d) on entrainment ratio ω for cases #1 and #2.
The bottom border of the 3D-surface forms its intersection with the mixing chamber (shrinkage of the Mach number of primary
the ω = 0 plane and corresponds in Fig. 9(b) to the red “Upper gas from M20n to M22n ) corresponds to a maximum entrainment of
Limit” curve. The calculations show that for a fixed value of back- secondary flow.
pressure (along a horizontal line in Fig. 9(b)), the Mach number When, by applying fixed nozzle area ratio, backpressure is de-
Ma of the mixed stream a, first decreases, passes through a mini- creased, the evolution of the entrainment ratio follows a verti-
mum, then increases and becomes at last equal to that of the pri- cal line segment in Fig. 9(b), beginning on the red “Upper Limit”
mary flow at the nozzle exit. That means, the mixed gas mass flow curve with ω = 0 and ending on the “Lower Limit” curve with
rate reduces to that of the primary flow and hence, no secondary ω = 0 again. Downwards along this line segment, ω increases first,
gas is entrained, i.e. ω = 0. Concomitantly, the ejector area ratio reaches a maximum and then abruptly falls to zero. In Fig. 8 just
(Ac /At ) declines and reaches its minimum value at that limit. For those branches of the ω vs. backpressure curves are depicted
ideal flow conditions (isentropic flow and ideal mixing of primary where the entrainment ratio is falling with a rising P23 (or T14 ).
and secondary gas streams: ηn = ηm = ηd = 1), the ejector area ra- More generally, on increasing the ejector backpressure, and conse-
tio reduces, at that limit, to the nozzle area ratio, quently the secondary flow pressure, by fixing ejector geometry, a
gradual reduction in entrainment ratio is caused.
(Ac /At )min = An /At The COP evolution vs. backpressure (or alternatively HP-
generator temperature T14 ) represented in Fig. 7 exhibits rather
The maximum value of ω on this line corresponds to the low-
complex behaviour as it is conditioned by both the functioning of
est Mach number Ma , Ma = M22n . The deceleration of the gas in
D. Sioud, M. Bourouis and A. Bellagi / International Journal of Refrigeration 99 (2019) 453–468 465
Fig. 9. (a) 3D-representation of entrainment ratio vs. nozzle area ratio and backpressure for case #3 at driving steam temperature T20 = 240 ◦ C (P20 = 33.4 bar); (b) Contour
plot representation of the same. (For interpretation of the references to colour in this figure, the reader is referred to the web version of this article.)
6. Conclusions
120 °C–125 °C, lower by 20 °C to 25 °C than those for a max- as low as possible. The ejector geometry should be chosen for
imum COP of the conventional double-effect absorption cycle. a maximum, practical, and feasible entrainment ratio.
This maximum COP increased from 1.38 to 1.44 when the driv-
ing steam temperature was varied between 240 °C and 340 °C.
At an HP-generator temperature of 135 °C, the enhancement Acknowledgements
factor of the COP was in the range 1.34 – 1.70 for the above
mentioned interval of the driving steam temperature. Doniazed Sioud gratefully acknowledges the Tunisian Ministry
• COP values responding to changes in HP-generator temperature of Higher Education and Scientific Research for funding her intern-
were found to differ from those of the conventional double- ships at Rovira i Virgili University of Tarragona (Spain).
effect absorption cycle. In particular, the COP increased with
the heat source temperature T20 , even when the HP-generator
temperature T14 remained unchanged. Moreover, at a constant Appendix
temperature of the driving steam, the COP decreased just after
reaching its maximum value when the HP-generator tempera- Simplified 1D mathematical ejector model
ture increased.
• The ejector recompression technique affects the performance of The ejector performance is correlated to the entrainment ra-
the double-effect absorption refrigeration cycle in two ways: (i) tio ω. To predict the ejector performance, the complicated flow and
eventual improvement of the COP and (ii) shift of the maximum mixing problems within the ejector must be solved mathemati-
COP to lower HP-generator temperatures in each case consid- cally. The following simplified 1D–analysis is based on the assump-
ered. tions:
• The ejector powered double-effect absorption/recompression
• Primary and secondary fluids have comparable molecular
refrigeration cycle is a good configuration to make effective use
weights and ratios of specific heat and are correctly described
of hot heat sources at a specific temperature range in an HP-
using the ideal gas model with constant specific heat.
generator. For instance, at an evaporator temperature of 12 °C
• Primary fluid expands adiabatically in the nozzle, and mixture
and a steam generator temperature of 320 °C, the maximum
of primary and secondary fluid compresses adiabatically in the
COP of the ejector powered cycle is 1.57, i.e. 0.22 higher than
diffuser.
that of the corresponding value for the double-effect absorp-
• Isentropic efficiencies, ηn and ηd , take into account friction
tion cycle at a condenser temperature of 35 °C and 0.08 higher
losses in nozzle and diffuser.
at a condenser temperature of 40 °C with a COP= 1.35.
• Inlet velocities of primary and entrained fluids are insignifi-
• An efficient steam ejector is essential to obtain a high COP from
cant; velocity of the compressed mixture at ejector outlet is ne-
the ejector powered cycle. The enhancement of the cycle per-
glected.
formance due the presence of the ejector is however limited to
• Mixing of primary and secondary fluids in the suction chamber
a specific range of operating conditions and ejector geometry.
occurs at constant pressure.
Outside this range, the ejector is off-design. Furthermore, and
this may be of practical importance, the larger the entrainment Governing equations
ratio desired, the narrower this feasible range of operation and
geometrical parameters will be. • The primary vapour (20) expands irreversibly through the
• Generally, the following requirements should be met to make nozzle. During this process, a portion of available energy is
the ejector powered cycle run efficiently. The ratio between the transformed into kinetic energy. Assuming an isentropic effi-
solution generator pressure (secondary flow of the ejector) and ciency ηn , the velocity of the flow at the nozzle outlet (n) can
the steam pressure (primary flow of the ejector) should be kept be expressed in terms of the Mach number M20n by applying
the energy conservation, The relation between the Mach numbers upstream and down-
stream of this shock wave is given by:
2 ηn P20
γ −1
γ
2
γ −1 + Ma
2
M20n = −1 (A1)
γ −1 Pn Mb = 2γ
(A5)
γ −1 Ma − 1
2
• The secondary vapour (22) expands reversibly in the suction • The pressure increase across the shock wave is then
chamber. Its velocity at the nozzle exit plane is expressed in
terms of the Mach number M22n of the entrained fluid
Pb Ma 1 + γ 2−1 M2a
= (A6)
2 P22 (γ −1)/γ
Pa Mb 1 + γ 2−1 M2b
M22n = −1 (A2)
γ −1 Pn The constant pressure assumption implies Pa = Pn .
• The mixing process is modelled by 1D–continuity, momentum • The pressure lift in the diffuser is given by the relation
and energy equations. These equations are combined to de- P23 γ − 1 2 γ /(γ −1)
fine the critical Mach number M∗a of the mixture at plane (a) = 1 + ηd Mb (A7)
Pb 2
in terms of the critical Mach number for the primary and en-
trained fluids at section (n), • Further, the nozzle throat and outlet area ratio is
√ (γ +1)/(γ −1)
M∗20n +ω τ
M∗22n
M∗a = ηm (A3) An 1 2 γ −1
(1 + ωτ )(1 + ω ) = (1 + M220n (A8)
At M220n γ +1 2
M∗ denotes the ratio of the local fluid velocity and the velocity And the ratio of the nozzle throat area to the constant section
of sound at critical conditions and τ = T22 . The relation between
T
20
area,
both Mach numbers writes, γ −1 1/(γ −1) P23 Pb 1/γ
At Pb (γ −1)/γ
= 1− 2
P20 P23
(A9)
2M∗ 2 Ac P23 (1 + ωτ )(1 + ω )
M= (A4) 1 − γ 2+1
(γ + 1 ) − (γ − 1 )M∗ 2
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