Dr.

Rizvy Sir- Medical Admission

Sub: Chemistry 1st Chapter-04 (Set-D)
Time: 25 minute Mark: 50
1. B. 70 – 90% • cÖfveK wel n‡jv H mKj c`v_© hviv cÖfve‡Ki cÖfveb
e¨vL¨v : nvRvix bvM ; UwcK : ivmvqwbK wewµqv I wMÖY †Kwgw÷ª : wµqv‡K n«vm K‡i ev G‡Kev‡i eÜ K‡i †`q| †hgb :
eZ©gvb mvs‡køwlK c×wZ‡Z Drcv‡`i m‡e©v”P cwigvY 70 – a~jvevwj, mvjdvi Myov, Av‡m©wbK A·vBW BZ¨vw`|
90% Gi g‡a¨ _v‡K| A_©vr 30% ‡_‡K 10% wewµqK g~j 7. B. mqvweb †Zj †_‡K gvR©vwib Drcv`‡bi mgq
Drcv` ˆZwi bv K‡i wewµqvwenxb _v‡K|
2. A. KClO3 → KCl + O2 8 B. BDwi‡qR
e¨vL¨v : nvRvix bvM ; UwcK : wewµqvi gyL GKgyLx I DfgyLx e¨vL¨v : nvRvix bvM ; UwcK : ‰Re cÖfveK ev GbRvBg :
wewµqv : 1. B÷ bvgK Dw™¢` †Kvl †_‡K RvB‡gR GbRvBg wbtm„Z nq
• cUvwkqvg †K¬v‡iU‡K DËß Ki‡j GwU we‡qvwRZ n‡q KCl hv Møy‡KvR‡K we‡qvwRZ K‡i A¨vj‡Kvnj I CO2 M¨v‡m
I Aw·‡Rb Drcbœ K‡i| wecixZfv‡e KCl I Aw·‡R‡bi cwiYZ K‡i|
g‡a¨ †Kv‡bv wewµqv K‡i bv| 2. mqvwe‡b Dcw¯’Z BDwi‡qR GbRvBg BDwiqv‡K we‡qvwRZ
• e× cv‡Î CaCO3 Gi we‡qvRb DfgyLx| K‡i NH3 I CO2 G cwiYZ K‡i|
• nvB‡Wªv‡Rb I Av‡qvwWb‡K e× cv‡Î †i‡L 450℃ 9. D. mvg¨ve¯’v A¯’vqx
ZvcgvÎvq DËß Kiv n‡j nvB‡Wªv‡Rb Av‡qvWvBW Drcbœ e¨vL¨v : nvRvix bvM ; UwcK : ivmvqwbK mvg¨ve¯’vi kZ© I ˆewkó¨
nq| Avevi weï× nvB‡Wªv‡Rb Av‡qvWvBW M¨vm‡K e× cv‡Î :
450℃ ZvcgvÎvq DËß Ki‡j Zv †_‡K nvB‡Wªv‡Rb I mvg¨ve¯’vi kZ© PviwU : (K) mvg¨ve¯’vi ¯’vwqZ¡
Av‡qvwWb Drcbœ nq| (L) Dfq w`K †_‡K myMg¨Zv
3. A. ZvcgvÎv (M) wewµqvi Am¤ú~Y©Zv
e¨vL¨v : nvRvix bvM ; UwcK : wewµqvi MwZm~Î I wewµqvi nvi : (N) cÖfve‡Ki f~wgKvnxbZv
• ZvcgvÎvi cwieZ©b n‡j wewµqvi nvi aªæe‡Ki gvbI 10. B.7%
cwiewZ©Z nq| e¨vL¨v : nvRvix bvM ; UwcK : ivmvqwbK mvg¨ve¯’vi kZ© I ˆewkó¨
:
• ZvcgvÎv w¯’i †i‡L wewµq‡Ki NbgvÎv cwieZ©b Ki‡jI nvi
aªæe‡Ki gv‡bi †Kv‡bv cwieZ©b nq bv| • GKB Ae¯’vq GK AvqZb N2 M¨vm I wZb Avqb H2 M¨vm
• wewµqvi nvi NbgvÎvi Dci wbf©i Ki‡jI nvi aªæeK wbf©i wb‡q Zv‡Z we`y¨r ùzwj½ NUv‡j gvÎ 7% NH3 ‰Zwi nq|
K‡i bv| evwK 93% N2 I H2 wn‡m‡eB †_‡K hvq|
4. C. M-2s-1 11. C. ‡bBj cwjk wigyfvi wn‡m‡e
e¨vL¨v : nvRvix bvM ; UwcK : wewµqvi µg wbY©q : e¨vL¨v : nvRvix bvM ; UwcK : wkÿv_©xi KvR : 4.5
2NO(g) → O2(g) → 2NO2(g) / wewµqvi nvi = • wdsMvi - ‡bBj cwjk wigyfviiƒ‡c e¨eüZ B_vBj A¨vwm‡UU
K×[NO]2×[O2]1 cÖ¯‘Z Kiv nq A¨vwmwUK GwmWI B_vb‡ji g‡a¨|
Ms−1 Ms−1 • A‡Uv‡gvevBj Bwćb D”P ZvcgvÎvq N2 I O2 wewµqv K‡i
nvi aªæeK, K Gi GKK = M2+1 = = M-2s-1
M3 NO Drcbœ K‡i|
5. D. wewµq‡Ki NbgvÎv 12. B. evwj
e¨vL¨v : nvRvix bvM ; UwcK : ivmvqwbK wewµqvi msNl©ZË¡ : e¨vL¨v : nvRvix bvM ; UwcK : wk‡ívrcv`‡b jv-kv‡Zwjqv‡ii bxwZ
wewµqv NU‡bi Ñ :
1g kZ© : wewµqvq AskMÖnYKvix KYv¸‡jvi g‡a¨ msNl© n‡Z
• ‡nevi em c×wZ‡Z wewµqvi nvi e„w×i Rb¨ Fe cÖfve‡Ki
n‡e|
mv‡_ cÖ‡gvUiiƒ‡c MgO, Al2O3 Ges SiO2(evwj)
2q kZ© : msNl© Aek¨B GKwU wbw`©ó b~b¨Zg kw³ mn‡hv‡M n‡Z
e¨envi Kiv nq|
nq|
Fe Ges K2O n‡jv cÖfveKiƒ‡c e¨eüZ nq|
3q kZ© : msNl© GKwU wbw`©ó w`K web¨vm mn‡hv‡M n‡Z n‡e|
13. B. Qc > Kc n‡j
6. A. mvjdvi
e¨vL¨v : nvRvix bvM ; UwcK : cÖfveK, cÖfve‡Ki cÖKvi‡f`, e¨vL¨v : nvRvix bvM ; UwcK : mvg¨aªæeK Kc Gi Zvrch©
cÖfveK mnvqK I cÖfveK wel : (i) hw` Qc < Kc nq; ZLb wewµqvwU m¤§yLw`‡K AMÖmi n‡e,
Drcv` evo‡Z _vK‡e|
 (ii) hw` Qc > Kc nq; ZLb wewµqvwU mvg¨ve¯’vq Avmvi Rb¨ 20. C. wPwb Av`ª©we‡køwlZ n‡q ‰Zwi mg‡gvjvi Møy‡KvR I d«z‡±vR
cðvrgyLx n‡e; Drcv‡`i we‡qvRb NU‡e| e¨vL¨v : nvRvix bvM ; UwcK : imvqb wk‡í pH Gi ¸iæZ¡ :
(iii) hw` Qc = Kc nq; ZLb wewµqvwU mvg¨ve¯’vq †cŠu‡Q †M‡Q myMvi wg‡j Av‡Li im †_‡K wPwb Drcv`‡bi †ejvq pH wbq‡š¿‡Y
†evSvq| ivLv nq| d‡j wPwb Av`ª©we‡køwlZ n‡q BbfvU© wPwb A_©vr
14. B. 8.7 × 10−14 mg‡gvjvi Møy‡KvR I d«z‡±v‡R iƒcvšÍi ev my‡µv‡Ri Bbfvk©b †iva
e¨vL¨v : nvRvix bvM ; UwcK : cvwbi AvqwbK ¸Ydj I cvwbi nq|
A‡Uv Av‡qvwbKiY : 21. B. Gwm‡Wvwmm
ZvcgvÎv e¨vL¨v : nvRvix bvM ; UwcK : gvby‡li i‡³i pH :
10℃ 25℃ 30℃ 50℃ 100℃
(℃) • gvby‡li i‡³i pH gvb 7.45 Gi †ewk n‡j G Ae¯’v‡K
Kw Gi gvb 0.292 × 1.0 × 1.465 × 5.474 × 8.7 × wPwKrmv weÁv‡b A¨vjKv‡jvwmm e‡j| AwaK A¨vjKv‡jvwmm
10-14 10-14 10-14 10-14 10-14 Ae¯’vi †ivMxi g„Zz¨ N‡U|
15. A. nvBWªvwm‡Wi abvZ¥K Avq‡bi AvKvi • gvby‡li i‡³i pH 7.0 Gi Kg n‡j Zv‡K e‡j Gwm‡Wvwmm|
e¨vL¨v : nvRvix bvM ; UwcK : we‡qvRb aªæeK I GwmWÿv‡ii AwaK Gwm‡Wvwm‡mi Kvi‡Y †Kvgvq P‡j †h‡Z cv‡i|
ZxeªZv: 22. A. +717.02 kj/mol
Gwm‡Wi kw³gvÎv wbf©i K‡i wb‡¤œv³ welq¸‡jvi Dci : e¨vL¨v : nvRvix bvM ; UwcK : wewfbœ cÖKvi Zvcxq ev Gb_vjwc
1. Gwm‡Wi we‡qvRb aªæeK cwieZ©b :
2. nvBWªvwm‡Wi FYvZ¥K Avq‡bi AvKvi C(graphite) → C(g) ∆H°suld = +717.02 kj/mol
3. ‡K›`ªxq cigvYyi RviY Ae¯’v 23. A. −66.04 kj/mol
4. ‡K›`ªxq cigvYyi AvKvi e¨vL¨v : nvRvix bvM ; UwcK : wewfbœ cÖKvi Zvcxq ev Gb_vjwc
5. `ªve‡Ki cÖK…wZ cwieZ©b :
16 A. H3PO3 ‡hme Abv`ª© jeY cvwb‡Z AwZ mn‡RB nvB‡WªU MVb K‡i Zviv
e¨vL¨v : nvRvix bvM ; UwcK : A‡¤øi ÿviKZ¡ I ÿv‡ii A¤øZ¡ : cvwb‡Z `ªexf~Z nIqvi mgq Zvc Drcbœ K‡i| †m‡ÿ‡Î ∆H Gi
H3PO4 Gi ÿviKZ¡ 3 gvb FYvZ¥K nq|
H3PO3 Gi ÿviKZ¡ 2 CuSO4 + aq → CuSO4.5H2O(aq) ; ∆Hsoln =
HCl Gi ÿviKZ¡ 1 −66.04 kj/mol
P2O5 Gi ÿviKZ¡ 6 24. B. HF
H3PO3 + 2NaOH → Na2HPO3 + H2O e¨vL¨v : nvRvix bvM ; UwcK : cÖkgb Zvc :
17. B. H2PO4- + HPO42- cÖkgb Zvc,
e¨vL¨v : nvRvix bvM ; UwcK : evdvi `ªeY : GwmW Zxeª ÿvi ∆H°rxn
A¤øxq evdvi `ªeY : [`ye©j GwmW + AbyeÜx ÿviK]; (kJmol-1)
D`vniY : (i) CH3CO2H + CH3CO2- Avqb, HCl NaOH
− 57.34
**(ii) H2PO4- + HPO42- Avqb, (strong)
ÿvixq evdvi `ªeY : [`ye©j ÿviK + AbyeÜx GwmW]; H2SO4 NaOH
−57.44
D`vniY : (i) Na2CO3 + HCO3- Avqb, (strong)
(ii) NH4OH + NH4+ Avqb, HNO3 NaOH
−57.35
18. D. BDwiqv evdvi (strong)
e¨vL¨v : nvRvix bvM ; UwcK : gvby‡li i‡³i pH HCl KOH
−57.43
(strong)
• gvby‡li i‡³i pH wbqš¿Y cÖK…qvq wb‡¤œv³ evdvi wm‡÷g
CH3COOH NaOH
cÖZ¨ÿ I c‡ivÿfv‡e RwoZ| †hgb: (1) evBKve©‡bU evdvi −55.14
(weak)
(2) AvšÍt‡Kvlxq dm‡dU evdvi
CH3COOH NH4OH
(3) †cÖvwUb evdvi −50.40
(weak)
19. B. wU.Gm.wc
HF NaOH
e¨vL¨v : nvRvix bvM ; UwcK : K…wl Drcv`‡b pH Gi ¸iæZ¡ : −68.60
(weak)
• A¤ø ag©x gvwUi pH evov‡Z Pzb, K¨vjwmqvg, g¨vM‡bwmqvg
cÖf…wZi evBKve©‡bU| 25. B. CH3COOH
‡hgb : jvBg †÷vb, W‡jvgvBU e¨eüZ nq| e¨vL¨v : nvRvix bvM ; UwcK : cÖkgb Zvc :
• ÿvixq gvwUi pH Kgv‡Z bvB‡UªU mvi; dm‡dU mvi †hgb HF 2.60% AvqwbZ nq|
wU.Gm.wc ev g‡bvK¨vjwmqvg dm‡dU I mycvi dm‡dU CH3COOH 0.42% AvqwbZ nq|
BZ¨vw` e¨eüZ nq|
26. C. 283 kj/mol Zvc Drcbœ nq mvaviY c×wZ n‡jv Uw·K †ebwRb †_‡K RviY Øviv| wKš‘ meyR
D. 890.3 kj/mol Zvc Drcbœ nq imvq‡b cwi‡ek evÜe weD‡Ub †_‡K Gi Drcv`b Kiv nq|
e¨vL¨v : nvRvix bvM ; UwcK : ‡n‡mi m~Î cÖ‡qvM : 36. A. Bw_b
• C(s) + O2(g) → CO2(g) ; ∆H = −393.5 e¨vL¨v : Kexi m¨vi ; UwcK :
Al2 O3
kj/mol CH3–CH2–OH →∆ H2C = CH2 + H2O : wbiæ`b
1
• C(s) + 2 O2(g) → CO(g) ; ∆H = −110.5 Cu
CH3–CH2–OH∆→ CH3 CHO + H2 : nvB‡Wªv‡Rb wePz¨wZ
kj/mol 37. D. Pvcxq mvg¨ve¯’v
1
• CO + 2 O2(g) → CO2 ; ∆H = −283 kj/mol e¨vL¨v : Kexi m¨vi ; UwcK : ivmvqwbK mvg¨ve¯’v mvaviYZ `yB
27. A. 4.2 joul cÖKvi : mgmË¡ ev mylg mvg¨ve¯’v AmgmË¡ ev welg mvg¨ve¯’v|
e¨vL¨v : nvRvix bvM ; UwcK : Aa¨v‡qi mvims‡ÿc : GQvovI AvqwbK mvg¨ve¯’v bv‡g Av‡iKwU mvg¨ve¯’v wPwýZ Kiv
• K¨vjwi : GK MÖvg cvwbi ZvcgvÎv 1℃ (14.5℃– hvq|
15.5℃) evov‡Z †h cwigvY Zvckw³ cÖ‡qvRb nq, Zv‡K 38. B. HNO3
GK K¨vjwi e‡j| Avevi 1 K¨vjwi = 4.186 J (Ryb)| e¨vL¨v : Kexi m¨vi ; UwcK : wk‡ívrcv`b cÖwµqvq jv-
28. A. +121 kjmol-1 kv‡Zwjqv‡ii bxwZ :
e¨vL¨v : nvRvix bvM ; UwcK : wewfbœ cÖKvi Zvcxq ev Gb_vjwc evK©j¨vÛ Ñ AvBW c×wZ‡Z HNO3 Drcv`‡bi wewµqvmg~n :
cwieZ©b : • N2(g) + O2(g) ⇌ 2NO(g)
1
Cl2(g) → Cl(g) ; ∆H°atom = +121 kj/mol • 2NO + O2(g) = 2NO2(g)
2
• 4NO2(g) + O2 + 2H2O(l) → 4HNO3(l)
29. C. C4H2O3
39. A. P2O5
e¨vL¨v : nvRvix bvM ; UwcK : ivmvqwbK wewµqv I wMÖY †Kwgw÷ª :
e¨vL¨v : Kexi m¨vi ; UwcK : A¤øZ¡ I ÿviKZ¡ :
30. A. 2NO(g)+O2(g) → 2NO2(g)
• P2O5 + 6NaOH → 3Na3PO4 + 3H2O
e¨vL¨v : nvRvix bvM ; UwcK : wewµqvi µg :
• CO2 + 2NaOH → Na2CO3 + H2O
Z…Zxq µg wewµqv :
• H3PO4 + 3NaOH → Na3PO4 + 3H2O
2NO(g) + O2(g) → 2NO2(g)
NO(g) + Cl2(g) → 2NOCl(g) • HClO4 + NaOH → NaClO4 + H2O
31. B. e¨v¯ÍvbycvwZK 40. A. Al2O3
e¨vL¨v : nvRvix bvM ; UwcK : wewµqvi nvi I mwµqb kw³i 41. A. Na2S
gvÎvi g‡a¨ m¤úK© : e¨vL¨v : Kexi m¨vi ; UwcK : je‡Yi Rjxq `ªe‡Yi A¤øxq I ÿvixq
cÖK…wZ :
• ‡h wewµqvi mwµqb kw³ †ewk Zvi MwZi nvi Kg n‡e Ges
†h wewµqvi mwµqb kw³ Kg Zvi MwZi nvi †ewk n‡e| Zxeª ÿvi NaOH ev KOH Gi mv‡_ g„`y GwmW H2CO3,
H2S, CH3COOH ev H3PO4 Gi wewµqvi Drcbœ jeY
• wewµqvi nvi mwµqb kw³i gvÎvi e¨v¯ÍvbycvwZK|
Na2CO3, Na2S, CH3COONa ev K3PO4 BZ¨vw`i Rjxq
32. D. CO2
`ªeY ÿvixq nq|
e¨vL¨v : nvRvix bvM ; UwcK : cÖfve‡bi wµqv †KŠkj :
A‡Uv‡gvevBj Bwćbi wbM©gb cvB‡ci eR©¨ M¨v‡m _v‡K `nbgy³ 42. C. +249 kj/mol
e¨vL¨v : Kexi m¨vi ; UwcK : wewµqvi Zvc :
CxHy, CO, NO cÖK…wZ cwi‡ek `~lK M¨vm| G‡ÿ‡Î
†KUvjvBwUK KbfvU©vi H me `~lK M¨vm‡K CO2, N2, O2 M¨v‡m
cÖwµqv ∆H°298k kJ/mol.
1 + 79.1
cwiYZ K‡i| F2(g) = F(g)
2
33. C. DfgyLx wewµqvi mvg¨ve¯’v‡K cwieZ©b K‡i 1 +121.1
Cl2(g) = Cl(g)
2
34. A. 98% H2SO4 1
Br2(g) = Br(g) + 112.0
e¨vL¨v : nvRvix bvM ; UwcK : mvjwdDwiK GwmW wk‡ívrcv`‡bi 2
1 + 106.0
†ÿ‡Î SO2 Gi RviY : I2(g) = I(g)
2
cvwb‡Z SO3 Gi `ªeYxqZv Kg e‡j 98% H2SO4 Gwm‡W SO3 1 + 218.0
H2(g) = H(g)
M¨vm‡K †kvwlZ Kiv nq| 2
1 + 249.2
35. A. †ebwR‡bi RviY O2(g) = O(g)
2
e¨vL¨v : Kexi m¨vi ; UwcK : wMÖY K¨vwgw÷ª : 43. D. ‡K¬v‡ivdg©
AZ¨šÍ cÖ‡qvRbxq GKwU KvuPvgvj n‡jv g¨v‡jvwqK GbnvB‡WªU hv e¨vL¨v : Myn m¨vi ; UwcK : wMÖY †Kwgw÷ª :
†_‡K Ilya, cÖ‡qvRbxq cwjgvi ˆZwi Kiv hvq| Gi Drcv`‡bi
 meyR `ªveK : K…wl dm‡ji cÖwµqvRvZKi‡Yi gva¨‡g cÖvß cwi‡ek 48. B. CaSO4
evÜe ˆRe `ªveK‡K meyR `ªveK e‡j| wg_vbj, B_vbj, †n‡·ªb, e¨vL¨v : wjsKb m¨vi ; UwcK : je‡Yi Av`ª©we‡kølY :
†n‡Þb BZ¨vw` meyR `ªveK| je‡Yi Av`ª©we‡kølY `yB cÖKvi Ñ
44. A. Al2O3 (i) K¨vUvqwbK Av`ª©we‡kølY
e¨vL¨v : Myn m¨vi ; UwcK : wewµqvi µg : (ii) A¨vbvqwbK Av`ª©we‡kølY
Drcv` I e¨eüZ (i) K¨vUvqwbK Av`ª©we‡kølY N‡U A¤øxq jeY mg~‡ni :
wewµqv cÖfveK
evwYwR¨K c×wZ ‡hgb : ZnSO4, CaSO4, CuCl2, FeCl2, Al2(SO4)3,
AmIqvì c×wZ‡Z Al(NO3)3, NH4Cl BZ¨vw`|
HNO3 Drcv`‡bi cÖ_g (ii) A¨vbvqwbK Av`ª©we‡kølY Zv‡`iB N‡U hviv n‡jv ÿvixq jeY
4NH3 + 5O2
av‡c e¨eüZ nq| :
→ 4NO + Pt Ges Rh
we‡ùviK `ªe¨ Drcv`‡b, ‡hgb : K2CO3, CH3COONa, H-COONa cÖf…wZ|
6H2O
mviwk‡í, cøvw÷K wk‡í, 49. B. Pt
iswk‡í e¨eüZ nq| e¨vL¨v : nvRvix bvM ; UwcK : cÖfve‡Yi wµqv †KŠwkj :
w÷g-nvB‡WªvKve©‡bi e¨eüZ wk‡í avcwfwËK Kvw•ÿZ Drcv` I
cybM©V‡b I nvB‡Wªv‡Rb wewµqvmg~n
H2O + CH4 cÖfveK e¨envi e¨envi
Ni Drcv`‡b; ZvQvov H2O,
→ CO2 + H2 (K) AmgmË¡xq Pt ev ¯úk© c×wZ‡Z Drcv` H2SO4 :
NH3, CH3OH M¨vmxq : V2O5 H2SO4 wewfbœ ‡KwgK¨vj,
Drcv`‡b e¨eüZ nq| Drcv`‡b wØZxq ivmvqwbK mvi,
wkí‡ÿ‡Î CH3OH av‡c|
Drcv`‡b e¨eüZ nq| 1. 2SO2+O2 →
CO + 2H2 → ZnO Ges
cøvw÷K Drcv`‡b, ˆRe 2SO3
CH3OH Cr2O3
`ªveK I Mvg Drcv`‡b 2. 4NH3+5O2 Pt I AmIqvì Drcv` HNO3 :
e¨eüZ nq| → Rh c×wZ‡Z HNO3 we‡ùviK, mvi,
Am¤ú„³ ‡fvR¨‡Zj †_‡K 4NO+6H2O Drcv`‡b 1g cøvw÷K, iÄK I
CH2 = KwVb d¨vU Drcv`‡b, av‡c| evwb©k|
Ni, Pd A_ev
CH2 + H2 → †fvR¨‡Z‡ji 3. N2+3H2 → Fe, ‡nevi c×wZ‡Z Drcv` NH3 :
Pt
CH3 – CH3 nvB‡Wªv‡R‡bk‡b e¨eüZ 2NH3 K2O I NH3 mvi I HNO3
nq| Al2O3 Drcv`‡b| Drcv`‡b|
8CO + 17H2 M¨v‡mvwjb Drcv`‡b eûj
4. CH4+H2O Ni w÷g-A¨vj‡Kb H2 M¨vm :
CO A_ev
→ C8H18 + e¨eüZ nq|
→ widiwgs
Al2O3 A¨v‡gvwbqv,
8H2O CO+3H2 c×wZ‡Z H2 wg_vbj Drcv`b|
45. A. 5.54×10-8 ohm-1 cm-1 ms‡kølY|
e¨vL¨v : Myn m¨vi ; UwcK : cvwbi AvqwbK ¸Ydj I evdvi `ªeY (L) mgmË¡xq Mo(V ‡cÖvcvBwjb e¨envi :
: M¨vmxq : I) A·vBW ms‡kølY| cwjG÷vi
†Kvjivm I †nWIBjvi †`Lvb †h, AwZ weï× cvwbI AwZ mvgvb¨
1. ‡cÖvcvBwjb, Kg‡cø cwiBD‡i‡_b
gvÎvq we`y¨r cwienb K‡i| 25℃ ZvcgvÎvq cvwbi Av‡cwÿK Aw·WvBRvi · †dvg
cwievwnZv 5.54×10-8 ohm-1 cm-1| 2. weDUv-WvB-Bb, Ni/P GwW‡cvbvBUªvBj e¨envi : bvBjb,
46. A. [H3O+] > [OH-] HCN ‡hŠM dvBevi I cøvw÷K
e¨vL¨v : Myn m¨vi ; UwcK : Gwm‡Wi we‡qvRb aªæeK Ges ÿv‡ii Drcv`b|
we‡qvRb aªæeK :
• cÖkg `ªe‡Yi †ÿ‡Î : [H3O+] = [OH-] 50. C. −393.5 kj/mol
• GwmWxq `ªe‡Yi †ÿ‡Î : [H3O+] > [OH-] e¨vL¨v : wjsKb m¨vi ; UwcK : j¨vfqwm‡qI j¨vcjv‡mi m~Î :
• ÿvixq `ªe‡Yi †ÿ‡Î : [H3O+] < [OH-] • C(s) + O2(g) → CO2(g) ; ∆H = −393.5 kj/mol
47. A. H2(g) + Cl2(g) ⇌ 2HCl(g) •
1
C(s) + 2 O2(g) → CO(g) ; ∆H = −110.5
e¨vL¨v : Myn m¨vi ; UwcK : wewµqvi µg : kj/mol
k~Y¨µg wewµqvi nvi NbgvÎvi Dci wbf©ikxj bq| 1
hv • CO(g) + 2 O2(g) → CO2(g) ; ∆H = −283.0
H2(g) + Cl2(g) ⇌ 2HCl(g) ; GwU GKwU k~Y¨µg wewµqv|
kj/mol
G‡ÿ‡Î H2 I Cl2 ‡Kv‡bv wewµq‡Ki NbgvÎvB wewµqvi
MwZ‡e‡Mi Dci cÖfve †d‡j bv|