Control No.
Material Safety Data sheet (MSDS) Date First May 16, 2008
Date Final January 1, 2024
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
A. PRODUCT NAME : Lead-acid Battery
B. RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE
: Lead-acid Batteries for Marine
C. MANUFACTURER/SUPPLIER/DISTRIBUTOR INFORMATION
MANUFACTURER : Sebang Global Battery CO.,Ltd.
Sonjae-ro 287beon-gil, Gwangsan-Gu, Gwangju, KOREA
TEL: +82-62-601-6128 FAX: +82-62-951-4126
2. HAZARDS IDENTIFICATION
A. HAZARD CLASSIFICATION
PHYSICAL HAZARDS
: Not Classified.
HEALTH HAZARDS
: Acute toxicity Category 2 (inhalation)
: Skin corrosion/irritation Category 1
: Serious eye damage/eye irritation Category 1
: Carcinogenicity Category 1B
: Germ cell mutagenicity Category 2
: Specific target organ toxicity – single exposure Category 1
: Specific target organ toxicity – repeated exposure Category 1
: Hazardous to the aquatic environment_Acute hazard Category 1
: Hazardous to the aquatic environment_Chronic hazard Category 1
ENVIRONMENTAL HAZARDS
: Not Classified.
B. GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS
PICTOGRAMS :
SIGNAL WORD : DANGER.
HAZARD STATEMENTS
H332 Harmful if inhaled.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H350 May cause cancer (inhalation).
H341 Suspected of causing genetic defects.
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Control No.
Material Safety Data sheet (MSDS) Date First May 16, 2008
Date Final January 1, 2024
H370 Specific target organ toxicity – single exposure; Respiratory tract irritation
Causes damage to organs (Hematopoietic system, kidney, central nervous system,
H372
peripheral nervous system, cardiovascular system, immune system, respiratory).
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
PRECAUTIONARY STATEMENTS :
[Prevention]
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a wellventilated area.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P281 Use personal protective equipment as required.
P270 Do not eat, drink or smoke when using this product.
[Response]
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable
P304 + P340
for breathing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse
P303 + P361 + P353
skin with water/shower.
P363 Wash contaminated clothing before reuse.
P310 Immediately call a POISON CENTER or doctor/physician.
P321 Specific treatment (see ... on this label).
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
P305 + P351 + P338
lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/attention.
P307+P311 IF exposed: Call a POISON CENTER or doctor/physician.
P314 Get medical advice/attention if you feel unwell.
[Storage]
P405 Store locked up.
[Disposal]
P501 Dispose of contents/container in accordance with local/regional/national regulations.
C. OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION (e.g. Dust explosion hazards)
NFPA/HMIS Rating
Health=3, Flammability=0, Instability=1
:
(0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme)
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Control No.
Material Safety Data sheet (MSDS) Date First May 16, 2008
Date Final January 1, 2024
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical name / Synonym CAS No. or ID Content (%)
Lead 7439-92-1 52 - 59
Antimony 7440-36-0 0.5 - 0.7
Sulfuric acid / Oil of vitriol 7664-93-9 30 - 38
Polypropylene / PP Resin 9003-07-0 6-9
Separator Not available 1-2
* European Inventory of Existing Commercial Chemical Substances (EINECS).
4. FIRST AID MEASURES
If a battery ruptures, do not rub or scratch exposed eye. Immediately flush eyes with
A. EYE CONTACT : running water for at least 15 minutes, keeping eyelids open. Cold water may be
used. GET MEDICAL ATTENTION IMMEDIATELY.
If a battery ruptures, do not rub or scratch exposed skin. If liquid get on the skin,
immediately flush the contaminated skin with water for at least 15 minutes. If liquid
B. SKIN CONTACT : penetrate through the clothing, immediately remove the clothing and shoes under a
safety shower and continue to wash the skin for at least 15 minutes. GET MEDICAL
ATTENTION IMMEDIATELY.
If a battery ruptures, move to fresh air in case of accidental inhalation of mist. If
C. INHALATION : breathing has stopped, perform artificial respiration. If breathing is difficult, give
oxygen. GET MEDICAL ATTENTION AS SOON AS POSSIBLE.
If solutions of a battery chemicals have been swallowed and the person is
conscious, give one glass of water. Vomiting may occur spontaneously, but Do NOT
D. INGESTION :
induce vomiting. Never give anything by mouth to an unconscious person. GET
MEDICAL ATTENTION IMMEDIATELY.
E. MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE OR DELAYED
Not a likely route of exposure. If a battery ruptures, direct contact with the liquid or
EYES : exposure to vapors or mists may cause tearing, redness, swelling, corneal damage
and irreversible eye damage. Splashes in the eyes will cause severe burns.
Not a likely route of exposure. Direct contact with internal components of a battery
SKIN : can be severely irritating to the skin and may result in redness, swelling, burns and
severe skin damage. Skin contact may aggravate an existing dermatitis condition.
Not a likely route of exposure. If a battery ruptures, may be harmful or fatal if inhaled
INHALATION : in a confined area. May cause severe irritation and burns of the nose, throat and
respiratory tract.
Not a likely route of exposure. Causes serious burns of the mouth or perforation of
INGESTION :
the esophagus or stomach. May be fatal if swallowed.
* Lead may causes toxic to blood, kidneys, central nervous system (CNS). Repeated or prolonged exposure to
lead can produce target organs damage.
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Control No.
Material Safety Data sheet (MSDS) Date First May 16, 2008
Date Final January 1, 2024
F. INDICATION OF IMMEDIATE MEDICAL ATTENTION AND NOTES FOR PHYSICIAN
Based on the individual reactions of the patient, the physician's judgement should be
:
used to control symptoms and clinical condition.
5. FIRE FIGHTING MEASURES
A. SUITABLE (AND UNSUITABLE) EXTINGUISHING MEDIA
Use extinguishing media appropriate for surrounding fire.
:
If a battery ruptures, use dry chemical, soda ash, lime, sand or carbon dioxide.
B. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL
Lead, lead compounds and sulfuric acid fume may be released during a fire
:
involving the product.
C. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE FIGHTERS
Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective
:
clothing.
D. FIRE AND EXPLOSION HAZARD
Not flammable.
: Battery may rupture due to pressure buildup when exposed to excessive heat and
may be result in the release of corrosive materials.
6. ACCIDENTAL RELEASE MEASURES
A. NECESSARY MEASURES AND PROTECTIVE GEAR TO PROTECT HUMANS
If a battery ruptures, avoid contact with skin, eyes and clothing. Do not touch spilled
: material. Use personal protective equipment recommended in Section 8 (Exposure
Controls/Personal Protection).
B. NECESSARY MEASURES TO PROTECT ENVIRONMENT
Notify authorities and appropriate federal, state, and local agencies. Prevent the
:
product from spreading into the environment. Avoid direct discharge into drains.
C. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP
SMALL SPILLS: Collect all released material in a plastic lined metal container. If
necessary neutralize the residue with a dilute solution of sodium carbonate. Wash
affected area.
: LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by
building a dike. Absorb with dry earth, sand or other non-combustible material.
Neutralize the residue with a dilute solution of sodium carbonate. Dispose of all
contaminated materials in accordance with current local regulations.
7. HANDLING AND STORAGE
A. PRECAUTIONS FOR SAFE HANDLING
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Control No.
Material Safety Data sheet (MSDS) Date First May 16, 2008
Date Final January 1, 2024
: Protect from physical damage.
B. CONDITIONS FOR SAFE STORAGE (INCLUDING ANY INCOMPATIBILITIES)
Avoid contact with eyes. Store in a cool, dry, ventilated area away from sources of
: heat, moisture, incompatibilities, and direct sunlight. Have emergency equipment (for
fires, spills, leaks, etc.) readily available.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
A. OCCUPATIONAL EXPOSURE LIMIT(S), BIOLOGICAL EXPOSURE STANDARD
OSHA-PEL 0.05 mg/m3 (Lead), 1 mg/m3 (Sulfuric acid), 0.5 mg/m3 (Antimony)
TWA 0.05 mg/m3 (Lead), TWA 0.2 mg/m3 (Sulfuric acid)
ACGIH-TLV
TWA 0.5 mg/m3(Antimony)
B. APPROPRIATE ENGINEERING CONTROLS
: Use local exhaust ventilation if necessary to control airborne mist and vapor.
C. INDIVIDUAL PROTECTION MEASURES
If significant mists or aerosols are generated an approved respirator is
recommended. If respiratory protection is required, institute a complete respiratory
Respiratory protection:
protection program including selection, fit testing, training, maintenance and
inspection.
Eye protection : Wear safety glasses with side shields (or goggles).
Wear chemical resistant gloves. Gloves should be replaced immediately if signs of
Hand protection :
degradation are observed.
Use good work and personal hygiene practices to avoid exposure. Consider the
Body protection : provision in the work area of a safety shower and eyewash. Always wash thoroughly
after handling chemicals.
9. PHYSICAL AND CHEMICAL PROPERTIES
A. APPEARANCE (PHYSICAL STATE, COLOUR etc.) : Off-white cloudy liquid with solid object.
B. Odour : Characteristics.
C. ODOR THRESHOLD : Not available.
D. pH : pH < 1 (Sulfuric acid)
E. MELTING POINT/FREEZING POINT : Not available.
F. INITIAL BOILING POINT AND BOILING RANGE : Not available.
G. FLASH POINT : Non-flammable.
H. EVAPORATION RATE : Not available.
I. FLAMMABILITY (SOLID, GAS) : Not applicable.
J. UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS
: Non-flammable.
K. VAPOR PRESSURE : Not available.
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Control No.
Material Safety Data sheet (MSDS) Date First May 16, 2008
Date Final January 1, 2024
L. SOLUBILITY : Soluble in water.
M. VAPOR DENSITY : Not available.
N. SPECIFIC GRAVITY : Not available.
O. PARTITION COEFFICIENT OF n-OCTANOL/WATER: Not available.
P. AUTO-IGNITION TEMPERATURE : Not applicable.
Q. DECOMPOSITION TEMPERATURE : Not available.
R. VISCOSITY : Not available.
S. MOLECULAR WEIGHT : Mixture.
Note: These physical properties are typical values for this product.
A. APPEARANCE (PHYSICAL STATE, COLOUR etc.) : Bluish white, silvery gray.
B. Odour : None.
C. ODOR THRESHOLD : Not available.
D. pH : Not applicable.
E. MELTING POINT/FREEZING POINT : 327.5℃
F. INITIAL BOILING POINT AND BOILING RANGE : 1740℃ (1013 hPa)
G. FLASH POINT : Non-flammable.
H. EVAPORATION RATE : Not applicable.
I. FLAMMABILITY (SOLID, GAS) : Not applicable.
J. UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS
: Non-flammable.
K. VAPOR PRESSURE : 1.33 hPa (973℃)
L. SOLUBILITY : Insoluble in water.
M. VAPOR DENSITY : Not applicable.
N. SPECIFIC GRAVITY : 11.34 g/cm3
O. PARTITION COEFFICIENT OF n-OCTANOL/WATER: Not applicable.
P. AUTO-IGNITION TEMPERATURE : Not applicable.
Q. DECOMPOSITION TEMPERATURE : Not applicable.
R. VISCOSITY : Not applicable.
S. MOLECULAR WEIGHT : 207.2
Note: These physical properties are typical values for Lead(Pb).
10. STABILITY AND REACTIVITY
: Stable at normal temperatures and storage conditions.
A. CHEMICAL STABILITY
B. POSSIBILITY OF HAZARDOUS REACTIONS
: Hazardous polymerization will not occur.
C. CONDITIONS TO AVOID (STATIC DISCHARGE, SHOCK, VIBRATION etc.):
Overcharging. Sources of ignition. Mechanical impact. Contact with incompatible
:
chemicals.
D. SUBSTANCES TO AVOID
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Control No.
Material Safety Data sheet (MSDS) Date First May 16, 2008
Date Final January 1, 2024
: If a battery ruptures, avoid contact with organic materials and alkaline materials.
E. HAZARDOUS DECOMPOSITION PRODUCTS
Lead, Lead compounds and sulfuric acid fumes may be released during a fire
:
involving the product.
11. TOXICOLOGICAL INFORMATION
A. Information on the likely routes of exposure
Inhalation : Corrosive. severe irritation and burns.
Ingestion : Serious burns.
Eye/Skin
Tearing, redness, swelling, corneal damage, irreversible eye damage and severe
Eye :
burns.
Skin : Redness, swelling, burns and severe skin damage.
B. Delayed and immediate effects and also chronic effects from short and long term exposure
Acute toxicity (possible route of exposure) :
2140 mg/kg (Sulfuric acid),
Oral (LD50) : Rat
7000 mg/kg (Antimony)
Skin (LD50) : Not available.
Inhalation (LC50) : Rat 0.347 mg/L(4hr) (dust//mist)
Skin corrosion/irritation : cat 1
Serious eye damage/irritation : cat 1
Respiratory sensitization : Not available.
Skin sensitization : Not available.
Carcinogenicity : cat 1B
ACGIH Group A2, IARC Group 1 (Mist containing sulfuric acid)
* Note: Sulfuric acid mist is not expected under normal use of the product.
ACGIH Group A3, IARC Group 2B (Lead), IARC Group 3 (Polypropylene)
Germ cell mutagenicity : cat 2
Reproductive toxicity : Not available.
STOST-single exposure : cat 1
: Respiratory.
STOST-repeated exposure : cat 1
Hematopoietic system, kidney, central nervous system, peripheral nervous system,
:
cardiovascular system, immune system, respiratory.
Aspiration hazard : Not available.
C. Numeric measure of toxicity (such as acute toxicity estimates) - ATEmix
Oral (LD50) : Rat > 5,000 mg/kg
Skin (LD50) : Not available.
Inhalation (LC50) : Rat 2.51 mg/L(4hr) (dust//mist)
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Control No.
Material Safety Data sheet (MSDS) Date First May 16, 2008
Date Final January 1, 2024
12. ECOLOGICAL INFORMATION
A. Aquatic/terrestrial ecology toxicity
Fish (LC50)
Lead : LC50 2.2 ㎎/ℓ 96 hr
Sulfuric acid : LC50 16 ㎎/ℓ 96 hr
Antimony : LC50 5.2 ㎎/ℓ 96 hr
Daphnia (EC50)
Lead : Not available.
Sulfuric acid : EC50 200 ㎎/ℓ 48 hr
Antimony : Not available.
Algae (EC50) : Not available.
B. Persistence and degradability
Persistence
Lead : log kow 2.98
Sulfuric acid : log kow -1.43
Antimony : log kow 0.73
Degradability : Not available.
C. Bioaccumulative potential
Lead : Not available.
Sulfuric acid : BCF 250
Antimony : Not available.
D. Mobility in soil : Not available.
E. Other hazardous effects : Not available.
13. DISPOSAL CONSIDERATIONS
A. DISPOSAL METHODS
Dispose of in accordance with local, state, and federal regulations. Hazardous
wastes must be transported by a licensed hazardous waste transporter and
: disposed of or treated in a properly licensed hazardous waste treatment, storage,
disposal or recycling facility. Consult local, state, and federal regulations for specific
requirements.
B. PRECAUTIONS (INCLUDING DISPOSAL OF CONTAMINATED CONTAINER OR PACKAGE)
Since emptied containers retain product residue, follow label warnings even after
:
container is emptied.
14. TRANSPORT INFORMATION
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Control No.
Material Safety Data sheet (MSDS) Date First May 16, 2008
Date Final January 1, 2024
The information in this section is for reference only and should not take the place of a shipping paper (BL). Please
note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation.
A. UN NUMBER : UN 2794
B. UN PROPER SHIPPING NAME
BATTERIES, WET, FILLED WITH ACID, electric storage.
C. TRANSPORT HAZARD CLASS(ES) : 8
D. PACKING GROUP (IF APPLICABLE) : None.
E. MARINE POLLUTANT SUBSTANCES (APPLICABLE/NOT APPLICABLE)
: Not Applicable.
F. SPECIAL PRECAUTIONS FOR USER : Not available.
15. REGULATORY INFORMATION
₪ INVENTORIES
EINECS/EU : Listed (EINECS No. 231-100-4(Lead), 231-639-5(Sulfuric acid))
TSCA/US : Listed.
ENCS/JAPAN : Listed (ENCS No. 1-527(Lead), 1-430(Sulfuric acid))
AICS/AUSTRALIA : Listed.
DSL/CANADA : Listed.
IECSC/CHINA : Listed.
PICCS/PHILIPPINES : Listed.
KECI/S.KOREA : Listed (KE-21887(Lead), KE-32570(Sulfuric acid))
₪ International Environmental Agreement
PIC : Not listed.
POPs : Not listed.
Ozone depletion : Not listed.
EU. Directive 67/548/EEC on the classification, packaging, and labelling of dangerous substances, Annex I
Classification : C; R35
Risk Phrases : R35
Safety Phrases : S1/2, S26, S30, S45
₪ U.S. Federal, Heanth and Environment) and U.S. Federal, Right-To-Know
CERCLA Section 103 (40 CFR 302.4)
: 10lb (4.535 kg) (Lead), 1000 lb (453.599 kg) (Sulfuric acid)
EPCRA (SARA Title III) Section 302 (EHS -TPQ)
: 1000 lb (453.599 kg) (Sulfuric acid)
EPCRA (SARA Title III) Section 304 (EHS - Reporting Quantities)
: 1000 lb (453.599 kg) (Sulfuric acid)
EPCRA (SARA Title III) Section 313 - Toxic chemical release reporting
Sulfuric acid (acid aerosols including mists, vapors, gas, fog, and other airborne
:
forms of any particle size)
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Control No.
Material Safety Data sheet (MSDS) Date First May 16, 2008
Date Final January 1, 2024
OSHA Specifically Regulated Substances (29 CFR 1910.1001-.1052)
: Not applicable.
₪ CANADA REGULATORY INFORMATION
WHMIS Ingredient Disclosure List : Regulated.
NOTE: The regulatory information given above only indicates the principal regulations specifically applicable to the product
described in the Safety Data Sheet. The user's attention is drawn to the possible existence of additional provisions which
complete these regulations. Refer to all applicable national, international and local regulations or provisions.
16. OTHER INFORMATION
A. SOURCE OF DATA :
Guideline for Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
EC-ECB, International Uniform Chemical Information Database (IUCLID)
Hazardous Substances Data Bank (HSDB)
Registry of Toxic Effects of Chemical Substances (RTECS)
National Institute of Technology and Evaluatio -NITE (Japan).
NFPA 704 Standard System for the Identification of the Hazards of Materials for Emergency Response.
International Chemical Safety Cards(ICSC)(http://www.nihs.go.jp/ICSC)
3E Company/Ariel WebInsight DB.
B. THE DATE OF PREPARATION OF THE MSDS : May 16, 2008
C. THE DATE OF PREPARATION OF THE LATEST REVISION
: January 1, 2024
D. OTHER INFORMATION
:
The above information is believed to be correct but does not propose to be all inclusive and shall be used only
as a guide. Sebang Global Battery CO.,Ltd. shall not be held liable for any damage resulting from handling or
from contact with the above product. Each individual should make a determination as to the suitability of the
information for their particular purpose(s). Various government agencies may have specific regulations
regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by
this MSDS. The user is responsible for full compliance.
Support on preparation of the GHS-MSDS: RGB Chemicals Co.,Ltd. +82-2-597-0645
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