Chemistry Unit 5 Review Name: ___________________

Date: ______
Useful Information: q = m•cp•∆T; cp = specific heat capacity (J/g•°C); ∆T = Tf – Ti; ∆H°rxn = ∑ Hf°products - ∑ Hf°reactants

Multiple Choice: Choose the single most correct answer.

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1. _____ Given the following thermochemical equations:

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N2 (g) + 2 O2 (g) à 2 NO2 (g) ∆H° = 66.4 kJ
2 NO (g) + O2 (g) à 2 NO2 (g) ∆H° = -114 kJ
Use Hess’s Law to calculate the value for ∆H° for the equation shown below:
in
N2 (g) + O2 (g) à 2 NO (g) ∆H° = ?
A. 181 kJ B. -47.8 kJ C. 47.8 kJ D. 90.3 kJ

2. D
_____ Using ∆H°rxn = ∑ Hf°products - ∑ Hf°reactants, determine the value of ∆H° for the following reaction.
Ca(OH)2 (s) + 2 H3AsO4 (aq) à Ca(H2AsO4)2 (aq) + 2 H2O (l)
Given: Substance ∆Hf° (kJ/mole)
Ca(OH)2 -986.6
H3AsO4 -900.4
Ca(H2AsO4)2 a -23467
H2 O -285.9
A. -744.9 kJ B. -4519 kJ C. -4219 kJ D. -130.4 kJ E. none of these

3. _____ In the lab, you mix two solutions (each originally at the same temperature) and the temperature of
the resulting solution decreases. Which of the following is true?
A. The chemical system releases energy B. The energy released is equal to m•c•∆T
C. The chemical system absorbs energy
E. More than one of these
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D. The chemical reaction is exothermic

4. _____ Which oneown difference

of the following is true concerning enthalpy?

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A. it is an intensive property, always having the units energy per mole
B. it usually is largely different in magnitude than the internal energy of a process
C. it is a state function isn't it D. it is measured under conditions of constant volume
E. the enthalpy change of a reaction is the inverse of the enthalpy change of the reverse reaction
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Use the following equations to answer the next 2 questions.
I Na (s) + ½ F2 (l) à NaF (s) + 110 kcal
II Na (s) + ½ F2 (g) à NaF (s) + 136 kcal
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5. _____ Which one of these statements about Equation I is false?
A. The Potential Energy of NaF is less than that of the reactants.
B. If the reaction occurs in an insulated container, the temperature in the container will rise. mom

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C. For each mole of NaF(s) formed, 110 kcal of heat is released.
D. The potential energy of the reactants is less than that of the products.

6. B
_____ The formation of 7.0 g of NaF (s) in Equation II is accompanied by the release of which amount
of heat? A. 17 kcal B. 23 kcal C. 55 kcal D. 136 kcal

7. c
_____
41.9989 1
15 1360 22.661
Of the following 100.0g samples, which would have its temperature change the least by addition of
600.0 joules of heat?
A. iron, cp = 0.449 J/g•ºC B. copper, cp = 0.385 J/g•ºC C. aluminum, cp = 0.897 J/g•ºC

8. _____ The value of ∆H° for the following reaction is -336 kJ. Determine the amount of heat (in kJ)
exchanged with the surroundings when 23.0 g of HCl is formed in the following thermochemical reaction.
CH4 (g) + 3 Cl2 (g)336à CHCl3 (l) + 3 HCl (g)
A. 177 B. 2.57 x 103 C. 70.7 D. 211

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 Problems: For calculation questions-show all calculation work for full credit. Provide answers with the proper units and
significant figures.

9. Using the information below, calculate ∆Hf° for CuO (s): Cu (s) + ½ O2 (g) à CuO (s)
Cu2O (s) + ½ O2 (g) à 2 CuO (s) ∆H° = -144 kJ

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Cu2O (s) à Cu (s) + CuO (s)
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∆H° = + 11 kJ
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10. For the following reaction:

2 C2H2(g) + 5 O2 (g) à 4 CO2 (g) + 2 H2O (l)
a) Calculate the Enthalpy of Reaction (∆H) 0
(Listed here are the ∆Hf°: C2H2 (g) = +226.7 kJ/mol; CO2 (g) = -393.5 kJ/mol; H2O (l) = -285.8 kJ/mol )

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b) Place the reactants and products on a Potential Energy Diagram:

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c) Is the reaction endothermic or exothermic?
exothermic
d) Which has more potential energy: the reactants or the products?
reactants
e) Does the potential energy (enthalpy) of the system increase or decrease through the process of this reaction?
decrease
f) Which is greater for this reaction: the energy absorbed by breaking bonds, or the energy released by
forming bonds?
energy released by forming bonds
g) How many grams of C2H2 (g) are needed to give off 560 kJ of heat by the thermochemical reaction?

2 12.011 2 1.008 26.038

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b11. When 50.0 g of BaI2 is mixed with 50.0 g of a dilute H2SO4 solution (in excess) in a coffee-cup calorimeter, the
temperature of the mixed solutions increases by 0.55°C. The temperature increase is caused by the following reaction:
H2SO4 (aq) + BaI2 (aq) à BaSO4 (s) + 2 HI (aq)

Calculate the enthalpy change (∆H) for the reaction in kJ/mol BaI2 (aq), assuming the combined solution has a mass of
100.0 g.
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1T 100g 0
1 230.12

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1137.3281 2126.904 391.136 as
50.0gBatzX 391 0.128not Bat
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12. Find ∆H for this reaction: H2O (l) à H2 (g) + ½ O2 (g) [Link]
Given: CO2 (g) + 688.6 kJ à C (s) + O2 (g)

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CO2 (g) + 2 H2O (l) + 1558.4 kJ à CH4 (g) + 2 O2 (g)
C (s) + 2 H2 (g) à CH4 (g) + 130.9 kJ
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13. Write the formation reaction for ammonium carbonate. (NH4)2CO3.

(∆H for this reaction is the “heat of formation” for ammonium carbonate)

9 4H 9 Clg 320 g NHy263 s

14. The chemical equation for photosynthesis is

6 CO2(g) + 6 H2O(l) à C6H12O6(s) + 6 O2(g) ΔH rxn = 2801 kJ
6 393.5 6 285.8
Given this information and your Heat of Formation Table, calculate the heat of formation of glucose, C6H12O6 (s).

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2801k X 1 4075.8

4 1 40758
1275140 [Link]/worksheets/Gen_Chem_1/Chp6,Hess's_Law.doc

15. a) What combination of change in entropy (ΔS) and change in enthalpy (ΔH) will lead to a spontaneous
(thermodynamically favored) process at any temperature?

b) What combination of ΔS and ΔH will lead to a spontaneous process only at low temperatures?

16. In which of the following processes does entropy increase from reactants to products?

2 H2 (g) + O2 (g) à 2 H2O (g) 2 Hg (l) + O2 (g) à 2 HgO (s)

H2O (s) à H2O (l) 2 NO2 (g) à N2O4 (g)

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IN ADDITION:

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*To study the Unit 5 information, use your class notes to define the terms: “temperature”, “thermal (kinetic)
energy”, “heat”, “potential energy”, “activation energy”, “catalyst”, “change in enthalpy (heat of reaction)”,
“state function”, “specific heat capacity”, and “entropy”.

*List the many differentTreat it tales

ways in which you
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can distinguish an endothermic
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reaction from an exothermic reaction
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(what the potential energy diagram looks like, which side the kJ term goes on, whether the solution gets hotter or
colder, etc.).
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started