Gandaki Boarding School

(National School) 10. Batch process is used to manufacture of ……….

Lamachaur, Pokhara a. petrol b. cement c. H2SO4 d. cosmetics
FINAL EXAMINATIONS, 2080
Grade: XI Time: 3 hours FM=75 11. Nitrogen content in urea is about ……….
Subject: Chemistry a. 46% b. 36% c. 56% d. 66%
Candidates are required to give their answers in their own words as far as Group B: Short Answer Questions (8x5=40)
practicable. The figures in the margin indicate full marks. 1. A chemical reaction is carried out by mixing 25 g pure CaCO3 and 0.75
mol of pure HCl to give CaCl2, H2O and CO2. [2]
a. Find out which one limiting reagent and why?
Group A: Multiple choice Questions (11x1=11)
b. Calculate the mass of unreacted reagent left over. [1]
1. Number of atoms present in 0.1 mole of water is ……….
c. How many number of water molecules are produced? [1]
a. 0.1 NA b. 0.2 NA c. 0.3NA d.0.4NA
d. What mass of NaOH is required to absorb the whole CO2 produced? [1]
2. The type of bond in NH4Cl is ………….
a. covalent only b. covalent + ionic
2. a. Quantum numbers consist of a set of four numbers which give
c. ionic only d. Covalent + Ionic + co-ordinate covalent
complete information about the electron in an atom. An atom has 20
electrons. Find out the values of azimuthal quantum number and (l) and
3. The charge of one mole of electron is ……….
magnetic quantum number (m) of the 19th electron. [2]
a. 96500 F b. 1 F c. 1 C d. 97500 C
b. what are the differences between atomic orbit and atomic orbitals. Draw
the shapes of s and p orbitals. [3]
4. CO on heating with Ni gives …….
a. Ni(CO)4 b. Ni(CO)3 c. Ni(CO)2 d. Ni2(CO)8
3. a. Define ionization energy and atomic radius. [1]
b. Arrange the elements Na, Li and K in the increasing order of first
5. The oxidizing power of halogens is in the order …………
ionization energy with reason. [2]
a. F2 > Cl2 > Br2 > I2 b. F2 < Cl2 < Br2 < I2
c. Which of the following has larger electron affinity in between Cl and F?
c. C2 > F2 > Br2 > I2 d. Br2 > Cl2 > F2 > I2
Explain with suitable reason [2]
6. Which of the following is the correct sequence of solubility trend of
4. There are several theories related to the chemical bonding like Octet
hydroxide of alkaline earth metals
theory, VSEPR theory, Valence bond theory, Concept of hybridization
a. Ba(OH)2 < Sr(OH)2 < Ca(OH)2 < Mg(OH)2 < Be(OH)2
etc.
b. Ba(OH)2 > Sr(OH)2 > Ca(OH)2 > Mg(OH)2 > Be(OH)2
a. Predict the geometry of BeCl2 and BF3 according to the VSEPR theory. [1]
c. Sr(OH)2 < Ba(OH)2 < Ca(OH)2 < Mg(OH)2 < Be(OH)2
b. What is the mode of hybridization of the central atom whose molecular
d. Mg(OH)2 < Sr(OH)2 < Ca(OH)2 < Ba(OH)2 < Be(OH)2
geometry is tetrahedral? Give an example also draw the orbital picture of
it. [2]
7. Sodium – Potassium pump is an example of
c. H2S is in gaseous state whereas H2O is in liquid state. Explain it with
a. Primary active transport protein b. Secondary active transport protein
suitable reason. [2]
c. primary passive transport protein d. secondary passive transport protein
8. Lassaigne’s test can detect ………… in organic compound
5. a. Balance the following equation by oxidation number method or ion
a. nitrogen b. oxygen c. phosphorus d. iron
electron method. [3]
I2 + HNO3 → HIO3 + NO2 + H2O
9. Typical reaction of aromatic compound is …………
b. Calculate the number of coulomb of electricity required to discharge
a. electrophilic addition b. nucleophilic addition
0.3 mole of Zn2+ [2]
c. free radical addition d. electrophilic substitution
OR
 Chemical equilibrium is the state of reversible reaction in which both the 9. a. The idea that particles of gases are moving has been used to explain
reactant and product are present in concentration which have no further the behavior of gases under different conditions.
tendency to change with time, so that there is no observable change in the i. Draw a sketch of P against 1/V at constant temperature and V against T
properties of the system. (°C) at constant pressure for a constant number of moles of ideal gas. (1)
a. Write the characteristics of equilibrium constant. [1] ii. A mixture of two gases in container exerts pressure of 800mm Hg and
b. Write the expression for the equilibrium constant (Kc) for the following occupies a volume of 300 cc. If one of these gases, ‘X’ occupies a volume
reaction. [2] of 400cc at the same temperature and pressure, what pressure does the
i. CaCO3 (s) ⇋ CaO (s) + CO2 (g) other gas ‘Y’ exert in the mixture? What would be the effect on the partial
ii. 4NO (g) + 6H2O (g) ⇋ 4NH3 (g) + 5O2 (g) pressure of the gases ‘X’ and ‘Y’ if 100 cc of He is added to the gaseous
mixture at the same temperature and pressure. [3+1]
c. How can you apply Le-Chatelier’s principle for the better yield of b. Give Reason (2)
ammonia by using Haber’s process. [2] i. Rain drops are spherical. ii) Water moves faster than glycerine.
c. Define Hygroscopic substance with an example. [1]
6 a) Hydrogen gas is a direct source of clean energy and has application in
food industries, petrochemical refinery, cutting/welding, metallurgy, etc. 10. a. How is nitric acid is manufactured by Ostwald’s process? Describe
i What is nascent hydrogen. [1] with principle involved and flow sheet diagram. [4]
ii. Show that nascent hydrogen is powerful reducing agent than molecular b. How is ring test for nitrate ion done? Explain with reaction involved. [2]
hydrogen. Giving two examples. [2] c. How is bleaching action of SO 2 differ from Cl2. Write in any two points.
b) Justify that OF2 is not oxide but OCl2 is oxide. [2] [2]
OR OR
Metallurgy is the process of extraction of metal from their ores. The a. How is sodium hydroxide manufactured? Describe with principle
methods for the extraction of metals from their ores varies from metal to involved and flow suitable diagram? [4]
metal. b. Write down the reaction involved in the following conditions.
a. Show your acquaintance to the froth floatation process with necessary i. Sulphuric acid as a dehydrating agent. [1]
diagram. [3] ii. Laboratory preparation of chlorine. [1]
b. Write any two differences between Calcination and Roasting. [2] iii. Precipitation of salt solution by using sodium hydroxide. [1]
iv. Reaction of ammonia with mercurous nitrate paper. [1]
7. a. Define homologous series. Write down the structure and IUPAC name 11. a. An unsaturated hydrocarbon A is subjected to ozonolysis followed by
of 3rd member of aldehyde. [3] hydrolysis with zinc and water gives Methanal and Propanal. Compound A
b. A monochloroalkane ‘A’ undergoes dehydrohalogenation to give upon treatment with Hydrogen bromide in presence of organic peroxide
ethene. produces compound B. Compound B reacts with Na metal in presence of
i. Write the reaction involved. [1] dry ether produces compound C having molecular formula C8H18.
ii. Give the chemical test for ethene. [1] i) Give all the chemical reactions involved in the above conversion from A
to B and B to C. [2]
8 a. Complete the following reaction sequence by identifying compounds A ii) Write down the IUPAC name of compound A, B and C. [1]
and B. Also write their IUPAC names iii) Give the possible isomers of compound B. [2]
CHCl3 Ag→, Δ A H 2 O, H 2 SO 4 , Hg SO 4 B b. Identify the compounds A, B and C in following reaction scheme and
→ give their names. [3]
b. Show your familiarity to the following reactions. [3]
i. Wurtz reaction ii. Markovnikov’s addition iii. Friedel craft
alkylation
Group ‘C’ Long Answer Questions (3x8=24)
……… XXXX……….