SR NEET G2
Part - A Chemistry
Section - I: Single Correct
This section contains a total of 35 questions.
All questions in this section are mandatory.
For every correct response you shall be awarded 4 marks.
For every incorrect response -1 marks shall be deducted.
For more details refer the first page of this booklet.
1. Which of the following belongs to the class of vinyl 8. The final product of the following reaction is
halides?
(a) CH 2 = CH–CHBr–CH 3
(b)
(c) HC≡C–Br
(d) CH 3–CH = CH–CH 2–Br
(a)
2. Statement I: Chlorobenzene on reaction with sodium metal
in the presence of dry ether gives diphenyl.
Statement II: This reaction is called Ullmann reaction.
Statement I and Statement II are true and the
(a) Statement II is the correct explanation of the
Statement I
Statement I and Statement II are true but the
(b) Statement II is not the correct explanation of the (b)
Statement I
(c) Statement I is true but Statement II is false
(d) Statement I and Statement II are false
3. The reaction, CH 3Br + OH – → CH 3OH + Br–
(c)
proceeds mainly by the mechanism
(a) SN 1 (b) SN 2 (c) SE1 (d) SE2
4. Ethylene dichloride and ethylidene chloride are isomeric (d)
compounds. The false statement about these isomers is
that they
(a) are both hydrolysed to the same product 9. C6H 5CH 2Cl + KCN(aq.) → X + Y Compounds X and Y are:
(b) contain the same percentage of chlorine
(a) C6H 5CN + KCl (b) C6H 5CH 2CN + KCl
(c) are position isomers
react with alcoholic potash and give the same (c) C6H 5CH 3 + KCl (d) None of these
(d)
product
10. The reactivity of ethyl chloride is:
5. Which reaction is termed as Darzen’s Reaction (a) More or less equal to that of benzyl chloride
(a) ROH + HCl (b) ROH + PCl5 (b) More than that of chlorobenzene
(c) ROH + SOCl2 (d) ROH + PCl3 (c) More or less equal to that of chlorobenzene
(d) Less than that of chlorobenzene
6. Grignard reagent is prepared by the reaction between:
11. The hydrogen atom in chloroform is -
(a) Zinc and alkyl halide
(a) Acidic (b) Basic
(b) Magnesium and alkyl halide
(c) Magnesium and alkane (c) Neutral (d) None of these
(d) Magnesium and aromatic hydrocarbon 12. Which of the following is a secondary alkyl halide?
7. The compound formed on heating chlorobenzene (a) Isobutyl chloride (b) Isopentyl chloride
with chloral in the presence of concentrated sulphuric acid,
is: (c) Neopentyl chloride (d) Isopropyl chloride
(a) Freon (b) DDT
(c) Gammexene (d) Hexachloroethane
ASHWAMEDHA IIT-JEE, NEET ACADEMY: Tirupati, Andhra Pradesh
SR NEET G2
13. Consider the following reaction: (d)
19. (p-ClC6H 4)2CHCCl3 is used as a/an
(a) Antiseptic for wounds
(b) Insecticide
The reaction proceeds with 98% racemisation. The reaction
(c) Pyrene
may follow
(d) Refrigerant
(a) SN1 mechanism (b) SN2 mechanism
(c) E1 mechanism (d) E2 mechanism. 20. The decreasing order of reactivity towards
dehydrohalogenation (E1) reaction of the following
14. Statement I: compounds is :
(I)
on reaction with KNH 2 gives but-1-ene as major product.
Statement II: It follows E1CB mechanism.
(II)
Statement I and Statement II are true and the
(a) Statement II is the correct explanation of the
Statement I
Statement I and Statement II are true but the (III)
(b) Statement II is not the correct explanation of the
Statement I
(c) Statement I is true but Statement II is false
(d) Statement I and Statement II are false
(IV)
15. Which of the following is most reactive towards aqueous
NaOH?
(a) C6H 5Cl (b) C6H 5CH 2Cl
(c) C6H 5Br (d) BrC6H 4Br
(a) I > II > III > IV
16. Which of the following alkyl halides has the maximum (b) I > II > IV > III
density.
(c) IV > II > I > III
(a) C2H 5Cl (b) C2H 5Br (c) C2H 5I (d) C2H 5F (d) III > II > IV > I
17. 21. The correct sequence of bond enthalpy of ‘C—X’ bond is :
(a) CH 3 – F < CH 3 – Cl > CH 3 – Br > CH 3 – I
(b) CH 3 – Cl >CH 3 – F > CH 3 – Br > CH 3 – I
(c) CH 3 – F < CH 3 – Cl < CH 3 – Br < CH 3 – I
Select the incorrect statement for the SN 2 mechanism in
given figure. (d) CH 3 – F > CH 3 – Cl > CH 3 – Br > CH 3 – I
As reaction progress, bond between carbon atom and
(a) nucleophile is formed with weakening of carbon atom 22. CHI3 is used as a/an
and the leaving group bond (a) Antiseptic for wounds
(b) There is the inversion of configuration (b) Insecticide
The transition state is unstable and cannot be (c) Pyrene
(c)
isolated (d) Refrigerant
Carbon atom is bonded to four atoms during the
(d) 23. Chloroform can be obtained from -
transition state
(a) Methanol (b) Methanal
18. Identify (Z) in the following reaction series,
Alcoholic Br2 KCN (c) Propanol–1 (d) Propanol– 2
C2 H 5 I −−−−−→ (X) −
−→ (Y) −−
−→ (Z)
KOH
24. Benzyl chloride when oxidised by Pb(NO3)2 gives:
(a)
(a) Benzoic acid (b) Benzaldehyde
(b)
(c) Benzene (d) None
(c)
ASHWAMEDHA IIT-JEE, NEET ACADEMY: Tirupati, Andhra Pradesh
SR NEET G2
25. The major product obtained in the follwing reaction is:
(b)
(a) C6H 5CH = CHC6H 5
(b) (+)C6H 5CH(OtBu)CH 2C6H 5
(c) (-)C6H 5CH(OtBu)CH 2C6H 5
(c)
(d) (±) C6 H 5 CH(OtBu)CH 2 C6 H 5
26. The IUPAC name of the compound
CH 3 – CH = CH – CH 2 – Br is
(a) 4-Bromobut-2-ene (b) 1-Bromobut-2-ene
(c) 3-Bromobut-2-ene (d) Allyl bromide
(d)
27. Given below are two statement one is labeled as Assertion
(A) and the other is labeled as Reason (R).
Assertion (A): CH 2 = CH – CH 2 – Cl is an example of allyl
halide
Reason (R): Allyl halides are the compounds in which the 31. C6H 5Cl prepared by aniline with:
halogen atom is attached to sp2 hybridized carbon atom. (a) HCl
In the light of the two above statements, choose the most (b) Cu 2Cl2
appropriate answer from the options given below:
(a) (A) is true but (R) is false (c) Cl2 in presence of anhydrous AlCl3
Both (A) and (R) are true but (R) is not the correct (d) HNO2 and then heated with Cu 2Cl2
(b)
explanation of (A)
32.
(c) (A) is false but (R) is true
Both (A) and (R) are true and (R) is the correct
(d)
explanation of (A)
Above equilibrium is more towards right because
28. The reactivity of halogens towards of alkanes decreases in (a) NaI is more reactive than NaCl
order :
(b) CH 3I is more reactive than CH 3Cl
(a) F 2 > Cl2 > Br2 > I2
(c) NaCl is less soluble than NaI in acetone
(b) I2 > Br2 > Cl2 > F 2
(d) It is Finkelstein’s reaction
(c) Cl2 > F 2 > I2 > Br2
33. Arrange the following alkyl halides in order of
(d) F 2 > Br2 > I2 > Cl2 dehydrohalogenation;
C2H 5F, C2H 5Cl, C2H 5Br, C2H 5I
29. Tertiary alkyl halides are practically inert to substitution by
SN 2 mechanism because (a) C2H 5F > C2H 5Cl > C2H 5Br > C2H 5I
(a) The carbocation formed is unstable (b) C2H 5I > C2H 5Br > C2H 5Cl > C2H 5F
(b) There is steric hindrance (c) C2H 5I > C2H 5Cl > C2H 5Br > C2H 5F
(c) There is inductive effect
(d) C2H 5F > C2H 5I > C2H 5Br > C2H 5Cl
(d) The rate of reaction is faster in SN 2 mechanism.
34. The increasing order of nucleophilicity of the following
30. Which of the following potential energy (PE) diagrams nucleophiles is :
represents the SN 1 reaction?
(a) (b) H2 O
⊖
CH 3 CO
2
(c) CH3 SO⊖
3
(d) OH
(a) (d) < (a) < (c) < (b)
(a)
(b) (b) < (c) < (d) < (a)
(c) (a) < (d) < (c) < (b)
(d) (b) < (c) < (a) < (d)
ASHWAMEDHA IIT-JEE, NEET ACADEMY: Tirupati, Andhra Pradesh
SR NEET G2
Inversion of configuration occurs at the carbon
35. Which describes the best stereochemical aspects of the (a)
undergoing substitution.
following reaction ?
Retention of configuration occurs at the carbon
(b)
undergoing substitution.
Racemization occurs at the carbon undergoing
(c)
substitution.
The carbon undergoing substitution is not
(d)
stereogenic.
Section - II: Single Correct - Sec. 2
This section contains a total of 15 questions.
Out of the 15 questions, 10 questions are mandatory.
For every correct response you shall be awarded 4 marks.
For every incorrect response -1 marks shall be deducted.
For more details refer the first page of this booklet.
36. Which of the following acts as a poisonous gas?
(d)
(a) COCl2 (b) CCl2F 2 (c) Benzene (d) CH 3Cl
37. Ethylene difluoride on hydrolysis gives: 41. For the reaction C2H 5OH + HX → C2H 5X + H 2O
(a) Glycol (b) Fluoroethanol The order of reactivity is
(c) Difluoroethanol (d) Freon (a) HCl > HBr > HI
(b) HI > HBr > HCl
38. In the given reactions sequence, the major product 'C' is:
(c) HBr > HCl > HI
(d) HI > HCl > HBr
42.
(a)
(b) Consider the above chemical reaction. Product "A" is:
(a)
(c)
(b)
(d)
(c)
39. The ease of dehydrohalogenation of alkyl halide with
alcoholic KOH is (d)
(a) 3o < 2o < 1o
(b) 3o > 2o > 1o 43. Assertion: SN 1 reactions are generally carried out in polar
(c) 3o < 2o > 1o protic solvents (like water, alcohol, acetic acid, etc.)
Reason: C6H 5CH(C6H 5)Br is less reactive than
(d) 3o > 2o < 1o
C6H 5CH(CH 3)Br in SN 1 reactions.
40. Which of the following will most readily give the Both assertion and reason are true, and the reason is
dehydrohalogenation product? (a)
the correct explanation for the assertion.
Both assertion and reason are true, but the reason is
(a) (b)
not the correct explanation for the assertion.
(c) Assertion is true but reason is false.
(b) (d) Both Assertion and reason are false.
44. Which of the following would be produced when
acetylene reacts with excess of HCl?
(c)
(a) CH 3CH 2Cl (b) CH 3CHCl2
ASHWAMEDHA IIT-JEE, NEET ACADEMY: Tirupati, Andhra Pradesh
SR NEET G2
(c) CHCl = CHCl (d) CH 2 = CHCl 48. Grignard reagent, a very useful starting compound for a
number of organic reactions can be prepared by
45. Assertion: Melting points of isomeric dihalobenzenes are Reaction of alkyl halides with a solution of
nearly the same. (a)
magnesium hydroxide
Reason: Isomeric dihalobenzenes have different molecular Reaction of alkyl halides with dry magnesium powder
masses. (b)
in Presence of dry ether
Both assertion and reason are true, and the reason is
(a) (c) Reaction of MgCl2 with ether and alcohol
the correct explanation for the assertion.
Both assertion and reason are true, but the reason is Reaction of alkyl halide with magnesium in presence
(b) (d)
not the correct explanation for the assertion. ofalcohol
(c) Assertion is true but reason is false. 49. An organic halogen compound which is used as
(d) Both Assertion and reason are false. refrigenrant in refrigerators and air conditioners is
(a) BHC (b) CCl4 (c) Freon (d) CHCl3
46. Phosgene is the common name for:
(a) PH 3 50. Which of the following may be classified as an aryl halide?
(b) Phosphoryl chloride
(a)
(c) Carbonyl chloride
(d) Carbon tetrachloride
(b)
47. Which of the following isthe most reactive towards
nucleophilic substitution reaction?
(c)
(a) ClCH 2–CH=CH 2 (b) CH 2=CH–Cl
(c) CH 3CH=CH–Cl (d) C6H 5Cl
(d)
ASHWAMEDHA IIT-JEE, NEET ACADEMY: Tirupati, Andhra Pradesh
