Prayas JEE (2025)

MANTHAN
Chemistry Some Basic Concepts of Chemistry
Exercise-1 8. 1 mol of CH4 contains:
(a) 6.02 × 1023 atoms of H
(b) 4 g-atom of Hydrogen
FUNDAMENTAL QUANTITIES, LAWS OF (c) 1.81 × 1023 molecules of CH4
CHEMICAL COMBINATION (d) 3.0 g of carbon
9. 7.5 grams of a gas occupy 5.6 litres of volume at STP, the
1. Express the result of (0.582 + 324.65) to the appropriate
gas is:
number of significant figures:
(a) NO (b) N2O (c) CO (d) CO2
(a) 325.24 (b) 325.23
10. The number of atoms in 4.25 g of NH3 is approximately:
(c) 325.2 (d) 325.232
(a) 1 × 1023 (b) 2 × 1023 (c) 4 × 1023 (d) 6 × 1023
2. The correctly reported answer of the area of rectangle which
11. One litre of a gas at STP weighs 1.16 g. The possible gas is:
is 12.34 cm long and 1.23 cm wide is :
(a) C2H2 (b) CO
(a) 15.2 m2 (b) 15.2 cm2 (c) O2 (d) CH4
(c) 15.1 cm­ 2 (d) 15.17 cm2
12. The mass of a molecule of water is approximately:
3. If an object has a mass of 0.2876 g, then find the mass of (a) 3 × 10–26 kg (b) 3 × 10–25 kg
nine such objects: –26
(c) 1.5 × 10 kg (d) 2.5 × 10–26 kg
(a) 2.5884 g (b) 2.5886 g (c) 2.588 g (d) 2.5 g 13. If N A is Avogadro’s number, then number of valence
4. Two elements X and Y combine in gaseous state to form electrons in 4.2 g of nitride ions (N3–) is:
XY in the ratio 1:35.5 by mass. The mass of Y that will be (a) 2.4 NA (b) 4.2 NA
required to react with 2 g of X is: (c) 1.6 NA (d) 3.2 NA
(a) 7.1 g (b) 3.55 g (c) 71 g (d) 35.5 g 14. The number of molecules at STP in 1 ml of an ideal gas will be:
(a) 6 ×1023 (b) 2.69 × 1019
5. 4.4 g of an oxide of nitrogen gives 2.24 L of nitrogen and 23
(c) 2.69 ×10 (d) None of these
60 g of another oxide of nitrogen gives 22.4 L of nitrogen
15. Volume of a gas at STP is 1.12 × 10–7 cc. The number of
at S.T.P. The data illustrates:
molecules in it are:
(a) Law of conservation of mass (a) 3.01 × 1020 (b) 3.01 × 1012
(b) Law of constant proportions (c) 3.01 × 10 23 (d) 3.01 × 1024
(c) Law of multiple proportions 16. 4.4 g of an unknown gas occupies 2.24 L of volume at
(d) Law of reciprocal proportions standard temperature and pressure. The gas may be:
6. Two elements X and Y combine to form compounds A, B (a) Carbon dioxide (b) Carbon monoxide
and C. The ratio of different masses of Y which combine (c) Oxygen (d) Sulphur dioxide
with a fixed mass of X in A, B and C is 1 : 3 : 5. If 32 parts 17. The number of oxygen atoms in 4.4 g of CO2 is approx.:
by mass of X combines with 84 parts by mass of Y in B, (a) 1.2 × 1023 (b) 6 × 1022
then in C, 16 parts by mass of X will combine with; (c) 6 × 1023 (d) 12 × 1023
(a) 14 parts by mass of Y (b) 42 parts by mass of Y 18. The total number of protons in 10 g of calcium carbonate
(c) 70 parts by mass of Y (d) 84 parts by mass of Y is: (NA = 6.022 × 1023)
(a) 1.5057 × 1024 (b) 2.0478 × 1024
ATOMIC MASS & MOLECULAR MASS, MOLE (c) 3.0115 × 10 24 (d) 4.0956 × 1024
CONCEPT AND APPLICATIONS 19. Number of molecules in 100 ml each of O2,NH3 and CO2
7. 1 amu is equal to: at STP are:
(a) In the order: CO2 < O2 < NH3
1
(a) of mass of C12 atom (b) In the order: NH3 < O2 < CO2
12
(c) The same in all
1 (d) In the order: NH3 < CO2 < O2
(b) of mass of O16 atom
14
20. The number of water molecules in 1 litre of water is:
(c) 1 g of H2 (a) 18 (b) 18 × 1000
(d) 1.66 × 10–23 kg
(c) NA (d) 55.55 NA

1
 21. 2 g of oxygen contains number of atoms equal to that in: 35. 0.02 gm of an unknown substance is dissolved in 3.9 gm of
(a) 0.5 g of hydrogen (b) 4 g of sulphur benzene. The molality of solution is 0.08 m.Calculate the
(c) 7 g of nitrogen (d) 2.3 g of sodium molecular mass of unknown substance:
(a) 60 g/mol (b) 164 g/mol
PERCENTAGE COMPOSITION, EMPIRICAL (c) 264 g/mol (d) 64.1 g/mol
FORMULA & MOLECULAR FORMULA 36. A 500 g solution has 0.1 g fluoride concentration. Then
fluoride concentration in term of ppm will be:
22. Caffeine has a molecular weight of 194. If it contains 28.9%
(a) 200 ppm (b) 100 ppm
by mass of nitrogen, number of atoms of nitrogen in one
molecule of caffeine is: (c) 400 ppm (d) 50 ppm
(a) 4 (b) 6 (c) 2 (d) 3
23. The percentage of oxygen in NaOH is: STOICHIOMETRY, EQUATION BASED
(a) 40 (b) 60 (c) 8 (d) 10 CALCULATIONS
24. A compound (60 g) on analysis gave C = 24 g, H = 4 g,
37. In the reaction;
O = 32 g. Its empirical formula is:
(a) C2H2O2 (b) C2H2O (c) CH2O2 (d) CH2O 4NH3(g) + 5O2 (g) → 4NO(g) + 6H2O(g), when 1 mole
of ammonia and 1 mole of O 2 are made to react to
25. What is the % of H2O in Fe(CNS)3.3H2O? completion:
(a) 45 (b) 30 (c) 19 (d) 25
(a) 1.0 mole of H2O is produced.
26. A hydrocarbon contains 86% carbon, Then, the hydrocarbon
(b) 1.0 mole of NO will be produced.
is an:
(c) All the oxygen will be consumed.
(a) Alkane (b) Alkene (c) Alkyne (d) Arene
(d) All the ammonia will be consumed.
27. The simplest formula of a compound containing 50% of
element X (atomic mass 10) and 50% of element Y (atomic 38. H2 evolved at STP on complete reaction of 27 g of aluminium
mass 20) is: with excess of aqueous NaOH would be:
(a) XY (b) X2Y (c) XY3 (d) X2Y3 3
Al + H 2 O + NaOH → NaAlO 2 + H 2
28. Haemoglobin contains 0.33% of iron by weight. The 2
molecular weight of haemoglobin is approximately 67,200. (a) 22.4 litres (b) 44.8 litres
The number of iron atoms (At. wt. of Fe = 56) present in
(c) 67.2 litres (d) 33.6 litres
one molecule of haemoglobin is:
(a) 6 (b) 1 (c) 4 (d) 2 39. 12 g of Mg (at. mass 24) will react completely with acid to
give:
CONCENTRATION TERMS (a) One mole of H2
(b) 1/2 mole of H2
29. What is the molarity of NaOH solution if 250 mL of it
(c) 2/3 mole of O2
contains 1 mg of NaOH?
(d) Both 1/2 mol of H2 and 1/2 mol of O2
(a) 10–1 M (b) 10–2 M (c) 10–4 M (d) 10–3 M
40. 100 g CaCO3 reacts with 1 litre 1 N HCl. On completion of
30. Molarity of H2SO4 (density 1.8 g/mL) is 18 M. The molality reaction, how much weight of CO2 will be obtained?
of this H2SO4 is: (a) 5.5 g (b) 11 g (c) 22 g (d) 33 g
(a) 36 (b) 200 (c) 500 (d) 18 41. What weight of HNO3 is needed to convert 5 g of iodine
31. The percentage of sodium in a breakfast cereal be labeled into iodic acid according to the reaction,
as 110 mg of sodium per 100 g of cereal is I2 + 10HNO3 → 2HIO3 + 10NO2 + 4H2O
(a) 11% (b) 1.10% (c) 0.11% (d) 1.10% (a) 12.4 g (b) 24.8 g (c) 0.248 g (d) 49.6 g
32. 200 ml, 3M NaOH is mixed with 300 ml 2 M NaOH forming 42. How much Cl2 at STP is liberated when 1 mole KMnO4
a solution of density 1200 Kg/m3 . Then molality of final reacts with HCl?
solution is : (a) 11.2 L (b) 22.4 L (c) 44.8 L (d) 56 L
(a) 2.2 m (b) 3 m (c) 2.4 m (d) 2 m 43. 27 g of Al will react completely with how many grams of
oxygen?
33. Calculate molality of 0.2 M urea solution having density
(a) 8 g (b) 16 g (c) 32 g (d) 24 g
1.2 gm/ml.
44. If 0.50 mole of BaC12 is mixed with 0.20 mol of Na3PO4,
1 1 1 1
(a) ≈ m (b) ≈ m (c) ≈ m (d) ≈ m the maximum number of moles of Ba3(PO4)2 that can be
6 3 9 12 formed is:
34. Commercial HNO2(aq) has density 1.41 g/ml and is 10M. (a) 0.70 (b) 0.50 (c) 0.20 (d) 0.10
Then mass percentage of solution is : 45. 0.5 mole of H2SO4 is mixed with 0.2 mole of Ca(OH)2. The
100 maximum number of moles of CaSO4 formed is:
(a) % (b) 50% (c) 75% (d) 25%
3 (a) 0.2 (b) 0.5 (c) 0.4 (d) 1.5

2
 Exercise-2 7. The amount of oxygen in 3.6 moles of water is:
SINGLE CORRECT TYPE QUESTIONS (a) 115.2 g (b) 57.6 g
16 17 18 (c) 28.8 g (d) 18.4 g
1. Oxygen exists as three isotopes 8 O, 8 O, 8 O with
relative abundance 90%, 7% and 3% respectively, then 8. The density of 3 M solution of sodium chloride is
average atomic mass of oxygen is 1.252 g mL–1. The molality of the solution will be :
(a) 16.13 amu (b) 17 amu
(molar mass of NaCl = 58.5 g mol–1)
(c) 17.2 amu (d) 18.13 amu (a) 260 m (b) 2.18 m
(c) 2.79 m (d) 3.00 m
2. For a reaction,
N2(g) + 3H2(g) → 2NH3(g) 9. The ppm level of F– in a 500 g sample of a tooth paste
Identify dihydrogen (H2) as a limiting reagent in the containing 0.2 g F– is
following reaction mixtures. (a) 400 (b) 1000
(a) 56 g of N2 + 10 g of H2 (c) 250 (d) 200
(b) 35 g of N2 + 8 g of H2
(c) 14 g of N2 + 4 g of H2 10. With increase of temperature, which of these changes?
(d) 28 g of N2 + 6 g of H2 (a) molality
(b) weight fraction of solute
3. Molarity of pure D2O will be (assume density of D2O (c) molarity
is 1 g/ml) (d) mole fraction
(a) 55.56 (b) 1
(c) 50 (d) 10 11. One mole of a hydrocarbon requires 100 litres (at STP)
of dioxygen for complete combustion; then what is the
4. If a rocket runs on a fuel (C15H30 ) and liquid oxygen, volume of dioxygen required by its 20th next
the weight of oxygen required and CO2 released for homologue?
every litre of fuel respectively are (Given, density of (a) 175 L (b) 395 L
the fuel is 0.756 g/mL) (c) 772 L (d) 1087 L
(a) 1188 g and 1296 g
(b) 2376 g and 2592 g 12. The modern atomic weight scale is based on :
(c) 2592 g and 2376 g (a) C12 (b) O16
(d) 3429 g and 3142 g (c) H1 (d) N14

5. In a compound C, H and N atoms are present in 13. The charge on 1 gram ions of Al3+ is: (NA = Avogadro
9 : 1 : 3.5 by weight. Molecular weight of compound is number, e = charge on one electron)
108. Molecular formula of compound is 1
(a) N A e coulomb
(a) C2H6 N2 27
(b) C3H4 N 1
(b)  NAe coulomb
(c) C6H8 N2 3
(d) C9H12 N3 1
(c)  NA e coulomb
9
6. If we consider that 1/6, in place of 1/12, mass of (d) 3  N A e coulomb
carbon atom is taken to be the relative atomic mass
unit, the mass of one mole of the substance will 14. Which of the following contains the greatest number of
(a) be a function of the molecular mass of the atoms?
substance (a) 1.0 g of butane (C4H10)
(b) remain unchanged (b) 1.0 g of nitrogen (N2)
(c) increase two fold (c) 1.0 g of silver (Ag)
(d) decrease twice (d) 1.0 g of water (H2O)
3
15. The weight of a molecule of the compound C60H22 is: 23. For the reaction 2P + Q → R, 8 mol of P and 5 mol of
(a) 1.06 10−21 g (b) 1.24 10−21 g Q will produce
(a) 8 mol of R (b) 5 mol of R
(c) 5.025  10−23 g (d) 16.023  10−23 g (c) 4 mol of R (d) 13 mol of R

16. 3g of a hydrocarbon on combustion in excess of oxygen 24. What weights of P4O6 and P4O10 will be produced by
produces 8.8 g of CO2 and 5.4 g of H2O. The data the combustion of 31 g of P4 in 32g of oxygen leaving
illustrates the law of: no P4 and O2.
(a) Conservation of mass (a) 2.75 g, 219.5 g
(b) Multiple proportions (b) 27.5 g, 35.5 g
(c) Constant proportions (c) 55 g, 71 kg
(d) None of these (d) 17.5 g, 190.5 g

17. 16 g of an ideal gas SOx occupies 5.6 L at STP.

The value of x is
(a) x = 3 (b) x = 2 25. 500 mL of a glucose solution contains 6.02  1022
(c) x = 4 (d) none of these molecules. The concentration of the solution is
(a) 0.1 M (b) 1.0 M
18. Boron has two stable isotopes, 10B (relative abundance (c) 0.2 M (d) 2.0 M
= 19%) and 11B (relative abundance = 81 %). The
atomic mass (in amu) that should appear for boron 26. Equal moles of H2O and NaCl are present in a solution.
in the periodic table is: Hence, molality of NaCl solution is :
(a) 10.8 (b) 10.2 (a) 0.55 (b) 55.5
(c) 11.2 (d) 10.6 (c) 1.00 (d) 0.18
M
27. A Solution of FeCl3 is , its molarity for Cl– ion will
19. Calculate the molecular formula of compound which 30
contains 20% Ca and 80% Br (by wt.) if molecular be
weight of compound is 200. (Atomic wt. Ca = 40, Br = M M
80) (a) (b)
90 30
(a) Ca1/2Br (b) CaBr2
M M
(c) CaBr (d) Ca2Br (c) (d)
10 5
20. A compound possess 8% sulphur by mass. The least
molecular mass is: 28. If 500 ml of 1 M solution of glucose is mixed with 500
(a) 200 (b) 400 ml of 1 M solution of glucose final molarity of solution
(c) 155 (d) 355 will be:
(a) 1 M (b) 0.05 M
(c) 2 M (d) 1.5 M
21. If 1.5 moles of oxygen combine with Al to form Al2O3,
29. What volume of a 0.8 M solution contains 100 milli
the weight of Al used in the reaction is:
moles of the solute?
(a) 27 g (b) 40.5 g
(a) 100 mL (b) 125 mL
(c) 54 g (d) 81 g
(c) 500 mL (d) 62.5 mL
22. How many moles of potassium chlorate need to be
30. 2M of 100 ml Na2SO4 is mixed with 3M of 100 ml
heated to produce 11.2 litre oxygen at N.T.P.
1 1 NaCl solution and 1M of 200 ml CaCl2 solution. Then
(a) mol (b) mol the ratio of the concentration of cation and anion.
2 3
(a) 1/2 (b) 2
1 2 (c) 1.5 (d) 1
(c) mol (d) mol
4 3

4
ONE OR MORE THAN ONE TYPE QUESTIONS 37. If average atomic mass of Cl is 35.5. Chlorine exist in
31. 1 mole of CO2 contains nature in the form of two isotopes 17Cl35 and 17Cl37, then
(a) 6.023  1023 atoms of O ratio in which they exist in nature will be
(b) 6.023  1023 atoms of C (a) 1 : 1
(c) 6.023  1023 molecules of CO2 (b) 3 : 1
(d) All of these (c) 2 : 1
(d) 3 : 2
32. Which of the following pairs follow law of multiple
Passage-II
proportion?
All chemical reactions take place under certain laws out
(a) CO2, CO (b) Fe2O3, Fe0.90O
of which three laws are given here.
(c) 12CO2,14CO (d) N2O4, N2O3
(i) Law of conservation of mass: According to this law,
total mass of reactants is equal to total mass of
33. For the reaction,
products.
A + 2B → 2C,
(ii) Law of constant composition: According to this law,
5 moles of A and 8 moles of B are reacted, then
a chemical compound is always found to be made up of
(a) Whole A is consumed
same elements combined together in fixed proportion
(b) Whole B is consumed
by weight.
(c) 8 moles of C are formed
(iii) Law of multiple proportion: According to this law,
(d) 8 equivalents of C are formed
when two elements are combined to form two or more
chemical compounds, the weight of one of the elements
34. Which of the following pairs have same number of which combine with a fixed weight of another bear a
molecules? simple whole number ratio to one another.
(a) 2 g of O2, 4 g of SO2
(b) 2 g CO2, 2 g of N2O 38. Two samples of lead oxide were separately reduced to
(c) 224 ml O2 at STP, 448 ml of He at 0.5 atm metallic lead by heating in a current of hydrogen. The
and 273 K weight of lead from one oxide was half the weight of
(d) 2 g oxygen and 2 g ozone lead obtained from the other oxide. The data illustrates
(a) Law of reciprocal proportions
35. Which of the following is/are independent of (b) Law of constant proportions
temperature? (c) Law of multiple proportions
(a) Molarity (b) Molality (d) Law of conservation of mass
(c) Mole fraction (d) Normality
39. 3 g of a hydrocarbon on combustion with 11.2 g of
PASSAGE TYPE QUESTIONS oxygen produces 8.8 g CO2 and 5.4 g H2O. The data
Passage-I illustrates
Atoms of same element having same atomic number and (a) Law of conservation of mass
different atomic mass are known as isotopes. If atomic masses (b) Law of multiple proportions
of two isotopes of an element are A1 and A2 and they exist in (c) Law of definite proportions
the ratio P1 : P2, then average atomic mass
(d) Law of reciprocal proportions
A1P1 + A 2 P2
Aavg =
P1 + P2 40. The percentage of carbon and oxygen in samples of
36. If % abundance of two isotopes of carbon 6C12 and 6C14 CO2 obtained by different methods were found to be
are 90% and 10% respectively then number of C-12 the same. This illustrates
atoms in 12 g of sample will be approximately (a) Law of conservation of mass
(a) 0.44 NA (b) Law of constant proportions
(b) 0.88 NA (c) Law of multiple proportions
(c) 0.22 NA (d) Law of reciprocal proportions
(d) 0.11 NA

5
MATCH THE COLUMN TYPE QUESTIONS taking170 g AgNO3
41. Match the following physical quantity with their units and 18.25 g HCl
and choose the correct option from the given below. (Ag = 108)

Column I Column II CaCO3(s) → CaO(s)

(Physical quantity) (Unit) + O2(g) 1 moles of solid
(A) Molarity (p) Mol (C) 100g CaCO3 is (r) (product)
(B) Mole fraction (q) Unitless decomposed obtained.
(C) Mole (r) mol L–1
2 KClO3(S) →
(D) Molality (s) mol kg–1 2KCl(s) + 3O2(g)
HCl is the
(D) 2/3 moles of KCIO3 (s)
(a) A-(r); B-(q); C-(p); D-(s) limiting reagent
decomposed
(b) A-(s); B-(p); C-(r); D-(q)
(c) A-(p); B-(s); C-(q); D-(r)
(d) A-(s); B-(q); C-(p); D-(r) (a) A-(p, q, r, s); B-(p, s); C-(q, r); D-(q)
(b) A-(p, r, s); B-(p, r); C-(q, s); D-(r)
(c) A-(p, q, s); B-(q, s); C-(p, r); D-(s)
42. Match the following (d) A-(p, r, s); B-(r, s); C-(p, q); D-(q)
Column I Column II
Dependent on 44. Match the following
(A) Molarity (p)
temperature Column I Column II
MA  n A Number of carbon atoms
(B) Molality (q) 100 (A) (p) 0.5 N0
n A M A + n BM B in 1 g molecule of CO2
Independent on Number of molecules in
(C) Mole fraction (r) (B) (q) N0
temperature 48 g O2
XA No. of molecules in 11.2
(D) Mass % (s) 1000 (C)
L H2 at STP
(r) 3 N0
X BM B
No. of hydrogen atoms in
Where MA, MB are molar masses, nA, nB are no of (D) 1 mole of NH3 (s) 1.5 N0
moles & XA, XB are mole fractions of solute and (N0 = Avogadro’s No.)
solvent respectively.
(a) A-(q); B-(p, r); C-(s); D-(p, s) (a) A-(r); B-(s); C-(q); D-(p)
(b) A-(p); B-(r, s); C-(r); D-(r, q) (b) A-(r); B-(s); C-(p); D-(q)
(c) A-(p); B-(q, s); C-(q); D-(p, q) (c) A-(q); B-(s); C-(p); D-(r)
(d) A-(r); B-(s); C-(p, r); D-(r, s) (d) A-(s); B-(q); C-(p); D-(r)

43. Match the following 45. Match the following

Column I Column II Column I Column II
Zn(s) + 2HCl(aq) → (% by mass of oxygen)
ZnCl2(s) + H2(g) (A) Na2S2O3 (p)  30%
Above reaction is 50% of excess (B) KMnO4 (q)  39%
(A) carried out by taking (p)
2 moles each of Zn
reagent left (C) Na3PO4 (r)  57%
and HCl (D) MgCO3 (s)  40.5%

AgNO3(aq) + (a) A-(r); B-(s); C-(q); D-(p)

HCl(aq) → AgCl(s) (b) A-(s); B-(p); C-(r); D-(q)
22.4 L of gas at
(B) + HNO3(g) (q) (c) A-(p); B-(s); C-(q); D-(r)
STP is liberated
Above reaction is (d) A-(s); B-(q); C-(p); D-(r)
carried out by

6
INTEGER TYPE QUESTIONS 49. If the concentration of glucose (C6H12O6 ) in blood is
46. A solution has 80% w/w NaOH with density 2 gL−1 0.72 g L−1 , the molarity of glucose in blood is
then molality of solution is _______ mol kg–1. _______ 10−3 M (Nearest integer)
[Given : Atomic mass of C = 12, H = 1, O = 16 u]
47. The molarity of H2SO4 in a sample which has density
1.4 g/ml and mass percentage of 98% is ________ M. 50. Number of hydrogen atoms in 36 ml of H2O at 277
48. Complete combustion of 3 g of ethane gives x 10 22
K are x NA. x is______.
molecules of water. The value of x is _________
(Rounded off to the Nearest Integer).
[Use: NA = 6.023 1023 ; Atomic masses in
u : C = 12.0; O = 16.0; H = 1.0]

7
 Exercise-3 (PYQ's) 7. The incorrect postulates of the Dalton's atomic theory are:
(A) Atoms of different elements differ in mass.
(B) Matter consists of divisible atoms.
PROPERTIES OF MATTER AND (C) Compounds are formed when atoms of different element
THEIR MEASUREMENT combine in a fixed ratio.
(D) All the atoms of given element have different properties
1. The candela is the luminous intensity, in a given direction, including mass.
of a source that emits monochromatic radiation of (E) Chemical reactions involve reorganisation of atoms.
frequency 'A' × 1012 hertz and that has a radiant intensity Choose the correct answer from the options given below:
 [05 April, 2024 (Shift-I)]
1
in that direction of watt per steradian. 'A' and 'B' are (a) (B), (D), (E) only (b) (A), (B), (D) only
'B' (c) (C), (D), (E) only (d) (B), (D) only
respectively.
 [09 April, 2024 (Shift-II)]
(a) 540 and
1
(b) 540 and 683 ATOMIC & MOLECULAR MASSES
683
8. The average molar mass of chlorine is 35.5 g mol–1. The
1 ratio of 35Cl to 37Cl in naturally occurring chlorine is close
(c) 450 and (d) 450 and 683 to:
683
 [6 Sept, 2020 (Shift-II)]
(a) 4 : 1 (b) 3 : 1
UNCERTAINTY IN MEASUREMENT AND (c) 2 : 1 (d) 1 : 1
LAWS OF CHEMICAL COMBINATIONS
2. Which of the following have same number of significant
MOLE CONCEPT AND MOLAR MASSES
figures? [8 April, 2023 (Shift-II)] 9. 0.05 cm thick coating of silver is deposited on a plate of
0.05 m2 area. The number of silver atoms deposited on plate
(A) 0.00253 (B) 1.0003
are _____________ × 1023. (At mass Ag = 108, d = 7.9 g
(C) 15.0 (D) 163 cm–3)
Choose the correct answer from the options given below  [30 Jan, 2024 (Shift-I)]
(a) A, B and C only (b) C and D only 10. The number of molecules and moles in 2.8375 litres of O2
(c) A, C and D only (d) B and C only at STP are respectively [10 April, 2023 (Shift-I)]
3. Using the rules for significant figures, the correct answer for (a) 7.527 × 10 and 0.250 mol(b) 1.505 × 1023 and 0.250 mol
22

the expression 0.02858 × 0.112  [29 June, 2022 (Shift-II)] (c) 7.527 × 1023 and 0.125 mol(d) 7.527 × 1022 and 0.125 mol
0.5702
11. Match List-I with List-II. [10 April, 2023 (Shift-II)]
(a) 0.005613 (b) 0.00561
(c) 0.0056 (d) 0.006 LIST-I LIST-II

4. The number of significant figure in 0.00340 is __________. A. 16g of CH4(g) I. Weighs 28 g

[25 July, 2021 (Shift-II)] B. 1g of H2(g) II. 60.2 × 1023 electrons

5. The number of significant figures in 50000.020 × 10–3 C. 1 mole of N2(g) III. Weighs 32g
is_______. [26 Feb, 2021 (Shift-I)]
Occupies 11.4 L volume
D. 0.5 mol of SO2(g) IV.
at STP
DALTON'S ATOMIC THEORY Choose the correct answer from the options given below:
6. Choose the Incorrect Statement about Dalton’s Atomic (a) (A)-(I), B-(III), C-(II), D-(IV)
Theory (b) (A)-(II), B-(III), C-(IV), D-(I)
 [04 April, 2024 (Shift-II)] (c) (A)-(II), B-(IV), C-(III), D-(I)
(a) Compounds are formed when atoms of different (d) (A)-(II), B-(IV), C-(I), D-(III)
elements combine in any ratio 12. When 0.01 mol of an organic compound containing 60%
(b) All the atoms of a given element have identical carbon was burnt completely, 4.4 g of CO2 was produced.
properties including identical mass The molar mass of compound is _________ g mol–1 (Nearest
(c) Matter consists of indivisible atoms integer)
(d) Chemical reactions involve recorganization of atoms  [29 Jan, 2023 (Shift-II)]

8
 13. Production of iron in blast furnace follows the following 22. 1 L aqueous solution of H2SO4 contains 0.02 m mol H2SO4.
equation Fe3O4(s) + 4CO(g) → 3Fe(l) + 4CO2(g) 50% of this solution is diluted with deionized water to give 1
When 4.640 kg of Fe3O4 and 2.520 kg of CO are allowed to L solution (A). In solution (A), 0.01 m mol of H2SO4 are
react then the amount of iron (in g) produced is: added. Total m mols of H2SO4 in the final solution is ______
[Given: Molar Atomic mass (g mol–1); Fe = 56 × 103 m moles.
Molar Atomic mass (g mol–1); O = 16  [25 June, 2022 (Shift-I)]
Molar Atomic mass (g mol–1); C = 12] [29 June, 2022 23. Two elements A and B forms 0.15 moles of A2B and AB3
(Shift-I)] type compounds. If both A2B and AB3 weigh equally, then
(a) 1400 (b) 2200 the atomic weight of A is______ times of atomic weight of
(c) 3360 (d) 4200 B.
14. SO2Cl2 on reaction with excess of water results into acidic  [27 June, 2022 (Shift-I)]
mixture 24. Number of grams of bromine that will completely react with 5.0 g
SO2Cl2 + 2H2O → H2SO4 + 2HCl of pent-1-ene is _______________ × 10–2 g. (Atomic mass of
16 moles of NaOH is required for the complete neutralisation of Br = 80 g/mol) (Nearest Integer)[25 June, 2022 (Shift-I)]
the resultant acidic mixture. The number of moles of SO2Cl2 25. The moles of methane required to produce 81 g of water
used is: [25 July, 2022 (Shift-I)] after complete combustion is________ ×10–2 mol. (nearest
(a) 16 (b) 8 integer)
(c) 4 (d) 2  [26 June, 2022 (Shift-II)]
15. Hemoglobin contains 0.34% of iron by mass. The number of Fe 26. In the following reaction
atoms in 3.3 g of hemoglobin is (Given: Atomic mass of Fe is 56 u, SO3H OH
NA = 6.022 1023 mol–1.) [26 July, 2022 (Shift-II)]
(a) 1.21  10 5 (b) 12.0 1016 Oleum NaOH (excess)
+
H
(c) 1.21  10 20 (d) 3.4  1022 I II
16. 250 g solution of D-glucose in water contains 10.8% of The % yield for reaction I is 60% and that of reaction
carbon by weight. The molality of the solution is nearest to II is 50%. The overall yield of the complete reaction
(Given: Atomic weights are, H = 1u ; C = 12u ; O = 16u) is__________% [ Nearest integer][27 July, 2022 (Shift-I)]
[27 July, 2022 (Shift-I)]
27. In the below reaction, 5g of toluene is converted into
(a) 1.03 (b) 2.06 benzaldehyde with 92% yield. The amount of benzaldehyde
(c) 3.09 (d) 5.40 produced is_______ × 10–2 g. (Nearest integer) [27 July,
17. The number of N atoms in 681 g of C7H5N3O6 is x × 1021. 2022 (Shift-II)]
The value of x is____________. CH3 CHO
(NA = 6.02 × 1023 mol–1) (Nearest Integer)
[25 June, 2022 (Shift-I)]
18. A protein ‘A’ contains 0.30% of glycine (molecular weight 75).
The minimum molar mass of the protein ‘A’ is ____________ 5g (92%)
× 103 g mol–1 [ nearest integer] [25 June, 2022 (Shift-II)] 28. A reaction of 0.1 mole of Benzylamine with bromomethane
19. CNG is an important transportation fuel. When 100 g gave 23g of Benzyl trimethyl ammonium bromide.
CNG is mixed with 208 g oxygen in vehicles, it leads to The number of moles of bromomethane consumed in
the formation of CO2 and H2O and produces large quantity this reaction are n × 10–1, when n = ____ (Round off to
of heat during this combustion, then the amount of carbon the nearest integer) (Given: Atomic masses: C: 12.0 u,
dioxide produced in grams is______. (nearest integer) H : 1.0u, N : 14.0u, Br : 80.0u]  [18 March, 2021 (Shift-I)]
[Assume CNG to be methane] [26 June, 2022 (Shift-II)] 29. 4g equimolar mixture of NaOH and Na2CO3 contains x g
of NaOH and y g of Na2CO3. The value of x is __________ g.
20. 56.0 L of nitrogen gas is mixed with excess of hydrogen gas (Nearest Integer) [20 July, 2021 (Shift-II)]
and it is found that 20 L of ammonia gas is produced. The 30. Consider the complete combustion of butane, the amount of
volume of unused nitrogen gas is found to be_____ L. butane utilized to produce 72.0 g of water is__________ × 10−1g,
[25 July, 2022 (Shift-II)] (in nearest integer) [25 July, 2021 (Shift-I)]
31. The number of atoms in 8 g of sodium is x × 1023. The value
21. Chlorophyll extracted from the crushed green leaves was of x is ________. (Nearest integer)
dissolved in water to make 2 L solution of Mg of concentration [Given: NA = 6.02 × 1023 mol–1, Atomic mass of Na = 23.0 u]
48 ppm. The number of atoms of Mg in this solution is x × 1020 [1 Sept, 2021 (Shift-I)]
atoms. The value of x is __________. (Nearest Integer) 32. The NaNO3 weighed out to make 50 mL of an aqueous solution
(Given: Atomic mass of Mg is 24 g mol–1; NA = 6.02 × 1023 containing 70.0 mg Na+ per mL is____g. (Rounded off to the
mol–1) [26 July, 2022 (Shift-I)] nearest integer)  [26 Feb, 2021 (Shift-II)]
[Given; Atomic weight in g mol–1 -Na : 23; N :14; O :16]

9
 33. The minimum number of moles of O2 required for complete 42. A metal chloride contains 55.0% of chlorine by weight. 100
combustion of 1 mole of propane and 2 moles of butane is mL vapours of the metal chloride at STP weigh 0.57 g. The
_______. [5 Sept, 2020 (Shift-I)] molecular formula of the metal chloride is
34. The mass of ammonia in grams produced when 2.8 kg of (Given: Atomic mass of chlorine is 35.5 u)
dinitrogen quantitatively reacts with 1 kg of dihydrogen is [12 April, 2023 (Shift-I)]
__________. (a) MCl2 (b) MCl4
 [4 Sept, 2020 (Shift-I)] (c) MCl3 (d) MCl
35. Ferrous sulphate heptahydrate is used to fortify foods with
iron. The amount (in grams) of the salt required to achieve 43. An organic compound gives 0.220 g of CO2 and 0.126 g of
10 ppm of iron in 100 kg of wheat is _________ H2O on complete combustion. If the % of carbon is 24, then
Atomic weight: Fe = 55.85; S = 32.00; O = 16.00 the % hydrogen is ________ × 10–1 . (Nearest integer) [13
[8 Jan, 2020 (Shift-I)] April, 2023 (Shift-I)]
36. NaClO3 is used, even in spacecraft, to produce O2. The daily 44. 0.5 g of an organic compound (X) with 60% carbon
consumption of pure O2 by a person is 492L at 1  atm, 300 will produce __________ × 10–1 g of CO2 on complete
K. How much amount of NaClO3, in grams, is required to combustion.
produce O2 for the daily consumption of a person at 1 atm,  [8 April, 2023 (Shift-I)]
300 K?
NaClO3(s) + Fe(s) → O2(g) + NaCl(s) + FeO(s) 45. 120 g of an organic compound that contains only carbon and
hydrogen gives 330 g of CO2 and 270 g of water on complete
R = 0.082 L atm mol–1 K–1. [8 Jan, 2020 (Shift-II)] combustion. The percentage of carbon and hydrogen,
37. At 300 K and 1 atmospheric pressure, 10 mL of a hydrocarbon respectively are [24 June, 2022 (Shift-I)]
required 55 mL of O2 for complete combustion and 40 mL
(a) 25 and 75 (b) 40 and 60
of CO2 is formed. The formula of the hydrocarbon is:
 [10 April, 2019 (Shift-I)] (c) 60 and 40 (d) 75 and 25
(a) C4H8 (b) C4H7Cl 46. Compound A contains 8.7% Hydrogen, 74% Carbon and
(c) C4H10 (d) C4H6 17.3% Nitrogen. The molecular formula of the compound is,
Given: Atomic masses of C, H and N are 12, 1 and 14 amu
38. 5 moles of AB2 weigh 125 × 10–3 kg and 10 moles of A2B2
respectively. The molar mass of the compound A is 162 g
weigh 300 × 10–3 kg. The molar mass of A (M A) and molar mol-1.
mass of B(M B ) in kg mol­–1 are: [12 April, 2019 (Shift-I)]  [28 June, 2022 (Shift-II)]
(a) MA = 50 × 10–3­ and MB = 25 × 10–3 (a) C4H6N2 (b) C2H3N
(b) MA = 25 × 10–3­ and MB = 50 × 10–3 (c) C5H7N (d) C10H14N2
(c) MA = 5 × 10–3­ and MB = 10 × 10–3 47. 116 g of a substance upon dissociation reaction yields 7.5
g of hydrogen, 60g of oxygen and 48.5 g of carbon. Given
(d) MA = 10 × 10–3­ and MB = 5 × 10–3 that the atomic masses of H, O and C are 1,16 and 12 g/mol
respectively. The data agrees with how many formulae of
PERCENTAGE COMPOSITION AND the following?
 [27 June, 2022 (Shift-II)]
EMPIRICAL & MOLECULAR FORMULA
(1) CH3COOH (2) HCHO
39. A sample of CaCO3 and MgCO3 weighed 2.21 g is ignited
(3) CH3OOCH3 (4) CH3CHO
to constant weight of 1.152 g. The composition of mixture
is: 48. A 2.0 g sample containing MnO 2 is treated with HCl
(Given molar mass in g mol–1 liberating Cl2. The Cl2 gas is passed into a solution of KI
CaCO3 : 100, MgCO3 : 84 ) [31 Jan, 2024 (Shift-II)] and 60.0 mL of 0.1 M Na2S2O3 is required to titrate the
liberated iodine. The percentage of MnO2 in the sample
(a) 1.187 g CaCO3 + 1.023 g MgCO3
is____. (Nearest integer)
(b) 1.023 g CaCO3 + 1.023 g MgCO3 [Atomic masses (in u ) Mn = 55; Cl = 35.5; O = 16, I = 127, Na = 23,
(c) 1.187 g CaCO3 + 1.187 g MgCO3 K = 39, S = 32] [28 June, 2022 (Shift-I)]
(d) 1.023 g CaCO3 + 1.187 g MgCO3 49. O n c o m p l e t e c o m b u s t i o n 0 . 3 0 g o f
40. 10 mL of gaseous hydrocarbon on combustion gives 40 an organic compound gave 0.20 g
mL of CO2(g) and 50 mL of water vapour. Total number of of carbon dioxide and 0.10 g of water. The percentage of
carbon in the given organic compound is ________. (Nearest
carbon and hydrogen atoms in the hydrocarbon is _____.
integer)
 [01 Feb, 2024 (Shift-II)]  [26 June, 2022 (Shift-I)]
41. An organic compound has 42.1% carbon, 6.4% hydrogen and 50. The complete combustion of 0.492 g of an organic compound
remainder is oxygen. If its molecular weight is 342, then its containing ‘C’, ‘H’ and ‘O’ gives 0.793g of CO2 and 0.442 g
molecular formula is: [05 April, 2024 (Shift-I)] H2O. The percentage of oxygen composition in the organic
(a) C11H18O12 (b) C12H20O12 compound is _________. (nearest integer) [28 June, 2022
(c) C14H20O10 (d) C12H22O11 (Shift-II)]

10
 51. I n t h e e s t i m a t i o n o f b r o m i n e , 0 . 5 g 60. Consider the following reaction:
of an organic compound gave 0.40 g 3PbCl2 + 2(NH4)3PO4 → Pb3(PO4)2 + 6NH4Cl
of silver bromide. The percentage of bromine in the given If 72 mmol of PbCl2 is mixed with 50 mmol of (NH4)3PO4,
compound is ___________% (Nearest integer) then amount of Pb3(PO4)2 formed is ______ mmol. (nearest
(Relative atomic masses of Ag and Br are 108 u and 80 u, integer)
respectively). [28 June, 2022 (Shift-II)]  [01 Feb, 2024 (Shift-I)]
52. Complete combustion of 1.80 g of an oxygen containing 61. Combustion of glucose (C6H12O6) produces CO2 and water.
compound (Cx Hy Oz) gave 2.64 g of CO2 and 1.08g of H2O. The amount of oxygen (in g) required for the complete
The percentage of oxygen in the organic compound is [25 combustion of 900 g of glucose is: [Molar mass of glucose
Feb, 2021 (Shift-I)] in gmol–1) = 180
(a) 53.33 (b) 50.33  [08 April, 2024 (Shift-I)]
(c) 63.53 (d) 51.63 (a) 480 (b) 960
53. Complete combustion of 750g of an organic compound (c) 800 (d) 32
provides 420 g of CO2 and 210 g of H2O. The percentage
62. If 279 g of aniline is reacted with one equivalent of
composition of carbon and hydrogen in organic compound is benzenediazonium chloride, the maximum amount of aniline
15.3 and _________ respectively. (Round off to the nearest yellow formed will be ______ g (nearest integer).
Integer).
(consider complete conversion) [08 April, 2024 (Shift-I)]
 [16 March, 2021 (Shift-I)]
63. 9.3 g of pure aniline upon diazotisation followed by coupling
54. Methylation of 10 g of benezene give 9.2 g of toluene. with phenol gives an orange dye. The mass of orange dye
Calculate the percentage yield of toluene _________ . produced (assume 100% yield/ conversion) is _______ g.
(Nearest integer) (nearest integer) [06 April, 2024 (Shift-I)]
 [22 July, 2021 (Shift-II)] 64. The number of moles of methane required to produce 11g
55. The percentage composition of carbon by mole in methane is: CO2(g) after complete combustion is:
 [8 April, 2019 (Shift-II)] (Given molar mass of methane in g mol–1 : 16)
(a) 80% (b) 25%  [05 April, 2024 (Shift-II)]
(c) 75% (d) 20% (a) 0.75 (b) 0.25 (c) 0.35 (d) 0.5
56. A 10 mg effervescent tablet containing sodium bicarbonate 65. X of enthanamine was subjected to reaction with NaNO2/
and oxalic acid releases 0.25 ml of CO2 at T = 298.15 K HCl followed by hydrolysis to liberate N2 and HCl. The
and p = 1 bar. If molar volume of CO2 is 25.0 L under such HCl generated was completely neutralised by 0.2 moles of
condition, what is the percentage of sodium bicarbonate in NaOH. X is ____ g.
each tablet? [Molar mass of NaHCO3 = 84 g mol–¹]  [05 April, 2024 (Shift-II)]
 [11 Jan, 2019 (Shift-I)] 66. In the Claisen-Schmidt reaction to prepare 351 g of
(a) 0.84 (b) 33.6 dibenzalacetone using 87 g of acetone, the amount of
(c) 16.8 (d) 8.4 benzaldehyde required is _________g. (Nearest integer)
 [05 April, 2024 (Shift-II)]
STOICHIOMETRY &
67. 9.3 g of pure aniline is treated with bromine water at room
STOICHIOMETRIC CALCULATIONS temperature to give a white precipitate of the product ‘P’.
57. Mass of methane required to produce 22 g of CO2 after The mass of product ‘P’ obtained is 26.4 g. The percentage
complete combustion is _______ g. yield is ____%. [05 April, 2024 (Shift-I)]
(Given Molar mass in g mol–1 68. X g of ethylamine is subjected to reaction with NaNO2/HCl
followed by water; evolved dinitrogen gas which occupied
C = 12.0
2.24 L volume at STP. X is ______ × 10–1 g. [04 April,
H = 1.0
2024 (Shift-I)]
O = 16.0) [27 Jan, 2024 (Shift-I)]
58. Number of moles of methane required to produce 69. From 6.55 g of aniline, the maximum amount of acetanilide
22g CO2(g) after combustion is x × 10–2 moles. The value that can be prepared will be ___ ×10–1 g.
of x is  [04 April, 2024 (Shift-II)]
70. When a hydrocarbon A undergoes combustion in the
 [31 Jan, 2024 (Shift-I)] presence of air, it requires 9.5 equivalents of oxygen and
produces 3 equivalents of water. What is the molecular
59. A compound (x) with molar mass 108 g mol–1 undergoes formula of A?
acetylation to give product with molar mass 192 g mol–1.
 [29 Jan, 2023 (Shift-II)]
The number of amino groups in the compound (x) is
______. (a) C8H6 (b) C9H9
 [31 Jan, 2024 (Shift-II)] (c) C6H6 (d) C9H6

11
 71. When a hydrocarbon A undergoes complete combustion it 81. Consider the reaction
requires 11 equivalents of oxygen and produces 4 equivalents 4HNO3(l) + 3KCl(s) → Cl2(g) + NOCl(g) + 2H2O(g) +
of water. What is the molecular formula of A?  [31 Jan, 3KNO3(s)
2023 (Shift-II)] The amount of HNO3 required to produce 110.0 g of KNO3
(a) C9H8 (b) C11H4 is (Given: Atomic masses of H, O, N and K are 1, 16, 14 and
(c) C5H8 (d) C11H8 39, respectively) [29 July, 2022 (Shift-II)]
72. 1 g of a carbonate (M2CO3) on treatment with excess HCl (a) 32.2g (b) 69.4g
produces 0.01 mol of CO2. The molar mass of M2CO3 is ___ (c) 91.5g (d) 162.5g
g mol–1. (Nearest integer) [13 April, 2023 (Shift-II)]
82. N2(g) + 3H2(g)  2NH3(g)
73. On complete combustion, 0.492 g of an organic compound
gave 0.792 g of CO2. The % of carbon in the organic 20 g 5g
compound is _____ (Nearest integer) [31 Jan, 2023 Consider the above reaction, the limiting reagent of the
(Shift-I)] reaction and number of moles of NH3 formed respectively
74. Number of hydrogen atoms per molecule of a hydrocarbon are:
A having 85.8% carbon is __________  [29 July, 2022 (Shift-I)]
(Given: Molar mass of A = 84 g mol–1) [25 Jan, 2023 (a) H2, 1.42 moles (b) H2, 0.71 moles
(Shift-II)] (c) N2, 1.42 moles (d) N2, 0.71 moles
75. Zinc reacts with hydrochloric acid to give hydrogen and zinc 83. The normality of H2SO4 in the solution obtained on mixing 100
chloride. The volume of hydrogen gas produced at STP from mL of 0.1 M H2SO4 with 50 mL of 0.1 M NaOH is __________
the reaction of 11.5 g of zinc with excess HCl is ______ L × 10–1 N. (Nearest Integer) [27 July, 2022 (Shift-II)]
(Nearest integer) 84. In the given reaction, X + Y + 3Z  XYZ3
(Given: Molar mass of Zn is 65.4g mol–1 and Molar volume If one mole of each of X and Y with 0.05 mol of Z gives
of H2 at STP = 22.7L) [31 Jan, 2023 (Shift-I)] compound XYZ3. (Given: Atomic masses of X, Y and Z are 10,
20 and 30 amu, respectively.) The yield of XYZ3 is _________
76. Assume carbon burns according to following equation: g. (Nearest integer) [28 July, 2022 (Shift-I)]
2C(s) +O2(g) → 2CO(g)
85. 2L of 0.2 M H2SO4 is reacted with 2L of 0.1 M NaOH
When 12 g carbon is burnt in 48 g of oxygen, the volume solution, the molarity of the resulting product Na2SO4 in
of carbon monoxide produced is ______× 10−1 L at STP the solution is __________ millimolar (Nearest integer)
[nearest integer]
[28 July, 2022 (Shift-II)]
[Given: Assume CO as ideal gas, Mass of C is 12 g mol−1, Mass
86. When 200 mL of 0.2 M acetic acid is shaken with 0.6 g of
of O is 16 g mol−1and molar volume of an ideal gas at STP is wood charcoal, the final concentration of acetic acid after
22.7 L mol−1] [31 Jan, 2023 (Shift-II)] adsorption is 0.1M. The mass of acetic acid adsorbed per gram
77. If 5 moles of BaCl2 is mixed with 2 moles of Na3PO4, the of carbon is ___ g.
maximum number of moles of Ba3(PO4)2 formed is
 [24 June, 2022 (Shift-II)]
(Nearest integer) [6 April, 2023 (Shift-I)]
87. A 0.166 g sample of an organic compound was digested with
78. The volume of hydrogen liberated at STP by treating 2.4 g of conc. H2SO4 and then distilled with NaOH. The ammonia
magnesium with excess of hydrochloric acid is _________ × gas evolved was passed through 50.0 mL of 0.5 N H2SO4.
10–2 L. The used acid required 30.0 mL of 0.25 N NaOH for
complete neutralization. The mass percentage of nitrogen
Given: Molar volume of gas is 22.4 L at STP. Molar mass
in the organic compound is__________.
of magnesium is 24 g mol–1. [11 April, 2023 (Shift-II)]
[24 June, 2022 (Shift-I)]
79. 17 mg of a hydrocarbon (M.F. C10H16) takes up 8.40 mL of 88.
the H2 gas measured at 0ºC and 760 mm of Hg. Ozonolysis O
of the same hydrocarbon yields. [29 Jan, 2023 (Shift-I)]
C
Cl O
—

—
—

+ C6H5NHC6H5 C6H5 C N (C6H5)2

The number of double bond/s present in the hydrocarbon is
80. If a rocket runs on a fuel (C15H30) and liquid oxygen, the 0.140g 0.388g 0.210g
weight of oxygen required and CO2 released for every Consider the above reaction. The percentage yield of amide
litre of fuel respectively are: [24 June, 2022 (Shift-I)] product is _______.
(Given: density of the fuel is 0.756 g/mL) (Round off to the nearest integer).
(a) 1188 g and 1296 g (b) 2376 g and 2592 g (Given: Atomic mass: C : 12.0 u, H : 1.0 u, N : 14.0 u, O :
(c) 2592 g and 2376 g (d) 3429 g and 3142 g 16.0 u, Cl : 35.5 u) [17 March, 2021 (Shift-II)]

12
 89. The formula of a gaseous hydrocarbon which requires 6 95. The first and second ionisation enthalpies of a metal are
–1
times of its own volume of O2 for complete oxidation and 496 and 4560 kJ mol , respectively. How many moles of HCl
produces 4 times its own volume of CO2 is CxHy. The value and H2SO4, respectively, will be needed to react completely with
of y is _________. 1 mole of the metal hydroxide?
 [24 Feb, 2021 (Shift-II)] [9 Jan, 2020 (Shift-II)]
90. ___________ grams of 3-Hydroxy propanal (MW = 74) (a) 1 and 1 (b) 1 and 2
must be dehydrated to produce 7.8g of acrolein (MW  =  56) (c) 2 and 0.5 (d) 1 and 0.5
(C3H4O) if the percentage yield is 64. (Round off to the 96. 5 g of zinc is treated separately with an excess of
nearest integer). (A) dilute hydrochloric acid and
 [18 March, 2021 (Shift-I)] (B) aqueous sodium hydroxide.
[Given: Atomic masses: C : 12.0u, H : 1.0u, O : 16.0u] The ratio of the volumes of H2 evolved in these two reactions
is:
COOH COOH  [9 Jan, 2020 (Shift-II)]
(a) 1 : 4 (b) 1 : 1
91. (c) 1 : 2 (d) 2 : 1
FeBr3
+ Br2 → + HBr 97. The ammonia (NH3) released on quantitative reaction of 0.6 g
Br urea (NH 2 CONH 2 ) with sodium hydroxide(NaOH) can be
neutralized by  [7 Jan, 2020 (Shift-II)]
Consider the above reaction where 6.1 g of Benzoic acid is
used to get 7.8g of m- bromo benzoic acid. The percentage (a) 100 mL of 0.1 N HCl (b) 100 mL of 0.2 N HCl
yield of the product is________. (Round off to the nearest (c) 200 mL of 0.2 N HCl (d) 200 mL of 0.4 N HCl
integer). 98. A solution of phenol in chloroform when treated with aqueous
[Given: Atomic masses: C : 12.0u, H : 1.0u, O : 16.0u, Br : 80.0 u] NaOH gives compound P as a major product. The mass percentage
[18 March, 2021 (Shift-II)] of carbon in P is ___________. (to the nearest integer) (Atomic
mass: C = 12; H = 1; O = 16) [6 September, 2020 (Shift-II)]
92. NO2
99. For the following reaction, the mass of water produced from 445 g
of C57H110O6 is:
HNO3 2C57H110O6 (s) + 163 O2 (g) → 114 CO2 (g) + 110 H2O (l)
H2SO4 [9 Jan, 2019 (Shift-II)]
(a) 490 g (b) 445 g
In the above reaction, 3.9 g of benzene on nitration gives (c) 495 g (d) 890 g
4.92 g of nitrobenzene. The percentage yield of nitrobenzene
in the above reaction is_____________ % 100. 50 mL of 0.5 M oxalic acid is needed to neutralize 25 ml of sodium
hydroxide solution. The amount of NaOH in 50 mL of the given
(Round off to the nearest integer).
sodium hydroxide solution is: [12 Jan, 2019 (Shift-I)]
(Given atomic mass: C: 12.0u, H:1.0u, O:16.0u, N:14.0u)
(a) 40 g (b) 10 g
[17 March, 2021 (Shift-I)]
93. Complete combustion of 3g of ethane gives x × 1022 molecules (c) 20 g (d) 80 g
of water. The value of x is __________. (Round off to the nearest 101. For a reaction,
integer). N2(g) + 3H2(g) → 2NH3(g);
[Use: NA = 6.023 × 1023; Atomic masses in u: C:12.0, O:16.0;
Identify dihydrogen (H 2) as a limiting reagent in the
H:1.0] [17 March, 2021 (Shift-I)]
following reaction mixtures. [9 April, 2019 (Shift-I)]
94. 100 g of propane is completely reacted with 1000 g of oxygen. The
mole fraction of carbon dioxide in the resulting mixture is x ×10–2. (a) 14 g of N2 + 4 g of H2
The value of x is _______. (Nearest integer) (b) 28 g of N2 + 6 g of H2
[Atomic weight: H = 1.008; C = 12.00; O = 16.00] (c) 56 g of N2 + 10 g of H2
 [27August 2021 (Shift-II)] (d) 35 g of N2 + 8 g of H2

13
 Answer Key (Manthan)
Exercise-1
1. (b) 2. (b) 3. (c) 4. (c) 5. (c) 6. (c) 7. (a) 8. (b) 9. (a) 10. (d)
11. (a) 12. (a) 13. (a) 14. (b) 15. (b) 16. (a) 17. (a) 18. (c) 19. (c) 20. (d)
21. (b) 22. (a) 23. (a) 24. (d) 25. (c) 26. (b) 27. (b) 28. (c) 29. (c) 30. (c)
31. (c) 32. (a) 33. (a) 34. (a) 35. (d) 36. (a) 37. (c) 38. (d) 39. (b) 40. (c)
41. (a) 42. (d) 43. (d) 44. (d) 45. (a)

Exercise-2
1. (a) 2. (a) 3. (c) 4. (c) 5. (c) 6. (b) 7. (b) 8. (c) 9. (a) 10. (c)
11. (c) 12. (a) 13. (d) 14. (a) 15. (b) 16. (a) 17. (b) 18. (a) 19. (b) 20. (b)
21. (c) 22. (b) 23. (c) 24. (b) 25. (c) 26. (b) 27. (c) 28. (a) 29. (b) 30. (d)
31. (2, 3) 32. (1, 4) 33. (2, 3) 34. (1, 2, 3) 35. (2, 3) 36. (b) 37. (b) 38. (c) 39. (a) 40. (b)
41. (a) 42. (b) 43. (a) 44. (c) 45. (c) 46. (100) 47. (14) 48. (18) 49. (d) 50. (d)

Exercise-3 (PYQ's)
1. (b) 2. (c) 3. (b) 4. [3] 5. [8] 6. (a) 7. (d) 8. (b) 9. [11] 10. (d)
11. (d) 12. [200] 13. (c) 14. (c) 15. (c) 16. (b) 17. [5418] 18. [25] 19. [143] 20. [46]
21. [24] 22. [0] 23. [2] 24. [1143] 25. [225] 26. [30] 27. [530] 28. [3] 29. [1] 30. [464]
31. [2] 32. [13] 33. [18] 34. [3400] 35. [496] 36. [2130] 37. (d) 38. (c) 39. (a) 40. [14]
41. (d) 42. (a) 43. [56] 44. [11] 45. (d) 46. (d) 47. [2] 48. [13] 49. [18] 50. [46]
51. [34] 52. (a) 53. [3] 54. [78] 55. (d) 56. (d) 57. [8] 58. [50] 59. [2] 60. [24]
61. (b) 62. [591] 63. [20] 64. (b) 65. [9] 66. [318] 67. [80] 68. [45] 69. [95] 70. (a)
71. (a) 72. [100] 73. [44] 74. [12] 75. [4] 76. [227] 77. [1] 78. [224] 79. [3] 80. (c)
81. (c) 82. (c) 83. [1] 84. [2] 85. [25] 86. [2] 87. [63] 88. [77] 89. [8] 90. [16]
91. [78] 92. [80] 93. [18] 94. [19] 95. (d) 96. (b) 97. (b) 98. [69] 99. (c) 100. (*)
101. (c)

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