SAFETY DATA SHEET

FERROCOTE™ 5856 BF T1
SDS according to the U.S. OSHA Hazard Communication Standard (29 CFR 1910.1200), Revision 2012

Section 1. Identification
Product code : 013315-05
Product name : FERROCOTE™ 5856 BF T1
Other means of : Not available.
identification

Relevant identified uses of the substance or mixture and uses advised against
Relevant uses : Corrosion inhibitor
Uses advised against : Any other purpose.

Supplier : Quaker Houghton PA, Inc.

901 E. Hector Street
Conshohocken, PA 19428 USA
T: 610-832-4000

Wallover Oil Company

21845 Drake Road
Strongsville, OH 44149 USA
www.wallover.com
T: (440) 238-9250

[email protected]
www.quakerhoughton.com

Emergency telephone : CHEMTREC US/Canada:1-800-424-9300 or 1-703-527-3887 (24 hours)

number (with hours of
operation)

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE LIQUIDS - Category 4
substance or mixture SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2

GHS label elements

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Section 2. Hazards identification

Hazard pictograms :

Signal word : Warning

Hazard statements : Combustible liquid.
Causes skin irritation.
Causes serious eye irritation.
May cause damage to organs through prolonged or repeated exposure. (gastrointestinal
tract, immune system, liver)
Precautionary statements
Prevention : Wear protective gloves, protective clothing and eye or face protection. Keep away from
flames and hot surfaces. No smoking. Do not breathe vapor. Wash thoroughly after
handling.
Response : Get medical advice or attention if you feel unwell. Take off contaminated clothing and
wash it before reuse. IF ON SKIN: Wash with plenty of water. If skin irritation occurs:
Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical advice or attention.
Storage : Store in a well-ventilated place. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients

Substance/mixture : Mixture

Ingredient name % CAS number

Distillates (petroleum), hydrotreated light ≥50 - ≤75 64742-47-8
Distillates (petroleum), hydrotreated light naphthenic ≥10 - ≤25 64742-53-6
Mineral oil ** ≥10 - ≤25 -
Mineral oil ≤5 -
calcium bis(dinonylnaphthalenesulphonate) ≤3 57855-77-3
hexadecylamine <3 143-27-1
** May contain : 64742-52-5
Product containing mineral oil with less than 3% DMSO extract as measured by IP 346.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Section 4. First aid measures

Description of necessary first aid measures
General advice : Get medical attention. If medical advice is needed, have product container or label at
hand. Use personal protective equipment as required. Remove contaminated clothing
and wash it before reuse. Wash skin surfaces thoroughly after contact.
Inhalation : Move affected person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Get medical attention.

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Section 4. First aid measures

Skin contact : Wash with plenty of soap and water. Remove contaminated clothing and wash it before
reuse. Get medical attention if symptoms occur.
Eye contact : Flush with plenty of water for at least 15 minutes, occasionally lifting the upper and
lower eyelids. Remove contact lenses, if present and easy to do. Get medical attention
if symptoms occur.
Ingestion : Ingestion may cause gastrointestinal irritation and diarrhea. Do not induce vomiting
unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person.

Most important symptoms and effects, both acute and delayed

Inhalation : Not expected under normal use.
Skin contact : pain or irritation,redness
Eye contact : pain or irritation,redness,watering
Ingestion : Not expected under normal use.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves. Use
personal protective equipment as required.

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Combustible liquid. Runoff to sewer may create fire or explosion hazard. In a fire or if
from the chemical heated, a pressure increase will occur and the container may burst, with the risk of a
subsequent explosion.
Hazardous thermal : In a fire, hazardous decomposition products may be produced. carbon oxides (CO,
decomposition products CO₂) nitrogen oxides sulfur oxides metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

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Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : Eliminate all ignition sources. No action shall be taken involving any personal risk or
personnel without suitable training. Put on appropriate personal protective equipment (see Section
8). Keep unnecessary personnel away. Avoid breathing vapor or mist. Provide
adequate ventilation.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel". Evacuate area.

Environmental precautions : Inform the relevant authorities if the product has caused environmental pollution
(sewers, waterways, soil or air). Do not allow any potentially contaminated water,
including rain water, runoff from fire fighting or spills, to enter any waterway, sewer or
drain.

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Prevent entry into sewers,
water courses, basements or confined areas. Absorb with an inert material and place in
an appropriate waste disposal container. Use non-sparking tools. Dispose of via a
licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Absorb with an inert material
and place in an appropriate waste disposal container. Dike large spills and use a non-
sparking or explosion-proof means to transfer material to an appropriate container for
disposal. To reduce potential for static discharge, use proper bonding and grounding
procedures. Dispose of via a licensed waste disposal contractor.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or
on skin or clothing. Do not breathe vapor or mist. Do not ingest.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected from
including any direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
incompatibilities (see Section 10) and food and drink. Do not store in unlabeled containers. Use
appropriate containment to avoid environmental contamination. Keep away from heat,
hot surfaces, sparks, open flames and other ignition sources. No smoking.
Storage temperature : Store between the following temperatures: 4 to 40°C (39.2 to 104°F).

Shelf life : 12 months

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Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Distillates (petroleum), hydrotreated light ACGIH TLV (United States, 1/2022).
[Kerosene as total hydrocarbon vapor]
Absorbed through skin.
TWA: 200 mg/m³, (as total hydrocarbon
vapor) 8 hours.
Distillates (petroleum), hydrotreated light naphthenic OSHA PEL (United States, 5/2018). [Oil
mist, mineral]
TWA: 5 mg/m³ 8 hours.
ACGIH TLV (United States, 1/2022).
[Mineral Oil, pure, highly and severely
refined]
TWA: 5 mg/m³ 8 hours. Form: Inhalable
fraction
NIOSH REL (United States, 10/2020). [OIL
MIST MINERAL]
TWA: 5 mg/m³ 10 hours. Form: Mist
STEL: 10 mg/m³ 15 minutes. Form: Mist
Mineral oil ** NIOSH REL (United States, 10/2016).
TWA: 5 mg/m³ 10 hours. Form: Mist
STEL: 10 mg/m³ 15 minutes. Form: Mist
ACGIH TLV (United States).
TWA: 5 mg/m³ 8 hours.
STEL: 10 mg/m³ 15 minutes.
Mineral oil NIOSH REL (United States, 10/2016).
TWA: 5 mg/m³ 10 hours. Form: Mist
STEL: 10 mg/m³ 15 minutes. Form: Mist
ACGIH TLV (United States).
TWA: 5 mg/m³ 8 hours.
calcium bis(dinonylnaphthalenesulphonate) None.
hexadecylamine None.

Appropriate engineering : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
controls local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period. Eating,
drinking and smoking should be prohibited in areas where this material is handled,
stored and processed. Appropriate techniques should be used to remove potentially
contaminated clothing. Wash contaminated clothing before reusing. Ensure that
eyewash stations and safety showers are close to the workstation location. Keep
equipment clean.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
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Section 8. Exposure controls/personal protection

Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers.
Other skin protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. Appropriate footwear and any additional skin protection
measures should be selected based on the task being performed and the risks involved
and should be approved by a specialist before handling this product.
Respiratory protection : A respirator is not needed under normal and intended conditions of product use. Use
appropriate respiratory protection if there is a risk of exceeding any exposure limits.
Thermal hazards : Not expected under normal use. Not relevant/applicable due to nature of the product.

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Color : Clear. Amber.
Odor : Pleasant.
Odor threshold : Not available.
pH : Not available.
Melting point : Not available.
Boiling point : 148°C (298.4°F)
Flash point : Open cup: 80°C (176°F)
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Vapor pressure : Not available.
Vapor density : Not available.
Density : 0.828 g/cm³ [15°C (59°F)]
Solubility :
Media Result
water Not soluble
Partition coefficient: n- : Not applicable.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.

VOC content
Product : 3.48 lbs/gal EPA Method 24
Particle characteristics
Median particle size : Not applicable.

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Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.

Incompatible materials : oxidizing materials

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity : Based on available data, the classification criteria are not met.
Acute toxicity estimates
Not available.
Numerical measures of toxicity
Product/ingredient name Result Species Dose Exposure
Distillates (petroleum), LC50 Inhalation Dusts and mists Rat 2180 mg/m³ 4 hours
hydrotreated light naphthenic
LD50 Oral Rat >5000 mg/kg -
calcium bis LD50 Dermal Rabbit >20 g/kg -
(dinonylnaphthalenesulphonate)
LD50 Oral Rat >4000 mg/kg -

Irritation/Corrosion : Causes severe eye irritation. Causes skin irritation.

Product/ingredient name Result Species Score Exposure Observation
Distillates (petroleum), Skin - Moderate irritant Rabbit - 24 hours 0.5 -
hydrotreated light naphthenic Ml
Skin - Severe irritant Rabbit - 500 mg -
calcium bis Skin - Moderate irritant Rabbit - 0.5 Ml -
(dinonylnaphthalenesulphonate)
Sensitization : Based on available data, the classification criteria are not met.
Mutagenicity : Based on available data, the classification criteria are not met.
Carcinogenicity : Based on available data, the classification criteria are not met.
Reproductive toxicity : Based on available data, the classification criteria are not met.
Specific target organ toxicity (single exposure) : Based on available data, the classification criteria are not met.
Specific target organ toxicity (repeated : May cause damage to organs through prolonged or repeated
exposure) exposure.

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Section 11. Toxicological information

Name Category Route of Target organs
exposure
hexadecylamine Category 2 - gastrointestinal
tract, immune
system, liver
Aspiration hazard : Based on available data, the classification criteria are not met.
Name Result
Distillates (petroleum), hydrotreated light ASPIRATION HAZARD - Category 1
Distillates (petroleum), hydrotreated light naphthenic ASPIRATION HAZARD - Category 1
hexadecylamine ASPIRATION HAZARD - Category 1
Other information : None identified.

Information on the likely routes of exposure

Inhalation : No known significant effects or critical hazards.
Skin contact : Causes skin irritation.
Eye contact : Causes serious eye irritation.
Ingestion : No known significant effects or critical hazards.

Delayed and immediate effects and also chronic effects from short and long term exposure
May cause damage to organs through prolonged or repeated exposure.

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation : Not expected under normal use.
Skin contact : pain or irritation,redness
Eye contact : pain or irritation,redness,watering
Ingestion : Not expected under normal use.

Section 12. Ecological information

This material is harmful to aquatic life with long lasting effects.
Toxicity
Product/ingredient name Result Species Exposure
Distillates (petroleum), Acute EC50 1000 mg/l Algae - Pseudokirchneriella 72 hours
hydrotreated light subcapitata
Acute EC50 1000 mg/l Daphnia - Daphnia magna 48 hours
Acute LC50 2200 µg/l Fresh water Fish - Lepomis macrochirus 4 days
hexadecylamine Acute EC50 0.0036 mg/l Fresh water Daphnia - Daphnia magna 48 hours

Persistence and degradability

Bioaccumulative potential
Not available.

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

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Section 12. Ecological information

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : Disposal of this product, solutions and any by-products should at all times comply with
the requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Empty containers or liners may retain some
product residues. Empty containers retain product residue and can be hazardous.
Care should be taken when handling emptied containers that have not been cleaned or
rinsed out.

Section 14. Transport information

DOT Classification IMDG IATA
UN number NA1993 Not regulated. Not regulated.

UN proper Combustible liquid, n.o.s. - -

shipping name (Distillates (petroleum),
hydrotreated light naphthenic)
Transport Combustible liquid. - -
hazard class(es)

Packing group III - -

Environmental No. No. No.
hazards
Additional information
DOT Classification : Non-bulk packages (less than or equal to 119 gal) of combustible liquids are not
regulated as hazardous materials.
Limited quantity Yes.
Packaging instruction Exceptions: 150. Non-bulk: 203. Bulk: 241.
Quantity limitation Passenger aircraft/rail: 60 L. Cargo aircraft: 220 L.
Special provisions 148, IB3, T1, TP1

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.

Transport in bulk according : Not available.

to IMO instruments

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Section 15. Regulatory information

U.S. Federal regulations
Clean Water Act (CWA) 311
None of the components are listed.
Clean Water Act (CWA) 307
None of the components are listed.
Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs)
None of the components are listed.

CERCLA: Hazardous substances.

To the best of our knowledge, this product does not contain chemicals at levels which require reporting under this
regulation, Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the
Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements
at the local, regional, or state level pertaining to releases of this material.
SARA 302/304
None of the components are listed.
SARA 311/312
Classification : See GHS Classification in section 2 for hazard class information
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not
contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal
Regulations, Part 372.

State regulations
Massachusetts : The following components are listed: MINERAL OIL, PETROLEUM DISTILLATES,
HYDROTREATED LIGHT NAPHTHENIC
New York : None of the components are listed.
New Jersey : None of the components are listed.
Pennsylvania : None of the components are listed.
California
California Prop. 65
This product does not contain any Proposition 65 chemicals.
SCAQMD Rule 1144
This product has not been tested for VOC content by the ASTM E-1868-10 (2021) method and is not approved for sale
or distribution in the SCAQM District of California if the product is used as a metal forming, metal removal, metal
treating, metal protection fluid

International regulations
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.

Rotterdam Convention on Prior Informed Consent (PIC)

Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.

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Section 15. Regulatory information

Inventory list
United States : All components are active or exempted.
Canada : All components are listed or exempted.

Section 16. Other information

Date of issue/Date of : 7/6/2023
revision
Version : 8
Quaker Houghton Product Stewardship
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
VOC = Volatile Organic Compound
References : Safety data sheets of raw materials, global regulatory body information, scientific
literature, and testing data .
Indicates information that has changed from previously issued version.
Notice to reader
This product's safety information is provided to assist our customers in assessing compliance with safety/health/
environmental regulations. The information contained herein is based on data available to us and is correct to the best of
our knowledge, information and belief at the date of its publication. However, no warranty of merchantability, fitness for
any use, or any other warranty is expressed or implied regarding the accuracy of this data, the results to be obtained from
the use thereof, or the hazards connected with the use of the product. Since the use of this product is within the exclusive
control of the user, it is the user's obligation to determine the conditions for safe use of the product. Such conditions
should comply with all regulations concerning the product. The company referenced in this Safety Data Sheet assumes
no liability for any injury or damage, direct or consequential, resulting from the use of this product unless such injury or
damage is attributable to the gross negligence of such company.

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