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MCQ Test : MCQ 1B(B)
1. Some Basic Concepts of Chemistry 2. Structure of Atom
1. 3 g of an oxide of a metal is converted a) 250 ml b) 500 ml c)750 ml d)1000 ml
into chloride completely and it yielded 5
8. In a photoelectric experiment,
g of metal chloride. The equivalent weight
doubling the intensity of the incident
of the metal is:
light results in emitting electrons:
a) 12 b) 20 c) 33.25 d) 2.325
a) in a larger number
2. The quantum numbers of four b) in a lesser number
electrons are given below. c) associated with higher frequency
I. 𝑛 = 4, 𝑙 = 2, 𝑚 = −2, 𝑠 = −1/2 d) associated with lower frequency
II. 𝑛 = 3, 𝑙 = 2, 𝑚 = 1, 𝑠 = +1/2
III. 𝑛 = 4, 𝑙 = 1, 𝑚 = 0, 𝑠 = +1/2 9. When 1L of 0.1 M sulphuric acid
IV. 𝑛 = 3, 𝑙 = 1, 𝑚 = −1, 𝑠 = +1/2 solution is allowed to react with 1L of
0.1M sodium hydroxide solution, the
The correct arrangement in the order of
molarity of sodium sulphate formed in
their increasing energies is:
the solution is:
a) III < I < II < IV b) IV < II < III < I
a) 0.1 M b) 0.025 M c) 0.05 M d) 0.2 M
c) I < III < IV < II d) II < IV < I < III
10. What is the maximum number of
3. Number of molecules of 𝐻2 𝑆𝑂4 present
emission lines obtained when the excited
in 100 ml of 0.02 M 𝐻2 𝑆𝑂4 solution is:
electron of a hydrogen atom in 𝑛 = 5
a) 12.044 × 1020 molecules
drops t ground state?
b) 6.022 × 1023 molecules
a) 10 b) 5 c) 12 d) 15
c) 1.0 × 1023 molecules
d) 12.044 × 1023 molecules 11. A 250 W electric bulb of 80%
efficiency emits a light of 6626 Ǻ
4. Which of the following sets of
wavelength. The number of photons
quantum numbers represents the 19th
emitted per second by the lamp is:
electron of Cr (Z = 24)?
a) 4, 1, −1, +1/2 b) 4, 0, 0, +1/2 a) 4.25 × 1016 b) 2.18 × 1016
c) 3, 2, 0, −1/2 d) 3, 2, −2, +1/2 c) 6.66 × 1020 d) 1.42 × 1017
12. Among the elements from atomic
5. The volume of ethyl alcohol (density = number 1 to 36, the number of elements
1.15 g/cc) that has to be added to which have an unpaired electron in their
prepare 100 cc of 0.5 M ethyl alcohol s-subshell is:
solution in water is: a) 4 b) 7 c) 6 d) 9
a) 1.15 cc b) 2 cc c) 2.15 cc d) 2.30 cc
13. If the de Broglie wavelength of a
particle of mass 𝑚 is 100 times its
6. If the shortest wavelength in Lyman velocity, then its value in terms of its
series of hydrogen atom is A, then the mass (𝑚) and Planck’s constant (ℎ)is:
longest wavelength in Paschen series of 1 𝑚 ℎ 1 ℎ 𝑚
5𝐴 36𝐴 36𝐴 9𝐴 a) √ℎ b) 10√𝑚 c) √ d) 10√ ℎ
𝐻𝑒 is: a)
+
b) c) d) 10 10 𝑚
9 5 7 5

7. You are supplied with 500ml each of 14. In a compound C, H and N are
2N HCl and 5N HCl. What is the present in 9 : 1 : 3.5 by weight. If
maximum volume of 3M HCl that you molecular weight of the compound is
can prepare using only these two 108, then the molecular formula of the
solutions? compound is:

MCQ 1B(B) (Some Basic Concepts & Atomic Structure) Snehangshu Dey Page 1
a) 𝐶2 𝐻6 𝑁2 b) 𝐶3 𝐻4 𝑁 c) 𝐶6 𝐻8 𝑁2 d) 𝐶9 𝐻12 𝑁3 a) 68.5 𝑛𝑚 b)137 𝑛𝑚 c) 274 𝑛𝑚 d)548 𝑛𝑚
15. Assertion (A): Combustion of 16 g of
22. For a reaction A + 2B → C, the
methane gives 18 g of water.
amount of C formed by starting the
Reason (R): In the combustion of
reaction with 5 moles of A and 8 moles of
methane, water is one of the products.
B is: a) 5 moles b) 8 moles
a) Both (A) and (R) are true but (R) is not c) 16 moles d) 4 moles
the correct explanation of (A).
b) (A) is true but (R) is false.
23. Assume that you are travelling at a
c) (A) is false but (R) is true.
speed of 90 km/hr in a small car with a
d) Both (A) and (R) are false. mass of 1050 kg. If the uncertainty in
16. Excess of aqueous NaOH was added velocity of the car is 1%, what is the
to 100 ml of aqueous 𝐹𝑒𝐶𝑙3 resulting into uncertainty (in meters) in the position of
2.14 g of 𝐹𝑒(𝑂𝐻)3 . The molarity of the car?
aqueous 𝐹𝑒𝐶𝑙3 solution is: a) ∆𝑥 ≥ 1 × 10−35 𝑚 b) ∆𝑥 ≥ 2 × 10−37 𝑚
a) 0.2 M b) 1.8 M c) 0.3 M d) 0.6 M c) ∆𝑥 ≥ 1 × 10−36 𝑚 d) ∆𝑥 ≥ 4 × 10−38 𝑚

17. Which of the following sets of 24. Magnetic quantum number specifies:
quantum numbers of an electron is a) size of orbitals b) shape of orbitals
correct? c) nuclear stability
a) 𝑛 = 4, 𝑙 = 2, 𝑚 = +2, 𝑠 = 0 d) orientation of orbitals
b) 𝑛 = 6, 𝑙 = 0, 𝑚 = +1, 𝑠 = −1/2
c) 𝑛 = 3, 𝑙 = 3, 𝑚 = +3, 𝑠 = +1/2 25. The wave number of the spectral line
d) 𝑛 = 5, 𝑙 = 4, 𝑚 = 0, 𝑠 = +1/2 in the emission spectrum of hydrogen
will be equal to 8/9 times the Rydberg’s
18. The threshold frequency of a metal constant if the electron jumps from:
corresponds to the wavelength of 𝑥 nm. a) 𝑛 = 3 to 𝑛 = 1 b) 𝑛 = 10 to 𝑛 = 1
In two separate experiments ‘A’ and ‘B’, c) 𝑛 = 9 to 𝑛 = 1 d) 𝑛 = 2 to 𝑛 = 1
incident radiations of wavelengths 𝑥/2
nm and 𝑥/4 nm, respectively are used. 26. 0.3 g of an organic compound
The ratio of kinetic energies of the containing C, H and O on combustion
released electrons in experiment ‘B’ to yields 0.44 g 𝐶𝑂2 and 0.18 g 𝐻2 𝑂. If one
that in experiment ‘A’ is: mole of compound weighs 60 g, then
a) 1/2 b) 2 c) 4 d) 3 molecular formula of the compound is:
a) 𝐶3 𝐻8 𝑂 b) 𝐶2 𝐻4 𝑂2 c) 𝐶𝐻2 𝑂 d) 𝐶4 𝐻6 𝑂
19. In the atomic spectrum of hydrogen,
the emission of the least energetic 27. Maximum how many electrons can
photon takes place during the transition be accommodated in the orbitals with
from 𝑛 = 6 level to 𝑛 = ⋯ energy level. 𝑛 + 𝑙 = 6 ? a) 8 b) 10 c) 18 d) 32
a) 2 b) 3 c) 4 d) 5
28. In a flask, the weight ratio of 𝐶𝐻4 (g)
20. Which of the following ions has the and 𝑆𝑂2 (g) at 298 K and 1 bar is1 : 2.
highest magnetic moment? The ratio of the number of molecules of
a) 𝐹𝑒 2+ b) 𝑀𝑛2+ c) 𝐶𝑢2+ d) 𝑁𝑖 2+ 𝐶𝐻4 (g) and 𝑆𝑂2 (g) is:
a) 4 : 1 b) 1 : 4 c) 2 : 1 d) 1 : 2
21. The energy required to break one
mole of 𝐻 − 𝐻 bonds in 𝐻2 is 436 kJ.
What is the longest wavelength of light
required to break a single 𝐻 − 𝐻 bond?

MCQ 1B(B) (Some Basic Concepts & Atomic Structure) Snehangshu Dey Page 2
29. The electron in the hydrogen atom
undergoes transition from higher orbits
to the orbit of radius 211.6 pm. This
transition is associated with :
a) Paschen series b) Brackett series
c) Lyman series d) Balmer series

30. Assertion(A): It is impossible to

determine the exact position and exact
momentum of an electron
simultaneously.
Reason(R): The path of an electron in an
atom is clearly defined.
a) Both (A) and (R) are true and (R) is the
correct explanation of (A).
b) Both (A) and (R) are true and (R) is not
the correct explanation of (A).
c) (A) is true but (R) is false.
d) Both (A) and (R) are false.
________________

MCQ 1B(B) (Some Basic Concepts & Atomic Structure) Snehangshu Dey Page 3
MCQ 1B(B) (Some Basic Concepts & Atomic Structure) Snehangshu Dey Page 4
Answer 1B(B): 1.c) 2.b) 3.a) 4.b) 5.b) 6.c) 7.c) 8.a) 9.b) 10.a) 11.c) 12.c)
13.b)14.c) 15.c) 16.a) 17.d) 18.d) 19.d) 20.b) 21.c) 22.d) 23.b) 24.d) 25.a)
26.b) 27.c) 28.c) 29.d) 30.c)
Source: 4. WBJEE 2017
6. JEE Main 2017
11. Kerala PET 2014
13. Karnataka CET 2014
19. Kerala PET 2016
21. WBJEE 2016
23. AIIMS 2010
25. Karnataka CET 2010
28. WBJEE 2017
29. NCERT Exemplar
30. AIEEE 2007

MCQ 1B(B) (Some Basic Concepts & Atomic Structure) Snehangshu Dey Page 5